Abstract: A protective colloid for use in an interfacial polymerization process comprising a graft copolymer of polyvinyl alcohol and methyl vinyl ether/maleic acid.
Abstract: The invention provides a process for rendering textiles or barrier fabric material flame retardant and smolder resistant with a flame retardant and smolder resistant composition comprised of an aminophosponate ester in combination with a thermosetting, nitrogen-containing resin and preferably a reactive elastomeric latex.
Abstract: A substantially agglomeration-free, finely divided catalyst component which is suitable for use as a cocatalyst with organoaluminum compounds in the polymerization of alpha olefins, which is formed by grinding a titanium trichloride material, an effective amount of an electron pair donor compound to enhance the performance of said catalyst component, and an effective amount for agglomeration control of an agglomeration control agent. The agglomeration control agent is effective in either reducing the attractive forces between the finely divided particles in the catalyst component or by preventing the close approach of these particles which would result in agglomeration.
Type:
Grant
Filed:
March 21, 1983
Date of Patent:
April 24, 1984
Assignee:
Stauffer Chemical Company
Inventors:
Gregory G. Arzoumanidis, Richard F. Gold, Christian G. Michel
Abstract: Diary whey, a waste product of cheese production, is fermented with Xanthomonas campestris ATTCC 31923 to produce a fermented whey product containing a thickening polymer. The fermented whey product can be used as a thickening agent by the food industry. Yeast extract may be added to the whey prior to fermentation. Xanthomonas campestris ATCC 31923 is a novel microorganism having the ability to grow on lactose as the sole source of carbon.
Abstract: Dairy whey, a waste product of cheese production, is fermented to produce a thickening agent for use in the food industry by forming a fermentation broth containing whey and sucrose, and fermenting the broth with Leuconostoc mesenteroides ATCC 14935. The fermentation broth can optionally contain a water-soluble phosphate as a pH buffer and yeast extract.
Abstract: A method of preparing N-phosphonomethylglycine comprising: (a) reacting O,O-dialkylaminomethylphosphonate with formaldehyde to produce a triazine compound; (b) reacting the triazine formed in step (a) with an acyl cyanide to form the O,O-dialkyl-N-phosphonomethyl-N-cyanomethyl amide; and (c) hydrolyzing the amide formed in step (b) to yield N-phosphonomethylglycine.
Abstract: The invention provides a process for rendering textiles or barrier fabric material flame retardant and smolder resistant with a flame retardant and smolder resistant composition comprised of an aminophosponate ester in combination with a thermosetting, nitrogen-containing resin and preferably a reactive elastomeric latex.
Abstract: The compound 3-(4-tolysulfonyl) acrylonitrile, when incorporated in meat products together with an alkali metal nitrite salt, has been found effective in inhibiting the growth of Clostridium botulinum and consequent production of toxin in meat products on storage.
Abstract: Sulfur dioxide (SO.sub.2) is absorbed from waste gases by absorbing SO.sub.2 in an aqueous absorbent comprising soluble sulfite in an absorber; stripping the SO.sub.2 from the absorbent; absorbing the stripped SO.sub.2 in a separate absorbent for the SO.sub.2 ; and reacting the thus absorbed SO.sub.2 in a liquid Claus reactor forming sulfur. In a preferred embodiment, the gas from the stripping step is subjected to a condensation step in a heat exchanger boiler where steam ingoing to the stripper is generated.
Abstract: Dairy whey, a waste product of chesse production, is fermented with an organism to produce a whey product containing a thickening polymer that serves as a thickening agent. Fermentation is carried out by forming a fermentation broth of whey and glucose, and optionally a water soluble phosphate and/or yeast extract and then fermenting the broth with Xanthomonas campestris ATCC 31922. The resultant fermented whey product is used as a thickening agent in the food industry.
Abstract: Herbicide antidote compounds and herbicidal compositions according consisting of an active herbicide compound and an antidote therefore and the methods of use of the antidote compound and compositions wherein the antidote compounds correspond to the formula ##STR1## in which R.sub.1 is haloalkyl, R.sub.2 is selected from haloalkyl and phenyl.
