Patents Assigned to Tocalo Co., Ltd.
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Publication number: 20240116076Abstract: The method for forming a coating of the present invention includes: a first step of applying a first solution containing a polysilazane to a surface 2a of a metal substrate 2 and heating the first solution to form a first coating 1 on the surface 2a of the metal substrate 2, and a second step of applying a second solution containing a polysilazane to a surface 1a of the first coating 1 and heating the second solution at a temperature lower than a heating temperature in the first step to form a second coating 3 on the surface 1a of the first coating 1, wherein a density of the first coating is less than 2.00 g/cm3, and a density of the second coating is 2.00 g/cm3 or more.Type: ApplicationFiled: November 11, 2021Publication date: April 11, 2024Applicant: TOCALO CO.,LTD.Inventors: Takaomi TANABE, Seiichiro KAWACHI, Kosaku HIYAMA
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Patent number: 11955360Abstract: A Johnsen-Rahbek force type electrostatic chuck including: a metal substrate; an electrode for electrostatic attraction provided on the metal substrate with an insulating layer interposed between the metal substrate and the electrode for electrostatic attraction; and a dielectric layer constituting an electrostatic attraction surface in contact with a workpiece. The dielectric layer includes a ceramic spray coating and a sealing component with which pores of the ceramic spray coating are filled, and the sealing component contains a metal organic salt containing a rare earth element.Type: GrantFiled: December 24, 2020Date of Patent: April 9, 2024Assignees: TOCALO CO., Ltd., HITACHI HIGH-TECH CORPORATIONInventors: Takeshi Takabatake, Tomohiro Nakasuji, Akira Itoh, Kentaro Seto, Yutaka Omoto, Hiroho Kitada, Kazuumi Tanaka
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Publication number: 20240044009Abstract: The method for forming a coating of the present invention includes: a first step of applying a first solution containing a polysilazane to a surface 2a of a metal substrate 2, heating the first solution to make the first solution undergo conversion into silica and form a first coating 1 having open defects 3, on the surface 2a of the metal substrate 2, and a second step of applying a second solution containing a polysilazane to a surface 1a of the first coating 1 to fill the open defects 3, and heating the second solution at a temperature lower than a heating temperature in the first step to make the second solution undergo conversion into silica and form a second coating 5 on a surface 1a of the first coating 1.Type: ApplicationFiled: November 11, 2021Publication date: February 8, 2024Applicant: TOCALO CO.,LTD.Inventors: Takaomi TANABE, Seiichiro KAWACHI, Kosaku HIYAMA
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Publication number: 20240043982Abstract: There is provided a thermal spray coating which has excellent plasma erosion resistance, which protects members of a plasma etching device from plasma erosion over a long period of term, and which can contribute to the stable production of devices and a longer life of members. The thermal spray material which is one aspect of this invention contains a composite compound containing a rare earth fluoride in the proportion of 40 mol % or more and 80 mol % or less, a magnesium fluoride in the proportion of 10 mol % or more and 40 mol % or less, and a calcium fluoride in the proportion of 0 mol % or more and 40 mol % or less.Type: ApplicationFiled: November 18, 2021Publication date: February 8, 2024Applicants: TOCALO Co., Ltd., FUJIMI INCORPORATEDInventors: Yasuhiro Shiojiri, Tatsuo Suidzu, Kensuke Taguchi, Hiroaki Mizuno, Takaya Masuda
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Publication number: 20230220531Abstract: To provide a new tungsten-based thermal spray coating suitable as e.g. a component for plasma etching device using halogen gas, and a material for thermal spraying for obtaining the thermal spray coating. A thermal spray coating characterized by containing tungsten as a matrix phase and oxides containing silicon and boron as a dispersed phase, and a component for plasma etching device having such a thermal spray coating. A material for thermal spraying characterized by containing from 1 to 7 wt % of silicon, from 0.5 to 3 wt % of boron and the reminder being tungsten and unavoidable impurities, and a method for producing a thermal spray coating by thermally spraying the material for thermal spraying.Type: ApplicationFiled: March 4, 2021Publication date: July 13, 2023Applicant: TOCALO CO., LTD.Inventors: Kazuo HAMASHIMA, Masashi MORISASA, Shinsuke ANAI
