Abstract: Disclosed is a method for the preparation of 8-methoxy-4,8-dimethyl-1-(4-isopropylphenyl)-nonane which comprises the steps of(a) reacting para-isopropylbenzyl chloride with triphenylphosphine in the presence of a suitable solvent for a sufficient period of time and at a sufficient temperature to form an intermediate product in solution, para-isopropylbenzyl triphenylphosphonium chloride, and(b) reacting said solution with sodium methoxide, followed by methoxycitronellal to produce cis- and trans-8-methoxy-4,8-dimethyl-1-(4-isopropylphenyl)-1-nonene,(c) separating said intermediate product from the residual reactants, and(d) hydrogenating said cis- and trans-8-methoxy-4,8-1-(4-isopropylphenyl)-1-nonene, in the presence of a suitable solvent and catalyst to form 8-methoxy-4,8-dimethyl-1-(4-isopropylphenyl)-nonane.
Abstract: Compounds having the structural formula ##STR1## wherein R is hydrogen or halogen, R.sup.1 is halogen, R.sup.2 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sup.3 is hydrogen or C.sub.1 -C.sub.4 alkyl, and X is oxygen or methylene useful as post-emergent herbicides against annual and perennial grasses.
Abstract: A method of preparing N-phosphonomethylglycine comprising (a) reacting a substituted triazine with an acyl halide to form the N-carboalkoxymethyl-N-halomethyl amide of the acyl halide; reacting the said amide with a phosphite to form a phosphonate compound; and hydrolyzing said phosphonate to yield N-phosphonomethylglycine.
Abstract: The aluminum salt of N-phosphonomethylglycine as a unique compound which has utility as a post-emergence herbicide and is also useful as a plant growth regulator; and herbicidal and growth regulating compositions comprising the compound aluminum N-phosphonomethylglycine.
Abstract: The invention is directed to a process for recovering elemental phosphorus values from phosphorus-containing waste materials. The process comprises reducing the size of the solid particulate materials of the sludge and forming a uniform homogenous sludge which is filtered through a high-pressure thin-cake filter resulting in a filtrate high in phosphorus values.The invention also discloses a pump retrieval means for retrieving the sludge from contaminated disposal areas and a preconditioning dewatering means for thickening and clarifying the sludge prior to comminuting the solids contained therein and filtrating to recover the phosphorus values contained therein.
Type:
Grant
Filed:
October 3, 1983
Date of Patent:
November 6, 1984
Assignee:
Stauffer Chemical Company
Inventors:
David L. Dodson, Bruce D. Pate, Philip C. Rogers
Abstract: Herbicidally active thiocarbamates are employed in combination with N-methylthiocarbamylethyl-N'-carbamate having the formula ##STR1## In a typical application, the thiocarbamylethylcarbamate is included in sufficient quantity to lessen the rate of soil degradation of the thiocarbamate. As a result, the herbicidal effectiveness of the thiocarbamate is enhanced and prolonged, rendering a single application of the herbicide effective over a longer period of time.
Abstract: Polyurethane foams prepared with halogenated phosphoric acid flame retardant have low scorch and surface discoloration when prepared in the presence of a composition containing phenothiazine, 4,4'-thio-bis-(6-tertiary butyl meta cresol), and organophosphite.
Abstract: This invention comprises a catalytic component for polymerizing olefins comprising a solid support containing magnesium-halogen bonds, a transition metal halide of a metal selected from Groups IVB and VB of the periodic table, and an electron donor obtained by the steps comprising:(a) reacting an organometallic compound whose metal comprise members of Groups I to III of the periodic table with an alcohol, ROH, where R is an alkyl, cycloalkyl, or arylalkyl moiety having 1 to 16 carbon atoms, a polysiloxane, and a transition metal halide to form a solid;(b) treating the solid with a transition metal halide optionally in the presence of a polysiloxane to form a treated solid; and(c) reacting the treated solid with an electron donor and a transition metal halide to form the component.
Abstract: The degradation of a hydrolyzable ester containing functional fluid is monitored by placing in the fluid a probe-containing a corrodible metal sensor and measuring by electrical means the corrosion of the sensor.
