Patents Assigned to Studiengesellschaft
  • Patent number: 5026877
    Abstract: Disclosed are new 1,3-dioxenones having the formulae ##STR1## in an optically pure state, a process for preparing same and the use thereof.
    Type: Grant
    Filed: May 10, 1989
    Date of Patent: June 25, 1991
    Assignee: Studiengesellschaft Kohle mbH
    Inventors: Kurt Schaffner, Martin Demuth
  • Patent number: 5007991
    Abstract: The invention relates to organoaluminum electrolytes for the electrolytic deposition of high-purity aluminum, which are characterized in that they contain mixtures of organoaluminum complex compounds of the type MF.2 AlR.sub.3 (A), wherein M represents potassium or mixtures of K with a maximum of about 15% by mole of sodium, as well as trialkylaluminum AlR.sub.3 (B) which has not been complexed to an alkali metal fluoride in a molar ratio of A:B of from 4:0.6 to 4:2, as well as a polyfunctional Lewis base of the type R'-OCH.sub.2 CH.sub.2 -OR" (C) in a molar ratio of B:C of from 1:0.5 to 1:1. The organyl radicals R in A are ethyl groups (Et), methyl groups (Me) and iso-butyl groups (iBu) in a molar ratio of Et:Me:iBu as 3:m:n, wherein m and n are numerical values of between 1.1 and 0 and the sum (m+n) is from 0.75 to 1.4. As the solvent for said electrolytes there are used from 3 to 4.5 moles, relative to the amount of alkali metal fluoride employed, of an aromatic hydrocarbon which is liquid at 0.degree. C.
    Type: Grant
    Filed: June 5, 1990
    Date of Patent: April 16, 1991
    Assignee: Studiengesellschaft Kohle mbH
    Inventors: Herbert Lehmkuhl, Klaus-Dieter Mehler
  • Patent number: 4972729
    Abstract: An apparatus for conducting split sampling gas chromatography of a liquid sample comprisinga vaporization chamber to receive a needle of a syringe,a first tube to receive the needle,a second tube directly adjacent the first tube and running substantially along the entire length of the first tube, the second tube accommodating a downward flow of cooling gas,a third tube surrounding the first tube and the second tube, thereby creating a annular space between the third tube and the first tube, the annular space accommodating an upward flow of gas exiting the third tube.
    Type: Grant
    Filed: August 9, 1989
    Date of Patent: November 27, 1990
    Assignee: Studiengesellschaft Kohle mbH
    Inventors: Gerhard Schomburg, Ulrich Hausig
  • Patent number: 4957727
    Abstract: A process for the production of hydrides of magnesium, comprising reacting magnesium with hydrogen in the presence of magnesium.
    Type: Grant
    Filed: April 27, 1988
    Date of Patent: September 18, 1990
    Assignee: Studiengesellschaft Kohle mbH
    Inventor: Borislav Bogdanovic
  • Patent number: 4925536
    Abstract: Disclosed are electrolytes and processes for the metal-plating of metallic materials, and more specifically low-alloy high-strength steels, which processes are characterized in that adhesion-bonding layers of iron, iron and nickel, nickel, cobalt, copper or alloys of said metals or Sn-Ni alloys are electrodeposited on said metallic materials from non-aqueous electrolytes, and then aluminum is electrodeposited thereon in a per se known manner.
    Type: Grant
    Filed: February 2, 1989
    Date of Patent: May 15, 1990
    Assignee: Studiengesellschaft Kohle mbH
    Inventors: Herbert Lehmkuhl, Klaus-Dieter Mehler
  • Patent number: 4912274
    Abstract: The invention relates to azaphospholenes of the type ##STR1## wherein R.sub.1 and R.sub.2 may be alkyl, aryl and aralkyl groups, processes for preparing same and the use thereof.
    Type: Grant
    Filed: July 26, 1989
    Date of Patent: March 27, 1990
    Assignee: Studiengesellschaft Kohle mbH
    Inventors: Gunther Wilke, Jaroslaw Monkiewicz, Herbert Kuhn
  • Patent number: 4900866
    Abstract: The invention relates to azaphospholenes of the type ##STR1## wherein R.sub.1 and R.sub.2 may be alkyl, aryl and aralkyl groups, processes for preparing same and the use thereof.
