Abstract: A light to heat conversion layer which has visible light permeability, excellent near infrared absorption characteristics, and which can improve the transfer accuracy of an organic electroluminescent element using laser irradiation; and a donor sheet using the light to heat conversion layer. The light to heat conversion layer contains near infrared absorption particles and a binder component. The near infrared absorption particles are composite tungsten oxide microparticles wherein if the value for the XRD peak intensity of the face of a silicon powder standard sample (manufactured by NIST, 640c) is defined as 1, the value for the ratio of XRD peak top intensity is at least 0.13, and the light transmissivity is at least 45%.
Abstract: A dispersion body having excellent heat ray shielding properties and long-term high temperature stability, and a dispersion liquid for producing the dispersion body, wherein the dispersion liquid contains liquid medium, absorbing fine particles dispersed in the medium, and a phosphite ester compound, the absorbing fine particles are one or more kinds of oxide fine particles selected from tungsten oxide fine particles represented by a general formula WyOz, and the phosphite ester compound is a phosphite ester compound represented by the following predetermined structural formula, and an addition amount of the phosphite ester compound is more than 500 parts by mass and 50000 parts by mass or less with respect to 100 parts by mass of the absorbing fine particles.
Abstract: A positive electrode active material for an all-solid-state lithium ion secondary battery, containing: a lithium-metal composite oxide particle having a niobium solid solution layer and a center other than the niobium solid solution layer; and a coating layer coating at least a part of a surface of the lithium-metal composite oxide particle and formed of a compound containing lithium and niobium, an average thickness of the coating layer is 2 nm or more and 1 ?m or less, and an average thickness of the niobium solid solution layer is 0.5 nm or more and 20 nm or less.
Abstract: The production method is a method for producing a positive electrode active material for a lithium ion secondary battery which contains at least nickel and lithium, the method including: a firing process in which a mixture of a nickel compound powder and a lithium compound powder is fired; and a water washing process in which a lithium-nickel composite oxide powder obtained in the firing process is washed with water, wherein the firing process is performed under conditions such that a value obtained by dividing a ratio of an amount-of-substance of lithium to a total amount-of-substance of transition metals other than lithium in the lithium-nickel composite oxide powder after the washing with water by a ratio of an amount-of-substance of lithium to a total amount-of-substance of transition metals other than lithium in the lithium-nickel composite oxide powder before the washing with water exceeds 0.95.
Abstract: A positive electrode active material for a lithium ion secondary battery, includes lithium-nickel composite oxide particles and a coating layer that covers at least a part of surfaces of the lithium-nickel composite oxide particles, in which components other than oxygen of the lithium-nickel composite oxide are represented by Li:Ni:Co:M=t:1?x?y:x:y (where, M is at least one element selected from the group consisting of Mg, Al, Ca, Si, Ti, V, Fe, Cu, Cr, Zn, Zr, Nb, Mo, or W, 0.95?t?1.20, 0<x?0.22, and 0?y?0.15), the coating layer contains a Ti compound, and a Ti amount per 1 m2 surface area of the lithium-nickel composite oxide is 7.0 ?mol or more and 60 ?mol or less.
Abstract: Provided are a cathode active material having a suitable particle size and high uniformity, and a nickel composite hydroxide as a precursor of the cathode active material. When obtaining nickel composite hydroxide by a crystallization reaction, nucleation is performed by controlling a nucleation aqueous solution that includes a metal compound, which includes nickel, and an ammonium ion donor so that the pH value at a standard solution temperature of 25° C. becomes 12.0 to 14.0, after which, particles are grown by controlling a particle growth aqueous solution that includes the formed nuclei so that the pH value at a standard solution temperature of 25° C. becomes 10.5 to 12.0, and so that the pH value is lower than the pH value during nucleation.
Abstract: Provided are a cathode active material having a suitable particle size and high uniformity, and a nickel composite hydroxide as a precursor of the cathode active material. When obtaining nickel composite hydroxide by a crystallization reaction, nucleation is performed by controlling a nucleation aqueous solution that includes a metal compound, which includes nickel, and an ammonium ion donor so that the pH value at a standard solution temperature of 25° C. becomes 12.0 to 14.0, after which, particles are grown by controlling a particle growth aqueous solution that includes the formed nuclei so that the pH value at a standard solution temperature of 25° C. becomes 10.5 to 12.0, and so that the pH value is lower than the pH value during nucleation.
Abstract: An electromagnetic wave absorbing particle dispersoid is provided that includes at least electromagnetic wave absorbing particles and a thermoplastic resin, wherein the electromagnetic wave absorbing particles contain hexagonal tungsten bronze having oxygen deficiency, wherein the tungsten bronze is expressed by a general formula: MxWO3-y (where one or more elements M include at least one or more species selected from among K, Rb, and Cs, 0.15?x?0.33, and 0<y?0.46), and wherein oxygen vacancy concentration NV in the electromagnetic wave absorbing particles is greater than or equal to 4.3×1014 cm?3 and less than or equal to 8.0×1021 cm?3.
