Abstract: Compositions comprising at least one type of carbon nanotube, at least one surfactant, and at least one polymer are disclosed. The compositions provide stable fluorescence over a wide range of pH in various embodiments. In some embodiments, the compositions are biocompatible. Methods for preparing the compositions from at least one pre-formed polymer are disclosed. Methods for preparing the compositions from at least one monomer are disclosed. Heating methods utilizing the compositions are disclosed.
Type:
Application
Filed:
September 24, 2008
Publication date:
November 11, 2010
Applicant:
WILLIAM MARSH RICE UNIVERSITY
Inventors:
Juan G. Duque, Matteo Pasquali, Howard K. Schmidt, Laurent Cogent, A. Nicholas G. Parra-Vasquez
Abstract: Vertically-stacked electronic devices having conductive carbon films are disclosed. The vertically-stacked devices exhibit non-linear current-versus-voltage response over a voltage sweep range in various embodiments. The vertically-stacked devices may be assembled into arrays where the vertically-stacked devices may be electrically addressed independently of one another. Uses of the vertically-stacked electronic devices and arrays as two-terminal memory devices, logic units, and sensors are disclosed. Crossbar arrays of vertically-stacked electronic devices having conductive carbon films and nanowire electrodes are disclosed.
Type:
Application
Filed:
November 13, 2008
Publication date:
November 11, 2010
Applicant:
William Marsh Rice University
Inventors:
James M. Tour, Yubao Li, Alexander Sinitskiy, Lin Zhong, Mian Dong, Jun Yao
Abstract: Techniques are able to lock and unlock and integrated circuit (IC) based device by encrypting/decrypting a bus on the device. The bus may be a system bus for the IC, a bus within the IC, or an external input/output bus. A shared secret protocol is used between an IC designer and a fabrication facility building the IC. The IC at the fabrication facility scrambles the bus on the IC using an encryption key generated from unique identification data received from the IC designer. With the IC bus locked by the encryption key, only the IC designer may be able to determine and communicate the appropriate activation key required to unlock (e.g., unscramble) the bus and thus make the integrated circuit usable.
Type:
Application
Filed:
March 9, 2010
Publication date:
November 11, 2010
Applicants:
THE REGENTS OF THE UNIVERSITY OF MICHIGAN, William Marsh Rice University
Inventors:
Jarrod A. Roy, Farinaz Koushanfar, Igor L. Markov
Abstract: A method for making hollow nanoparticles, comprises a) providing an amount of a polyelectrolyte having a charge, b) providing an amount of a counterion having a valence of at least 2, c) combining the polyelectrolyte and the counterion in a solution such that the polyelectrolyte self-assembles to form spherical aggregates, and d) adding nanoparticles to the solution such that nanoparticles arrange themselves around the spherical aggregates. The polyelectrolyte may have a positive or negative charge. The charge ratio R of total charge of the counterions to the total charge of the polyelectrolyte is greater than 1.0.
Type:
Grant
Filed:
October 20, 2004
Date of Patent:
November 9, 2010
Assignee:
William Marsh Rice University
Inventors:
Rohit K. Rana, Vinit S. Murthy, Michael S. Wong
Abstract: In various embodiments, methods for synthesizing single-crystalline zero-valent metal nanorings, such as single-crystalline copper nanorings, are described herein. The methods include providing a solution containing a metal cation, a complexing agent bound to the metal cation, thereby forming a metal complex that is at least partially soluble in the solution, and a reducing agent operable for reducing the metal complex to a zero-valent metal and then heating the solution for a sufficient time and at a sufficient temperature until zero-valent metal nanorings form. The solution may be an aqueous solution in an embodiment. Single-crystalline metal nanorings produced by the methods described herein may have a diameter less than about 100 ?m and a wall thickness between about 10 nm and about 500 nm.
Abstract: Electronic devices comprising a dielectric material, at least one carbon sheet, and two electrode terminals are described herein. The devices exhibit non-linear current-versus-voltage response over a voltage sweep range in various embodiments. Uses of the electronic devices as two-terminal memory devices, logic units, and sensors are disclosed. Processes for making the electronic devices are disclosed. Methods for using the electronic devices in analytical methods are disclosed.
Type:
Application
Filed:
September 29, 2008
Publication date:
November 4, 2010
Applicant:
William Marsh Rice University
Inventors:
James M. Tour, Yubao Li, Alexander Sinitskiy
Abstract: A process for making a porous catalyst, comprises a) providing an aqueous solution containing a nanoparticle precursor, b) forming a composition containing nanoparticles, c) adding a first catalytic component or precursor thereof and a pore-forming agent to the composition containing nanoparticles and allowing the first catalytic component, the pore-forming agent, and the nanoparticles form an organic-inorganic structure, d) removing water from the organic-inorganic structure; and e) removing the pore-forming agent from the organic-inorganic structure so as to yield a porous catalyst.
