Abstract: A method of removing a carboxylic acid from a liquid that contains a tertiary amide solvent includes a step of contacting the liquid with an extraction medium comprising an amine. The amine is immiscible with both water and the tertiary amide solvent, and the contacting step forms a de-acidified phase containing the tertiary amide solvent and a phase containing the extraction medium and the carboxylic acid. Both the liquid that contains the tertiary amide solvent and the de-acidified phase may also contain a sucrose-6-acylate.
Type:
Grant
Filed:
March 13, 2009
Date of Patent:
July 2, 2013
Assignee:
Tate & Lyle Technology Limited
Inventors:
John Kerr, Robert Jansen, Christian J. Isaac, James Edwin Wiley, Jr., Duane A. Leinhos
Abstract: The present invention provides a method for producing sucralose from a feed stream resulting from the chlorination of a sucrose-6-acylate in a reaction vehicle. The feed stream includes a sucralose-6-acylate, the reaction vehicle, water, and salts. The salts include one or more selected from the group consisting of alkali metal chlorides, alkaline earth metal chlorides and ammonium chloride. The method includes: (i) deacylation of the sucralose-6-acylate by treatment with a base to afford a product stream comprising sucralose; (ii) partial removal of water and, optionally, reaction vehicle from the product stream of (i) in order to cause precipitation of the salts from the product stream; (iii) removal of the precipitated salts from the product stream of (ii); and (iv) isolation of sucralose from the product stream of (iii).
Type:
Grant
Filed:
December 30, 2008
Date of Patent:
May 7, 2013
Assignee:
Tate & Lyle Technology Limited
Inventors:
John Kerr, Robert Jansen, Duane A. Leinhos, James Edwin Wiley, Jr., Sebastien Camborieux, Anthony Baiada, Gordon Walker, Carlo Maffezzoni
Abstract: Biodegradable detergent compositions comprising 1,3-propanediol are provided, and the 1,3-propanediol in the composition is biologically derived. The compositions exhibit a lower anthropogenic CO2 emission profile. Also provided are biodegradable detergent compositions comprising an ester of 1,3-propanediol. In these compositions, the ester can have at least 3% biobased carbon.
Type:
Grant
Filed:
September 21, 2011
Date of Patent:
May 7, 2013
Assignee:
DuPont Tate & Lyle Bio Products Company, LLC
Inventors:
Gyorgyi Fenyvesi, Melissa Joerger, Robert Miller, Raja Hari Poladi, Ann Wehner
Abstract: An air seal device having a housing with a passageway, a core body that is configured to fit tightly within the passageway to restrict air flow through the passageway and to seal the interface between the core body and the housing, and a top ring that locks to the housing and engages and compresses the core body within the housing. The core body has a slit extending vertically therethrough that allows an elongated member or members to pass through the core body while providing an airtight interface between the member or members and the slit of the core body.
Type:
Grant
Filed:
March 4, 2011
Date of Patent:
April 9, 2013
Assignee:
Tate Access Floors Leasing, Inc.
Inventors:
Daniel J. Curtin, William W. Reynolds, Daniel B. Kennedy
Abstract: Disclosed herein are food and flavorant compositions comprising 1,3-propanediol, wherein the 1,3-propanediol in said compositions has a bio-based carbon content of about 1% to 100%. In addition, it is preferred that the 1,3-propanediol be biologically-derived, and wherein upon biodegradation, the biologically-derived 1,3-propanediol contributes no anthropogenic CO2 emissions to the atmosphere.
Type:
Application
Filed:
March 7, 2012
Publication date:
March 21, 2013
Applicant:
DuPont Tate & Lyle Bio Products Company, LLC
Inventors:
Gyorgyi Fenyvesi, Melissa Joerger, Robert Miller, Ann Wehner
Abstract: A method of removing a carboxylic acid from a liquid including a tertiary amide solvent includes: A) forming an extraction medium including an acid-extracting tin species and an extraction solvent that is immiscible with the tertiary amide solvent; B) subsequently contacting the liquid with the extraction medium, forming a phase including a de-acidified tertiary amide solvent and a phase including the extraction solvent; and C) removing the phase including the extraction solvent, to afford a liquid including the de-acidified tertiary amide solvent. The acid-extracting tin species is one or more tin species obtainable by reaction of a di(hydrocarbyl)tin oxide with less than one equivalent of a carboxylic acid, tin species obtainable by reaction of a 1,3-diacyloxy-1,1,3,3-tetra-(hydrocarbyl)distannoxane with an aqueous base.
