Abstract: Bromobutyl rubber compounds of improved green strength are prepared by reacting bromobutyl rubber with selected amine compounds such that not less than about 1/100th and not more than 1/12th of the bromine in the bromobutyl is reacted with the amine compound.

Abstract: A process is provided for the polymerization of butadiene-1,3 to yield a high cis-1,4-polybutadiene in which the diluent for the polymerization is a mixture of cyclohexane and either or both of benzene and butene-1, wherein the amount of benzene is markedly reduced in comparison with that generally used. The polybutadiene may be used in the manufacture of tires and in impact polystyrene.

Abstract: The polymerization of butadiene and styrene in an emulsion, free-radical polymerization process using a persulphate initiator is effectively short-stopped by the addition of ascorbic acid or the sodium or potassium salts thereof. The butadiene-styrene polymer so produced may be used in those end uses generally associated with the prior known use of such polymers.

Abstract: Two preformed materials such as paper, fabrics, glass, sheet metal, at least one of which is pervious to water vapor, are joined together with a solvent-free adhesive based on a latex of a rubbery polymer. The latex is one which is stabilized with an emulsifier which forms water-insoluble compounds with zinc or cadmium ions. Included in the adhesive formulation is an ammonium or amine salt gelling agent for the latex, a zinc or cadmium ion donor compound and sufficient ammonia or a compound which releases ammonia to provide a pH of above 8 to the adhesive formulation. A surface of at least one of the preformed materials is coated with the adhesive and then contacted with a surface of the other material and held in such contact while heating to gel the latex and evaporate the water from the intersurface layer of adhesive.

Abstract: An improved method is provided for processing of rubbers in which one of the rubbers is a synthetic green strength polymer, the improvement being the addition of the synthetic green strength polymer at the second stage of mixing rather than at the prior art first stage. The method can be used for preparing rubber compounds whenever a synthetic green strength polymer is used as one component of the rubber compound.

Abstract: The gel range of acid-acting delayed-action gelling agents, such as sodium silicofluoride, in latex spread foam compounds which are to be gelled by subjecting them to a preliminary heat treatment prior to drying is substantially broadened by including a water-soluble ammonium or amine sulfamate in the compound. At least 0.5 parts by weight of the sulfamate should be used per 100 parts by weight of dry solids in the starting uncompounded latex. It can be added to the latex at any time before or during the compounding step and it is preferably added with 0.5-1 part of a soap per part of sulfamate and also with sufficient ammonium hydroxide or other ammonia donor compound to maintain the pH of the compounded latex composition at 9.5 or higher.

Abstract: A method of making sound insulating floor or wall covering in which carpet is backed with a layer of sound insulating material and a layer of contour retaining material for holding the covering in a desired contoured shape. The latter material, which is conveniently a carpet precoat, is made formable for instance by heating, the carpet and its backing is shaped to desired form, and the retaining material is allowed to set thus holding the carpet and sound insulating layer to that shape. Desirably, the insulating material is a curable rubbery polymer which is cured before carpet shaping takes place. For improved sound insulating properties, deaerated insulating material is used.

Abstract: A process, and the composition therefrom, is provided for crosslinking of polymers containing hydroxy or mercaptan groups by reaction with polyaldehyde compounds, the crosslinks being thermally labile.

Abstract: A process, and the product thereof, is provided for the production of improved silica filled rubbery vulcanizates which process comprises mixing a vulcanizable hydrocarbyl polymer containing epoxy groups and silica, shearing the mixture at an elevated temperature, incorporating vulcanization active compounds and vulcanizing. The vulcanizates may be used where reinforced vulcanizates are required.

Abstract: A container closure especially for large containers and having circumferentially spaced tool access regions in a rim flange for insertion of a removal tool. These access regions are located between a base of the flange and a locking bead. Between the access regions, sections of a discontinuous locking bead extend around the inside of the flange, the bead being discontinuous across the circumferential area occupied by the access regions to enable a removal tool to be inserted downwardly through the access regions and between bead sections. Rim stiffening protrusions project from the outer surface of the flange beneath the access regions and across the circumferential line of the locking bead to stiffen the flange to prevent it from splitting when a removal tool is inserted down through the access regions and between bead sections.

