Abstract: Disclosed herein are cobalt complexes containing terdentate pyridine di-imine ligands and their use as efficient and selective dehydrogenative silylation and crosslinking catalysts.

Abstract: The present invention provides for a personal care composition suitable for treating hair comprising a composition comprising the reaction product of a) an oxirane or oxetane compound comprising at least two oxirane or oxetane groups; and b) an amino silane having the formula: N(H)(R1)R2Si(OR3)3-a-b-c(OR4)a(R5Si(OR6)d(R7)c)bR8c with R1 is chosen from the group consisting of H or a monovalent hydrocarbon radical containing one to 20 carbon atoms; R2 is selected from a group consisting of a divalent linear or branched hydrocarbon radical consisting of 1-60 carbons; R4 is a hydrocarbon radical that contains 3 to 200 carbon atoms; R5 is selected from a group consisting of oxygen or a divalent linear or branched hydrocarbon radical consisting of 1-60 carbons; R3, R6, R7, and R8 and are each independently selected from the group of monovalent linear or branched hydrocarbon radicals having from 1 to 200 carbon atoms; the subscript b is zero or a positive number and has a value ranging from 0 to 3; the subscripts a i

Abstract: A method of forming and filling a pouch, comprises forming opposing walls of a film; sealing the opposing walls of film together to form at least one pouch; filling an interior section of the at least one pouch through an opening in an upper portion of the at least one pouch with a flowable material; forming a top sealed expressing-shaped region to close the opening in the at least one pouch; and cradling the pouch with a foldable flat that is more rigid than the pouch that can be folded or rolled to compress the pouch to express the flowable material through the expressing shaped region.

Abstract: A silicone adhesive composition including an ionic silicone and useful for healthcare applications such as wound care and drug delivery.

Abstract: A solid, water-soluble fast-dissolving antidrift composition includes a urea-based complex-forming component (i) complexed with an antidrift component (ii), the antidrift composition optionally further including an adjuvant component (iii).

Abstract: Disclosed herein is a catalytic process for the synthesis of organohalosilane monomers from tetraorganodihalodisilanes and other compounds that are not cleaved during the conventional hydrochlorination of Direct Process Residue. The process is characterized by the use of a catalyst containing (1) one or more heterocyclic amines and/or one or more heterocyclic ammonium halides, and (2) one or more quaternary Group 15 onium compounds.

Abstract: Disclosed herein are manganese, iron, cobalt, or nickel complexes containing 2,8-bis(imino)quinoline ligands and their use as catalysts or catalysts precursors for hydrosilylation reactions.

Abstract: Disclosed herein are novel copolycarbonates containing repeating units A and B respectively of the formulae: (A) —[R1OC(?O)O]—, and (B) —[(R2O)n-C(?O)—O]—, wherein the molar ratio of units (A) to units (B) is in the range of from about 9:1 to about 1:9, and wherein R1 is a divalent C8 to C12 alicyclic group, and R2 is ethylene or propylene, and n is an integer ranging from 4 to 40. Also disclosed are silicone hardcoat compositions containing the copolycarbonates and their derivatives. Upon cure, these silicone hardcoat compositions exhibit improved flexibility as compared to that of the conventional hardcoats while at the same time maintain the abrasion resistance of conventional silicone hardcoats.

Abstract: In one aspect, a self-lubricating component is provided for a pharmaceutical packaging assembly. The self-lubricating component comprises a polymer composition and an effective amount of a lubricating additive such as, for example, boron nitride. In another aspect, a pharmaceutical packaging assembly may be provided having a surface thereof coated with a lubricating composition comprising boron nitride. The pharmaceutical packaging composition may be, for example, a pre-filled syringe comprising a body (barrel) and a plunger assembly.

Abstract: Diol derived blocked mercaptofunctional silane compositions in which the silanes comprise cyclic and bridged alkoxy groups derived from hydrocarbon-based diols and processes for their preparation are provided. Also provided are rubber compositions comprising the cyclic diol-derived blocked mercaptofunctional silanes, processes for their preparation and articles of manufacture comprising the rubber compositions, in particular, automotive tires and components thereof.

Abstract: The invention relates to an insulated glass unit having an increased service life. An outer glass pane and inner glass pane are sealed to a spacer to provide an improved gas impermeable space. The glass unit includes a curable two-part sealer composition which, upon curing, exhibits unexpectedly high adhesion to substrates.