Abstract: A method for the preparation of N-phosphonomethylglycine is disclosed which comprises the steps of:(1) reacting N-(diethylphoshonomethyl)iminobisethanol in an oxygen free atmosphere with an alkali metal hydroxide selected from the group consisting of sodium hydroxide and potassium hydroxide, in the presence of water as solvent and a catalyst selected from the group consisting of zinc oxide and cadmium oxide at a high temperature and pressure for a sufficient period of time to cause the reaction to go to completion, and(2) acidifying the product formed.
Abstract: An herbicide antidote composition comprising:(a) an herbicidally effective amount of a pyrrolidone compound of the formula ##STR1## in which X is hydrogen, chlorine, or methyl;Y is hydrogen, chlorine or bromine;Z is chlorine or bromine;R is hydrogen, alkyl, acetyl, chlorine, bromine, fluorine, iodine, trifluoromethyl, nitro, cyano, alkoxy having 1 to 4 carbon atoms, inclusive, alkylthio having 1 to 4 carbon atoms, inclusive, alkylsulfinyl having 1 to 4 carbon atoms, inclusive, alkylsulfonyl having 1 to 4 carbon atoms, inclusive, trifluoromethylthio, trifluoromethylsulfinyl, trifluoromethylsulfonyl, pentafluoropropionamido, or 3-methylureido;R.sub.1 is hydrogen, alkyl having 1 to 4 carbon atoms, inclusive, chlorine or trifluoromethyl; andR.sub.
Type:
Grant
Filed:
December 30, 1981
Date of Patent:
April 10, 1984
Assignee:
Stauffer Chemical Company
Inventors:
Charles J. Duerksen, Benjamin P. Rodriquez
Abstract: A method for the production of N-phosphonomethylglycine which comprises reacting N,N-bis(phosphonomethyl)glycine having the formula ##STR1## with glycine in the presence of a hydrogen ion donor and of water, and at a sufficient temperature and at a sufficient pressure to cause the reaction to go to completion.
Abstract: A novel catalytic system for polymerizing olefins comprises:(a) a component containing an organometallic compound of Groups I-III of the periodic table, and(b) a component containing titanium obtained by steps comprising:treating a ferrous chloride support with at least one organic electron donor to form an adduct.milling the ferrous chloride, andpost-treating the milled ferrous chloride adduct with a liquid titanium compound containing halogen.The invention also encompasses the novel catalytic component supported by ferrous chloride, processes for preparing the catalytic component, and the use of the novel catalytic system for polymerizing olefins.
Abstract: An herbicide antidote composition comprising:(a) an herbicidally effective amount of a pyrrolidone compound of the formula ##STR1## in which X is hydrogen, chlorine or methyl;Y is hydrogen, chlorine, or bromine;Z is chlorine or bromine;R is hydrogen, alkyl, acetyl, chlorine, bromine, fluorine, iodine, trifluoromethyl, nitro, cyano, alkoxy, alkylthio, alkylsulfinyl, alkylsulfonyl, trifluoromethylthio, trifluoromethylsulfinyl, trifluoromethylsulfonyl, pentafluoropropionamido, or 3-methylureido;R.sub.1 is hydrogen, alkyl, chlorine, or trifluoromethyl; and,R.sub.
Abstract: A process for preparing phosphonomethylated amino acids comprising protecting a primary amino acid ester or salt with a carbon dioxide protecting group, phosphonomethylating the protected amino compound formed, and removing the carbon dioxide protecting group by acidification.
Abstract: Novel tri-mixed alkylsulfonium salts of N-phosphonomethylglycine are disclosed herein, having the formula ##STR1## in which R.sub.1, R.sub.2, and R.sub.3 represent C.sub.1 -C.sub.12 alkyl and n is zero or one, wherein no more than two of R.sub.1, R.sub.2, or R.sub.3 are identical. The compounds are useful in regulating the natural growth or development of plants and as herbicides.
Abstract: An improved method for preparing phenylphosphonous dihalide comprises reacting PCl.sub.3 and benzene in an electrically heated fluid bed reactor.