Patents Assigned to Phillips Petroleum
  • Patent number: 5109042
    Abstract: An additive for reducing water loss from cement comprising a tetrapolymer, base, an electrolyte, at least one surfactant, and water is disclosed. A process for producing cement slurries with improved water loss properties, as well as an improved method for cementing gas and oil wells is also disclosed.
    Type: Grant
    Filed: December 22, 1989
    Date of Patent: April 28, 1992
    Assignee: Phillips Petroleum Company
    Inventor: Michael Stephens
  • Patent number: 5108975
    Abstract: Described is a method for preparing a catalyst support material, comprising commercially available silica, by utilizing a fluorine-containing acid. The novel method is utilized to produce a novel composition that has unique physical properties different from those of typical commercially available silica materials. The novel support material has significantly improved values for crush strength and as good or better pore volume than comparable catalyst support materials. Due to these improved physical properties, the novel composition is more durable and longer lived. Furthermore, the greater pore volume of the novel composition provides for enhanced catalytic activity when the formed silica material is utilized as a catalyst support.
    Type: Grant
    Filed: January 28, 1991
    Date of Patent: April 28, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Paul F. Schubert, Donald H. Kubicek
  • Patent number: 5109102
    Abstract: This invention relates to making an arylene sulfide ketone polymer. In accordance with this invention, a diahloaromatic ketone, a polar organic compound, and an alkali metal sulfide are mixed together to form a first reaction mixture. This first reaction mixture is subjected to a first set of polymerization conditions effective to produce a polymerization mixture. This polymerization mixture is then dehydrated to form a dehydrated polymerization mixture. Additional dihaloaromatic ketone and polar organic compound is then mixed with the dehydrated polymerization mixture to form a second reaction mixture. This second reaction mixture is then subjected to a second set of polymerization conditions such that an arylene sulfide ketone polymer is formed.
    Type: Grant
    Filed: October 31, 1990
    Date of Patent: April 28, 1992
    Assignee: Phillips Petroleum Company
    Inventor: Jon F. Geibel
  • Patent number: 5109180
    Abstract: A shatter-resistant electric lamp includes a base; contacts for connecting the lamp to a source of electrical energy; a filament or light source electrically connected to the contacts for converting electrical energy to light; a shatterable encasement, connectable to the base, for translucently encasing the filament; and a polymer coating deposited on a first portion of the encasement so that a second portion of the encasement remains uncoated. The preferred polymer coating is poly(phenylene sulfide).
    Type: Grant
    Filed: September 5, 1991
    Date of Patent: April 28, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Harold D. Boultinghouse, Kenneth P. Taylor
  • Patent number: 5109085
    Abstract: A process for polymerizing olefins is disclosed which makes use of a catalyst comprising a cyclopentadienyl lanthanide halide alkali metal ether complex in combination with a cocatalyst comprising an alkali or alkaline earth metal alkyl. Preferred embodiments include the use of hydrogen during the polymerization or the use of an organoaluminum hydride as an additional cocatalyst.
    Type: Grant
    Filed: August 27, 1990
    Date of Patent: April 28, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Ted M. Pettijohn, Henry L. Hsieh
  • Patent number: 5108729
    Abstract: A method and apparatus are provided for producing a product comprising a carbide compound, such as for example silicon carbide. A reactor is provided which has a chamber defined therein which is divided into a combustion zone and a reaction zone. A combustible mixture is injected into the combustion zone and accordingly combusted to form hot combustion products. At least one reactant (i.e. silane) is injected at the boundary between the zones so as to be carried into the reaction zone by the combustion products and react to form raw product comprising the carbide compound. The raw product can be purified by subsequent processing to remove oxygen and convert by-products to the desired carbide compound. The product of the invention has a low level of impurities and is made up of submicron, highly uniform particles. This makes the product particularly useful for fabrication of sintered ceramic parts.
    Type: Grant
    Filed: October 2, 1989
    Date of Patent: April 28, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Bruce W. Gerhold, George F. Schuette, Kenneth E. Inkrott
  • Patent number: 5106929
    Abstract: The present invention provides crosslinked ampholytic ion pair (2-methacryloyloxyethyldiethylammonium cation (MEDEA)/sulfonate anion) copolymers that are highly absorbent to aqueous electrolyte solutions.
