Abstract: Process for preparing (meth)acrylates of the formula (I) CH2?C(R1)—CO—O—R2??(I) in which R1 is hydrogen or methyl and R2 is a saturated or unsaturated, linear or branched, aliphatic or cyclic alkyl radical having 6 to 22 carbon atoms, or a (C6-C14)-aryl-(C1-C8)-alkyl radical; by reacting a (meth)acrylate of the formula II CH2?C(R1)—CO—OR3??(II) with an alcohol of the formula (III) HO—R2??(III) in the presence of an amount of a suitable catalyst which catalyzes the reaction and of an amount of a phenolic polymerization inhibitor or a combination of two or more phenolic polymerization inhibitors which is sufficient to inhibit undesired polymerization; the reaction being undertaken with input or introduction into the reaction mixture resulting from the reaction of an amount of oxygen or of an oxygenous gas mixture sufficient to inhibit undesired polymerization, and the process is characterized in that the specific total oxygen input is less than or equal to 1.
Type:
Grant
Filed:
October 27, 2015
Date of Patent:
June 27, 2017
Assignee:
Evonik Roehm GmbH
Inventors:
Joachim Knebel, Ralf Merbach, Guido Protzmann, Klaus Gottmann, John Hirsh, Gerold Schmitt, Dieter Tessmer, Wilhelm Karnbrock, Wolfgang Klesse, Volker Kerscher
Abstract: The present invention relates to a process for preparing alpha-hydroxycarboxylic esters from the alcoholysis of alpha-hydroxycarboxam ides in the gas phase, characterized in that the conversion is effected in the presence of water.
Type:
Application
Filed:
July 23, 2015
Publication date:
May 25, 2017
Applicant:
Evonik Roehm GmbH
Inventors:
Steffen KRILL, Belaid AIT AISSA, Alexander MAY, Matthias GROEMPING
Abstract: The invention relates to a process for preparing methacrylic esters of hydroxyl-functional benzophenones and to their use. Methacrylated benzophenones (benzophenone (meth)acrylates) can be prepared in high purity by the process of the invention, in a simple way and in a high yield.
Type:
Grant
Filed:
September 29, 2014
Date of Patent:
May 23, 2017
Assignee:
Evonik Roehm GmbH
Inventors:
Wolfgang Klesse, Joachim Knebel, Doris Saal
Abstract: The invention relates to a process for the production of mould-foamed poly(meth)acrylimide (P(M)I) cores, in particular of polymethacrylimide (PMI) cores, which can be used by way of example in automobile construction or aircraft construction. A feature of this process is that polymer granules or polymer powder preheated under pressure are moreover charged under pressure to a compression mould where they are foamed with depressurization. In particular, a feature of the process is that it optionally uses a preferably two-shell compression mould for the heating and also for the cooling of the granules and, respectively, the rigid foam core formed therefrom.
Type:
Application
Filed:
June 25, 2015
Publication date:
May 18, 2017
Applicant:
Evonik Roehm GmbH
Inventors:
Kay BERNHARD, Ina LIEBL, Tim DENK, Florian BECKER, Thomas RICHTER
Abstract: A drilling apparatus has a housing, a motor in the housing, a drive spindle rotatable about an axis on the housing, a chuck body, and a plurality of jaws shiftable in the chuck body. First and second elements interconnected by a screw thread and engaged between the body and the jaws for shifting the jaws on the housing. A drive sleeve rotationally fixed to the first element is drivable by the motor.
Abstract: The present invention relates to a method for the continuous inline production of coated polymeric substrates or laminates and also to an apparatus for implementing this method.
Type:
Grant
Filed:
June 15, 2012
Date of Patent:
April 25, 2017
Assignee:
Evonik Roehm GmbH
Inventors:
Waldemar Kanzler, Thomas Hasskerl, Ghirmay Seyoum, Patrick Kliem, Werner Krebs, Dieter Foerster, Manfred Dannehl
Abstract: The present invention describes a method of removing ammonia from alcoholic solution in the presence of carbonic acid compounds while avoiding fouling by supplying the solution to be separated to the upper part of a distillation column and adjusting the temperature at the introduction point such that the ammonium salts of the carbonic acid compound in question are soluble in the in question at the top of the distillation column under the operating conditions.
