Abstract: A system and method of pre-purification of a feed gas stream is provided that is particularly suitable for pre-purification of a feed air stream in cryogenic air separation unit. The disclosed pre-purification systems and methods are configured to remove substantially all of the hydrogen, carbon monoxide, water, and carbon dioxide impurities from a feed air stream and is particularly suitable for use in a high purity or ultra-high purity nitrogen plant. The pre-purification systems and methods preferably employ two or more separate layers of hopcalite catalyst with the successive layers of the hopcalite separated by a zeolite adsorbent layer that removes water and carbon dioxide produced in the hopcalite layers. The separate layers of hopcalite catalyst preferably have different volumes and/or different average particle sizes of the hopcalite materials.

Abstract: A burner comprises a central conduit, a first annular conduit, and a nozzle plate across the outlet of the first annular conduit, wherein the nozzle plate comprises a plurality of orifices that extend through the nozzle plate, and a second annular conduit which opens into a downstream space, wherein the central conduit and the first annular conduit are controllably connected to a first reactant and the second annular conduit is controllably connected to a source of a second reactant, wherein one of the first and second reactants comprises fuel and the other of the first and second reactants comprises oxygen. Combustion apparatus comprises a plurality of the burners, preferably arranged in two planes each of which contain at least one of the burners. A fuel-rich flame can be emitted in one of the planes and a fuel-lean flame can be emitted in the other plane. The fuel-rich and fuel-lean nature of the flames emitted in the respective planes can be periodically alternated.

Abstract: Disclosed is a thermochemical regenerative combustion method in which a mixture of fuel components that can, and cannot, undergo endothermic reaction is passed through a heated regenerator to obtain improved heat recovery efficiency.

Abstract: The process of the present invention provides high recovery and low capital cost giving it an economic advantage over previously known purification processes. The present process has particular applicability to the purification of synthesis gases comprising at least hydrogen (H2), carbon monoxide (CO), methane (CH4), CO2, and H2O to obtain a gas stream including at least H2, CO, and CH4, that is substantially free of H2O and CO2. The process also has applicability to the purification of natural gases inclusive of at least CH4, N2, CO2, and H2O to produce a gas stream including at least CH4 and N2, but which is substantially free of H2O and CO2.

Abstract: A protective shroud for a valve integrated pressure regulator (VIPR) assembly is provided. The protective shroud includes a main body section, a top section extending from the main body section to form a primary handle with one or more connecting arm sections and a grip section, and a bottom section with an annular collar. The connecting sections and grip section of the primary handle are oriented in a parallel orientation to the annular collar. The front face of the main body section includes a recessed portion having a first port or opening configured to expose a pressure gauge/display from the VIPR assembly and a second port or opening configured to expose a gas outlet from the VIPR assembly. The top section of the protective shroud also includes a top opening sized to receive a control knob of the VIPR assembly.

Abstract: A liquid nitrogen energy storage (LNES) system that includes a liquid charging mode and a power generating mode is provided. The disclosed liquid nitrogen energy storage system comprises a nitrogen liquefier designed to cool or liquefy a first portion of the gaseous nitrogen and a cold recovery heat exchanger designed to cool or liquefy a second portion of the gaseous nitrogen during a liquid charging mode and to warm a liquid nitrogen energy stream during a power generating mode. The liquid nitrogen energy storage system also includes a cold store configured to provide refrigeration for liquefaction of the second portion of the gaseous nitrogen in the cold recovery heat exchanger during the liquid charging mode and to warm a portion of the liquid nitrogen taken as a liquid nitrogen energy stream in the cold recovery heat exchanger during the power generating mode.

Abstract: Catalyst beds in refinery reactors require periodic change out due to build-up of contamination and loss of activity. The instant invention mists a liquid chemical solvent in nitrogen carrier gas to solubilize oils and heavy hydrocarbons and to further desorb light hydrocarbons and remove hydrogen sulfide (H2S), to effect decontamination. This process can be advantageously combined with nitrogen cool-down processes in preparation for catalyst unloading.

Abstract: A method of operating a reformer furnace is disclosed. The method comprises using a carbon margin in balancing the furnace temperature thereby leading to carbon free formation operation and improved efficiency.

Abstract: Dry ice shippers with unique structural features designed to deliver optimized performance for preserving one or more perishable items in a presence of dry ice during transport are provided. The improved dry ice shippers exhibit superior properties that overcome the performance limitations of conventional dry ice shippers.

