Abstract: Organic sulfur compounds contained in refinery off gas streams having either high ort low concentrations of olefins are converted to hydrogen sulfides which can be then be removed using conventional amine treating systems. The process uses a catalytic reactor with or without a hydrotreater depending on the olefin concentration of the off gas stream. The catalytic reactor operates in a hydrogenation mode or an oxidation mode to convert a majority of organic sulfur compounds into hydrogen sulfides.
Type:
Grant
Filed:
July 13, 2018
Date of Patent:
June 15, 2021
Assignee:
PRAXAIR TECHNOLOGY, INC.
Inventors:
Minish Mahendra Shah, Raymond Francis Drnevich, Vasilis Papavassiliou
Abstract: The present invention relates to a method for conditioning a soot-containing syngas stream in a single integrated apparatus containing a scrubbing vessel wherein particulate matter is decoupled from the waste water stream.
Type:
Grant
Filed:
August 27, 2020
Date of Patent:
June 1, 2021
Assignee:
PRAXAIR TECHNOLOGY, INC.
Inventors:
Luke Coleman, Minish Mahendra Shah, Joseph Schwartz, Jerome Jankowiak
Abstract: The present invention relates to a novel integrated system for providing nitrogen (N2) to a variety of industrial service applications such as, for example, process unit drying, pipeline purging, reactor cooling, vessel inerting, pipeline displacement.
Type:
Grant
Filed:
July 6, 2018
Date of Patent:
May 25, 2021
Assignee:
PRAXAIR TECHNOLOGY, INC.
Inventors:
Richard M Kelly, Mahesh Biradar, Matthew J Thomas, George Cieutat
Abstract: A system and method for argon and nitrogen extraction and liquefaction from a low-pressure tail gas of an ammonia production plant is provided. The preferred tail gas of the ammonia production plant comprises methane, nitrogen, argon, and hydrogen. The disclosed system and method provides for the methane rejection via rectification and hydrogen rejection by way of a side stripper column or phase separator. The resulting nitrogen and argon containing stream is separated and liquefied in a double column distillation system.
Abstract: A device (1) for dissolving a gas (G) in water (W) is provided, and includes a housing (100) configured to be submerged into the water (W) with the housing (100) having at least one water inlet (101), a gas inlet (102) and at least one water outlet (103) for discharging gas enriched water out of the housing (100), a pump (5) in fluid communication with the at least one water inlet (10) for sucking water (W) from a surrounding of the housing (100), the pump configured to generate a main water stream (S?), and means for injecting the gas (G) supplied via the gas inlet (102) into the main water stream (S?). The device (1) includes a probe (6) configured to measure a concentration of the gas dissolved in water, and the probe (6) is arranged in the housing (100) of the device (1).
Type:
Grant
Filed:
August 24, 2017
Date of Patent:
May 4, 2021
Assignee:
Praxair Technology, Inc.
Inventors:
Kenneth Glomset, Stefan Dullstein, Thomas Loevold Hellebust, John Bertil Aakernes
Abstract: The present invention relates to a method and control system to control the speed of centrifugal compressors operating within a vacuum pressure swing adsorption process to avoid an operation at which surge can occur and directly driven by an electric motor that is in turn controlled by a variable frequency drive, while subsequently operating the vacuum pressure swing process between set limits of highest adsorption and lowest desorption pressure. In accordance with present invention an optimal speed for operation of the compressor is determined at which the compressor will operate along a peak efficiency operating line of a compressor map thereof. This speed is adjusted by a feed back speed multiplier when the flow or other parameter referable to flow through the compressor is below a minimum and a feed forward multiplier during evacuation and evacuation with purge steps that multiplies the feed back multiplier to increase speed of the compressor and thereby avoid surge.
Type:
Grant
Filed:
July 10, 2017
Date of Patent:
April 27, 2021
Assignee:
PRAXAIR TECHNOLOGY, INC.
Inventors:
Garrett R. Swindlehurst, Andrew C. Rosinski, Michael S. Manning
Abstract: A multiple pass, parallel flow downcomer tray for a mass transfer column and method for liquid-vapor contacting in a mass transfer column is provided. The multiple pass, parallel flow downcomer tray has at least four mass transfer decks configured to provide contact between an ascending vapor passing upward through apertures on the tray surface and a traversing liquid on the tray surface. The tray further includes a central downcomers disposed near a central axis of the tray and two or more peripheral downcomers disposed near the edge of the tray and spaced apart from the central axis, wherein at least two of the four mass transfer decks are configured to discharge the traversing liquid into the peripheral downcomers and two of the four mass transfer decks are configured to discharge the traversing liquid into the central downcomer.
