Patents Assigned to Sumitomo Metal Mining Co., Ltd.
  • Patent number: 11411214
    Abstract: A positive electrode active material for nonaqueous electrolyte secondary batteries and production method thereof that are able to improve the stability of positive electrode mixture material pastes used to produce nonaqueous electrolyte secondary batteries, as well as to improve the output characteristics and charge/discharge cycle characteristics of secondary batteries. A method for producing a positive electrode active material for nonaqueous electrolyte secondary batteries includes mixing a fired powder formed of a lithium-metal composite oxide having a layered crystal structure, a first compound which is at least one selected from a group consisting of a lithium-free oxide, a hydrate of the oxide, and a lithium-free inorganic acid salt, and water and drying a mixture resulting from the mixing. The fired powder includes secondary particles formed by agglomeration of primary particles. The first compound reacts with lithium ions in the presence of water to form a second compound including lithium.
    Type: Grant
    Filed: September 30, 2016
    Date of Patent: August 9, 2022
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Taira Aida, Jiro Okada, Tetsufumi Komukai, Koji Yamaji, Ryozo Ushio
  • Patent number: 11404690
    Abstract: The presently disclosed subject matter is directed to a positive electrode active material for a non-aqueous electrolyte secondary battery including a lithium transition metal-containing composite oxide, comprising secondary particles formed by aggregates of primary particles. The secondary particles comprise: an outer-shell section formed by an aggregate of the primary particles; at least one aggregate section formed by an aggregate of primary particles and existing on an inside of the outer-shell section, and electrically and structurally connected to the outer-shell section; and at least one space section existing on the inside of the outer-shell section and in which there are no primary particles. The average particle size of the secondary particles being within the range 1 ?m to 15 ?m, an index [(d90-d10)/average particle size] that indicates a spread of a particle size distribution of the secondary particles being 0.7 or less, and the surface area per unit volume being 1.7 m2/cm3 or greater.
    Type: Grant
    Filed: December 10, 2019
    Date of Patent: August 2, 2022
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Takahiro Toma, Taira Aida, Tetsufumi Komukai, Yasutaka Kamata
  • Patent number: 11390534
    Abstract: A tungsten trioxide whose IWO2.90/IWO3.00 is less than or equal to 0.15 is provided. IWO2.90/IWO3.00 indicates a ratio of a peak intensity IWO2.90 of a (200) plane of WO2.90 to a peak intensity IWO3.00 of a (200) plane of WO3.00 in an XRD pattern.
    Type: Grant
    Filed: November 21, 2018
    Date of Patent: July 19, 2022
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Toshiaki Aihara, Hiroyuki Toya
  • Patent number: 11391658
    Abstract: An air bubble measurement device is a device that measures the air bubbles moving in the liquid. The air bubble measurement device includes a measurement chamber that holds a liquid. The measurement chamber includes an introduction port to introduce the air bubbles in the liquid from a lower side and a transparent inclined surface that faces obliquely downward and is disposed at a position to which the air bubbles present inside the liquid move up. The transparent inclined surface includes a hydrophilic membrane. The hydrophilic membrane has a contact angle with water of 20 degrees or less. This structural arrangement allows for reducing an attachment of the air bubbles on the transparent inclined surface even when the air bubbles become small. This allows for reducing stay of the air bubbles on the transparent inclined surface and allows for accurately measuring the states of the air bubbles (that is, the size and quantity of the air bubbles).
    Type: Grant
    Filed: September 28, 2020
    Date of Patent: July 19, 2022
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventor: Shintaro Ishikawa
  • Patent number: 11389875
    Abstract: The purpose of the present invention is to provide a process for producing nickel powder capable of obtaining fine nickel powder in wet process, and also, capable of decreasing content of impurities by medicament (additive) used in crystallization of nickel powder which is reduction reaction. 1.
    Type: Grant
    Filed: December 5, 2017
    Date of Patent: July 19, 2022
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Junji Ishii, Hiroyuki Tanaka, Masaya Yukinobu
  • Patent number: 11394024
    Abstract: An object of the present invention is to provide nickel cobalt manganese composite hydroxide particles having a small particle diameter and a uniform particle size distribution, and a method for producing the same. A method for producing a nickel cobalt manganese composite hydroxide by a crystallization reaction is provided. The method includes: a nucleation step of performing nucleation by controlling a pH of an aqueous solution for nucleation including metal compounds containing nickel, cobalt and manganese, and an ammonium ion donor to 12.0 to 14.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard; and a particle growth step of growing nuclei by controlling a pH of an aqueous solution for particle growth containing nuclei formed in the nucleation step to 10.5 to 12.0 in terms of the pH as measured at a liquid temperature of 25° C. as a standard.
