Abstract: Drilling fluids comprising graphenes and nanoplatelet additives and methods for production thereof are disclosed. Graphene includes graphite oxide, graphene oxide, chemically-converted graphene, and functionalized chemically-converted graphene. Derivatized graphenes and methods for production thereof are disclosed. The derivatized graphenes are prepared from a chemically-converted graphene through derivatization with a plurality of functional groups. Derivatization can be accomplished, for example, by reaction of a chemically-converted graphene with a diazonium species. Methods for preparation of graphite oxide are also disclosed.
Type:
Grant
Filed:
July 8, 2010
Date of Patent:
May 22, 2012
Assignee:
William Marsh Rice University
Inventors:
James M. Tour, Howard K. Schmidt, Jay R. Lomeda, Dmitry V. Kosynkin, Condell D. Doyle
Abstract: The present invention relates to coated fullerenes comprising a layer of at least one inorganic material covering at least a portion of at least one surface of a fullerene and methods for making. The present invention further relates to composites comprising the coated fullerenes of the present invention and further comprising polymers, ceramics, and/or inorganic oxides. A coated fullerene interconnect device where at least two fullerenes are contacting each other to form a spontaneous interconnect is also disclosed as well as methods of making. In addition, dielectric films comprising the coated fullerenes of the present invention and methods of making are further disclosed.
Type:
Application
Filed:
October 11, 2011
Publication date:
May 17, 2012
Applicants:
NATCORE TECHNOLOGY INC., WILLIAM MARSH RICE UNIVERSITY
Inventors:
Andrew R. Barron, Dennis J. Flood, Elizabeth Whitsitt
Abstract: A nanoparticle comprising a shell surrounding a core material with a lower conductivity than the shell material, wherein the core center is offset in relation to the shell center. A method comprising providing a nanoparticle comprising a nonconductive core and a conductive shell, and asymmetrically depositing additional conductive material on the conductive shell. A method comprising providing a concentric nanoshell having a core and a shell, immobilizing the concentric nanoshell onto a support, and asymmetrically depositing a conductive material onto the shell to produce a nanoegg.
Type:
Grant
Filed:
June 20, 2007
Date of Patent:
May 15, 2012
Assignee:
William Marsh Rice University
Inventors:
Nancy J. Halas, Hui Wang, Peter J. Nordlander, Yanpeng Wu
Abstract: In general, the invention relates to a method for designing a biological circuit. The method includes obtaining a target circuit objective for the biological circuit, determining an objective function corresponding to the target circuit objective, obtaining a number of nodes for the biological circuit, obtaining a set of possible circuit subgraphs using the number of nodes, obtaining a specific dissipation energy (SDE) for each one of the set of possible circuit subgraphs by optimizing the objective function, selecting at least one circuit subgraph from the set of possible circuit subgraphs with the lowest SDE, and designing the biological circuit using the at least one selected one circuit subgraph.
Type:
Application
Filed:
September 30, 2011
Publication date:
May 10, 2012
Applicant:
WILLIAM MARSH RICE UNIVERSITY
Inventors:
Deepak Nagrath, Marco Avila-Elchiver, Martin Yarmush
Abstract: According to one embodiment, the description relates to a method of nerolidol production. The method includes culturing a yeast strain lacking functional squalene synthase and overproducing HMG CoA reductase in synthetic medium lacking uracil and producing nerolidol. The pH of the medium may be adjusted to an acidic level to further increase nerolidol production. Other chemicals may also be produced by this method. The nerolidol or other chemicals may be removed from the yeast or medium or both. The medium may additionally contain a polyaromatic resin, which may adsorb nerolidol or other chemicals.
Type:
Grant
Filed:
December 12, 2007
Date of Patent:
May 8, 2012
Assignee:
William Marsh Rice University
Inventors:
Caroline Virginia McNeil, Pietro Morlacchi, Alyssa Baevich, Seiichi Paul Tillich Matsuda
Abstract: According to some embodiments, the present invention provides a system and method for supporting a carbon nanotube array that involve an entangled carbon nanotube mat integral with the array, where the mat is embedded in an embedding material. The embedding material may be depositable on a carbon nanotube. A depositable material may be metallic or nonmetallic. The embedding material may be an adhesive material. The adhesive material may optionally be mixed with a metal powder. The embedding material may be supported by a substrate or self-supportive. The embedding material may be conductive or nonconductive. The system and method provide superior mechanical and, when applicable, electrical, contact between the carbon nanotubes in the array and the embedding material. The optional use of a conductive material for the embedding material provides a mechanism useful for integration of carbon nanotube arrays into electronic devices.
