Abstract: A method of moving a print head between a plurality of partitioned chambers in a 3D printer includes providing the 3D printer having a thermal barrier having an area defined by a length and width, wherein a print head nozzle can be positioned through the thermal barrier along the width or the length and at least two partitioned chambers below the area of the thermal barrier, wherein a first chamber comprises a printing chamber and a second chamber comprises a chamber providing another functionality. The method includes raising the print head in a z direction from the second chamber to above the thermal barrier and moving the print head in a x-y direction from above the second chamber over the partition to a location above the first chamber. The method also includes lowering the print head in the z direction and into the first chamber such that an extrusion port of a nozzle of the print head is proximate a x-y print plane.

Abstract: A consumable assembly for a 3D printer includes a spool carrying wound filament. A 3D printer includes a print head configured to receive filament material and a spool cabinet configured to have a filament spool positioned therein to provide a controlled environment for filament on the filament spool. A dock of the 3D printer is located outside of a chamber of the spool cabinet and is configured to receive a filament key fob, including a spool chip, of the filament spool to maintain the spool chip outside of the controlled environment of the chamber.

Abstract: The present invention is directed to methods of manufacturing certain biodegradable and/or compostable biobased particulate compositions for additive manufacturing which incorporate a homopolymer or copolymer of 3-hydroxy butyric acid. Specifically, the methods of manufacturing claimed and described herein include the steps of providing a starting material comprising said 3-hydroxy butyric acid; optionally, compacting the starting material to obtain a compacted material; heating to a temperature sufficient to prevent sticking to obtaining an annealed material; and milling into a powder having specified particle size values. In addition, the present invention is directed to additive manufacturing processes utilizing the biodegradable and/or compostable biobased particulate compositions elsewhere described, along with the articles printed therefrom.

Abstract: Matrix-filled liquid radiation curable resin compositions for additive fabrication are described and claimed. Such resins include a cationically polymerizable component that is an aliphatic epoxide, a multifunctional (meth)acrylate component, a cationic photoinitiator, a free-radical photo initiator, and a matrix of inorganic fillers, wherein the matrix further constitutes prescribed ratios of at least one microparticle constituent and at least one nanoparticle constituent. Also described and claimed is a process for using the matrix-filled liquid radiation curable resins for additive fabrication to create three dimensional parts, and the three-dimensional parts made from the liquid radiation curable resins for additive fabrication.

Abstract: A method for 3D printing a part in a layer-wise manner includes providing a pool of polymerizable liquid in a vessel over a build window and positioning a downward-facing build platform in the pool, thereby defining a build region above the build window. The method includes selectively curing a volume of polymerizable liquid in the build region by imparting electromagnetic radiation through the build window to form a printed layer of the part adhered to the build platform and scanning at least a portion of the build window with monochromatic, polarized light along a plane of incidence. The method includes measuring a change in intensity and polarity of the light to obtain information about the printed layer. The method includes raising the build platform to a height of a next layer to be printed and modifying the electromagnetic energy imparted into the next layer based upon the obtained information to print a next layer.

Abstract: Liquid radiation curable compositions are disclosed which are suitable for hybrid (i.e. cationic and free-radical) polymerization when processed via additive fabrication equipment utilizing sources of actinic radiation with peak spectral intensities in the UV/vis region. According to one aspect, the compositions possess a first photoinitiator that is an iodonium salt of a non-fluorinated borate anion. According to another aspect, the composition is substantially devoid of a Norrish Type I and/or Type II photoinitiator. Also disclosed are methods of creating three-dimensional parts via additive fabrication processes utilizing sources of actinic radiation with peak spectral intensities in the UV/vis region employing liquid radiation curable compositions suitable for hybrid polymerization, and the parts cured therefrom.

Abstract: An additive manufacturing system including a base assembly and a tray assembly. The base assembly includes a build window, substantially transparent to electromagnetic radiation; a projection system configured to project electromagnetic radiation toward an upper surface of the build window; and a tray seat arranged around a perimeter of the build window. The tray assembly is configured to engage with the base assembly in an engaged configuration and includes: a tray structure defining a registration feature configured to engage the tray seat to locate an aperture proximal to the upper surface of the build window in the engaged configuration; and a separation membrane that is configured to laminate across the upper surface of the build window in response to an evacuation of gas from an interstitial region and configured to separate from the build window in response to injection of gas into the interstitial region.