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Publication number: 20230154780Abstract: A Johnsen-Rahbek force type electrostatic chuck including: a metal substrate; an electrode for electrostatic attraction provided on the metal substrate with an insulating layer interposed between the metal substrate and the electrode for electrostatic attraction; and a dielectric layer constituting an electrostatic attraction surface in contact with a workpiece. The dielectric layer includes a ceramic spray coating and a sealing component with which pores of the ceramic spray coating are filled, and the sealing component contains a metal organic salt containing a rare earth element.Type: ApplicationFiled: December 24, 2020Publication date: May 18, 2023Applicants: TOCALO Co., Ltd., HITACHI HIGH-TECH CORPORATIONInventors: Takeshi TAKABATAKE, Tomohiro NAKASUJI, Akira ITOH, Kentaro SETO, Yutaka OMOTO, Hiroho KITADA, Kazuumi TANAKA
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Patent number: 11631574Abstract: The heater component (1) has a substrate part (2), and a thin coating heater (4) which is equipped outside this substrate part (2) and generates heat by power supply. The thin coating heater (4) is formed of a thermal sprayed coating. The thin coating heater (4) has a heater body (10) and a heater extension part (11). The heater body (10) is arranged on a first end face (2a) of the substrate part (2). The heater extension part (11) is extended from the heater body (10) to a second end face (2b) of the substrate part (2) through a side surface (2c) of the substrate part (2). A tip part (11s) of the heater extension part (11) is a heater power supplying part (12) for supplying electric power to the heater body (10).Type: GrantFiled: October 29, 2018Date of Patent: April 18, 2023Assignee: TOCALO CO., LTD.Inventors: Shikou Abukawa, Kensuke Taguchi, Yu Asakimori, Ryutaro Kawamura
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Patent number: 11504738Abstract: A coating is formed on a surface of a base material of a furnace, and includes a base layer and a sliding material layer that is formed on a surface of the base layer and contains an oxide ceramic and a compound having a layered crystal structure. The sliding material layer causes the collided ashes to be slipped and facilitates the drop off of the adhered ashes. The base material forms a heat transfer tube or a wall surface of the furnace. The coating is also applied to a coal gasification furnace, a pulverized coal fired boiler, a combustion apparatus, or a reaction apparatus containing a furnace.Type: GrantFiled: September 1, 2020Date of Patent: November 22, 2022Assignees: IHI Corporation, TOCALO Co., LtdInventors: Naoki Sato, Nobuhiko Kubota, Koki Hamada, Tatsuo Suidzu, Kazuhiro Takeuchi
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Patent number: 11272579Abstract: Provided is a heat generating component of which volume resistivity hardly varies even if used repeatedly at a high temperature for a long period of time. Since a thin coating heater part (13) formed on a substrate part (12) is composed of a thermal sprayed coating containing TixOy (wherein, 0<y/x<2.0 is satisfied), obtained is a heat generating component (11) having volume resistivity which is suitable for a heater and hardly varies even if prescribed temperature change and temperature keeping are repeated.Type: GrantFiled: June 2, 2017Date of Patent: March 8, 2022Assignee: TOCALO CO., LTD.Inventors: Shikou Abukawa, Kensuke Taguchi, Toru Moriyama, Yasuhiro Sato, Akira Kumagai, Yu Asakimori
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Patent number: 11193195Abstract: A component for a hot-dip metal plating bath includes a base material and a thermal spray coating disposed to cover a surface of the base material. The base material includes ferritic stainless steel that contains: C: 0.10% to 0.50% by mass; Si: 0.01% to 4.00% by mass; Mn: 0.10% by mass to 3.00% by mass; Cr: 15.0% to 30.0% by mass; a total of Nb, V, Ti, and Ta: 0.9% by mass to 5.0% by mass; and a balance of Fe and unavoidable impurities. The ferritic stainless steel includes a microstructure that includes a ferrite phase as a main phase and a crystallized carbide, an area fraction of a Nb carbide, a Ti carbide, a V carbide, a Ta carbide, and a composite carbide thereof to the crystallized carbide of 30% or more. The hot-dip metal plating bath contains 50% by mass or more of Al.Type: GrantFiled: May 17, 2018Date of Patent: December 7, 2021Assignees: TOCALO CO., LTD., DAIDO STEEL CO., LTD., DAIDO CASTINGS CO., LTD.Inventors: Junichi Takeuchi, Masaya Nagai, Shinichi Kubo, Masashi Nagaya, Yoshinori Sumi, Yoshihiko Koyanagi, Hiroyuki Takabayashi, Yasuhiro Takenaka