    Type: Grant
    Filed: October 3, 2019
    Date of Patent: July 19, 2022
    Assignees: SUMITOMO METAL MINING CO., LTD., TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Hiroyuki Toya, Shin Imaizumi, Kensaku Mori, Atsushi Fukui, Kenji Ikeuchi, Kazuomi Ryoshi, Toshiyuki Osako, Hiroki Nagai
  • Patent number: 11387453
    Abstract: Provided are a positive electrode active material that can provide a secondary battery extremely excellent in output characteristics and having sufficient volume energy density, a nickel-manganese composite hydroxide as a precursor thereof, and methods for producing these. A nickel-manganese composite hydroxide is represented by General Formula (1): NixMnyMz(OH)2+?, and contains a secondary particle formed of a plurality of flocculated primary particles. The nickel-manganese composite hydroxide has a half width of a (001) plane of at least 0.40° and has an average degree of sparsity/density represented by [(a void area within the secondary particle/a cross section of the secondary particle)×100] (%) falling within a range of greater than 22% and up to 40%.
    Type: Grant
    Filed: July 28, 2017
    Date of Patent: July 12, 2022
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Haruki Kaneda, Yuki Koshika, Takaaki Ando
  • Patent number: 11376658
    Abstract: To provide a fine nickel powder for an internal electrode paste of an electronic component, the nickel powder obtained by a wet method and having high crystallinity, excellent sintering characteristics, and heat-shrinking characteristics. The nickel powder is obtained by precipitating nickel by a reduction reaction in a reaction solution including at least water-soluble nickel salt, salt of metal nobler than nickel, hydrazine as a reducing agent, and alkali metal hydroxide as a pH adjusting agent and water; the reaction solution is prepared by mixing a nickel salt solution including the water-soluble nickel salt and the salt of metal nobler than nickel with a mixed reducing agent solution including hydrazine and alkali metal hydroxide; and the hydrazine is additionally added to the reaction solution after a reduction reaction initiates in the reaction solution.
    Type: Grant
    Filed: March 14, 2017
    Date of Patent: July 5, 2022
    Assignees: SUMITOMO METAL MINING CO., LTD., MURATA MANUFACTURING CO., LTD.
    Inventors: Junji Ishii, Shingo Murakami, Hiroyuki Tanaka, Takahiro Kamata, Toshiaki Terao, Masaya Yukinobu, Yuji Watanabe, Tsutomu Tanimitsu, Yoshiyuki Kunifusa, Haruo Nishiyama
  • Patent number: 11374220
    Abstract: A positive electrode active material for non-aqueous electrolyte secondary batteries that can achieve a high output characteristic and a high battery capacity when used in a positive electrode of a battery and that can achieve a high electrode density, and a non-aqueous electrolyte secondary battery that uses such a positive electrode active material and can achieve a high capacity and a high output. A lithium-manganese-cobalt composite oxide includes plate-shaped secondary particles each obtained by aggregation of a plurality of plate-shaped primary particles caused by overlapping of plate surfaces of the plate-shaped primary particles, wherein a shape of the primary particles is any one of a spherical, elliptical, oval, or a planar projected shape of a block-shaped object, and the secondary particles have an aspect ratio of 3 to 20 and a volume-average particle size (Mv) of 4 ?m to 20 ?m as measured by a laser diffraction scattering process.
    Type: Grant
    Filed: July 24, 2019
    Date of Patent: June 28, 2022
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Mitsuru Yamauchi, Kazuomi Ryoshi
  • Patent number: 11374217
    Abstract: A positive electrode material for a lithium ion secondary battery, including core particles and a carbonaceous film coating a surface of the core particles, in which in a Raman spectrum analysis of the carbonaceous film, in a case where a peak intensity of a spectrum in a wave number band of 1,200 to 1,400 cm?1 is set as D, a minimum intensity of 1,400 to 1,550 cm?1 is set as V, and a peak intensity of the spectrum of 1,550 to 1,700 cm?1 is set as G, an average D/G is 0.77 or more and 0.98 or less and an average V/G is 0.50 or more and 0.66 or less, and in a case where the average D/G is set as a and the average V/G is set as b, X falls within a range of ?0.1?X?0.1 in Expression X=a?1.47b.
    Type: Grant
    Filed: March 9, 2020
    Date of Patent: June 28, 2022
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Tsutomu Nozoe, Toyomasa Nakano
  • Patent number: 11374210
    Abstract: Provided is a positive electrode material that allows reducing battery resistance. The positive electrode material disclosed herein has particles of a positive electrode active material, each having a void communicating between the surface and at least the interior; and an electronic conductor present on the surface of the particles of the positive electrode active material. The positive electrode active material has a layered rock salt structure, and has a composition represented by Formula (I) below. The electronic conductor has a composition represented by Formula (II) below, Li1+uNixMnyCozMtO2??(I) La1?pMapCo1?qMbqO3????(II) wherein the symbols in the formulas are as defined in the specification.