    Type: Grant
    Filed: September 19, 1988
    Date of Patent: February 13, 1990
    Assignee: Studiengesellschaft Kohle mbH
    Inventors: Gunther Wilke, Jaroslaw Monkiewicz, Herbert Kuhn
  • Patent number: 4895032
    Abstract: In the split sampling gas chromatographic process for analyzing a sample by introducing the needle of a syringe into the vaporization chamber of a gas chromatographic column, discharging a liquid sample from the syringe needle into the vaporization chamber, and passing the vapors of the sample through a chromatographic column along with a carrier gas, the improvement which comprises passing a cooling gas over the entire length of the syringe needle, thereby to cool the sample passing therethrough. The cooling may be effected by a flow of liquid or gaseous CO.sub.2, air or nitrogen through a tube which surrounds the needle over its length during introduction of the sample.
    Type: Grant
    Filed: September 13, 1988
    Date of Patent: January 23, 1990
    Assignee: Studiengesellschaft Kohle MbH
    Inventors: Gerhard Schomburg, Ulrich Hausig
  • Patent number: 4864037
    Abstract: Disclosed are new 1,3-dioxenones having the formulae ##STR1## in an optically pure state, a process for preparing same and the use thereof.
    Type: Grant
    Filed: July 21, 1987
    Date of Patent: September 5, 1989
    Assignee: Studiengesellschaft Kohle mbH
    Inventors: Kurt Schaffner, Martin Demuth
  • Patent number: 4832934
    Abstract: The present invention relates to [Mg.sub.2 X.sub.3 (Ether)y].sup.+ [AlH.sub.4 ].sup.- in whichX is halogen,ether is an aliphatic or cyclic ether, andy is from 0 to 6.
    Type: Grant
    Filed: December 7, 1987
    Date of Patent: May 23, 1989
    Assignee: Studiengesellschaft Kohle mbH
    Inventors: Borislav Bogdanovic, Manfred Schwickardi
  • Patent number: 4829772
    Abstract: A method of storing and transforming heat and of generating cold by means of two metal-hydride and metal-hydrogen systems operating in conjunction in closed circulation at different temperatures. Magnesium hydride, especially active magnesium hydride, is employed as a high-temperature hydride. A hydride with a hydrogen-dissociation pressure that is lower than that of the magnesium hydride subject to the conditions of thermal dissociation and higher than that of the magnesium hydride during its recovery is employed as a low-temperature hydride.
    Type: Grant
    Filed: November 16, 1987
    Date of Patent: May 16, 1989
    Assignee: Studiengesellschaft Kohle mbH
    Inventors: Borislav Bogdanovic, Alfred Ritter, Bernd Spliethoff
  • Patent number: 4828606
    Abstract: Intermetallic compounds and hydrides thereof, characterized in that they have been prepared by reacting hydrides of the elements of the main groups I, II, III and IV of the Periodic Table, magnesium hydridehalides or magnesium dialkyls having the general formula MgR.sub.2 (R=alkyl) in a solvent with bisallyl metal compounds of the metals of the subgroup VIII of the Periodic Table or of zinc or with the homologues of the bisallyl compounds of said metals, and processes for preparing said compounds.
    Type: Grant
    Filed: April 16, 1987
    Date of Patent: May 9, 1989
    Assignee: Studiengesellschaft Kohle GmbH
    Inventors: Borislav Bogdanovic, Ursula Wilczok
  • Patent number: 4827067
    Abstract: The invention relates to azaphospholene of the type ##STR1## wherein R.sub.1 and R.sub.2 may be alkyl, aryl and aralkyl groups, processes for preparing same and the use thereof.
    Type: Grant
    Filed: September 19, 1988
    Date of Patent: May 2, 1989
    Assignee: Studiengesellschaft Kohle mbH
    Inventors: Gunther Wilke, Jaroslaw Monkiewicz, Herbert Kuhn
  • Patent number: 4798718
    Abstract: A method of preparing an active magnesium-hydride or magnesium hydrogen-storer system which can reversibly take up H.sub.2, comprising contacting finely divided magnesium hydride or metallic magnesium with a solution of a metal complex or of a metal-organic compound of a transition metal of Subgroups IV-VIII of the periodic table, and then removing the solution. The product performs better with regard to speed and efficiency upon repeated hydrogenation and dehydrogenation, as in hydrogen storage and evolution.
