Abstract: One or more in situ oil shale retorts are alternately operated in a combustion mode and a purge mode with a steam or water purge to produce a greater yield of shale oil. Hydrogen-rich off gases emitted during purging are mixed with the shale oil in a reactor in the presence of a catalyst, after being stripped of carbon dioxide, to produce a high quality shale oil. The reactor off gases, purge mode off gases, and/or hydrogen gases can also be used as the purge gas.
Abstract: A process is provided for retorting synthetic fuels, such as oil shale, and disposing of the tailings in an environmentally acceptable manner. In the process, raw synthetic fuels are retorted in a surface retort to produce synthetic oil. The synthetic oil is dedusted and upgraded. The retorted synthetic fuels can be combusted and moisturized to generate heat for the retort, produce steam, and facilitate handling of the residual waste material (tailings). A disposal site of spent synthetic fuels, spent upgrading catalyst, dust, and/or other material is formed with vapor breaks at one or more levels in the pile. Air is passed through the vapor breaks to evaporate leachate rather than permitting the leachate to carry pollutants from the pile into the ground and surrounding bodies of water.
Type:
Grant
Filed:
March 26, 1984
Date of Patent:
July 16, 1985
Assignees:
Standard Oil Company (Indiana), Gulf Oil Corporation
Inventors:
George H. Watson, David B. McWhorter, Adrian Brown
Abstract: High molecular weight linear aromatic amorphous copolymers comprising copolymers of p- , m-hydroxymethylbenzoic acid and mixtures thereof and a polyamide are prepared in ratios of 1:20 to 20:1. The resulting polymers have an inherent viscosity of at least 0.4 dl/g in a 60/40 phenol/tetrachloroethane solvent at 30.degree. C., good molding properties and improved hydrophylic properties as compared with nylon-6.
Abstract: A method for recovering upgraded liquid products by the hydroconversion of coal, coke, lignite, petroleum fractions, biomass, tar sands bitumen and shale oil are disclosed. In particular, the catalyst composition employed consists of a Group VIB metal component and a highly dispersed tin component.
Type:
Grant
Filed:
May 26, 1983
Date of Patent:
July 2, 1985
Assignee:
Standard Oil Company (Indiana)
Inventors:
John A. Mahoney, Regis J. Pellet, John J. Helstrom
Abstract: A comminuted, supported polymerization catalyst for alpha-olefins comprises (A) an organoaluminum compound and (B) a solid titanium-containing component formed by at least one halogen-containing compound of titanium(IV); (b) at least one electron donor; and (c) at least one hydrocarbon-insoluble magnesium-containing compound; and (2) retreating such comminuted product with (a) at least one halogen-containing compound of titanium(IV); and (b) a mixture containing ethylbenzoate and a substituted alkyl aromatic acid ester in which the substituent group has a negative Hammett constant; and optionally, at least one chlorocarbon and/or at least one haloalkylchlorosilane.
Type:
Grant
Filed:
October 24, 1983
Date of Patent:
July 2, 1985
Assignee:
Standard Oil Company (Indiana)
Inventors:
Bryce V. Johnson, Nicholas M. Karayannis, John S. Skryantz
Abstract: An improved process for the preparation of zero valent bis-arene transition metal compounds comprises reducing bis-arene transition metal (I) compound with a high-electropositive metal in an ether solvent at reflux temperature.
Abstract: An indirect hydrogen sulfide conversion process for the production of elemental hydrogen and sulfur. The process is based upon the electrochemical oxidation of iodide in an aqueous solution with a pH in the range of 0 to 1 at high current densities and current efficiencies. Hydrogen gas is produced concurrently with soluble triiodide. Treatment of a gaseous or non-aqueous liquid stream with electrolyte solutions containing triiodide yields a sulfur product in plastic form. The sulfur product can be recrystallized from a solvent to yield sulfur of comparable purity to that presently produced.
Abstract: Quaternary ammonium compounds containing anhydride groups are prepared by halogenating dimethylmaleic anhydride and reacting the halogenated product with a tertiary amine. The products are useful as surfactants, biocides and as cosurfactants in enhanced oil recovery.