Type:
Application
Filed:
March 13, 2015
Publication date:
April 13, 2017
Applicant:
Evonik Roehm GmbH
Inventors:
Alexander MAY, Willi PLOESSER, Markus Rolf ROSSMEISSL, Steffen KRILL, Martin KOESTNER
Abstract: The present invention relates to a process for preparing methyl methacrylate by a direct oxidative esterification of methacrolein with oxygen and methanol, which is conducted in the liquid phase at a pressure of 2 to 100 bar with a gold catalyst. According to the invention, the liquid phase is withdrawn continuously from the reactor and optionally enriched with oxygenous gas, the pH, after the withdrawal, is adjusted to a pH between 5 and 9 by means of addition of a basic solution and this liquid phase is conducted back into the reactor again to an extent of at least 50%.
Type:
Grant
Filed:
December 5, 2014
Date of Patent:
April 11, 2017
Assignee:
EVONIK ROEHM GmbH
Inventors:
Steffen Krill, Alexander Lygin, Torsten Balduf, Rudolf Burghardt, Andreas Tepperis, Matthias Groemping
Abstract: The invention relates to a process for the production of mould-foamed poly(meth)acrylimide (P(M)I) cores, in particular of polymethacrylimide (PMI) cores, which can be used by way of example in automobile construction or aircraft construction. A feature of this process is that polymer granules or polymer powder are charged to a compression mould where they are foamed. A particular feature of the process is that said two-shell compression mould has, respectively on both sides, a cavity that conforms to the shape and which serves for both the heating and the cooling of the granules and, respectively, of the rigid foam core produced therefrom.
Type:
Application
Filed:
May 13, 2015
Publication date:
March 30, 2017
Applicant:
EVONIK ROEHM GmbH
Inventors:
Kay BERNHARD, Ina LIEBL, Florian BECKER, Juergen RETTING, Denis HOLLEYN, Tim DENK, Alida Suzanne Blanche DONGMO FEUDJIO, Sebastian BUEHLER, Amin KRAATZ
Abstract: The present invention relates to a process for preparing methyl methacrylate by direct oxidative esterification of methacrolein and the preparation of methacrolein. It is a feature of this novel process that it was possible to distinctly increase the yield and the efficiency of the process compared to the prior art through a sequence of different distillation steps.
Type:
Grant
Filed:
August 27, 2014
Date of Patent:
February 28, 2017
Assignee:
EVONIK ROEHM GmbH
Inventors:
Steffen Krill, Matthias Groemping, Alexander Lygin, Torsten Balduf, Rudolf Burghardt
Abstract: The invention relates to a pH-dependent controlled release pharmaceutical composition, comprising at least one pharmaceutical active ingredient, with the exception of opioids, wherein the core is coated at least by one coating layer, controlling the release of the pharmaceutical composition, wherein the coating layer comprises a polymer mixture of i) 40-95% by weight, based on dry weight of the polymer mixture, of at least one water insoluble essentially neutral vinyl polymer or copolymer, and ii) 5-60% by weight, based on dry weight of the polymer mixture, of at least one anionic polymer or copolymer, which is insoluble in a buffered medium below pH 4.0 and soluble at least in the range from pH 7.0 to pH 8.0. characterized in that the coating layer further contains 110 to 250% by weight, calculated on dry weight of the polymer mixture, of a non-porous inert lubricant and the is present in an amount of at least 60% by weight calculated on the weight of core.
Type:
Grant
Filed:
September 25, 2007
Date of Patent:
January 31, 2017
Assignee:
EVONIK ROEHM GmbH
Inventors:
Hans-Ulrich Petereit, Hema Ravishankar, Ashwini Samel
Abstract: The present invention claims a process for preparing high-purity glycerol dimethacrylate comprising <500 ppm of glycidyl methacrylate, characterized in that an aftertreatment with acidic adsorbent is effected.
Type:
Application
Filed:
February 10, 2015
Publication date:
January 26, 2017
Applicant:
Evonik Roehm GmbH
Inventors:
Joachim KNEBEL, Volker HERZOG, Maik CASPARI
Abstract: A method for the reversible crosslinking of, for example, adhesives or coating materials, and a composition stable on storage at room temperature for implementing the crosslinking reaction. The reversible crosslinking method allows very rapid crosslinking even at a low first temperature, and undoing of the crosslinks at higher temperatures, thereby recovering thermoplastic processability and, for example, allowing the originally bonded substrates to be parted from one another again easily. A particular aspect is that a plurality of cycles of crosslinking and undoing of the crosslinks are possible with the present system. A feature of the system used for the reversible crosslinking is that it contains two components, A and B, where component A is a compound having at least two protected dithioester functionalities, preferably cyanodithioester functionalities, and component B is a compound having at least two diene functionalities.
