Patents Assigned to Snia Viscosa Societa' Nazionale Industria Applicazioni Viscosa S.p.A.
  • Patent number: 4292194
    Abstract: A composition for increasing the light and heat stability of polyamides crises a copper salt bound to a halogen atom and to a hydrosoluble organic compound. The organic compound is able to maintain the CuX compound or its complexes in solution in water up to about 60.degree. C.
    Type: Grant
    Filed: June 15, 1979
    Date of Patent: September 29, 1981
    Assignee: Snia Viscosa Societa' Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Pierluigi Perazzoni, Luigi Bilancini
  • Patent number: 4289723
    Abstract: A process for the preparation of regenerated cellulose formed bodies from lutions of cellulose derivatives in organic solvents is disclosed. The cellulose derivatives is firstly precipitated in a coagulating bath constituted of a cellulose non-solvent, non-regenerating organic liquid, then the coagulated body is drawn in subsequent baths and the cellulose is regenerated. The drawing and the regeneration occur, at least in part, concurrently.
    Type: Grant
    Filed: July 25, 1979
    Date of Patent: September 15, 1981
    Assignee: Snia Viscosa Societa' Nazionale Industria Applicazioni Viscosa S.P.A.
    Inventors: Roberto Leoni, Alberto Baldini, Gianfranco Angelini
  • Patent number: 4285900
    Abstract: A method for preparing flame-resisting modacrylic fibers containing pentaent antimony oxide is described wherein the antimony oxide is suspended in a mixture of water and an organic solvent selected from dimethylformamide and dimethylacetamide and the suspension is then mixed with the viscose solution of the modacrylic polymeric material to be spun. The process yield high luster, flame-resisting modacrylic fibre of the "L.O.I. uprated" type.
    Type: Grant
    Filed: February 27, 1980
    Date of Patent: August 25, 1981
    Assignee: Snia Viscosa Societa' Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Giorgio Cazzaro, Antonino Cavallaro, Antonio Salan, Giancarlo Matera
  • Patent number: 4282637
    Abstract: A Venturi type nozzle for the texturization of yarns includes a hollow body o which compressed air is fed, a needle housed therein to which yarn is fed, and a plug, wherein the needle is provided with a longitudinal passage for the yarn, the air passes between the body and the needle, and yarn and air pass through a passage shaped like a Venturi cone in the plug, and wherein mutually facing portions of the needle head and of the plug have frusto-conical surfaces. The ratio of the axial distance between said frusto-conical surfaces to the diameter of the needle orifice is not more than 0.5, and preferably not more than 0.4. Preferably the conicity of the two frusto-conical surfaces is the same. Preferably also the outer surface of the needle head is cut off to provide a plane portion. The needle is axially displaceable and can be fixed in the desired axial position with respect to the body.
    Type: Grant
    Filed: September 21, 1978
    Date of Patent: August 11, 1981
    Assignee: Snia Viscosa Societa' Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Giuseppe Mosseri, Enrico Lucioni
  • Patent number: 4268666
    Abstract: A process for the dissolution of cellulose in organic solvents such as dihylformamide, dimethylacetamide, and N-methylpyrrolidone is described which comprises contacting the cellulose with an excess of paraformaldehyde and with the solvent at elevated temperatures, preferably higher than 115.degree. C. The amount of paraformaldehyde used preferably corresponds to at least 13 CH.sub.2 O units per anhydroglucosidic unit of the cellulose. The solution obtained can be rendered stable at room temperature by heating it under stirring to lower the paraformaldehyde content, preferably to not less than 8 CH.sub.2 O units per anhydroglucosidic unit. Formed bodies of regenerated cellulose can be obtained from said solutions by coagulating them in an aqueous bath, which may be alkaline or may be a mixture of water and the solvent of the solution, or even by evaporating the solvent.
    Type: Grant
    Filed: March 29, 1979
    Date of Patent: May 19, 1981
    Assignee: SNIA VISCOSA Societa Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Alberto Baldini, Roberto Leoni, Angelo Calloni, Gianfranco Angelini
  • Patent number: 4255101
    Abstract: A device for the continuous spinning of viscose rayon includes a main or cessing roller and a plurality of secondary or advancing rollers set askew with respect to the processing roller. The processing and advancing rollers are carried bracket-like by a support arm in which they are rotatively supported. The actuating structures are located in the vicinity of the supports of the respective rollers. The support arm is hollow and contains the roller supports and the actuating structures, and is located at the end of the unit at which the yarns leave the same after being processed. A plurality of spinning units are arranged in rows and the rows are born by a frame carrying all the necessary accessory devices. Means are provided for preventing the escape of fumes from the treatment liquors into the surrounding room.