Type:
Grant
Filed:
September 20, 2019
Date of Patent:
April 27, 2021
Assignee:
PRAXAIR TECHNOLOGY, INC.
Inventors:
Arya Ayaskanta, Steven C. Brown, John P. Ricotta
Abstract: Operation of a combustion control system of furnace is controlled by image analysis, outside of the furnace or within the furnace, of a flame produced by combustion within the furnace, to correlate the image with carbon monoxide content of the flame, and adjustment of the oxygen and/or fuel flow into the furnace in response to the correlation.
Type:
Grant
Filed:
January 10, 2018
Date of Patent:
April 27, 2021
Assignee:
Praxair Technology, Inc.
Inventors:
Valmiro Correia e Sa Neto, Euan J. Evenson, Kevin W. Albrecht, James E. Kelly, Joaquín de Diego Rincón, Jorge Visús Pool
Abstract: A moderate pressure, argon and nitrogen producing cryogenic air separation unit and air separation cycle having a higher pressure column, a lower pressure column and an argon column arrangement is disclosed. The moderate pressure, argon and nitrogen producing cryogenic air separation unit is configured to take a first portion of an oxygen enriched stream from the lower pressure column, which together with an external source of liquid nitrogen is used as the boiling side refrigerant to condense the argon in the argon condenser. Use of the external source of liquid nitrogen in the argon condenser allows a second portion of the oxygen enriched stream from the lower pressure column to be taken as a liquid oxygen product stream.
Type:
Grant
Filed:
October 24, 2019
Date of Patent:
April 20, 2021
Assignee:
PRAXAIR TECHNOLOGY, INC.
Inventors:
David R. Parsnick, Neil M. Prosser, John F. Billingham, Henry E. Howard
Abstract: A moderate pressure air separation unit and air separation cycle is disclosed that provides for up to about 96% recovery of argon, an overall nitrogen recovery of 98 percent or greater and limited gaseous oxygen production. The air separation is configured to produce a first high purity oxygen enriched stream and a second lower purity oxygen enriched stream from the lower pressure column, one of which is used as the refrigerant to condense the argon in the argon condenser, with the resulting vaporized oxygen stream used to regenerate the temperature swing adsorption pre-purifier unit. All or a portion of the first high purity oxygen enriched stream is vaporized in the main heat exchanger to produce the gaseous oxygen products.
Type:
Grant
Filed:
January 15, 2020
Date of Patent:
April 6, 2021
Assignee:
PRAXAIR TECHNOLOGY, INC.
Inventors:
Brian R. Kromer, James R. Handley, Neil M. Prosser
Abstract: An annular divided wall column for the cryogenic rectification of air or constituents of air is provided. The annular divided wall column includes a first annular column wall and a second annular column wall disposed within the first annular column wall to define an annulus column region and an interior core column region. The present annular divided wall column further includes structured packing elements disposed within at least the annulus column region as well as a ring-shaped cantilevered collector; and a ring-shaped distributor disposed in the annulus column region above or below the plurality of structured packing elements. The thermal expansion and contraction of the second annular column wall in a radial direction and in an axial direction is independent of the thermal expansion and contraction of the first annular column wall in the radial and axial directions.
Type:
Grant
Filed:
January 13, 2020
Date of Patent:
February 23, 2021
Assignee:
PRAXAIR TECHNOLOGY, INC.
Inventors:
Kevin J. Saboda, Paul W. Belanger, Richard D. Lenz, Kirk F. Larson, Steven C. Brown, John P. Ricotta, Guang X. Chen, Jeremy D. Faust
Abstract: An annular divided wall column is provided. The annular divided wall column includes a first annular column wall and a second annular column wall disposed within the first annular column wall and radially spaced therefrom to define an annulus column region as the space between the first annular column wall and the second annular column wall. An interior core column region is also defined by the interior space of the second annular column wall. The present annular divided wall column further includes a plurality of packing elements, disposed within the interior core column region within the annulus column region having different surface area densities and optionally, also have different geometries.
Type:
Grant
Filed:
April 24, 2020
Date of Patent:
December 15, 2020
Assignee:
PRAXAIR TECHNOLOGY, INC.