Type:
Application
Filed:
May 3, 2012
Publication date:
November 15, 2012
Applicant:
Tate & Lyle Technology Limited
Inventors:
David T. Coleman, Edward Micinski, James Edwin Wiley, JR., Thomas A. Eilers, David A. Dentel
Abstract: Personal care compositions comprising esters of 1,3-propanediol and acceptable carriers are provided. The esters can have at least 3% biobased carbon, and the compositions can further comprise 1,3-propanediol that is biologically-derived. Also provided are processes for producing personal care compositions comprising esters of 1,3-propanediol and acceptable carriers. The processes comprise providing biologically produced 1,3-propanediol, contacting the 1,3-propanediol with organic acids, which produces the esters, recovering the esters, and incorporating the esters into personal care formulations. Also provided are processes of making a personal care composition comprising providing an ester of 1,3 propanediol and mixing the ester with an acceptable carrier to form a personal care composition.
Type:
Grant
Filed:
October 15, 2009
Date of Patent:
November 13, 2012
Assignee:
DuPont Tate & Lyle Bio Products Company, LLC
Inventors:
Gyorgyi Fenyvesi, Ann Wehner, Melissa Joerger, Raja Hari Prasad R. Poladi
Abstract: The present invention relates to the use of sweet steviol glycoside compounds, particularly rebaudioside B, in sweetening compositions. Sweetening compositions comprising selected amounts of rebaudioside B have been shown to possess favorable flavor profiles when compared to other high intensity sweetener compounds and are useful in the preparation of consumables.
Type:
Application
Filed:
October 19, 2011
Publication date:
October 25, 2012
Applicant:
Tate & Lyle Ingredients Americas LLC
Inventors:
John R. Bridges, Alfred Carlson, Penelope A. Patton
Abstract: A composition includes Mogroside V and a Rebaudioside component in a weight ratio ?1:1 and ?6:1, wherein the Rebaudioside component consists of one or more compounds selected from the group consisting of Rebaudioside A, Rebaudioside B and Rebaudioside D. A method of purifying a Luo Han Guo extract includes contacting the Luo Han Guo extract with activated carbon and a macroporous polymeric adsorbent resin, an ion exchange resin, or both. A composition includes a Luo Han Guo extract, wherein Mogroside V constitutes from 50 wt % to 75 wt % of the Luo Han Guo extract and the composition includes from 0 to 13 wt % in total relative to the Mogroside V of aromatic glycosides, and from 0 to 15 ppm of semi-volatile organic compounds relative to the Mogroside V.
Type:
Application
Filed:
January 23, 2012
Publication date:
October 18, 2012
Applicant:
Tate & Lyle Ingredients Americas LLC
Inventors:
John R. Bridges, Alfred Carlson, Brian Timothy Pohrte, Mary Quinlan, Timothy C. Schunk, Elber F. Tejada, Shelly Yuqing Zhou
Abstract: The present invention provides for a digestive enzyme inhibitor comprising the hydrolysis products of an ?-amylase hydrolyzed hydroxypropyl substituted starch. The present invention further provides for a food or beverage ingredient composition comprising the hydrolysis products of an ?-amylase hydrolyzed hydroxypropyl substituted starch and a rapidly digestible starch, a food or beverage comprising such ingredient, and methods of use thereof, including a method of controlling postprandial glucose release after ingestion of a rapidly digestible starch.
Type:
Application
Filed:
March 7, 2012
Publication date:
September 13, 2012
Applicant:
TATE & LYLE INGREDIENTS AMERICAS, LLC
Inventors:
Xian-Zhong Han, Rohit A. Medhekar, Andrew J. Hoffman
Abstract: An air seal device having a housing with a passageway, a core body that is configured to fit tightly within the passageway to restrict air flow through the passageway and to seal the interface between the core body and the housing, and a top ring that locks to the housing and engages and compresses the core body within the housing. The core body has a slit extending vertically therethrough that allows an elongated member or members to pass through the core body while providing an airtight interface between the member or members and the slit of the core body.
Type:
Application
Filed:
March 4, 2011
Publication date:
September 6, 2012
Applicant:
TATE ACCESS FLOORS LEASING, INC.