    Type: Grant
    Filed: April 9, 1979
    Date of Patent: March 10, 1981
    Assignee: SNIA Viscosa Societa' Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Ugo Paoletti, Alessandro Volterra
  • Patent number: 4252766
    Abstract: A process for the preparation of formed bodies of regenerated cellulose f cellulose derivative solutions in dimethylsulphoxide is disclosed. The solution is extruded and coagulated in a coagulating bath which is a saline acqueous solution having a substantially non-alkaline or preferably a substantially neutral reaction, a formed body being thus produced.
    Type: Grant
    Filed: July 25, 1979
    Date of Patent: February 24, 1981
    Assignee: SNIA VISCOSA Societa Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Alberto Baldini, Roberto Leoni, Angelo Calloni, Gianfranco Angelini
  • Patent number: 4250295
    Abstract: Unsaturated polyester resins, not inhibited by atmospheric oxygen and not hibiting persistent residual surface tackiness are disclosed. These polyester resins contain at least one compound, the melting point whereof is higher than 30.degree. C., which has the formula R--X--OH, wherein R is an aliphatic or cycloaliphatic, saturated or unsaturated radical having 11-46 carbon atoms and X is a ##STR1## or --CHR', wherein R' is hydrogen, an aliphatic or cycloaliphatic radical.
    Type: Grant
    Filed: July 17, 1979
    Date of Patent: February 10, 1981
    Assignee: SNIA VISCOSA Societa Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Giovanni Corrado, Bruno Sopino
  • Patent number: 4240188
    Abstract: A process and a device for interlacing multifilament yarns includes forwang the yarn through an interlacing zone, to which an interlacing air jet is also conveyed through a nozzle, in a non-rectilinear trajectory which is essentially planar and symmetrical with respect to the jet axis, and under tension. The resultant of the tension forces have a line of application which ideally coincides with the jet axis and a direction opposite to that of the jet. The jet is so directed as to contact the yarn in a zone about the point of application of the resultant force. The nozzle includes an orifice located at the vertex of a convex surface directed towards the yarn trajectory, and means for guiding the yarn near the nozzle and for limiting the freedom of motion of the yarn.
    Type: Grant
    Filed: April 25, 1979
    Date of Patent: December 23, 1980
    Assignee: SNIA VISCOSA Societa Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventor: Giuseppe Zoina
  • Patent number: 4237274
    Abstract: A process for the preparation of solutions of cellulose derivatives from which formed bodies, such as fibres or films, of regenerated cellulose can be obtained by coagulation and regeneration, e.g. by wet spinning, is disclosed. The cellulose is transformed into a methylol derivative containing more than 2 units of formaldehyde per anydroglucosidic unit, which derivative is soluble in organic solvents of the class consisting of polar aprotic solvents constituted by N-substituted amides, pyridine and formamide. The methylol derivative is prepared by treating cellulose with paraformaldehyde and dimethylsulphoxide. The methylol derivative is then dissolved in one of the aforesaid solvents, preferably dimethylformamide or dimethylacetamide, to provide spinnable viscous solutions from which formed bodies can be obtained, e.g. by spinning in an aqueous alkaline bath.
    Type: Grant
    Filed: February 23, 1979
    Date of Patent: December 2, 1980
    Assignee: SNIA VISCOSA Societa' Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Roberto Leoni, Alberto Baldini, Gianfranco Angelini
  • Patent number: 4224210
    Abstract: Textile fibers having reduced inflammability and high luster, constituted copolymers of acrylonitrile, vinylidene chloride and a significantly homopolymerizable sulphonic comonomer are described. Significantly homopolymerizable comonomers are defined as monomers which homopolymerize with a conversion above 30.degree.-40.degree. under standard conditions set forth in the specification. A preferred class of such comonomers are the derivatives of acrylamidoalkanesulphonic acids, e.g. 2-acrylamido-2-methylpropane-sodium sulphonate. The fibers are spun from spinning dopes containing said copolymers in solution in organic solvent miscible with water and less than 4% of water. Said spinning dopes can be obtained by preparing a binary copolymer of acrylonitrile and the sulphonic monomer, in solution in the solvent, mixing the solution with a solution of acrylonitrile and vinylidene monomers in the same solvent, and subjecting the mixture to copolymerization.