Type:
Grant
Filed:
November 11, 2013
Date of Patent:
January 24, 2017
Assignee:
EVONIK ROEHM GmbH
Inventors:
Christopher Barner-Kowollik, Kim Klaus Oehlenschlaeger, Stefan Hilf, Friedrich Georg Schmidt, Nathalie Guimard, Jan Mueller
Abstract: A power drill has a housing holding a motor and a drive member rotatable about an axis. An arbor extending along the axis outside the housing is rotationally coupled by complementary formations with the drive member. A tube shaft on which is fixed a chuck body holding a plurality of axially displaceable jaws. A sleeve in the tube shaft is rotationally coupled to the arbor. A pusher element braced axially forward against the jaws extends axially rearward into the sleeve, and interengaging screwthreads on the sleeve and pusher element axially displace the pusher element and the jaws on relative rotation of the sleeve and pusher element. A setting sleeve rotationally coupled to the rear end of the tube shaft is axially displaceable between a tightening position engaging a slip coupling on the housing and a drilling position disengaged from the slip coupling and rotationally coupled to the arbor.
Abstract: The invention refers to a pharmaceutical or nutraceutical composition, comprising a) a core, comprising a pharmaceutical or a nutraceutical active ingredient, b) an inner coating layer comprising one or more salts of alginic acid and c) an outer coating layer comprising one or more water-insoluble polymers or copolymers and one or more water-soluble polymers, selected from the group of water soluble celluloses, polyvinyl pyrrolidones or polyethylene glycols or any combinations thereof. wherein the ratio by weight of the amount of the one or more salts of alginic acid in the inner coating layer to the amount of the one or more water-insoluble polymers or copolymers in outer coating layer is from 0.6 to less than 2.5:1.
Abstract: A novel process is described which allows N-isopropyl(meth)acrylamide to be obtained in high purity and yield in a simple manner, by reacting methacrylic anhydride with isopropylamine, optionally in a solvent.
Type:
Grant
Filed:
November 19, 2009
Date of Patent:
December 6, 2016
Assignee:
EVONIK ROEHM GmbH
Inventors:
Joachim Knebel, Wilhelm Karnbrock, Volker Kerscher
Abstract: The invention relates to a process for the production of prefoamed poly(meth)acrylimide (P(M)I) particles which can be further processed to give foam mouldings or composites. A feature of this process is that a polymer granulate is first heated and thus prefoamed in an apparatus by means of IR radiation of a wavelength suitable for this purpose. Said granulate can be further processed in subsequent steps, e.g. in a press mould with foaming to give a moulding or a composite workpiece with foam core.
Type:
Application
Filed:
December 3, 2014
Publication date:
November 17, 2016
Applicant:
EVONIK ROEHM GMBH
Inventors:
Kay BERNHARD, Ina LIEBL, Denis HOLLEYN, Christoph SEIPEL
Abstract: The invention relates to a gastric resistant pharmaceutical or nutraceutical composition, comprising a core, comprising a pharmaceutical or nutraceutical active ingredient and a gastric resistant coating layer onto the core, wherein the release of the pharmaceutical or nutraceutical active ingredient is not more than 15% under in-vitro conditions at pH 1.2 for 2 hours in medium according to USP with and without the addition of 40% (v/v) ethanol, wherein the gastric resistant coating layer comprises 10 to 100% by weight of one or more salts of alginic acid with a viscosity of 30 to 720 cP of a 1% aqueous solution.
Abstract: A drill chuck and a drill apparatus is provided that includes a drilling machine, which has a motor and a machine spindle that is supported in rotary fashion in a machine housing. The a drill chuck is connected to the machine spindle and can be moved between a clamping configuration and a drilling configuration and has a clamping sleeve and a chuck body in which clamping jaws are movably guided by a threaded connection. When a sliding sleeve is moved relative to the chuck body between a first position that corresponds to the clamping configuration and a second position that corresponds to the drilling configuration, a flow of force traveling from the motor via the machine spindle to the threaded connection is shifted to a flow of force traveling from the motor via the machine spindle to the chuck body and vice versa.
Abstract: The invention relates to novel particulate drug-delivery systems based on a polymer support containing at least one linear, branched or cross-linked polymer in a fraction of over 50 percent by weight in relation to the total weight of the support. The system is characterized in that at least one signal substance for transport through a biological barrier and at least one active ingredient are stored, the support, signal substance and active ingredient having no covalent links and no active-ingredient specific and signal substance specific coordinative links between one another.