Type:
Grant
Filed:
June 3, 2004
Date of Patent:
November 2, 2010
Assignee:
William Marsh Rice University
Inventors:
Michael S. Wong, Israel E. Wachs, William V. Knowles
Abstract: The present invention is directed to functionalized nanoscale diamond powders, methods for making such powders, applications for using such powders, and articles of manufacture comprising such powders. Methods for making such functionalized nanodiamond powders generally comprise a fluorination of nanodiamond powder. In some embodiments, such methods comprise reacting fluorinated nanodiamond powder with a subsequent derivatization agent, such as a strong nucleophile.
Type:
Grant
Filed:
November 24, 2004
Date of Patent:
October 26, 2010
Assignee:
William Marsh Rice University
Inventors:
Valery N. Khabashesku, Yu Liu, John L. Margrave, Mary Lou Margrave, legal representative
Abstract: The invented ink-jet printing method for the construction of thin film transistors using all SWNTs on flexible plastic films is a new process. This method is more practical than all of existing printing methods in the construction TFT and RFID tags because SWNTs have superior properties of both electrical and mechanical over organic conducting oligomers and polymers which often used for TFT. Furthermore, this method can be applied on thin films such as paper and plastic films while silicon based techniques can not used on such flexible films. These are superior to the traditional conducting polymers used in printable devices since they need no dopant and they are more stable. They could be used in conjunction with conducting polymers, or as stand-alone inks.
Type:
Grant
Filed:
November 24, 2006
Date of Patent:
October 26, 2010
Assignee:
William Marsh Rice University
Inventors:
Gyou-Jin Cho, Min Hun Jung, Jared L. Hudson, James M. Tour
Abstract: This invention is generally related to a method of making a molecule-surface interface comprising at least one surface comprising at least one material and at least one organic group wherein the organic group is adjoined to the surface and the method comprises contacting at least one organic group precursor with at least one surface wherein the organic group precursor is capable of reacting with the surface in a manner sufficient to adjoin the organic group and the surface. The present invention is directed to hybrid molecular electronic devices having a molecule-surface interface. Such hybrid molecular electronic devices may advantageously have either a top or bottom gate electrode for modifying a conductivity of the devices.
Type:
Application
Filed:
April 5, 2010
Publication date:
October 7, 2010
Applicant:
WILLIAM MARSH RICE UNIVERSITY
Inventors:
James M. Tour, Michael P. Stewart, Jianli He, Harrry F. Pang
Abstract: A method for detecting a target fluid in a fluid sample comprising a first fluid and the target fluid using photoacoustic spectroscopy (PAS), comprises a) providing a light source configured to introduce an optical signal having at least one wavelength into the fluid sample; b) modulating the optical signal at a desired modulation frequency such that the optical signal generates an acoustic signal in the fluid sample; c) measuring the acoustic signal in a resonant acoustic detector; and d) using the phase of the acoustic signal to detect the presence of the target fluid.
Abstract: The disclosure relates to recombinant adult human apohemoglobin (apo-rHb) in which the stability has been increased by replacement of an amino acid with a counterpart from another organism, such as a deep sea diving mammal. This mutated apo-rHb may be more stable and/or give higher production yields than unmutated adult human apo-rHb. The mutated apo-rHb may be produced in microorganisms, such as E. coli or yeast cells, or animal erythroid cells. Some apo-rHb of the present disclosure may be used as part of a blood substitute.
Type:
Grant
Filed:
March 14, 2007
Date of Patent:
September 28, 2010
Assignees:
William Marsh Rice University, Wisconsin Alumni Research Foundation
Abstract: The invention relates to a mutant strain of bacteria, which either lacks or contains mutant genes for several key metabolic enzymes, and which produces high amounts of succinic acid under anaerobic conditions.
Type:
Grant
Filed:
April 5, 2007
Date of Patent:
September 7, 2010
Assignee:
Rice University
Inventors:
Ka-Yiu San, George N. Bennett, Ailen Sanchez
Abstract: A new hybrid nanoparticle, i.e., a nanorice particle, which combines the intense local fields of nanorods with the highly tunable plasmon resonances of nanoshells, is described herein. This geometry possesses far greater structural tunability than previous nanoparticle geometries, along with much larger local field enhancements and far greater sensitivity as a surface plasmon resonance (SPR) nanosensor than presently known dielectric-conductive material nanostructures. In an embodiment, a nanoparticle comprises a prolate spheroid-shaped core having a first aspect ratio. The nanoparticle also comprises at least one conductive shell surrounding said prolate spheroid-shaped core. The nanoparticle has a surface plasmon resonance sensitivity of at least 600 nm RIU?1. Methods of making the disclosed nanorice particles are also described herein.