Abstract: Provided are a nickel-manganese composite hydroxide capable of producing a secondary battery having a high particle fillability and excellent battery characteristics when used as a precursor of a positive electrode active material and a method for producing the same. A nickel-manganese composite hydroxide is represented by General Formula: NixMnyMz(OH)2+? and contains a secondary particle formed of a plurality of flocculated primary particles. The primary particles have an aspect ratio of at least 3, and at least some of the primary particles are disposed radially from a central part of the secondary particle toward an outer circumference thereof. The secondary particle has a ratio I(101)/I(001) of a diffraction peak intensity I(101) of a 101 plane to a peak intensity I(001) of a 001 plane, measured by an X-ray diffraction measurement, of up to 0.15.
Abstract: A positive electrode active material is constituted by lithium transition metal-containing composite oxide particles having a layered rock salt type crystal structure and are composed of secondary particles each formed of an aggregation of primary particles. The secondary particles have a d50 of 3.0 to 7.0 ?m, a BET specific surface area of 1.8 to 5.5 m2/g, a pore peak diameter of 0.01 to 0.30 ?m, and a log differential pore volume [dV/d(log D)] of 0.2 to 0.6 ml/g within a range of the pore peak diameter. In each of a plurality of primary particles having a primary particle size of 0.1 to 1.0 ?m, a coefficient of variation of the concentration of an additive element M is 1.5 or less.
Type:
Application
Filed:
September 18, 2020
Publication date:
December 1, 2022
Applicant:
SUMITOMO METAL MINING CO., LTD.
Inventors:
Tetsutaro Hayashi, Shun Kai Bong, Toshihiro Kato
Abstract: A solar radiation shielding fine particle dispersion body containing a thermoplastic resin, solar radiation shielding fine particles, a solar radiation shielding fine particle-containing masterbatch, a solar radiation shielding resin formed body formed into a predetermined shape using the same, and a solar radiation shielding resin laminate including the solar radiation shielding resin formed body stacked on another transparent formed body.
Abstract: The positive electrode active material is capable of reducing positive electrode resistance, exhibiting better output characteristics, and having high mechanical strength when the positive electrode active material is used in a lithium ion secondary battery. Secondary particles have a d50 of 3.0 to 7.0 ?m, a BET specific surface area of 2.0 to 5.0 m2/g, a tap density of 1.0 to 2.0 g/cm3, and an oil absorption amount of 30 to 60 ml/100 g. In each of a plurality of primary particles having a primary particle size of 0.1 to 1.0 ?m, a coefficient of variation of the concentration of an additive element M is 1.5 or less. The volume of a linking section between the primary particles per primary particle, obtained from the total volume of the linking section and the number of primary particles constituting the secondary particles, is 5×105 to 9×107 nm3.
Abstract: A positive electrode active material that can achieve high thermal stability at low cost is provided. Provided is a positive electrode active material for a lithium ion secondary battery, the positive electrode active material containing a lithium-nickel-manganese composite oxide, in which metal elements constituting the lithium-nickel-manganese composite oxide include lithium (Li), nickel (Ni), manganese (Mn), cobalt (Co), titanium (Ti), niobium (Nb), and optionally zirconium (Zr), an amount of substance ratio of the elements is represented as Li:Ni:Mn:Co:Zr:Ti:Nb=a:b:c:d:e:f:g (provided that, 0.97?a?1.10, 0.80?b?0.88, 0.04?c?0.12, 0.04?d?0.10, 0?e?0.004, 0.003<f?0.030, 0.001<g?0.006, and b+c+d+e+f+g=1), and in the amount of substance ratio, (f+g)?0.030 and f>g are satisfied.
Type:
Application
Filed:
June 30, 2020
Publication date:
November 17, 2022
Applicants:
SUMITOMO METAL MINING CO., LTD., PANASONIC CORPORATION
Abstract: A positive electrode active material includes lithium transition metal-containing composite oxide particles containing an additive element M1 and includes a coating layer formed of a metal composite oxide of Li and a metal element M2 on a part of a surface of the particles. The particles have a d50 of 3.0 to 7.0 ?m, a BET specific surface area of 2.0 to 5.0 m2/g, a tap density of 1.0 to 2.0 g/cm3, and an oil absorption amount of 30 to 60 ml/100 g. For each of a plurality of primary particles having a primary particle size within a range of 0.1 to 1.0 ?m among the primary particles, a coefficient of variation of the concentration of M1 is 1.5 or less, and the amount of M2 is 0.1 to 1.5 atom % with respect to the total number of atoms of Ni, Mn, and Co contained in the composite oxide particles.
Type:
Application
Filed:
September 18, 2020
Publication date:
November 17, 2022
Applicant:
SUMITOMO METAL MINING CO., LTD.