Type:
Application
Filed:
April 23, 2007
Publication date:
May 3, 2012
Applicant:
WILLIAM MARSH RICE UNIVERSITY
Inventors:
Myung Jong Kim, Nolan Walker Nicholas, W. Carter Kittrell, Howard K. Schmidt
Abstract: The invention relates to the development of appropriate cultivation conditions for a bacteria to grow anaerobically (fermentatively) on a glycerol substrate. The method requires culturing bacteria having a functional 1,2-propanediol pathway and a functional type II glycerol dehydrogenase-dihydroxyacetone kinase pathway in a culture medium containing high concentrations of glycerol, a neutral to mildly acidic pH, low levels of potassium and phosphate, and high levels of CO2, such that glycerol is thus converted into a desirable product, such as ethanol, hydrogen, formate, succinate, or 1,2-propanediol.
Abstract: An apparatus has a data acquisition device, an environmental cell in a spatial registration relative to the data acquisition device, the environmental cell being configured to support a sample, and a fluid management system configured to initiate and discontinue exposure of the sample to a reaction fluid while the spatial registration is maintained. A method of performing data acquisition for a sample includes spatially registering the sample relative to a data acquisition device, at least partially exposing the sample to a reaction fluid while substantially maintaining the spatial registration of the sample relative to the data acquisition device, at least partially discontinuing exposing the sample to the reaction fluid while substantially maintaining the spatial registration of the sample relative to the data acquisition device, and acquiring data about the sample while substantially maintaining the spatial registration of the sample relative to the data acquisition device.
Abstract: A heat exchanger with mini channels or micro channels provides enhanced heat transfer abilities. One or more surfaces of the channels may be covered with a nanostructure, such as single walled carbon nanotubes or multiwalled carbon nanotubes. The nanostructures may fully cover the entire surface of the channel or a selected surface area of the channel. Further, the nanostructures may be arranged into multiple patterned bundles covering the surface of the channel.
Abstract: The present invention is directed toward methods of attaching or grafting carbon nanotubes (CNTs) to silicon surfaces. In some embodiments, such attaching or grafting occurs via functional groups on either or both of the CNTs and silicon surface. In some embodiments, the methods of the present invention include: (1) reacting a silicon surface with a functionalizing agent (such as oligo(phenylene ethynylene)) to form a functionalized silicon surface; (2) dispersing a quantity of CNTs in a solvent to form dispersed CNTs; and (3) reacting the functionalized silicon surface with the dispersed CNTs. The present invention is also directed to the novel compositions produced by such methods.
Type:
Grant
Filed:
May 6, 2005
Date of Patent:
April 17, 2012
Assignee:
William Marsh Rice University
Inventors:
James M. Tour, Bo Chen, Austen K. Flatt, Michael P. Stewart, Christopher A. Dyke, Francisco Maya
Abstract: A novel low-power and compact laser spectroscopic sensor is described herein. Embodiments of the disclosed sensor utilize state-of-the-art microprocessors and digital processing techniques to reduce power consumption and integrate functions into a small device. In particular, novel software methods are disclosed which allow the use of low-power microprocessors which draw no more than about 0.02 W of power. Such low-power enables long battery life and allows embodiments of the sensor to be used in portable applications. In addition, the system architecture and methods described in this disclosure allow a single integrated embedded processor to control all the subsystems necessary for a laser spectroscopic sensor further reducing sensor size and power consumption. In addition, a power efficient method of calibrating a photoacoustic laser spectroscopic sensor is disclosed.
Type:
Application
Filed:
December 14, 2011
Publication date:
April 5, 2012
Applicant:
WILLIAM MARSH RICE UNIVERSITY
Inventors:
Stephen SO, Gerard WYSOCKI, J. Patrick FRANTZ, Frank K. TITTEL
Abstract: The invention relates to the synthesis of polyketides in Actinomycetes by overexpression of pantothenate kinase and supplementation with pantothenic acid. This results in increasing in vivo CoA production and thereby drives increased production of secondary metabolites, such as polyketides.
Type:
Grant
Filed:
September 22, 2006
Date of Patent:
March 27, 2012
Assignee:
Rice University
Inventors:
Hei Chan Lee, Jae Kyung Sohng, Ka-Yiu San
Abstract: A method for managing TCP flows in a mobile device adapted to connect to two or more wireless network types includes enabling connection to a number of networks of different types at the mobile device and executing a plurality of Internet-enabled applications on the mobile device. Each such application forms an existing TCP connection over a first one of the wireless networks. The routing table is modified such that any additional TCP connection will be created on a second one of the wireless networks. The device determines that a termination condition has occurred and in response to determining that the termination condition has occurred, renders an interface on the mobile device to the first one of the wireless networks inoperative.