Inventors:
Kirk F. Larson, Paul W. Belanger, Steven C. Brown, John P. Ricotta, Guang X. Chen, Richard D. Lenz
Abstract: An annular divided wall column for the cryogenic rectification of air or constituents of air is provided. The annular divided wall column includes a first annular column wall and a second annular column wall disposed within the first annular column wall to define an annulus column region and an interior core column region. The present annular divided wall column further includes structured packing elements disposed within at least the annulus column region as well as a ring-shaped cantilevered collector; and a ring-shaped distributor disposed in the annulus column region above or below the plurality of structured packing elements. The thermal expansion and contraction of the second annular column wall in a radial direction and in an axial direction is independent of the thermal expansion and contraction of the first annular column wall in the radial and axial directions.
Type:
Grant
Filed:
January 13, 2020
Date of Patent:
December 15, 2020
Assignee:
PRAXAIR TECHNOLOGY, INC.
Inventors:
Kevin J. Saboda, Paul W. Belanger, Richard D. Lenz, Kirk F. Larson, Steven C. Brown, John P. Ricotta, Guang X. Chen, Jeremy D. Faust
Abstract: In staged combustion, wherein fuel is fed into a furnace, and less than all of the gaseous oxidant needed to completely combust the fuel is fed with the fuel and combusted, providing uncombusted fuel, and the remaining portion of gaseous oxidant needed to combust the fuel is fed into the furnace through a second port, fuel is fed and combusted at the second port to heat the second port and lessen the tendency of deposits to form at the second port.
Abstract: The present invention relates to a proppant laden fracture fluid having a Mitchell quality of at least 50% and fracturing a subterranean formation therewith.
Type:
Grant
Filed:
August 23, 2018
Date of Patent:
November 10, 2020
Assignee:
PRAXAIR TECHNOLOGY, INC.
Inventors:
Richard M Kelly, Afshin Esmaeil Zadeh, Mark K Weise
Abstract: A system and method for oxygen transport membrane enhanced Integrated Gasifier Combined Cycle (IGCC) is provided. The oxygen transport membrane enhanced IGCC system is configured to generate electric power and optionally produce a fuel/liquid product from coal-derived synthesis gas or a mixture of coal-derived synthesis gas and natural gas derived synthesis gas.
Type:
Grant
Filed:
April 9, 2015
Date of Patent:
November 3, 2020
Assignee:
PRAXAIR TECHNOLOGY, INC.
Inventors:
Sean M. Kelly, Shrikar Chakravarti, Raymond F. Drnevich
Abstract: A moderate pressure air separation unit and air separation cycle is disclosed that provides for up to about 96% recovery of argon and an overall nitrogen recovery of 98% or greater. The air separation is configured to produce a high purity oxygen enriched stream which is used as the refrigerant to condense the argon in the argon condenser, with the resulting vaporized oxygen stream used to regenerate the temperature swing adsorption prepurifier unit. Argon recovery is facilitated with the use of an argon superstaged column.
Type:
Grant
Filed:
April 25, 2018
Date of Patent:
October 27, 2020
Assignee:
PRAXAIR TECHNOLOGY, INC.
Inventors:
Neil M. Prosser, James R. Handley, Brian R. Kromer
Abstract: Closed-loop refrigeration cycles for liquid oxygen densification are disclosed. The disclosed refrigeration cycles may be turbine-based refrigeration cycles or a Joule-Thompson (JT) expansion valve based refrigeration cycles and include a refrigerant or working fluid comprising a mixture of neon or helium together with nitrogen and/or oxygen.
Type:
Grant
Filed:
January 15, 2018
Date of Patent:
October 20, 2020
Assignee:
PRAXAIR TECHNOLOGY, INC.
Inventors:
Neil M. Prosser, James R. Dray, Paul W. Belanger, Maulik R. Shelat
Abstract: The present invention relates to a process cycle that allows for the stable production of mid-range purity oxygen from air, using traditional system designs. Typical cycles have a limited production benefit when generating O2 at lower than 90% purity, however they suffer a production loss at higher purity. The process cycles of the invention are capable of producing significantly more contained O2 at a lower purity. In addition to enhanced production capacity, lower power consumed per mass of product and more stable product purity and flow are realized by the process of the invention compared to traditional alternatives.
Abstract: The present invention relates to a method for conditioning a soot-containing syngas stream in a single integrated apparatus containing a scrubbing vessel wherein particulate matter is decoupled from the waste water stream.
Type:
Grant
Filed:
August 16, 2017
Date of Patent:
October 6, 2020
Assignee:
PRAXAIR TECHNOLOGY, INC.
Inventors:
Luke Coleman, Minish Mahendra Shah, Joseph Schwartz, Jerome Jankowiak