Type:
Grant
Filed:
March 2, 2007
Date of Patent:
September 7, 2010
Assignee:
William Marsh Rice University
Inventors:
Hui Wang, Daniel Brandl, Fei Le, Peter Nordlander, Nancy J. Halas
Abstract: A method for functionalizing the wall of single-wall or multi-wall carbon nanotubes involves the use of acyl peroxides to generate carbon-centered free radicals. The method allows for the chemical attachment of a variety of functional groups to the wall or end cap of carbon nanotubes through covalent carbon bonds without destroying the wall or endcap structure of the nanotube. Carbon-centered radicals generated from acyl peroxides can have terminal functional groups that provide sites for further reaction with other compounds. Organic groups with terminal carboxylic acid functionality can be converted to an acyl chloride and further reacted with an amine to form an amide or with a diamine to form an amide with terminal amine. The reactive functional groups attached to the nanotubes provide improved solvent dispersibility and provide reaction sites for monomers for incorporation in polymer structures. The nanotubes can also be functionalized by generating free radicals from organic sulfoxides.
Type:
Application
Filed:
May 12, 2010
Publication date:
September 2, 2010
Applicant:
William Marsh Rice University
Inventors:
Valery N. Khabashesku, Haiqing Peng, John L. Margrave, Mary Lou Margrave, Wilbur Edward Billups, Yunming Ying
Abstract: The present invention relates to the ability of SAP to suppress fibrocytes. It also relates to the ability of IL-12, laminin-1, cross-linked IgG and IgG aggregates to suppress fibrocytes. Methods and compositions for suppressing fibrocytes using these proteins are provided. These methods are useful in a variety of applications including treatment and prevention of fibrosing diseases such as scleroderma, pulmonary fibrosis and asthma. Finally, the invention includes assays for detecting the ability of various agents to modulate differentiation into fibrocytes. Such assays may also be used to diagnose scleroderma, pulmonary fibrosis, or other fibrosing diseases.
Abstract: A method for making composite nanoparticles comprises a) providing an amount of a polyelectrolyte having a charge, b) providing an amount of a counterion having a valence of at least 2, the counterion having a charge opposite the charge of the polyelectrolyte, c) combining the polyelectrolyte and the counterion in a solution such that the polyelectrolyte self-assembles to form a plurality of polymer aggregates, the plurality of polymer aggregates having an average diameter less than about 100 nm, d) adding a precursor to the solution, wherein the precursor has a charge opposite the charge of the polyelectrolyte, and e) allowing the precursor to infuse each polymer aggregate and polymerize so as to produce composite nanoparticles. The composite nanoparticles comprise a polymer aggregate containing at least one polyelectrolyte and at least one counterion and a polymer network crosslinked throughout the polymer aggregate. The polymer network may be inorganic, e.g silicon-containing.
Type:
Application
Filed:
August 11, 2006
Publication date:
September 2, 2010
Applicant:
WM. MARSH RICE UNIVERSITY
Inventors:
Vinit S. Murthy, Tildon G. Belgard, Michael S. Wong
Abstract: This invention is directed to chemical derivatives of carbon nanotubes wherein the carbon nanotubes have a diameter up to 3 nm. In one embodiment, this invention also provides a method for preparing carbon nanotubes having substituents attached to the side wall of the nanotube by reacting single-wall carbon nanotubes with fluorine gas and recovering fluorine derivatized carbon nanotubes, then reacting fluorine derivatized carbon nanotubes with a nucleophile. Some of the fluorine substituents are replaced by nucleophilic substitution. If desired, the remaining fluorine can be completely or partially eliminated to produce carbon nanotubes having substituents attached to the side wall of the nanotube. The substituents are dependent on the nucleophile, and preferred nucleophiles include alkyl lithium species such as methyl lithium.
Type:
Grant
Filed:
June 13, 2006
Date of Patent:
August 24, 2010
Assignee:
William Marsh Rice University
Inventors:
John L. Margrave, Edward T. Mickelson, Robert Hauge, Peter Boul, Chad Huffman, Jie Liu, Richard E. Smalley, Ken Smith, Daniel T. Colbert
Abstract: A parallel dynamical system for computing sparse representations of data, i.e., where the data can be fully represented in terms of a small number of non-zero code elements, and for reconstructing compressively sensed images. The system is based on the principles of thresholding and local competition that solves a family of sparse approximation problems corresponding to various sparsity metrics. The system utilizes Locally Competitive Algorithms (LCAs), nodes in a population continually compete with neighboring units using (usually one-way) lateral inhibition to calculate coefficients representing an input in an over complete dictionary.
Type:
Grant
Filed:
February 21, 2008
Date of Patent:
August 24, 2010
Assignee:
William Marsh Rice University
Inventors:
Christopher John Rozell, Don Herrick Johnson, Richard Gordon Baraniuk, Bruno A. Olshausen, Robert Lowell Ortman
Abstract: A method of producing biological products using bacteria with an inactivated ptsHI and wild type err and no added glucose transport activity and which consumes nearly all glucose in the media is described. The ?ptsHI bacteria produce large quantities of recombinant protein without producing significant amounts of acetate. The bacteria grow well on standard LB broth without additional supplementation.
Type:
Application
Filed:
April 15, 2008
Publication date:
August 5, 2010
Applicant:
Rice University
Inventors:
Ka-Yiu San, George N. Bennett, Thomas Bryce Causey, Matthew Sing Wong, Steven Wu