Abstract: A curable composition useful for treating textiles to impart thereto upon the curing of one or more textile use-enhancing characteristics includes a first macromonomer (i) which is a polysiloxane possessing two or more terminal functional groups selected from the group consisting of hydroxyl, alkoxy and combinations thereof, a second macromonomer (ii) which is a polysiloxane containing two or more hydrosilyl (?C—SiH) groups, catalyst (iii) and, optionally, one more additional component(s) (iv) such as surfactant(s), water, etc.

Abstract: A method for manufacturing a composite article of polytetrafluoroethylene and silicone includes: (a) providing a UV-curable silicone: (b) applying the UV-curable silicone to a polytetrafluoroethylene backing; and (c) exposing the UV-curable silicone to UV radiation sufficient to cure the silicone.

Abstract: There is provided herein a composition comprising a silicone copolymer of the general formula (I) MaMEcDdDEeTfTEgQh where M=R1R2R3SiO1/2; ME=R4R5RESiO1/2; D=R6R7SiO2/2; DE=R8RESiO2/2; T=R9RESiO2/2; T=R9SiO3/2; TE=RESiO2/2; and Q=SiO4/2; where R1, R2, R3, R4, R5, R6, R7, R8, and R9 are each independently selected from the group of monovalent hydrocarbon radicals RE is a monovalent radical defined as: —R10O—(C2H4O)h(C3H6O)i(C4H8O)i—R11 or —R12 with the provision that the copolymer must contain at least one RE group; R10 is a linear or branched divalent hydrocarbon radical containing from 3 to about 10 carbon atoms; R11 is H or —C(?O)CH3 or a monovalent saturated or unsaturated hydrocarbon radical, optionally containing heteroatoms and hydroxyl groups, containing from 1 to about 30 carbon atoms; R12 is a hydrocarbon radical, containing from 2 to about 30 carbon atoms and at least 1 hydroxyl group, optionally containing heteroatoms; subscripts a, b, c, d, e, f, and g are 0 or positive subject to the limitation a+

Abstract: The invention relates to a high thermal efficiency, insulated glass unit structure sealed with a cured composition containing, inter alia, moisture-curable linear silylated resin and organic nanoclay, the cured composition exhibiting low permeability to gas(es).

Abstract: An apparatus for forming and filling a flexible package, comprises: a film unwind station for unwinding a web of flexible film from a roll of film includes: a folding station for folding the web into a pair of opposing walls; a strip unwind station for unwinding a strip of semi-rigid material from a roll of material and positioning the strip between the pair of opposing walls of the web; a metal buffer plate insertable between the strip and one of the opposing walls of the web; sealing stations, separating stations and filling stations.

Abstract: There is provided a hydroxyl-functional carbamoyl organosilicon compound, an anti-corrosion and/or adhesion promoting coating composition based thereon, a method for coating a metal surface employing the coating composition and the resulting coated metal article.

Abstract: The present invention is directed to a method of making metal oxide and mixed metal oxide particles. The method includes treating a mixture formed from a metal source, such as metal alkoxide, a surfactant, and a first alcohol in an aqueous media at a very high metal oxide yield. The mixture is reacted using a catalyst to form metal oxide particles having a desired particle size in said mixture. The method is particularly suitable for forming silica particles. The metal oxide particles can then be heat treated to form synthetic fused metal oxides such as, for example, synthetic fused silica.

Abstract: The present invention provides for a composition comprising a silane having the formula: (R1)(R2)(R3)Si—R4—Si(R5)(R6)(R7) wherein R1, R2, R3, R5, and R6 are each independently selected from the group consisting of 1 to 6 monovalent hydrocarbon radicals, aryl, and a hydrocarbon group of 7 to 10 carbons containing an aryl group; R4 is a hydrocarbon group of 1 to 3 carbons; R7 comprises an anionic, cationic or zwitterionic substituent. The silanes of the present invention exhibit resistance to hydrolysis over a wide pH range.

Abstract: A cleaning composition for cleaning microelectronic or nanoelectronic devices, the cleaning composition having HF as the sole acid and sole fluoride compound in the composition, at least one primary solvent selected from the group consisting of sulfones and selenones, at least one polyhydroxyl alkyl or aryl alcohol co-solvent having metal ion complexing or binding sites, and water, and optionally at least one phosphonic acid corrosion inhibitor compound and the is free of amines, bases and other salts.