Inventors:
Tetsutaro Hayashi, Shun Kai Bong, Shinsuke Suganuma, Toshihiro Kato
Abstract: Provided is a mineral processing method that can efficiently separate a copper mineral and a molybdenum mineral. A mineral processing method includes a conditioning step of adding a disulfite to a mineral slurry containing a copper mineral and a molybdenum mineral and a flotation step of performing flotation using the mineral slurry after the conditioning step. By selectively enhancing hydrophilicity of the copper mineral with the disulfite, the hydrophilicity between the copper mineral and the molybdenum mineral can be differentiated. Thus, the molybdenum mineral can be selectively floated, and the copper mineral and the molybdenum mineral can be efficiently separated.
Type:
Application
Filed:
November 13, 2020
Publication date:
November 10, 2022
Applicants:
KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION, SUMITOMO METAL MINING CO., LTD.
Abstract: The positive electrode active material has high capacity and high output and exhibiting excellent cycle characteristics when being used for a positive electrode of a non-aqueous electrolyte secondary battery. A positive electrode active material for a lithium ion secondary battery contains: a lithium-metal composite oxide containing secondary particles with a plurality of aggregated primary particles; and a compound containing lithium and tungsten present on surfaces of the primary particles. The amount of tungsten contained in the compound containing lithium and tungsten is 0.5 atom % or more and 3.0 atom % or less in terms of a ratio of the number of atoms of W with respect to the total number of atoms of Ni, Co, and an element M, and a conductivity when the positive electrode active material is compressed to 4.0 g/cm3 as determined by powder resistance measurement is 6×10?3 S/cm or less.
Abstract: Provided is a positive electrode active material for a nonaqueous electrolyte secondary battery including a LiNi composite oxide having low internal resistance and excellent thermal stability. The positive electrode active material is obtained by performing a water washing process using a water spray on a LiNi composite oxide powder obtained by a firing step until the filtrate has an electric conductivity of 30 to 60 mS/cm, and then dried, where the LiNi composite oxide is represented by the composition formula (1): LibNi1-aM1aO2, where M1 represents at least one kind of element selected from transition metal elements other than Ni, group 2 elements, and group 13 elements, and 0.01?a?0.5, and 0.85?b?1.05.
Type:
Application
Filed:
July 14, 2022
Publication date:
November 3, 2022
Applicant:
SUMITOMO METAL MINING CO., LTD.
Inventors:
Tomoko Nakayama, Jun Yokoyama, Tetsufumi Komukai
Abstract: To provide a positive electrode active material capable of further reducing positive electrode resistance and exhibiting better output characteristics. A positive electrode active material includes a coating layer formed of a metal composite oxide of Li and one or more metal elements selected from Al, Ti, Zr, Nb, Mo, and W on at least a part of a surface of lithium transition metal-containing composite oxide particles, and has d50 of 3.0 to 7.0 ?m, a BET specific surface area of 2.0 to 5.0 m2/g, a tap density of 1.0 to 2.0 g/cm3, and an oil absorption amount of 30 to 60 ml/100 g, in which the amount of metal elements other than Li contained in the coating layer is 0.1 to 1.5 atom % with respect to the total number of atoms of Ni, Mn, and Co contained in the composite oxide particles.
Type:
Application
Filed:
September 18, 2020
Publication date:
October 27, 2022
Applicant:
SUMITOMO METAL MINING CO., LTD.
Inventors:
Tetsutaro Hayashi, Shun Kai Bong, Shinsuke Suganuma, Toshihiro Kato
Abstract: A positive-electrode active material precursor for a nonaqueous electrolyte secondary battery is provided that includes a nickel-cobalt-manganese carbonate composite represented by general formula NixCoyMnzMtCO3 (where x+y+z+t=1, 0.05?x?0.3, 0.1?y?0.4, 0.55?z?0.8, 0?t?0.1, and M denotes at least one additional element selected from a group consisting of Mg, Ca, Al, Ti, V, Cr, Zr, Nb, Mo, and W) and a hydrogen-containing functional group, wherein H/Me representing the ratio of the amount of hydrogen to the amount of metal components Me included in the positive-electrode active material precursor is greater than or equal to 1.60.
Abstract: A positive electrode active material for a nonaqueous electrolyte secondary battery includes a lithium-nickel-cobalt-zinc composite oxide powder that contains lithium (Li); nickel (Ni); cobalt (Co); element M, which is at least one element selected from the group consisting of manganese (Mn), vanadium (V), magnesium (Mg), molybdenum (Mo), niobium (Nb), silicon (Si), titanium (Ti), and aluminum (Al); and zinc (Zn). A molar element ratio (Li:Ni:Co:M) of the lithium-nickel-cobalt-zinc composite oxide powder satisfies Li:Ni:Co:M=z:(1-x-y):x:y (where 0.95?z?1.10, 0.05?x?0.35, and 0?y?0.10); a zinc content with respect to Li, Ni, Co, the element M, and oxygen in the lithium-nickel-cobalt-zinc composite oxide powder is greater than or equal to 0.01 mass % and less than or equal to 1.5 mass %; and at least a part of a surface of the lithium-nickel-cobalt-zinc composite oxide powder includes a zinc solid-solved region where zinc is solid-solved.