Abstract: Synthetic elastomer compositions of high green strength comprise the reaction product of a rubbery polymer of a conjugated alkadiene having a small number of aldehyde groups attached to and randomly distributed along the polymer chain, and a polyamine having at least two non-tertiary amine groups. An example is a copolymer of styrene, butadiene and cinnamaldehyde (0.5 parts by weight) reacted with p-phenylene diamine, in an amount of 1 mole diamine per mole of cinnamaldehyde.

Abstract: In a container and closure assembly, there is a resilient seal between the two components and the resiliency of the seal determines the normal relative closed positions of the closure and container. When the assembly is included within a stack, there is movement of the closure in the closing direction further to compress the seal. To prevent over-compression of the seal, opposed movement limiting surfaces are provided upon the closure and container, these surfaces being slightly spaced normally, but closing together to take loads directly from closure to container and thus avoid overloading the seal, when the assembly is located in a stack.

Abstract: A plastic closure with a U-shaped rim surrounding a closure portion, an upper wall of the rim extending both upwardly and downwardly from the closure portion and flaring outwardly away from the closure portion. The upper end of the inner wall joins into the base of the `U` shape and the lower end is resiliently flexible. When fitted to a container, upper and lower ends of the inner wall seal against the lip and inner surface of the wall of the container, resiliency of the inner wall of the closure ensuring its sealing engagement with the container wall.

Abstract: There is provided a process, and the product of that process, for the production of improved silica or calcium silicate filled rubbery vulcanizates which comprises the preparation of a mixture comprising a vulcanizable hydrocarbyl polymer containing hydroxyl groups, silica or calcium silicate and an organic acid or salt thereof, shearing the mixture at an elevated temperature, incorporating vulcanization active compounds and vulcanizing to produce the improved vulcanizates. Such improved vulcanizates may be used generally in the rubber industry.

Abstract: There is provided a process, and the product of that process, for the production of improved silica or calcium silicate filled rubbery vulcanizates in which a polymer containing hydroxyl groups is mixed with silica or calcium silicate and an amine, the mixture is subjected to shearing at an elevated temperature and vulcanized to yield the improved vulcanizates. Such vulcanizates may be used in place of carbon black vulcanizates.

Abstract: A process is provided, and the product of that process, for the production of improved silica filled rubbery vulcanizates in which process a mixture is prepared comprising 100 parts by weight of a vulcanizable hydrocarbyl polymer containing hydroxyl groups, about 5 to about 100 parts by weight of silica and about 1 to about 10 parts by weight of magnesium oxide, the mixture is subjected to shearing at an elevated temperature, cooled, vulcanization active compounds are incorporated and then vulcanized. Such vulcanizates may be generally used especially where light-colored products are desired.

Abstract: Blends of trans-1,4 polymers of C.sub.4 -C.sub.5 conjugated diolefinic compounds and poly(epsilon-caprolactone) have improved properties and are suitable for use in medical casts or, when vulcanized, as golf ball covers.

Abstract: Vulcanizable compositions contain in admixture a synthetic high molecular weight polymer and a compatible low molecular weight polymer containing a multiplicity of antioxidant functional groups chemically bound to the polymer. Vulcanizates derived from these compositions have improved aging characteristics.

Abstract: Crystal polystyrene is satisfactorily protected against oxidative degradation in foam extrusion processes and thermoforming of articles from the expanded product so formed, by incorporation therein of a combined stabilizer system, comprising from about 0.01 to about 0.5 parts by weight of a hindered phenol compound such as 1,1,3-tris(2-methyl-4-hydroxy-5-tert.butyl phenyl) butane, and from about 0.02 to about 1.0 parts by weight of a tris (substituted phenyl) phosphite such as tris (mixed mono- and dinonylphenyl phosphite), based upon 100 parts by weight of polystyrene. Such stabilized foamed crystal polystyrene may be used for the production of formed articles.

Abstract: Conjugated diolefin-vinyl nitrile compound rubbers are produced in powder form by treatment of the coagulated rubber with a conjugated diolefin-vinyl nitrile compound vinyl aromatic hydrocarbon polymer. Such powdered rubbers may be used wherever conjugated diolefin-vinyl nitrile compound rubbers are used.