Abstract: The invention provides a process for the production of purified dimethylether (DME). Methanol is dehydrated to provide a first DME-containing product. The first DME-containing product is purified in a two-stage process. The invention also provides an apparatus arranged to carry out said process.
Abstract: A method and system for temperature control in catalytic oxidation of hazardous compounds to protect the catalytic system against thermal overload by means of injecting adsorbing ammonia reagent, in order to reduce the exothermic reaction from oxidation and the resulting temperature rise.
Abstract: The invention relates to a catalytic reactor suited for exothermal reactions with a radial process fluid flow and process fluid flow guides which ensures an extended fluid flow path and higher flow velocity and thereby enhanced cooling of the catalyst bed in the reactor.
Type:
Application
Filed:
June 30, 2016
Publication date:
June 14, 2018
Applicant:
Haldor Topsøe A/S
Inventors:
Anders Lindhard Christensen, Emil Andreas Tjärnehov
Abstract: A reactor for a catalytic process comprising one or more catalyst beds has catalyst bed supports constructed as a grid comprising a plurality of cassettes (01), which are covered with easily removable screens (02). The down-time and service costs for the reactor are thereby lowered.
Abstract: In a process for the production of higher alcohols, i.e. C4+ alcohols, from syngas, the syngas is first reacted in a heterogeneous alcohol pre-converter (A) using an alcohol synthesis catalyst, whereby methanol as the main product in a concentration corresponding to or close to the equilibrium concentration is produced. Then the effluent from the pre-converter is mixed with unconverted wet recycle gas and reacted in a heterogeneous reactor for higher alcohols synthesis (B) containing a higher alcohols synthesis catalyst, and finally the effluent from the reactor for higher alcohols synthesis is separated into (i) unconverted syngas, which is recycled to the higher alcohols synthesis reactor, (ii) methanol and light alcohols, which are recycled to the higher alcohols synthesis reactor, and (iii) the final product consisting of higher alcohols.
Abstract: A process for co-production of ammonia, urea and methanol from natural gas, comprising the steps of (a) producing a synthesis gas by simultaneous feeding natural gas to an autothermal reformer (ATR) and to a steam methane reformer (SMR), the two reformers running in parallel, (b) feeding air to an air separation unit (ASU), where the air is split into oxygen, which is fed to the ATR, and nitrogen, (c) subjecting the synthesis gas from the SMR to a water gas shift, (d) removing the carbon dioxide from the synthesis gas from step (c) and leading it to urea synthesis in a urea synthesis unit, (e) combining the hydrogen-rich gas from step (d) with the nitrogen from step (b), removing catalyst poisons from the gases and leading the gas mixture to ammonia synthesis in an ammonia synthesis unit, (f) optionally removing part of the carbon dioxide from the syngas from the ATR in step (a) and leading it to urea synthesis in a urea synthesis unit and (g) leading the syngas from step (f) to the methanol synthesis unit, w
Abstract: A process for the preparation of lactic acid and 2-hydroxy-3-butenoic acid or esters thereof from a sugar in the presence of a metallo-silicate material, a metal ion and a solvent, wherein the metal ion is selected from one or more of the group consisting of potassium ions, sodium ions, lithium ions, rubidium ions and caesium ions.
Type:
Grant
Filed:
February 17, 2017
Date of Patent:
May 22, 2018
Assignee:
Haldor Topsoe A/S
Inventors:
Martin Spangsberg Holm, Irantzu Sadaba Zubiri, Søren Tolborg, Christian Mårup Osmundsen, Esben Taarning
Abstract: A process for the preparation of methionine ?-hydroxy analogue and derivatives thereof comprising contacting one or more sugars or derivatives thereof with a metallo-silicate composition in the presence of a compound comprising sulphur and a solvent.
Abstract: In a process for the removal of soot from a sulfurous gas stream, a process gas containing O2 and more than 500 ppm SO2 and/or SO3 together with soot is brought into contact with a VK type catalyst in a reactor, said catalyst comprising vanadium pentoxide (V2O5), sulfur in the form of sulfate, pyrosulfate, tri- or tetrasulfate and one or more alkali metals, such as Na, K, Rb or Cs, on a porous carrier, preferably a silicon dioxide carrier.
Type:
Application
Filed:
April 13, 2016
Publication date:
April 5, 2018
Applicant:
Haldor Topsøe A/S
Inventors:
Per Aggerholm Sørensen, Kurt Agerbæk Christensen
Abstract: The present application relates to a vessel support beam comprising two or more beam elements wherein each beam element comprises a first and second opposing long side connected by a top side, a lower side and two opposing end sides, said beam elements are arranged parallelly with at least one long side of one beam element facing a long side of another beam element, thereby forming a reactor support beam having a first and second opposing long side surface, a top surface and a lower surface.
Abstract: A process for the preparation of ethylene glycol comprising the steps of hydrogenating a composition comprising C2-oxygenate compounds in the gas phase in the presence of a catalyst.
