Abstract: A process for the synthesis of an acetylenic hydrocarbon from an acetylenic carbinol which involves first replacing the hydroxyl group of the carbinol with a halogen to form a propargylic halide, dehalogenating the propargylic halide to form an allene, and isomerizing said allene to the desired acetylene. The present invention is particularly useful in the synthesis of Vitamin E.
Abstract: Imitation cheese is manufactured by a flow process from a plurality of edible ingredients comprising fat, protein, water, and flavor wherein the cheese product is set by the addition of an acidulant, in lieu of fermentation. The edible ingredients are introduced into an elongated, confined mixing zone in such a way that the acidulant and protein are in distinct and separate flow streams until in said zone, and in the zone are subjected, at a temperature of at least about 100.degree. F, to medium-to-high intensity axial and radial flow mixing. The mixing is continued until a substantially homogeneous mixture is obtained.
Type:
Grant
Filed:
September 10, 1976
Date of Patent:
August 29, 1978
Assignee:
SCM Corporation
Inventors:
Charles E. Rule, Juan B. Ilagan, Donald E. Miller
Abstract: Welding electrodes and welding wheels can be hot forged from powdered dispersion strengthened metal wherein the powder is pressed into a preform, heated, and then hot forged to form a full density workpiece to produce a desirable grain structure.
Abstract: Spent clay from the bleaching of C.sub.18+ domestic glyceride esters ("oils") is deoiled by slurrying such spent clay with aqueous alkali at a temperature of at least about 80.degree. C. and a weight ratio of water to clay of about 2-6:1 at a high "pH window" for such oil recovery.
Abstract: A pourable, whippable, edible emulsion, containing about 45 to 60% water, 20 to 30% fat, 7 to 20% sweetener, 0.5 to 2.5% dispersible protein, 0.1 to 0.75% thickener, 0.1 to 1.0% buffer and 0.75 to 2.5% emulsifier, where the emulsifier has a major proportion of propylene glycol monostearate or hexaglycerol distearate in the range from 0.5 to 1.5% and a minor proportion of a combination of ethoxylated sorbitan ester in the range from 0.3 to 0.6%, sorbitan monostearate in the range from 0.05 to 0.25% and lecithin in the range from 0 to 0.15%, is stable against separation and/or gelation for at least one year at room temperature under aseptic conditions and whippable to at least 200% overrun from about 40.degree. to 100.degree. F.
Abstract: An improved ultraviolet curable aqueous latex paint suitable for use as coil coatings comprises a high molecular weight primary latex binder in combination with minor amounts of an emulsified low molecular weight cross-linking agent adapted to cross-link the high molecular weight latex particles upon exposure to ultraviolet energy.
Type:
Grant
Filed:
December 13, 1976
Date of Patent:
August 15, 1978
Assignee:
SCM Corporation
Inventors:
Vincent Daniel McGinniss, Robert Joseph Seidewand, James Robert Erickson
Abstract: An electrocoating composition useful for electrocoating a paint from an aqueous solution onto a cathode conductive substrate can be cured with ultraviolet energy. The electrocoating composition containing an ultraviolet sensitizer uniformly electrodeposits on the cathode substrate to provide a paint film thereon containing a constant level of ultraviolet sensitizer relative to a reactive ethylenically unsaturated polymer.
Abstract: A heat-curable aqueous coil coating primer for priming metal coil comprises a film-forming binder phase comprising a heat-curable, water-dispersible polyurethane polymer, and a thermosetting or thermoplastic resinous latex in synergistic combination; and a pigment phase which includes corrosion-inhibiting pigment and, optionally, opacifying pigment.
Abstract: There is disclosed a dry mix adapted for hydration with chilled water to provide a pourable batter which produces on baking a crust resembling traditional yeast-leavened pizza crust; a process for preparing such pourable batter, and a unitary package of one container for said dry mix in combination with one or more containers for other snack food topping ingredients are also described.
Abstract: Substantial benefits and economies are realized in a process for obtaining free fatty acids from soap stock by first acidulating the soap stock to liberate fatty acids from the soap present, separating the resulting first acid oil and aqueous saline phases, recovering free fatty acids by vacuum distillation from this first acid oil phase, saponifyng the glyceride-rich still residue to generate additional soap, acidulating the saponified product to liberate additional fatty acids therefrom and separating the resulting second acid oil and aqueous saline phases. These additional fatty acids can be recovered as free acids by vacuum distillation from the separated second acid oil phase. It is sometimes advantageous to neutralize residual mineral acid in the first acid oil phase before distillation.