Abstract: The Claus process gas is cooled in a condenser to condense most of the sulfur vapor in solid form. The gas leaving the condenser is then further cooled to condense water without producing substantially any sulfur in an undesirable form. The resulting gas of reduced water content is useful in Claus reaction, particularly the low temperature Claus reaction in which the product sulfur is adsorbed on the catalyst.
Abstract: In an acoustic logging system for providing information regarding selected parameters of the wall of a borehole in the earth, and of the rock formation which is adjacent the borehole, in which a single transmit/receive transducer system (T/RTS) mounted on a rotating assembly probes the wall of the borehole in a circular scanning pattern as a function of depth, the improvement which includes at least a second T/RTS mounted on the rotating assembly in known geometrical relation to the first T/RTS, and means to process two or more analog electrical scan signals for transmission over one or more electrical transmission channels in a logging cable. In particular, methods and means are described for transmitting multiple scan signals whereby a higher speed of logging is possible without loss of detail of the logs and without modification of the mechanical system of the logging sonde.
Abstract: A corrosion-resistant, multilayer photoelectrode for use in a photoelectrochemical cell and a process for producing said photoelectrode by preparing an effective layer of an insulator material on a base semiconductor and depositing a layer of conducting material on said layer of insulating material.
Abstract: A process is disclosed for electrolysis of a spent caustic solution in a three-compartment cell to produce alkali metal hydroxide, hydrogen and hydrogen sulfide. The hydrogen sulfide is oxidized to sulfur dioxide which is returned to the electrolysis cell to form sulfuric acid.
Abstract: Polyborate ester compositions are prepared by reacting ortho-boric acid with at least one alcohol or phenol in a substantially inert organic liquid, which is immiscible with water and has a boiling point in the range from about 80.degree. to about 300.degree. C. at standard pressure, and by continuously removing the water which is produced by the reaction.
Type:
Grant
Filed:
February 18, 1983
Date of Patent:
May 28, 1985
Assignee:
Standard Oil Company (Indiana)
Inventors:
Robert J. Basalay, C. Thomas West, Dennis G. Petrille
Abstract: Disclosed is an ambient temperature, rechargeable non-aqueous electrochemical cell having an active metal anode of the second kind, a cathode depolarizer, positive electrode current collector and an electrolyte comprising a solvent, a supporting electrolyte salt, and an active metal salt. Also disclosed is an electrolyte for non-aqueous active metal cells.
Type:
Grant
Filed:
March 2, 1983
Date of Patent:
May 28, 1985
Assignee:
Standard Oil Company (Indiana)
Inventors:
Keith B. Prater, Robert J. Thrash, John F. Connolly
Abstract: A high surface area, porous active carbon matrix containing a substantially uniform dispersion of a metal or metal-containing material and methods for making and using the same are disclosed.
Abstract: A coal liquefaction hydrotreating catalyst composition comprising particles of Component A consisting essentially of at least one Group VIB metal component supported on refractory inorganic oxide and particles of Component B consisting essentially of either cobalt and/or nickel component supported on a refractory inorganic oxide.
Abstract: Flow properties of polyamide-imide polymers are improved by the addition of semi-crystalline nylons or amorphous polyamides. These polymers are useful as engineering resins, laminates, and molded objects.
Abstract: A process for the manufacture of a phosphorus-vanadium and phosphorus-vanadium-co-metal catalysts suitable for use in the manufacture of maleic anhydride from butane which process comprises reacting at a temperature of about 0.degree. C. to about 200.degree. C. a vanadium compound in an organic ether solvent having about 2 to about 10 carbon atoms with a phosphoryl halide in the presence of water or an aliphatic alcohol having from about 1 to about 8 carbon atoms, eliminating the solvent and activating the catalyst by the addition of butane or other hydrocarbon feedstock and a phosphorus compound at a temperature of about 300.degree. C. to about 500.degree. C. The catalysts are useful for the manufacture of maleic anhydride from butane feedstock.