    Type: Grant
    Filed: May 13, 2019
    Date of Patent: June 28, 2022
    Assignees: TOYOTA JIDOSHA KABUSHIKI KAISHA, SUMITOMO METAL MINING CO., LTD.
    Inventors: Ryuta Sugiura, Taira Aida, Tetsutaro Hayashi, Satoshi Kanada
  • Patent number: 11374221
    Abstract: A lithium-ion secondary battery including a cathode, an anode, and an electrolyte, in which the lithium-ion secondary battery includes inorganic phosphate particles, and the cathode includes cathode active material particles which include central particles made of LixAyMzPO4 (0?x?1.1, 0.8?y?1.1, and 0?z?0.2; here, A represents at least one element selected from the group consisting of Fe, Mn, Co, and Ni, and M represents at least one element selected from the group consisting of Mg, Ca, Co, Sr, Ba, Ti, Zn, B, Al, Ga, In, Si, Ge, and rare earth elements) and a carbonaceous film that coats surfaces of the central particles.
    Type: Grant
    Filed: January 8, 2020
    Date of Patent: June 28, 2022
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Masataka Oyama, Takao Kitagawa
  • Patent number: 11369048
    Abstract: Electromagnetic wave absorbing particles are provided that include hexagonal tungsten bronze having oxygen deficiency, wherein the tungsten bronze is expressed by a general formula: MxWO3-y(where one or more elements M include at least one or more species selected from among K, Rb, and Cs, 0.15?x?0.33, and 0<y?0.46), and wherein oxygen vacancy concentration Nv in the electromagnetic wave absorbing particles is greater than or equal to 3×1014 cm?3 and less than or equal to 8.0×1021 cm?3.
    Type: Grant
    Filed: July 25, 2018
    Date of Patent: June 21, 2022
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Mika Okada, Katsushi Ono, Satoshi Yoshio, Kenji Adachi, Keisuke Machida
  • Publication number: 20220177326
    Abstract: A positive electrode active material for a lithium ion secondary battery, in which a lithium-nickel-manganese composite oxide has a hexagonal layered structure, a mole number ratio of metal elements is represented as Li:Ni:Mn:M:Ti=a:(1-x-y-z):x:y:z, provided that 0.97?a?1.25, 0.05?x?0.15, 0?y?0.15, and 0.01?z?0.05, a ratio of a total amount of peak intensities of most intense lines of a titanium compound to a (003) diffraction peak intensity in XRD measurement is 0.2 or less, a crystallite diameter at (003) plane is 160 nm to 300 nm, and an amount of lithium to be eluted in water when the positive electrode active material is immersed in water is 0.07% by mass or less.
    Type: Application
    Filed: February 21, 2020
    Publication date: June 9, 2022
    Applicant: SUMITOMO METAL MINING CO., LTD.
    Inventors: Yuki Koshika, Haruki Kaneda
  • Publication number: 20220177325
    Abstract: A positive electrode active material for a lithium ion secondary battery, in which a lithium-nickel-manganese composite oxide has a hexagonal layered structure, a mole number ratio of metal elements is represented as Li:Ni:Mn:M:Ti=a:(1?x?y?z):x:y:z, provided that 0.97?a?1.25, 0.05?x?0.15, 0?y?0.15, and 0.01?z?0.05, a ratio of a total amount of peak intensities of most intense lines of a titanium compound to a (003) diffraction peak intensity in XRD measurement is 0.2 or less, and a volume resistivity as determined by powder compact resistivity measurement compressed to 4.0 g/cm3 is 1.0×102 ?·cm or more and 1.0×104 ?·cm or less.
    Type: Application
    Filed: February 21, 2020
    Publication date: June 9, 2022
    Applicant: SUMITOMO METAL MINING CO., LTD.
    Inventors: Yuki Koshika, Haruki Kaneda
  • Patent number: 11352697
    Abstract: A treatment apparatus includes two can rolls provided on a transfer path through which a long resin film is transferred in a roll-to-roll manner in a vacuum chamber; and surface treatment means facing an outer circumference of each of the can rolls to treat a surface of the long resin film cooled by being wound around the outer circumference. The downstream can roll is provided with upper and lower two sets of feeding and sending systems, and one surface of the long resin film in contact with the outer circumference of the downstream can roll at a time when the long resin film travels through the lower one of the two sets of feeding and sending systems is opposite to the other surface of the resin film in contact with the outer circumference of the downstream can roll at a time when the resin film travels through the upper one.