    Type: Grant
    Filed: October 1, 1990
    Date of Patent: April 21, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Iqbal Ahmed, Henry Hsieh
  • Patent number: 5106569
    Abstract: A molding apparatus and method are adapted to mold an article having a hollow blow molded portion and a substantially solid compression molded portion. Defined within a mold is at least a first cavity portion and a second cavity portion. A parison is positioned within the mold and blow gas is injected into the interior of the parison to inflate the parison within each of the cavity portions. A compression member is then moved from a retracted position within a recess in the mold to an extended position outside of such recess. The compression member presses a first portion of the parison against the mold interior surface which defines the first cavity portion so as to compression mold a first portion of the parison. Inflation of a second portion of the parison in the second cavity portion accomplishes blow molding of such second parison portion.
    Type: Grant
    Filed: March 25, 1991
    Date of Patent: April 21, 1992
    Assignee: Phillips Petroleum Company
    Inventors: John R. Rathman, Donald L. Peters, Jimmie L. Dean
  • Patent number: 5105050
    Abstract: Catalyst supports, catalyst systems, methods for the preparation thereof, in dimerization processes therewith are provided. Catalyst supports are prepared from alkali metal bicarbonate, a liquid, and optionally alkali metal carbonate. Optionally, the catalyst support further comprises a carbonaceous compound. Catalyst systems comprise at least one elemental alkali metal deposited on the catalyst support. Optionally, the catalyst system further comprises at least one promoter.
    Type: Grant
    Filed: July 25, 1991
    Date of Patent: April 14, 1992
    Assignee: Phillips Petroleum Company
    Inventor: Charles A. Drake
  • Patent number: 5104841
    Abstract: Olefin polymerization catalysts, processes for preparing the catalysts and processes for producing polyolefins utilizing the catalysts are provided. The catalysts are basically comprised of a trialkylsilylamide-chromium complex adsorbed on an activated inorganic refractory compound.
    Type: Grant
    Filed: April 22, 1991
    Date of Patent: April 14, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Brian K. Conroy, Paul D. Smith
  • Patent number: 5104950
    Abstract: A lanthanide based olefin polymerization catalyst and its use in polymerization are disclosed. The lanthanide based catalyst is prepared by contacting a lanthanide halide with an ether, then contacting the resulting lanthanide composition with an alkali or alkaline earth metal alkyl compound, and depositing the resulting lanthanide product on a particulate support.
    Type: Grant
    Filed: December 17, 1990
    Date of Patent: April 14, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Shirley J. Martin, Max P. McDaniel, Conroy, Brian K., Joel L. Martin
  • Patent number: 5104570
    Abstract: Olefin complexing reagents comprising Cu(I) carboxylate/BF.sub.3 adducts in aromatic solvents and a method of preparation therefor, and use of said reagents in the separation of olefins from paraffins are provided.
    Type: Grant
    Filed: December 26, 1989
    Date of Patent: April 14, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Ted H. Cymbaluk, Donald C. Tabler, Marvin M. Johnson, Gerhard P. Nowack
  • Patent number: 5104839
    Abstract: Olefinic polymer exhibiting high environmental stress crack resistance are produced by contacting the olefin charge stock in a single reactor with a compatible mix of two transition metal catalyst systems. One component of the catalyst system comprises chromium oxide supported on an aluminophosphate material. Hydrogen can be used as adjuvant for the hexavalent chromium component of the catalyst mixture. The second catalyst component consists essentially of a beta-stabilized tetrahydrocarbyl zirconium compound supported on inorganic support material. The catalysts can be premixed before use in the reactor, or can be added to the reactor separately. A suitable cocatalyst can be utilized.
    Type: Grant
    Filed: July 12, 1991
    Date of Patent: April 14, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Max P. McDaniel, Paul D. Smith
  • Patent number: 5105049
    Abstract: Olefin dimerization process comprises catalyst systems and supports. Catalyst supports are prepared from extruding alkali metal carbonate and a liquid. Optionally, the extruded catalyst support further comprises a carbonaceous compound. Catalyst systems comprise at least one elemental alkali metal deposited on the extruded catalyst support. Optionally, the catalyst system further comprises of at least one promotor. A hydrided catalyst system is prepared by contacting the catalyst system with hydrogen to reduce the dimerization induction period.
    Type: Grant
    Filed: August 8, 1991
    Date of Patent: April 14, 1992
    Assignee: Phillips Petroleum Company
    Inventor: Lori G. Hasselbring
  • Patent number: 5104837
    Abstract: A catalyst useful for polymerizing olefins is prepared by contacting a highly porous magnesium-containing aluminum oxide support with an alcohol, then contacting the resulting solid with a mixture of titanium tetrachloride and dialkyl phthalate, and then contacting the resulting solid with additional titanium tetrachloride.