Abstract: A method of preparing N-phosphonomethylglycine comprising (a) reacting a triazine with an acyl halide to form the N-cyanomethyl-N-halomethyl amide of the acyl halide; reacting the said amide with a phosphite to form a phosphonate compound; and hydrolyzing said phosphonate to yield N-phosphonomethylglycine.
Abstract: An unmilled catalytic component for polymerizing olefins with high activity to yield polymers with high stereoregularity and a narrow particle size distribution with a low weight percentage of small particles comprises a solid, unmilled support containing magnesium-halogen bonds, a transition metal halide of a metal selected from Groups IVB and VB of the periodic table, and electron donors.This catalytic component is obtained by steps comprising:(a) contacting a Mg(OR).sub.2 and/or Mn(OR).sub.2 compound with a Ti(OR).sub.4 compound to comprise a liquid, where R is a hydrocarbyl or halogenated hydrocarbyl moiety containing 1 to 20 carbon atoms or a halogen,(b) reacting the liquid with a fluid comprising a halogenating agent and treatment with an electron donor to form a treated solid, and(c) post-treating the solid with a transition metal halide.
Abstract: Dicalcium phosphate dihydrate composition having improved monofluorophosphate compatibility are prepared by the addition of magnesium oxide and pyrophosphoric acid to the reaction mixture, and terminating the reaction by which the dicalcium phosphate dihydrate is formed at a low pH.
Abstract: Herbicide antidote compounds having the formula ##STR1## in which X and X' are halogens, independently selected from the group consisting of chlorine, bromine and iodine; andR is selected from the group consisting of alkyl having 1-12 carbon atoms, inclusive; halophenyl wherein halo is selected from the group consisting of chlorine, bromine and iodine; and substituted alkoxy carbonyl wherein the alkoxy group has 1-8 carbon atoms, inclusive and the substituents are halogen selected from the group consisting of chlorine, fluorine, and iodine; or dioxane.
Abstract: Novel compounds having the structural formula ##STR1## wherein R.sub.1 and R.sub.2 are independently selected from the group consisting of hydrogen, halo, alkyl, haloalkyl, thioalkyl, thiohaloalkyl, alkoxy, cyano and nitro are provided. The compounds have various pharmacological effects, including cardiotropic, hypoglycemic, hypocholesterolemic and/or antiulcerative effects in mammals. Methods of achieving these various pharmacological effects in mammals by administering the compounds thereto are provided. Pharmaceutical compositions and formulations including the compounds are provided along with methods of synthesis of the novel compounds.
Type:
Grant
Filed:
June 23, 1983
Date of Patent:
September 4, 1984
Assignee:
Stauffer Chemical Company
Inventors:
Jack R. DeBaun, Ferenc M. Pallos, Kent E. Matsumoto, John H. Ross
Abstract: Herbicide antidote compounds and herbicidal compositions according consisting of an active herbicide compound and an antidote therefore and the methods of use of the antidote compound and compositions wherein the antidote compounds correspond to the formula ##STR1## wherein R.sub.1 is halo substituted phenyl, R.sub.2 and R.sub.3 are individually selected from alkyl C.sub.1 -C.sub.4 and alkenyl C.sub.3 -C.sub.4.
Abstract: This invention comprises a catalytic component for polymerizing olefins comprising a siliceous support containing magnesium halide, a transition metal halide, and an electron donor obtained by steps comprising:(a) infusing siliceous oxide with magnesium halide complexed with an alcohol to form a support;(b) reacting the support with an organometallic compound of a metal from Groups I to III of the periodic table to form an intermediate;(c) reacting the intermediate complex with an electron donor to form an intermediary complex; and(d) reacting the intermediary complex with a fluid comprising a transition metal halide.
Abstract: Propagation of plants, particularly solanaceous plants, from tissue cultures is improved by the presence of exogenous carbon dioxide in the atmosphere.
Abstract: The yield of alkyl vanadate formed by the reaction of vanadium pentoxide and an alkyl alcohol in the presence of an azeotroping agent and, preferably, a catalyst is improved by the present invention. It involves lowering, prior to the reaction, the amount of vanadium having a valence lower than +5 in the vanadium pentoxide reagent.
Abstract: The color of alkyl vanadate compounds that have become discolored is improved by treating the vanadates with an oxygen-containing gas, e.g., air, preferably at elevated temperature.