    Type: Grant
    Filed: August 23, 2017
    Date of Patent: June 7, 2022
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventor: Hideharu Okami
  • Patent number: 11345607
    Abstract: There is provided a near-infrared absorbing fine particle dispersion liquid containing near-infrared absorbing fine particles, thereby as well as exhibiting near-infrared light absorption properties and suppressing a scorching sensation on the skin when used in structures such as window materials and the like, also enabling usage of communication devices, imaging devices, sensors and the like that employ near-infrared light through these structures, a near-infrared absorbing film or a near-infrared absorbing glass, a dispersion body or a laminated transparent substrate, the dispersion liquid containing at least composite tungsten oxide fine particles and antimony doped tin oxide fine particles and/or tin doped indium oxide fine particles as near-infrared absorbing fine particles, wherein in the composite tungsten oxide fine particles, an average value of a transmittance in a wavelength range of 800 to 900 nm is 30% or more and 60% or less, and an average value of a transmittance in a wavelength range of 1200
    Type: Grant
    Filed: May 31, 2017
    Date of Patent: May 31, 2022
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Hirofumi Tsunematsu, Takeshi Chonan
  • Publication number: 20220158185
    Abstract: A nickel composite hydroxide includes nickel, cobalt, manganese, and an element M with an atomic ratio of Ni:Co:Mn:M=1?x1?y1?z1:x1:y1:z1 (wherein M is at least one element selected from a group consisting of a transition metal element other than Ni, Co, Mn, a II group element, and a XIII group element, 0.15?0.25, 0.15?y1?0.25, 0?z1?0.1), the nickel composite hydroxide having a cobalt or manganese rich layer from a surface of a particle of the secondary particles toward an inside of the secondary particles and a layered low-density layer between the cobalt or manganese rich layer and a center of the particle of the secondary particles, and a thickness of the cobalt or manganese rich layer and low-density layer is 1% or more and 10% or less to a diameter of the secondary particles.
    Type: Application
    Filed: April 24, 2020
    Publication date: May 19, 2022
    Applicant: SUMITOMO METAL MINING CO., LTD.
    Inventors: Mitsuru YAMAUCHI, Tai ITO, Tetsufumi KOMUKAI
  • Publication number: 20220154308
    Abstract: A method of manufacturing a cobalt-nickel-containing solution including: preparing a crude nickel hydroxide and/or a crude cobalt hydroxide as a starting material, the crude nickel or cobalt hydroxide containing cobalt and nickel and elements except the cobalt and nickel as impurities, the crude nickel hydroxide containing the nickel more than the cobalt, and the crude cobalt hydroxide containing the cobalt more than the nickel; a water-washing process for obtaining a post-water-washing crude hydroxide from the starting material; a leaching process for obtaining a post-leaching solution from the post-water-washing crude hydroxide; a neutralization process of subjecting the post-leaching solution to neutralization and solid-liquid-separation to remove the impurities as a post-neutralization residue containing one or more of iron, silicon, aluminum, and chromium, thereby obtaining a post-neutralization solution; and an extraction process of subjecting the post-neutralization solution to solvent extraction to ob
    Type: Application
    Filed: March 16, 2020
    Publication date: May 19, 2022
    Applicant: SUMITOMO METAL MINING CO., LTD.
    Inventors: Hideki Ohara, Shota Sanjo, Masatoshi Takano, Satoshi Asano, Hiroshi Kobayashi, Yusuke Senba, Hiroto Watanabe
  • Publication number: 20220131144
    Abstract: A nickel manganese cobalt composite hydroxide, which is a precursor of a positive electrode active material and is composed of secondary particles to which primary particles containing a nickel, manganese, and cobalt are aggregated, or composed of the primary and secondary particles, wherein a sodium content contained in the nickel manganese cobalt composite hydroxide is less than 0.0005% by mass, and a void ratio of particles is more than 50% to 80%. Also, a ratio of an average particle size of a lithium nickel manganese cobalt composite oxide divided by an average particle size of the nickel manganese cobalt composite hydroxide, which is a precursor, is 0.95 to 1.05, and further, when observing 100 or more particles selected randomly by a scanning electron microscope, a number that an aggregation of secondary particles is observed is 5% or less with respect to a total number of observed secondary particles.
    Type: Application
    Filed: December 26, 2019
    Publication date: April 28, 2022
    Applicant: SUMITOMO METAL MINING CO., LTD.
    Inventors: Hiroko OSHITA, Kazuomi RYOSHI