Abstract: An integrated gas turbine cycle and liquid air energy conversion system is provided that utilizes very high pressure air stream(s) produced from vaporization of a supercritical liquid air against a low pressure cryogenic gas. The cooled, low pressure cryogenic gas is then cold compressed to yield a moderate pressure cryogenic gas stream(s). Both the very high pressure air stream(s) and the moderate pressure air stream(s) are warmed in the flue gas heat exchanger associated with the gas turbine cycle. A source of electrical power is produced from the expansion of combustion gas in a gas turbine while auxiliary sources of electrical power are produced from the turbine expansion of the warmed very high pressure air streams and moderate pressure cryogenic gas streams. The combustion gas includes a moderate pressure supplemental stream originating from the supercritical liquid air or from the cold compressed cryogenic gas.

Abstract: A system for providing a desired amount of cooling to a quantity of non-liquid conveyable product in a vessel within a given length of residence time including: (A) continuously feeding a mass of the product into, through and out of a vessel, at a rate that provides a predetermined length of residence time, wherein the product is moved through the vessel by engagement thereof with an impeller; and (B) feeding cryogen out of a plurality of nozzle openings directly into or onto the product in the vessel while the impeller is moving the product continuously past the nozzle openings, wherein the cryogen is fed into said non-liquid conveyable product from a sufficient number of nozzle openings to provide the desired amount of cooling to the product within the given period of residence time, and wherein the flow of cryogen out of each nozzle opening is continuous or intermittent.

Abstract: A system and method for high rate liquid hydrogen tank filling is provided. The flexible, pump-based filling system can achieve high fill rate of liquid hydrogen in excess of 100 kg per minute and accommodate maximum delivery pressures. The present system and method further includes recovery and re-liquefaction of displaced and flash generated tank vapors.

Abstract: Methods for selectively etching SiGe relative to Si are provided. Some of the methods incorporate formation of a passivation layer on a surface of the Si layer to enhance SiGe etchant selectivity and the use of interhalogen gases that preferentially etch the SiGe as opposed to the Si in the presence of the passivation layer. The methods can occur in a cyclic manner until the desired thickness of the SiGe layer is obtained.

Abstract: Disclosed are methodology and apparatus for freezing the exterior crust of products, such as food products, in a manner that does not cause the exterior of the product to adhere to the surface on which it is placed during or after the freezing.

Abstract: In a reactor for partial oxidation of feedstock employing a hot oxygen stream that is generated by a suitable burner, the same burner that generates and provides the hot oxygen stream in full-scale partial oxidation operation can be employed in the starting-up of the partial oxidation reactor by suitable control of the characteristics of the feed to the burner, or of the pressures.

Abstract: An air separation unit and associated method for separating air by cryogenic distillation using a distillation column system including a higher pressure column, a lower pressure column, an intermediate pressure kettle column, and an argon column arrangement is provided. The present air separation unit and associated method employs a once-through kettle column reboiler, a once-through kettle column condenser, and a once-through argon condenser. The once through argon condenser is disposed within the lower pressure column where an argon-rich vapor stream is condensed against the descending liquid in the lower pressure column.

Abstract: Disclosed are methods for accommodating changes in the conditions of partial oxidation of hydrocarbonaceous feedstock by changing characteristics of the hot oxygen used in the partial oxidation.

Abstract: The present invention relates to a method of combusting a fuel gas with a stoichiometric or near stoichiometric amount of molecular oxygen in the presence of a controlled amount of a diluent to enhance the extent of combustion reactions in high heat transfer environment. The energy released is utilized to heat a fluid by direct contact with the flame. The diluent can be different from the fluid to be heated with respect to composition, temperature or pressure. The diluent can be same as or derived from the fluid to be heated.

Abstract: The present invention relates to a method and system for improving VPSA plant energy and capital efficiency through optimizing direct drive variable speed centrifugal feed, vacuum, and/or product compressors to achieve lower unit gas product production cost. More specifically, the present invention relates to a new energy efficient VPSA process and system which employs high speed direct drive centrifugal compressors to achieve wider production range. Significant lower energy consumption can be achieved over the plant operation life by employing compressors sized with average ambient and production demand, utilizing direct drive variable high speed centrifugal compressors' speed and operating range to meet the desired production demand. Since majority of the plants tend to run at below peak production most of operating life of the plant. In addition, the smaller size machine offers plant capital savings from the initial investment.

Abstract: The present invention relates to a method of preparing a gas coolant for the direct cooling of a unit operation under a fixed heat load from its normal operating temperature (e.g., 300° F. and above) to a lower temperature (e.g., below 100° F.) in order to allow for maintenance or other non-routine work to be carried out in said unit operation.