Type:
Application
Filed:
July 7, 2011
Publication date:
March 22, 2012
Applicants:
WILLIAM MARSH RICE UNIVERSITY, DEUTSCHE TELEKOM AG
Inventors:
Angela Nicoara, Ahmad Rahmati, Clayton Shepard, Lin Zhong, Jatinder Pal Singh
Abstract: Methods for dissolving carbon materials such as, for example, graphite, graphite oxide, oxidized graphene nanoribbons and reduced graphene nanoribbons in a solvent containing at least one superacid are described herein. Both isotropic and liquid crystalline solutions can be produced, depending on the concentration of the carbon material The superacid solutions can be formed into articles such as, for example, fibers and films, mixed with other materials such as, for example, polymers, or used for functionalization of the carbon material. The superacid results in exfoliation of the carbon material to produce individual particles of the carbon material. In some embodiments, graphite or graphite oxide is dissolved in a solvent containing at least one superacid to form graphene or graphene oxide, which can be subsequently isolated. In some embodiments, liquid crystalline solutions of oxidized graphene nanoribbons in water are also described.
Type:
Application
Filed:
February 19, 2010
Publication date:
March 15, 2012
Applicant:
WILLIAM MARSH RICE UNIVERSITY
Inventors:
James M. Tour, Matteo Pasquali, Natnael Behabtu, Jay R. Lomeda, Dmitry V. Kosynkin, Amanda Duque, Micah J. Green, A. Nicholas Parra-Vasquez, Colin Young
Abstract: An apparatus comprising a processor configured to implement a method comprising obtaining a pipe profile comprising a diameter, a nominal thickness, and a material, receiving a magnetic flux leakage (MFL) indication for a pipe associated with the pipe profile, and determining a wall thickness for the pipe using the pipe profile and the MFL indication. Also disclosed is a method comprising modeling an apparatus comprising a magnet configured to induce a magnetic field in a pipe, and determining a wall thickness measurement (WTM) for the pipe using a model of the apparatus and the pipe, a detected MFL signal, and a simulated MFL signal.
Abstract: A method of removing metal impurities from carbon nanotubes includes treating carbon nanotubes with distilled bromine in a substantially oxygen- and water-free atmosphere and then removing the distilled bromine from the carbon nanotubes. Purified carbon nanotubes having an iron content from about 2.5 to about 3.5 by weight that are substantially free of derivatization at the ends and defect sites are made available via this method.
Abstract: The invention relates to the development of appropriate cultivation conditions for a bacteria to grow anaerobically (fermentatively) on a glycerol substrate. The method requires culturing bacteria having a functional 1,2-propanediol pathway and a functional type II glycerol dehydrogenase-dihydroxyacetone kinase pathway in a culture medium containing high concentrations of glycerol, a neutral to mildly acidic pH, low levels of potassium and phosphate, and high levels of CO2, such that glycerol is thus converted into a desirable product, such as ethanol, hydrogen, formate, succinate, or 1,2-propanediol.
Abstract: A new and useful nanotube growth substrate conditioning processes is herein disclosed that allows the growth of vertical arrays of carbon nanotubes where the average diameter of the nanotubes can be selected and/or controlled as compared to the prior art.
Type:
Grant
Filed:
March 5, 2007
Date of Patent:
February 28, 2012
Assignee:
William Marsh Rice University
Inventors:
Robert H. Hauge, Ya-Qiong Xu, Hongwei Shan, Nolan Walker Nicholas, Myung Jong Kim, Howard K. Schmidt, W. Carter Kittrell
Abstract: A composition and method is described for intracellular delivery of fullerene containing peptides. The composition and method involve fullerene-substituted phenylalanine as part of a peptide based delivery system. The presence of a fullerene-substituted amino acid in a peptide is found to alter the intracellular transport properties of the peptide.
Type:
Application
Filed:
March 30, 2007
Publication date:
February 9, 2012
Applicant:
William March Rice University
Inventors:
Andrew R. Barron, Jianzhong Yang, Jianhua Yang, Kuan Wang, Jonathan Driver
Abstract: A composition of matter, and method to make same, for a nano-based material including a nanocarbon support to which is attached an aliphatic amine. In particular, the composition of matter is an aliphatic amine-nanocarbon material that includes a nanocarbon (NC) support, such as C60, nano-graphite, graphene, nanocarbon ribbons, graphite intercalation compounds, graphite oxide, nano-coal, nanohorns, and combinations thereof, and further includes an aliphatic amine, such as polyethyleneimine (PEI).