Inventors:
Daniel J. CURTIN, William W. REYNOLDS, Daniel B. KENNEDY
Abstract: A process for the purification of aqueous feed streams containing sucralose and/or sucralose 6-esters includes, providing an aqueous feed stream including the sucralose and/or sucralose 6-esters, concentrating the aqueous feed stream to form a concentrated aqueous feed stream containing at least 10 wt % total carbohydrates and extracting the concentrated aqueous feed stream with an organic solvent and producing an organic extract and an aqueous extract, in which the organic solvent is immiscible with water, and in which the carbohydrate preferentially passes into the organic extract.
Type:
Grant
Filed:
April 1, 2009
Date of Patent:
July 3, 2012
Assignee:
Tate & Lyle Technology Limited
Inventors:
Edward Micinski, James Edwin Wiley, Jr.
Abstract: A multizone variable damper for air passageways having a plurality of damper zones, a plurality of opposed blades that are rotatable about a horizontal axis, a pair of blades of the plurality of blades being provided in each zone of the plurality of damper zones, and an actuator for each pair of blades, each actuator being configured to independently rotate each of the pairs of blades of the plurality of opposed blades so as to selectively and independently control a degree of openness of each of the pairs of blades of the plurality of opposed blades in each damper zone of the plurality of damper zones.
Type:
Application
Filed:
December 17, 2010
Publication date:
June 21, 2012
Applicant:
TATE ACCESS FLOORS LEASING, INC.
Inventors:
Daniel J. CURTIN, William W. REYNOLDS, Daniel B. KENNEDY
Abstract: A chlorinating agent such as a chloroiminium species is used to remove or neutralize tertiary acetamide present as a contaminant in a tertiary formamide solvent. Tertiary formamide solvent purified or treated in this manner can be used as a reaction vehicle for the chlorination of sucrose-6-acylates, thereby improving the yields of the desired sucralose-6-acylate (an intermediate in the production of sucralose).
Type:
Application
Filed:
June 18, 2010
Publication date:
June 21, 2012
Applicant:
Tate & Lyle Technology Limited
Inventors:
James Edwin Wiley, JR., Mohamad R. Jaber
Abstract: A process for removing dimethylamine (DMA) before and/or during and/or after deacylation in a reaction vessel of a feed stream comprising a sucralose-6-acylate resulting from the chlorination of a sucrose-6-acylate in the presence of dimethyl formamide (DMF), wherein the deacylation is conducted at a first set of conditions of temperature, pH and pressure, the process comprising: (a) providing a side stream loop from and to the reaction vessel; (b) adjusting the conditions of one or more of temperature, pH, and pressure in the loop, and setting the flow rate through the loop, to remove DMA while minimising carbohydrate degradation.
Type:
Application
Filed:
March 24, 2010
Publication date:
June 21, 2012
Applicant:
Tate & Lyle Technology Ltd.
Inventors:
John Kerr, Robert Jansen, Anthony Baiada, Duane Leinhos, James Edwin Wiley
Abstract: A process for purifying 1,3-propanediol from the fermentation broth of a cultured E. coli that has been bioengineered to synthesize 1,3-propanediol from sugar is provided. The basic process entails filtration, ion exchange and distillation of the fermentation broth product stream, preferably including chemical reduction of the product during the distillation procedure. Also provided are highly purified compositions of 1,3-propanediol.
Type:
Grant
Filed:
February 25, 2011
Date of Patent:
May 22, 2012
Assignees:
E. I. du Pont de Nemours and Company, Tate & Lyle Ingredients Americas LLC
Inventors:
Dennis N. Adkesson, Albert W. Alsop, Tyler T. Ames, Luis A. Chu, James M. Disney, Bryan C. Dravis, Patrick Fitzgibbon, James M. Gaddy, F. Glenn Gallagher, William F. Lehnhardt, Jefferson C. Lievense, Michael L. Luyben, Mayis Seapan, Robert E. Trotter, Gregory M. Wenndt, Eugene K. Yu
Abstract: A method of forming a sucrose-6-ester includes in sequence the steps of: a) contacting sucrose with a organotinbased acylation promoter in a solvent in the presence of a base selected from amines and basic alkali metal salts; b) removing water to form a tin-sucrose adduct; and c) contacting the tin-sucrose adduct with an acylating agent to form the sucrose- 6-ester. The sucrose-6-ester may then be converted to sucralose.
Type:
Application
Filed:
March 10, 2010
Publication date:
April 19, 2012
Applicant:
Tate & Lyle Technology Ltd.
Inventors:
Thomas Kennedy Hutton, Peter Jay Seaberg, Christopher C. Kerwood