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Patent number: 11174812Abstract: A sliding member capable of improving friction characteristics under an environment of a lubricant containing Mo, and a production method therefor, is provided. The sliding member contains a sliding portion formed of a metallic material having a Ti-containing thermally sprayed coating on a surface layer part of the sliding portion. The sliding member slides under the environment of the lubricant containing Mo as an additive, in which active Ti exposed on a surface by sliding accelerates decomposition reaction of the additive contained in the lubricant to form a molybdenum disulfide-containing low-friction coating having low friction on the surface of the sliding portion.Type: GrantFiled: August 20, 2019Date of Patent: November 16, 2021Assignees: TOYOTA MOTOR EAST JAPAN, INC., TOYOTA JIDOSHA KABUSHIKI KAISHA, TOCALO Co., Ltd.Inventors: Ryo Koike, Kazuyoshi Manabe, Akihiro Kanno
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Patent number: 11131014Abstract: A ceramic substrate is irradiated in an atmospheric air with a laser having a power density of 1.0×107-1.0×109 W/cm2 for an action time on an irradiation area of 1.0×10?7-1.0×10?5 s to roughen a surface of the ceramic substrate, as well as to form an oxide layer on a roughened surface. A thermal sprayed coating formed on the ceramic substrate sufficiently adheres to the ceramic substrate via the oxide layer.Type: GrantFiled: March 23, 2016Date of Patent: September 28, 2021Assignee: TOCALO CO., LTD.Inventors: Hiroki Yokota, Daisuke Kawai, Tatsuo Suidzu
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Publication number: 20210199054Abstract: A thermal barrier coating material contains a compound X that is a cation-deficient-type defective perovskite complex oxide. Unit cells of the compound X each include six oxygen atoms and has a structure in which two octahedrons sharing one oxygen atom are aligned. In the compound X, central axes of two octahedrons that belong to adjacent unit cells, respectively, and are adjacent to each other are inclined relative to each other. A plurality of sets of the two octahedrons that belong to the adjacent unit cells, respectively, and are adjacent to each other are arranged to form a periodic structure in which octahedrons having different inclinations are alternately arranged, and the compound X has a boundary surface at which a periodicity of the periodic structure changes, in a crystal structure thereof.Type: ApplicationFiled: September 2, 2019Publication date: July 1, 2021Applicants: JAPAN FINE CERAMICS CENTER, TOCALO CO., LTD.Inventors: Tsuneaki MATSUDAIRA, Satoshi KITAOKA, Naoki KAWASHIMA, Takeharu KATO, Daisaku YOKOE, Takashi OGAWA, Craig FISHER, Yoichiro HABU, Mikako NAGAO, Yoshiyasu ITO, Yuhei OHIDE, Kaito TAKAGI
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Publication number: 20210047968Abstract: A thermal barrier coating includes: a metal bonding layer made of an alloy containing Al; a thermal barrier layer; and an intermediate layer provided between the metal bonding layer and the thermal barrier layer. The thermal barrier layer contains a compound represented by the following general formula (1), LnxTayHfzO(3x+5y+4z)/2 (1) (wherein Ln is an atom of one element selected from among rare earth elements, x is 0 to 1.0, y is 0.8 to 3.0, and z is 0 to 7.0). The intermediate layer contains at least one layer selected from among the following (A) to (C): (A) a layer containing hafnium oxide (HfO2) as a main component; (B) a layer containing, as a main component, a compound consisting of tantalum (Ta), hafnium (Hf), and oxygen (O); and (C) a layer containing, as a main component, a compound consisting of a rare earth element, tantalum (Ta), hafnium (Hf), and oxygen (O).Type: ApplicationFiled: March 1, 2019Publication date: February 18, 2021Applicants: JAPAN FINE CERAMICS CENTER, TOCALO CO.,LTD.Inventors: Tsuneaki MATSUDAIRA, Satoshi KITAOKA, Naoki KAWASHIMA, Daisaku YOKOE, Makoto TANAKA, Yoichiro HABU, Mikako NAGAO, Kazuo NODA, Yoshiyasu ITO, Yuhei OHIDE, Kaito TAKAGI
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Patent number: 10914342Abstract: A sliding member includes: a base material; a solid lubricant layer arranged on a surface of the base material; a defect layer having a material defect, disposed in the solid lubricant layer, and being changeable into an ultra low friction layer by mechanical stress more easily than changing from the solid lubricant layer to the ultra low friction layer; and a ultra low friction layer covering a surface of the defect layer.Type: GrantFiled: December 21, 2018Date of Patent: February 9, 2021Assignees: DENSO CORPORATION, TOHOKU UNIVERSITY, TOCALO CO., LTD.Inventors: Kentaro Kishi, Yasunori Niiyama, Koshi Adachi, Shinya Miki