Abstract: Substituted cyclopropyl ketones can be made by heating unsaturated halo-ketones in the presence of alkaline earth metal carbonate and liquid glycol vehicle.
Type:
Grant
Filed:
April 11, 1977
Date of Patent:
June 27, 1978
Assignee:
SCM Corporation
Inventors:
James O. Bledsoe, Jr., Walter E. Johnson, Jr.
Abstract: Silica flatting agents having improved flatting and settling characteristics and which impart improved mar resistance to certain coatings are prepared by treating a silica hydrogel in the absence of dispersion or emulsifying agents with up to 14 parts by weight of specific mixtures of microcrystalline waxes and synthetic waxes in the respective ratios of from 1:1.5 to 1:12.
Type:
Grant
Filed:
February 17, 1976
Date of Patent:
June 27, 1978
Assignee:
SCM Corporation
Inventors:
Howard Joseph Cohen, Francis Michael Vojik
Abstract: A heat-curable, aqueous coating composition comprises a polymer having pendant primary and/or secondary amine groups and a cross-linking agent having alpha-, beta-ethylenically unsaturated carbonyl groups in aqueous dispersion. The amine groups are protonated to render the polymer water dispersible. In one preferred embodiment, the coating composition is useful in cathodic electrocoating.
Abstract: Ferric chloride from the selective chlorination of titaniferous material such as ilmenite is partially oxidized to obtain a chlorine-rich stream and byproduct iron oxide. Unreacted ferric chloride is separated as solid particles from said stream and at least a portion of said particles are returned to the chlorination operation for absorbing heat generated in such operation.
Abstract: A curable coating composition contains a polymer having pendant mercaptan groups and a bis-maleimide cross-linking agent. The mercaptan groups of the polymer cross-link with the bis-maleimide upon curing to form a fully cured coating. In a preferred embodiment, the coating composition serves as a cathodic electrocoating composition.
Abstract: A solar air heater comprises in array a plurality of structurally rigid, air-canalizing modular ducts communicating in parallel flow with a common header, each duct being about 4-6 meters long, about 1.2 meters wide, and about 100-650 cm.sup.2 in cross sectional area of its bottom plenum air passageway, and having a top, low velocity air plenum between a transparent cover and a solar heat collector element, and a bottom, higher velocity walled air plenum between said collector element and the base of the duct.
Abstract: A synthesis of novel Vitamin A intermediates from betaionone is described as well as a conversion of the intermediates to Vitamin A. The length of the conjugated aliphatic side chain of beta-ionone is increased while still ultimately obtaining the desired trans form of Vitamin A. In general, beta-ionone is ethynylated to ethynyl-beta-ionol, the hydroxyl of which is etherified to form an ethynyl-terminated, alkoxy-substituted, beta-ionol intermediate. The intermediate is coupled through its copper derivative with a compound like chloro-isopentenyl acetate to produce a C.sub.20 skeleton. By semi-hydrogenation, the acetylenic bond on the C.sub.20 skeleton is converted to an ethylenic bond, and by hydrolysis the terminal ester moiety is converted to a hydroxyl group. Treatment with a strong base removes the alkoxy group to produce Vitamin A.
Abstract: A flux for metal casting comprising an intimate blend of two parts is described. One part comprises a glass network former vitrified with a fluxing agent therefor, while the other part comprises a fluorine-providing material, said two parts being proportioned to provide on melting in the casting operation a glass of the desired fluorine content.
Abstract: A machine for simultaneously making typewritten and magnetic records, for editing magnetic records, and for automatically making typewritten copies of the magnetic record. A magnetic memory (a disc, say) is driven by the motor in the typewriter with the drive arrangement having a flywheel for reducing variations in memory speed, and a writing and reading transducer head is moved concomitantly with line feed of the printed record. The magnetic recording medium has concentric (or parallel) storage tracks so that each line appearing on the printed record is separately recorded in a different storage track of the memory to provide for easy editing and allow a simplified system for recording and playback.