Type:
Grant
Filed:
June 29, 2015
Date of Patent:
March 27, 2018
Assignee:
Haldor Topsoe A/S
Inventors:
Christian Mårup Osmundsen, Esben Taarning, Martin Spangsberg Holm
Abstract: A reformer device including a reaction chamber for carrying out a reaction having a hydrocarbon stream as a reactant gas and with hydrogen rich synthesis gas as a reaction product. The membrane is provided within the reaction chamber. The reformer device further includes a heating reactor for heating the reaction chamber, where the membrane is a semi-permeable membrane arranged to allow CO2 pass through it; the reaction chamber includes a catalyst material arranged to catalyze a steam methane reforming reaction and to catalyze a water gas shift reaction; and the reformer device is arranged to carry out the steam methane reforming reaction at a pressure between about 15 and about 50 barg within the reaction chamber. A method for carrying out a reaction having a hydrocarbon stream as a reactant gas and with hydrogen rich synthesis gas as reaction product, in a reformer device.
Type:
Application
Filed:
March 31, 2016
Publication date:
March 22, 2018
Applicant:
Haldor Topsøe A/S
Inventors:
Peter Mølgaard MORTENSEN, Martin ØSTBERG
Abstract: Method and system for removal of particles such as soot, ash and heavy metals, and optionally additionally NOX and SOX being present in exhaust gas from an engine or process equipment.
Abstract: Method for the preparation of a metal exchanged crystalline microporous metalloaluminophosphate or mixtures containing metal exchanged microporous metalloaluminophosphates materials comprising the steps of providing a dry mixture containing a) one or more metalloaluminophosphates starting materials that exhibit ion exchange capacity, and b) one or more metal compounds; heating the mixture in a gaseous atmosphere containing ammonia to a temperature (less than 300 C) and for a time sufficient to initiate and perform a solid state ion exchange of ions of the metal compound and ions of the crystalline microporous material; and obtaining the metal-exchanged microporous metalloaluminophosphate material or mixtures containing the metal-exchanged microporous metalloaluminophosphate material.
Type:
Grant
Filed:
October 15, 2014
Date of Patent:
March 13, 2018
Assignee:
Haldor Topsoe A/S
Inventors:
Ton V. W. Janssens, Peter N. R. Vennestrøm
Abstract: A method is disclosed for the preparation of a metal exchanged microporous materials, e.g. metal exchanged silicoaluminophosphates or metal exchanged zeolites, or mixtures of metal exchanged microporous materials, comprising the steps of providing a dry mixture of a) one or more microporous materials that exhibit ion exchange capacity and b) one or more metal compounds; heating the mixture in a gaseous atmosphere containing ammonia and one or more oxides of nitrogen to a temperature and for a time sufficient to initiate and perform a solid state ion exchange of ions of the metal compound and ions of the microporous material; and obtaining the metal-exchanged microporous material.
Type:
Grant
Filed:
October 15, 2014
Date of Patent:
February 20, 2018
Assignee:
Haldor Topsoe A/S
Inventors:
Ton V. W. Janssens, Peter N. R. Vennestrøm
Abstract: Catalyzed filter consisting of a filter body of bio-soluble fibers catalyzed with a catalyst comprising oxides of vanadium and titanium, wherein the total concentration of alkali metals in the filter body is less than 3000 ppm by weight and/or the total concentration of alkali earth metals in the filter body is less than 20% by weight.
Type:
Grant
Filed:
March 13, 2014
Date of Patent:
February 20, 2018
Assignee:
Haldor Topsoe A/S
Inventors:
Francesco Castellino, Joakim Reimer Thøgersen, Peter Schoubye
Abstract: The invention relates to a catalyst regeneration process for a tar reforming catalyst within a catalyst bed in a tar reformer. The process comprises the steps of:—Admitting a main gas stream with controlled temperature and oxygen content to an inlet into the tar reformer;—Passing the main gas stream through the catalyst bed to form an oxygen depleted gas stream;—Exiting the oxygen depleted gas stream from the tar reformer; and—Recycling at least a part of the oxygen depleted gas stream exiting from the tar reformer back into said main gas stream upstream said tar reformer. The temperature of said main gas stream at the inlet is controlled to be within the range from about 500° C. to about 1000° C.
Type:
Grant
Filed:
December 15, 2015
Date of Patent:
February 20, 2018
Assignee:
Haldor Topsoe A/S
Inventors:
John Bøgild Hansen, Jørgen Madsen, Klas Jerker Andersson
Abstract: Process for the production of a synthesis gas for use in the production of chemical compounds from a hydrocarbon feed stock containing higher hydrocarbons comprising the steps of: (a) in a pre-reforming stage pre-reforming the feed stock with steam to a pre-reformed gas containing methane, hydrogen, carbon monoxide and carbon dioxide; and (b) cooling the pre-reformed gas to below its dewpoint and removing condensed water; and (c) reducing the amount of carbon dioxide the in the pre-reformed gas from step (b) to obtain a module of (H2?CO2)/(CO+CO2) of between 1.0 and 3.8 in the pre-reformed gas.
Abstract: Process for the production of synthesis gas from hydrocarbon feed containing higher hydrocarbons comprising bypassing a portion of the hydrocarbon feed around a first pre-reforming stage and passing the pre-reformed and bypassed portions through at least a second pre-reforming stage.