    Type: Grant
    Filed: March 16, 1990
    Date of Patent: April 14, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Gil R. Hawley, Max P. McDaniel
  • Patent number: 5105048
    Abstract: This invention concerns catalyst systems for olefin dimerization wherein said catalyst system comprises at least one elemental alkali metal catalyst, supported on an alkali metal carbonate support, wherein said support includes an inorganic nitrate. This invention further concerns processes for the dimerization of olefins. The catalytic support can optionally comprise a carbonaceous compound(s), an inorganic oxide(s), or a mixture thereof. Furthermore, the catalyst system optionally can comprise at least one promoter selected from the group consisting of elemental copper, elemental cobalt, finely divided stainless steel, finely divided glass, or mixtures thereof.
    Type: Grant
    Filed: April 19, 1990
    Date of Patent: April 14, 1992
    Assignee: Phillips Petroleum Company
    Inventor: Charles A. Brake
  • Patent number: 5105045
    Abstract: A method for the oxidative conversion of feed organic compounds, such as methane and ethane, to product organic compounds, such as ethylene, in the presence of a free oxygen containing gas and a contact material comprising: (1) Group IA and/or Group IIA metals/O.sub.2 /halogen; (2) Group IA metals/La Series metals/O.sub.2 /halogen and, optionally, Group IIA metals; (3) Group IA metals/Zn/O.sub.2 /halogen and, optionally, Group IIA metals; (4) Group IA metals/Ti or Zr/O.sub.2 /halogen and, optionally, Group IIA metals; (5) Group IA and/or IIA metals/phosphate/halogen or (6) Co/Zr, Zn, Nb, In, Pb and/or Bi/P/O.sub.2 halogen, and, optionally, Group IA metals and/or S, in which a contact material containing no halogen or an ineffective amount are activated and/or regenerated by contacting them with a halogen and, when the contact material is contact material (6), with a reducing agent or both a reducing agent and a halogen.
    Type: Grant
    Filed: October 15, 1990
    Date of Patent: April 14, 1992
    Assignee: Phillips Petroleum Company
    Inventors: James B. Kimble, John H. Kolts
  • Patent number: 5105024
    Abstract: Isobutane and propane are separately charged to different catalytic dehydrogenation zones. The reaction products, including principally propylene and isobutylene, are combined, followed by separation of steam condensate, carbon dioxide and fuel gas from the mixture of effluents from the two separate dehydrogenation reaction zones. Propane and propylene are then separated from the isobutylene. The propylene product is recovered, and isobutylene is charged to an etherification reactor and there reacted with methanol to yield methyltertiarybutyl ether (MTBE). The etherification reactor effluent is fractionated to separate MTBE from n-butane and from isobutane. The latter is separated from n-butane and recycled to the isobutane dehydrogenation zone. Unreacted propane is also recovered and recycled.
    Type: Grant
    Filed: April 20, 1990
    Date of Patent: April 14, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Dwight L. McKay, Michael L. Gray
  • Patent number: 5102854
    Abstract: A novel sorbent comprising zinc oxide and a Group IIA metal silicate. A process for the removal of hydrogen sulfide from a fluid stream that comprises contacting a fluid stream with the novel sorbent. A further feature of this invention includes a novel method for preparing a composition comprising zinc oxide and a Group IIA metal silicate.
    Type: Grant
    Filed: March 8, 1991
    Date of Patent: April 7, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Gary A. Delzer, Dennis R. Kidd
  • Patent number: 5102611
    Abstract: A process for forming plastic tubing which involves extruding a molten plastic composition through a die which produces an extended length of plastic tubing, passing the hot tubing through a vacuum sizing tube wherein the wall of the tubing is sized by being drawn to the wall of the sizing tube by a vacuum, and cooling the sized tubing so that the tubing will be self-supporting at normal ambient temperatures, wherein the plastic composition contains a phosphorus-containing additive in an amount sufficient to cause an improvement in the smoothness of the interior of said tubing.
    Type: Grant
    Filed: May 18, 1990
    Date of Patent: April 7, 1992
    Assignee: Phillips Petroleum Company
    Inventors: Al R. Wolfe, David R. Battiste, Harry E. Straw