    Type: Grant
    Filed: October 19, 1978
    Date of Patent: September 23, 1980
    Assignee: SNIA Viscosa Societa' Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Giorgio Cazzaro, Giancarlo Matera, Domenico Malgeri, Antonino Cavallaro
  • Patent number: 4223108
    Abstract: Modacrylic fibres from acrylonitrile, vinylidene chloride, and a sulphona comonomer, having reduced inflammability and high glossiness and dye yield are prepared by wet spinnning a polybend obtained by mixing two binary copolymers, the first from acrylonitrile and the sulphonated comonomer, and the second from acrylonitrile and vinylidene chloride. As the sulphonated comonomer, a significantly homopolymerizable monomer is used, viz. a monomer which homopolymerizes with a conversion of at least 30-40% by weight, in the presence of azobisisobutyronitrile catalyst, under given standard reaction conditions. Preferred sulphonated monomers are acid or salts of the acrylamidoalkanesulphonic series. The spinning dope is a polyblend solution in an organic solvent chosen among dimethylformamide, dimethylacetamide, and dimethylsulphoxide, mixed with water.
    Type: Grant
    Filed: November 2, 1977
    Date of Patent: September 16, 1980
    Assignee: SNIA VISCOSA Societa' Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Giorgio Cazzaro, Giancarlo Matera, Antonino Cavallaro, Marina Zani
  • Patent number: 4221692
    Abstract: A process for the production of synthetic linear polymers which contain atives is described, in which the polymer and the additives, both in the fluid state, are mixed, the resulting mixture is homogenized, and the homogenized mixture is in part conveyed to apparatus which uses it to make a product and in part is recycled, the recycled amount being preferably at least 5% of the total weight of the mixture. The preferred polymers are polyamides. The additives may be of any kind, e.g. antistatics, and they may be added as such or as a master batch consisting of a polymeric base containing finely particulated solid materials such as carbon black, matting agents or pigments.
    Type: Grant
    Filed: September 27, 1978
    Date of Patent: September 9, 1980
    Assignee: SNIA VISCOSA Societa Nazionale Industria Applicazioni Viscosa s.p.a.
    Inventors: Giorgio Lambertini, Gianfranco Sala
  • Patent number: 4218384
    Abstract: An omega-amino alkenoic acid containing from 8 to 12 carbon atoms is obtad from an omega-formyl alkenoic acid, which also contains from 8 to 12 carbon atoms, by reacting the acid with ammonia and hydrogen in the presence of a hydrogenation catalyst. Preferably the omega-formyl alkenoic acid is obtained by reacting a polyunsaturated hydrocarbon cycloolefin with ozone to form a mono-ozonide in solution with a polar solvent, the solution being in the form of a separable phase which can be transposed to form the starting omega-formyl alkenoic acid.
    Type: Grant
    Filed: March 13, 1978
    Date of Patent: August 19, 1980
    Assignee: SNIA VISCOSA Societa Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Francesco Siclari, Pietro P. Rossi
  • Patent number: 4198348
    Abstract: There is described a process for the preparation of amines of the type RNH.sub.2, wherein R represents a hydrocarbon radical containing up to 18 carbon atoms, in particular an aliphatic, arylaliphatic, cycloaliphatic or aromatic radical, the said process being characterized by the fact that an amide having the formula RCONH.sub.2, wherein R has the aforesaid meaning, is reacted, at a pH less than or equal to 7, firstly with gaseous chlorine, in the absence or in the presence of a diluent, and the N-chloroamide thus formed is subsequently reacted with an alkali hydroxide and/or an earth alkali hydroxide.
