Abstract: As a new compound, mixed alkylsulfonium salts of N-phosphonomethylglycine having the formula ##STR1## wherein R.sup.1 is selected from the group consisting of long-chain saturated or unsaturated alkyl groups having from 12 to 20 carbon atoms and R.sup.2 and R.sub.3 are the same or different and are selected from the group consisting of lower alkyl having from 1-3 carbon atoms.
Abstract: A method of treating the residue generated in the production of diphenylphosphinous chloride is presented. The method comprises extracting the aluminum content of the residue by contacting the residue with an organic solvent to produce a mixture which when hydrolyzed results in a two-phase solution, the organic phase of which can be incinerated.
Abstract: An acid resistant phosphate ester functional fluid comprises phosphate ester basestock and an additive composition comprising: (1) N-alkyl-2-pyrrolidone, (2) epoxide, and (3) triazole. The functional fluid has utility for lubricating machinery. The additive composition may be prepared separately and used for imparting acid resistance to phosphate esters.
Abstract: A stabilized photopolymerizable composition comprising photopolymerizable ethylenically unsaturated monomeric compounds, a photoinitiator and at least one epoxide compound as a stabilizer.
Abstract: Polyurethane foams prepared from the reaction of polyester polyol with organic isocyanate have improved flame retardance and dripping ember retardance by incorporation of an additive comprising (1) halogenated flame retardant, and (2) organic solvent soluble glycoluril-formaldehyde material.
Abstract: A process for preparing phosphonomethylated amino acids comprising phosphonomethylating a N-carboxymethyl-S-methylene bisdithiocarbamate with formaldehyde and a phosphorus source to obtain a phosphonomethylated bisdithiocarbamate which is then hydrolyzed to the phosphonomethylated amino acid salt. Acidification yields the corresponding phosphonomethylated amino acid, e.g. glyphosate, or acid derivative.
Abstract: Flame retardant oligomeric phosphate ester compositions having the structural formula: ##STR1## are prepared, wherein R is C.sub.1 -C.sub.10 alkyl or haloalkyl, R.sup.1 and R.sup.2 can be the same or different and are hydrogen, C.sub.1 -C.sub.10 alkyl or haloalkyl and n is an integer from zero to about 10.The method of preparing the compositions comprises reacting P.sub.2 O.sub.5 with a trialkyl or tris(haloalkyl)phosphate in the presence of about 0.01% to about 5% of a phosphite at a temperature from about 0.degree.-200.degree. C. A polyphosphate ester having P--O--P bonds is formed which is then reacted with an epoxide to yield the oligomeric phosphate ester flame retardant compositions.Alternatively, a method of preparing similar compositions comprises reacting P.sub.2 O.sub.5 with a trialkyl or tris (haloalkyl)phosphite at a temperature from about 0.degree. C. to about 200.degree. C.
Abstract: Compounds having the formula ##STR1## in which R is C.sub.3 -C.sub.5 alkyl, C.sub.3 -C.sub.5 alkenyl, cyclopropyl, or ##STR2## R.sub.1 is C.sub.1 -C.sub.4 alkyl; R.sub.2 is C.sub.1 -C.sub.4 alkyl, and the side chain is substituted on the pyridyl ring at the 2- or 3-position, are effective insect repellents.
Abstract: A process is provided for the preparation of diaryl methylphosphonates through the reaction of triaryl phosphites with methanol in the pressure of a catalytic quantity of methyl iodide. The reaction is conducted at a temperature of from about 170.degree. C. to about 250.degree. C. New and useful derivatives are produced by reaction of the diaryl methylphosphonates with polyols or amines.
Abstract: A mixture of the herbicides napropamide and butam has been found to exhibit synergistic results, particularly in pre-emergence surface application or pre-plant incorporation, and for controlling weeds in the presence of a rapeseed crop.
Abstract: A protective colloid for use in an interfacial polymerization process comprising a graft copolymer of polyvinyl alcohol and methyl vinyl ether/maleic acid.
Abstract: A high acid monocalcium phosphate can be prepared by partially neutralizing phosphoric acid with lime. A substantially non-caking product can be made by hydrating the high acid product dried to a L.O.I. of between about 16% to less than 18.5% with water to an L.O.I. of from 18.5% to about 23% and drying to a free water content of less than 1%. The product is useful in effervescent dry beverage mixes and pharmaceuticals.
Abstract: A method for preparing N-phosphonomethylglycine comprising (a) O,O-dialkylaminomethylphosphonate with formaldehyde to produce a triazine; (b) reacting the triazine formed in step (a) with an acyl halide to form the O,O-dialkyl-N-phosphonomethyl-N-chloromethyl acetamide of the acyl halide; (c) reacting the amide formed in step (b) with metal cyanide to form O,O-dialkyl-N-cyanomethyl-N-acetamide; and (d) hydrolyzing the acetamide formed in step (c) to yield N-phosphonomethylglycine.
Abstract: Compounds having the formula ##STR1## in which R is selected from the group consisting of chloro and fluoro;R.sub.1 -R.sub.4 are each independently selected from the group consisting of hydrogen and 1-4 carbon alkyl; andX is oxygen or sulfur protect crops from thiocarbamate herbicidal injury.
Abstract: The color of alkyl vanadate compounds that have become discolored is improved by treating the vanadates with a nitrogen oxide oxidant to achieve the color improvement.
Abstract: Herbicide antidote compounds and herbicidal compositions consisting of at least one active thiolcarbamate herbicide compound and an antidote therefor and the methods of use of the antidote compound and compositions wherein the antidote compounds correspond to the formula ##STR1## wherein R is haloalkyl having 1-4 carbon atoms, inclusive, and n is 2 or 3.
Abstract: Waste heat is recovered during the production of phosphorus pentoxide by a process comprising the combustion of phosphorus and the passing of the combustion gases through a fluid bed, wherein the solids making up the fluid bed are utilized to recover heat values derived from the process by contacting the same with water to produce steam.
Abstract: A novel catalytic system for polymerizing olefins comprises:(a) a cocatalytic component containing an organometallic compound of Groups I-III of the periodic table, and(b) a catalytic component containing titanium obtained by:(i) copulverizing a substantially anhydrous magnesium compound containing halogen or manganese compound containing halogen with: a phenol, an organic polymer containing silicon, a titanium halide, and an electron-donor compound to produce a copulverized product, and(ii) reacting the copulverized product with a liquid titanium compound containing halogen.The invention also encompasses the novel catalytic component, processes for preparing the catalytic component containing titanium, and the use of the novel catalytic system for polyermizing olefins.
Abstract: The removal of SO.sub.2 from two or more gas streams of differing SO.sub.2 content is accomplished by feeding each of the streams to an absorbent so that the more dilute SO.sub.2 -containing stream or streams is supplied to the absorbent upstream from the point at which the more concentrated stream or streams is supplied. By supplying the gas streams to the absorbent flow in ascending order of SO.sub.2 concentration, the amount of SO.sub.2 absorbed by the absorbent flow is increased.