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Patent number: 10900111Abstract: A method for producing a surface-modified component includes: a process of forming a thermal sprayed coating on a substrate; a process of irradiating a surface of the thermal sprayed coating with a high energy beam so as to cause an entirety of the thermal sprayed coating and a part of the substrate in a thickness direction to melt and then solidify, and thereby forming a densified modified layer; a process of forming a thermal sprayed coating on the modified layer which has been formed in the latest; and a process of irradiating a surface of the thermal sprayed coating with a high energy beam so as to cause an entirety of the thermal sprayed coating and a part of the modified layer which has been formed in the latest in the thickness direction to melt and then solidify, and thereby forming a densified modified layer.Type: GrantFiled: June 27, 2016Date of Patent: January 26, 2021Assignee: TOCALO CO., LTD.Inventors: Hiroki Yokota, Tatsuya Fukushi, Tatsuo Suidzu
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Publication number: 20200391243Abstract: A coating is formed on a surface of a base material 11 of a furnace, and includes a base layer 12 and a sliding material layer 13 that is formed on a surface of the base layer 12 and contains an oxide ceramic and a compound having a layered crystal structure. The sliding material layer 13 causes the collided ashes to be slipped and facilitates the drop off of the adhered ashes. The base material 11 forms a heat transfer tube or a wall surface of the furnace. The coating is also applied to a coal gasification furnace, a pulverized coal fired boiler, a combustion apparatus, or a reaction apparatus containing a furnace.Type: ApplicationFiled: September 1, 2020Publication date: December 17, 2020Applicants: IHI Corporation, TOCALO Co.,LtdInventors: Naoki SATO, Nobuhiko KUBOTA, Koki HAMADA, Tatsuo SUIDZU, Kazuhiro TAKEUCHI
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Patent number: 10793818Abstract: The purpose of the present invention is to provide a culture container capable of preventing a concave meniscus without using a jig. In order to achieve this purpose, the present invention provides a culture container (1A) provided with: a base (3) having a concave portion (4); and a water-repellent layer (5) formed on an outer edge region (411) of the bottom (41) of the concave portion (4) and the inner circumferential surface (42) of the concave portion (4). One of the surfaces of the water-repellent layer (5) is exposed to the space in the concave portion (4).Type: GrantFiled: August 19, 2016Date of Patent: October 6, 2020Assignee: TOCALO CO., LTD.Inventors: Shinichi Gomi, Kenichi Kagawa, Yusuke Yoda, Shinya Miki, Tatsuya Hamaguchi
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Patent number: 10605304Abstract: An insulated bearing includes a pair of bearing rings arranged concentrically to each other and rolling elements arranged to be rotatable between the pair of bearing rings, at least one of the bearing rings having an insulating layer formed thereon. The one of the bearing rings having the insulating layer formed thereon has an annular groove having an arc-shaped cross section formed on each of both end surfaces of the bearing ring. At least a surface from a non-raceway surface side circumferential surface to the annular groove of the bearing ring is covered by the insulating layer. The insulating layer is a ceramic thermal sprayed layer.Type: GrantFiled: April 12, 2017Date of Patent: March 31, 2020Assignees: NSK LTD., TOCALO CO., LTDInventors: Manabu Yamada, Naozumi Nakata, Shinichi Nishiguchi, Junichi Takeuchi, Seiki Matsuura, Yuji Okada
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Patent number: 10605300Abstract: A thermal spray powder is provided that contains, as constituent elements, a first element selected from W and Mo; a second element selected from Co, Ni, and Fe; a third element selected from C and B; and a fourth element formed of Si. The amount of the second element in the thermal spray powder is 40% by mole or less. The mole ratio of the fourth element to the second element in the thermal spray powder is 0.002 or greater and 0.03 or less. The thermal spray powder has a crystal phase containing Co, Ni, or Fe; W; and C or a crystal phase containing Co, Ni, or Fe; W or Mo; and B. In an X-ray diffraction spectrum of the thermal spray powder, the peak intensity attributed to Co, Ni, or Fe is at most 0.1 times the largest peak intensity in the same X-ray diffraction spectrum.Type: GrantFiled: October 28, 2015Date of Patent: March 31, 2020Assignees: TOCALO CO., LTD., FUJIMI INCORPORATEDInventors: Noriyuki Yasuo, Takeshi Takabatake, Tatsuo Suidzu, Hiroaki Mizuno, Takaya Masuda, Tatsuya Kuno