    Type: Grant
    Filed: June 8, 1978
    Date of Patent: April 15, 1980
    Assignee: SNIA VISCOSA Societa Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Franco Bertini, Carlo A. Pauri
  • Patent number: 4197260
    Abstract: Aliphatic, linear, saturated or unsaturated .alpha.,.omega.-diamines, conning from 8 to 12 carbon atoms, are prepared from the corresponding .alpha.,.omega.-dialdehydes by firstly converting the dialdehyde to di-imine by reaction with ammonia at less than 25.degree. C. and preferably less than 5.degree. C. in a mixture of water and of an organic solvent, and subsequently subjecting the di-imine to reduction with hydrogen in the presence of a catalyst which under the reaction conditions is capable of reducing all the iminic double bonds while leaving any olefinic bonds unchanged. When olefinic bonds are present and it is desired to obtain a saturated diamine, the unsaturated diamine obtained as hereinbefore stated is subjected to hydrogenation in the presence of a catalyst chosen among palladium, platinum, ruthenium and rodium. Preferred catalysts for the reduction of the di-imine are finely subdivided nickel and cobalt.
    Type: Grant
    Filed: August 4, 1978
    Date of Patent: April 8, 1980
    Assignee: Snia Viscosa, Societa Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Francesco Siclari, Pietro P. Rossi, Mario De Gaetano
  • Patent number: 4185450
    Abstract: There is described a process for making a texturized polycapronamide yarn erein the yarn is spun at a spinning speed below 1500 metres per minute and then subjected to a drawing and texturizing treatment including drawing, false twisting and heat treatment operations. The process is noted in that no more than two of said operations are carried out concurrently at least when the processing of the yarn is being started and the heat treatment is carried out under temperature conditions such as to set the false twist. There are also described the polycapronamide fibres and yarns texturized and manufactured by carrying out the process.
    Type: Grant
    Filed: December 22, 1977
    Date of Patent: January 29, 1980
    Assignee: Snia Viscosa Societa' Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Pietro Moruzzi, Francesco Cadau
  • Patent number: 4185062
    Abstract: A process for the high speed production of pre-oriented yarns from synthe linear polymers, in particular polyesters, comprising the steps of melt spinning the polymer by extrusion through a spinneret and, before winding up the extruded filament bundle, causing said bundle to pass through a zone wherein the ambient gas, in particular air, is caused to move in a direction parallel to and concurrent with that of the filament bundle progressing towards the wind up means.
    Type: Grant
    Filed: February 23, 1978
    Date of Patent: January 22, 1980
    Assignee: Snia Viscosa Societa Nazionale Industria Applicazioni Viscosa s.p.a.
    Inventor: Ettore Luzzatto
  • Patent number: 4178287
    Abstract: There is described a process for the purification of caprolactam from the idable impurities present therein, by means of a treatment with an oxidizing agent consisting of ozone, the process comprising the steps of dissolving the polluted caprolactam into a solvent inert to ozone, such as water, and of causing the ozone to bubble through the resulting solution, the concentration of the caprolactam in the solution being preferably comprised between about 40% and 78% by weight of caprolactam, and the treatment being preferably effected at a temperature between the freezing temperature of the solution and 70.degree. C.
    Type: Grant
    Filed: December 12, 1978
    Date of Patent: December 11, 1979
    Assignee: SNIA Viscosa Societa Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Roberto Mattone, Mario Catoni
  • Patent number: 4177214
    Abstract: There is described a procedure for preparing unsaturated or saturated .al.,.omega.-dialdehydes, wherein the monoozonide of the corresponding olefine undergoes hydrogenation in a solution and in presence of a catalyst system comprising(A) a noble metal comprising palladium or platinum and carried on a carrier comprising alumina, coal or barium sulphate, and(B) at least one compound of a heavy metal, and wherein, when a saturated dialdehyde is to be prepared, the unsaturated dialdehyde prepared as above undergoes a further catalytic hydrogenation in an organic solvent after removal of component (B) of the said system by means of a treatment with an ion-exchange resin acidified with sulphuric acid, the resin being of such quantity that the acid equivalents of the resin are at least equal to the equivalents of the heavy metal in the component (B) of said catalytic system.
    Type: Grant
    Filed: December 28, 1977
    Date of Patent: December 4, 1979
    Assignee: Snia Viscosa Societa' Nazionale Industria Applicazioni Viscosa S.p.A.
    Inventors: Francesco Siclari, Pietro P. Rossi, Cesare Guaita, Vito L'Acqua