    Type: Grant
    Filed: March 27, 1987
    Date of Patent: January 17, 1989
    Assignee: Studiengesellschaft Kohle, GmbH
    Inventor: Borislav Bogdanovic
  • Patent number: 4752586
    Abstract: This invention relates to a process for the encapsulation in human or animal erythrocytes of at least one substance having a biological activity, characterized in that the primary compartment of at least one dialysis element is continuously supplied with an aqueous suspension of erythrocytes, the secondary compartment of the dialysis element contains an aqueous solution which is hypotonic with respect to the erythrocyte suspension in order to lyse the erythrocytes, the erythrocyte lysate is in contact with said substance having a biological activity and, in order to reseal the membrane of the erythrocytes, the osmotic and/or oncotic pressure of the erythrocyte lysate is increased after it has been brought into contact with said substance having a biological activity.
    Type: Grant
    Filed: November 20, 1986
    Date of Patent: June 21, 1988
    Assignees: Centre National de la Recherche Scientifique, Centre Hospitalier Regional de Tours, Studiengesellschaft Kohle mbH
    Inventors: Claude Ropars, Yves Nicolau, Maurice Chassaigne
  • Patent number: 4749558
    Abstract: A method of separating hydrogen from mixture with at least one gas selected from the group consisting of methane and its higher homologs, nitrogen, noble gases, CO, CO.sub.2, O.sub.2, NH.sub.3, H.sub.2 O, and H.sub.2 S, comprising contacting the mixture with active magnesium thereby selectively to absorb the hydrogen by forming magnesium hydride, separating the unabsorbed gas from the magnesium hydride, heating the magnesium hydride thereby to desorb the hydrogen in purified form and regenerate active magnesium from the hydride, and recovering the desorbed hydrogen.
    Type: Grant
    Filed: March 24, 1987
    Date of Patent: June 7, 1988
    Assignee: Studiengesellschaft Kohle mbH
    Inventor: Borislav Bogdanovic
  • Patent number: 4731203
    Abstract: The present invention relates to a process for preparing a finely divided, highly reactive magnesium from magnesium hydride, magnesium anthracene and/or its derivatives or magnesium butadiene and/or its alkyl or phenyl derivatives, which process is characterized in that the respective magnesium-containing compound is thermally decomposed at a pressure from 10.sup.
    Type: Grant
    Filed: August 12, 1986
    Date of Patent: March 15, 1988
    Assignee: Studiengesellschaft Kohle mbH
    Inventor: Borislav Bogdanovic
  • Patent number: 4724273
    Abstract: The invention relates to polymers and oligomers characterized in that they have been prepared from .alpha.-olefin monomers or mixtures thereof and the distances between the methyl branching points are controllable by the selection of the .alpha.-olefins and to a process for preparing said novel polymers and oligomers.
    Type: Grant
    Filed: February 7, 1986
    Date of Patent: February 9, 1988
    Assignee: Studiengesellschaft Kohle mbH
    Inventors: Gerhard Fink, Volker Mohring
  • Patent number: 4713110
    Abstract: The invention relates to a process for preparing finely divided metal powders, which process is characterized in that metal salts are reacted with magnesium, to which a catalytic amount of anthracene and/or magnesium anthracene or of one of their derivatives has been added as an activator, in a solvent, and optionally in the presence of an inorganic support material.
    Type: Grant
    Filed: November 21, 1986
    Date of Patent: December 15, 1987
    Assignee: Studiengesellschaft Kohle mbH
    Inventors: Borislav Bogdanovic, Helmut Bonnemann
  • Patent number: 4695446
    Abstract: A method of separating hydrogen from mixture with at least one gas selected from the group consisting of methane and its higher homologs, nitrogen, noble gases, CO, CO.sub.2, O.sub.2, NH.sub.3, H.sub.2 O, and H.sub.2 S, comprising contacting the mixture with active magnesium thereby selectively to absorb the hydrogen by forming magnesium hydride, separating the unabsorbed gas from the magnesium hydride, heating the magnesium hydride thereby to desorb the hydrogen in purified form and regenerate active magnesium from the hydride, and recovering the desorbed hydrogen.
    Type: Grant
    Filed: June 3, 1985
    Date of Patent: September 22, 1987
    Assignee: Studiengesellschaft Kohle mbH
    Inventor: Borislav Bogdanovic