Abstract: A method for producing an object comprises the step of producing the object by means of an additive manufacturing process from a construction material. The construction material comprises a first polyurethane polymer which has: a weight percentage ratio of O to N of ?2 to ?2.5, determined by elementary analysis; a weight percentage ratio of N to C of ?0.1 to ?0.25, determined by elementary analysis; a full-width at half maximum of the melting peak of ?20 K, determined by dynamic differential scanning calorimetry DSC (2nd heating at heating rate 20 k/min); and a difference between the melting temperature and the recrystallisation temperature of ?5 K and ?100 K, determined by dynamic differential scanning calorimetry DSC (2nd heating) at a heating and cooling rate of 20 K/min.

Abstract: The present disclosure is directed to pulverulent thermoplastic polymer blends comminuted to a particle size of less than 300 ?m. The pulverulent thermoplastic polymer blends can include a first thermoplastic polyurethane and a second thermoplastic polyurethane at a weight ratio of from about 90:10 to about 30:70 first thermoplastic polyurethane to second thermoplastic polyurethane. The first thermoplastic polyurethane can include a reaction product of a first reaction mixture consisting of or consisting essentially of an aliphatic diisocyanate having a number average molecular weight of from 140 g/mol to 170 g/mol and an aliphatic diol having a number average molecular weight of from 62 g/mol to 120 g/mol.

Abstract: A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group. Either or both of the particulate composition and the liquid composition comprise an initiator capable of initiating polymerization of at least the first resin. At least the first resin undergoes melting and polymerization in a plurality of the locations where the liquid composition has been selectively deposited.

Abstract: A layer-by layer method for additive manufacturing that includes: photocuring a first volume of resin to form a layer of a build at an upper surface of a separation membrane laminated over a build window; injecting a fluid into an interstitial region between the separation membrane and the build window; retracting the build from the build window; evacuating the fluid from the interstitial region; and photocuring a second volume of liquid resin to form a subsequent layer of the build between an upper surface of a separation membrane and the previous layer of the build.

Abstract: A method for calibrating a 3D printer includes the steps of providing information obtained in a factory calibration indicating a center of an inner diameter of a tip orifice in a metal extrusion nozzle and a center of a tip surface for the nozzle and inductively sensing the nozzle with an eddy current sensor when secured to a print head on a gantry or robotic arm of the 3D printer to identify a sensed location of the center of the tip surface of the nozzle. The method includes determining a location of the center of the inner diameter of the tip orifice on the nozzle on the print head and utilizing the provided information to locate the center of the inner diameter of the tip orifice.

Abstract: A consumable assembly for a 3D printer includes a spool carrying wound filament. The spool is configured to be installed into a spool cabinet to maintain the filament in a controlled environment. A filament key fob that carries a spool chip programmed with identification data for the consumable assembly is tethered to the spool. The filament key fob is configured to be received in a dock of the 3D printer outside of a controlled environment of a chamber of the spool cabinet while remaining tethered to the spool installed in the chamber of the spool cabinet.

Abstract: A method includes: accessing a first selection of a first test variable; based on the selection, photocuring a first test build by varying a value of the first test variable over a first set of test regions; accessing a first set of measurements of the first test build; calculating a target range of the first test variable based on the first set of measurements; accessing a second selection of a second test variable; based on the second selection, photocuring a second test build by varying a value of the second test variable over a second set of test regions while maintaining a target value of the first test variable within the target range of the first test variable; accessing a second set of measurements of the second test build; and calculating a second target range of the second test variable based on the second set of measurements.

Abstract: A method of processing a water-dispersible, polymer-based material in a bath of a water-based solution includes providing a molten water-dispersible polymer material having monovalent cations. The water-dispersible polymer is introduced into a water bath comprising multivalent salt dissociated in the water bath into multivalent cations and anions. The water-dispersible polymer is retained within the water bath with the dissociated multivalent cations to quench the water-dispersible, polymer-based material while the monovalent cations proximate a surface of the water-dispersible polymer are exchanged with multivalent cations to form a barrier that temporarily resists dispersion of the water-dispersible, polymer-based material within the water bath. The method includes removing the water-dispersible polymer from water bath after the exchange step.

Abstract: A method for printing a 3D part in a layer-wise manner includes providing a pool of polymerizable liquid in a vessel over a build window and positioning a downward-facing build platform in the pool, thereby defining a build region above the build window. The method includes selectively curing a volume of polymerizable liquid in the build region by imparting electromagnetic radiation through the build window to form a printed layer of the part adhered to the build platform and actively cooling the build window to remove energy imparted by the electromagnetic radiation and the polymerization reaction of the polymerizable liquid such that the printed layer is between about 1° C. and about 30° C. below an average part temperature prior to raising the print layer and printing the next layer.