Abstract: Process and plant for conversion of a feed hydrocarbon stream to liquid hydrocarbon products in a small scale GTL plant, comprising the use of a cryogenic air separation unit (ASU), optionally together with vacuum pressure swing adsorption (VPSA), an autothermal reformer (ATR) or catalytic partial oxidation (CPO), and pressure swing adsorption (PSA) unit to produce a synthesis gas for downstream Fischer-Tropsch (FT) synthesis for production of liquid hydrocarbons.
Abstract: Process for producing hydrogen in which tail gas from a separate plant for production of gasoline or diesel is added downstream the steam methane reforming stage and upstream the water gas shift stage of a hydrogen production plant.
Abstract: A process for the preparation of C4 oxygenate compounds such as threose, erythrose or erythrulose starting from a composition comprising C1-3 oxygenate compounds such as formaldehyde, glycolaldehyde, glyoxal, pyruvaldehyde or acetol, wherein the process is carried out in the presence of a crystalline microporous material having a ring pore structure selected from an eight-membered ring pore structure or a ten-membered ring pore structure.
Abstract: Present application relates to a mixing device (10) for mixing a first gas with a second gas, the second gas being corrosive to the mixing device. The mixing device comprises a first gas guiding part (12) having a first gas guiding inlet part (14) and a first gas guiding outlet part (16), a second gas guiding part (18) having a second gas guiding inlet part (20) and a second gas guiding outlet part (22), the second gas guiding outlet part arranged in the first gas guiding part so that the first gas and the second gas are mixed and a guide vane configured to establish a swirling motion in the first gas. Further disclosed is a related method.
Type:
Grant
Filed:
February 22, 2010
Date of Patent:
May 9, 2017
Assignee:
Haldor Topsoe A/S
Inventors:
Louise Jivan Shah, Per Morsing, Søren Heinesen
Abstract: Method for the preparation of a metal exchanged crystalline microporous metalloaluminophosphate or mixtures containing metal exchanged microporous metalloaluminophosphates materials comprising the steps of providing a dry mixture containing a) one or more metalloaluminophosphates starting materials that exhibit ion exchange capacity, and b) one or more metal compounds; heating the mixture in a gaseous atmosphere containing ammonia to a temperature and for a time sufficient to initiate and perform a solid state ion exchange of ions of the metal compound and ions of the crystalline microporous material; and obtaining the metal-exchanged microporous metalloaluminophosphate material or mixtures containing the metal-exchanged microporous metalloaluminophosphate material.
Type:
Application
Filed:
October 15, 2014
Publication date:
April 27, 2017
Applicant:
Haldor Topsøe A/S
Inventors:
Ton V.W. Janssens, Peter N.R. Vennestrøm
Abstract: Process and plant for conversion of a feed hydrocarbon stream to liquid hydrocarbon products in a small scale GTL plant, comprising the use of a cryogenic air separation unit (ASU), optionally together with vacuum pressure swing adsorption (VPSA), an autothermal reformer (ATR) or catalytic partial oxidation (CPO), and pressure swing adsorption (PSA) unit to produce a synthesis gas for downstream Fischer-Tropsch (FT) synthesis for production of liquid hydrocarbons.
Abstract: A catalyst for the conversion of oxygenates, such as alcohols or ethers, to olefins consists essentially of a selected SUZ-4 zeolite that has a Si/Al ratio of at least 20, preferably between 20 and 500, especially between 20 and 100. The basic SUZ-4 zeolite is prepared in a manner known per se, whereafter the Si/Al ratio is increased to the desired value. The selected SUZ-4 zeolite catalyst of the invention has a longer life time and a better product selectivity than the conventional/standard SUZ-4 zeolite catalysts.
Type:
Grant
Filed:
July 20, 2012
Date of Patent:
April 11, 2017
Assignee:
Haldor Topsoe A/S
Inventors:
Shewangizaw Teketel, Stian Svelle, Pablo Beato
Abstract: Method for the preparation of a metal-exchanged zeolites or mixtures of metal-exchanged zeolites, such as Cu-SSZ-13, Cu-ZSM-S, Cu-beta, or Fe-beta, comprising the steps of providing a dry mixture of a) one or more microporous zeotype materials that exhibit ion exchange capacity and b) one or more metal compounds; heating the mixture in a gaseous atmosphere containing ammonia to a temperature lower than 300° C. for a time sufficient to initiate and perform a solid state ion exchange of ions of the metal compound and ions of the zeolite material; and obtaining the metal-exchanged zeolitematerial.
Type:
Application
Filed:
October 15, 2014
Publication date:
April 6, 2017
Applicant:
Haldor Topsøe A/S
Inventors:
Ton V.W. Janssens, Peter N.R. Vennestrøm
Abstract: Process for the preparation of dimethyl ether product by catalytic conversion of synthesis gas to dimethyl ether comprising the steps of contacting a stream of synthesis gas comprising carbon dioxide in a dimethyl ether synthesis step in one or more reactors and with one or more catalysts active in the formation of methanol and dehydration of methanol to dimethyl ether and forming a product mixture comprising dimethyl ether, carbon dioxide and unconverted synthesis gas; cooling and separating the product mixture into a first liquid phase comprising dimethyl ether and carbon dioxide being dissolved in the formed dimethyl ether, and into a first gaseous phase comprising unconverted synthesis gas containing carbon monoxide and carbon dioxide; passing the first liquid phase to a scrubbing zone and contacting the phase with a liquid sorbent being effective in absorption of carbon dioxide; and withdrawing a dimethyl ether product being depleted in carbon dioxide from the scrubbing zone.
Type:
Grant
Filed:
August 14, 2013
Date of Patent:
April 4, 2017
Assignee:
Haldor Topsoe A/S
Inventors:
Finn Joensen, Jorgen Madsen, Poul Erik Højlund Nielsen
Abstract: A sandwiched gasket is used for an SOC stack system to provide flexible, yet electrically insulation properties to the sealing between mounting interfaces of the system.
Type:
Application
Filed:
March 30, 2015
Publication date:
March 23, 2017
Applicant:
Haldor Topsøe A/S
Inventors:
Lars Kiilstofte Hansen, Cliver Søren Klitholm, Thomas Heiredal-Clausen, Niels Erikstrup, Martin Refslund Niesen
Abstract: The invention relates to a gas treatment monolith article, said gas treatment article comprising: a full body porous material comprising a porous substrate and an aluminium oxide coating homogeneously distributed throughout said porous substrate, wherein said porous substrate is a fibrous material; and at least one acid gas absorption active component or a precursor thereof impregnated into said porous aluminium oxide coated substrate. The invention further relates to uses of the gas treatment monolith article of the invention.
Abstract: The invention relates to a process for the production of liquid hydrocarbons by Fischer-Tropsch synthesis in which the reforming section of the plant comprises a process line comprising autothermal reforming (ATR) (5) or catalytic partial oxidation (CPO), and a separate process line comprising steam methane reforming (SMR) (8).
Abstract: A reactor for a catalytic process comprising one or more catalyst beds has catalyst bed supports constructed as a grid comprising a plurality of cassettes (01), which are covered with easily removable screens (02). The down-time and service costs for the reactor are thereby lowered.
Abstract: Process for the production of synthesis gas by catalytic steam reforming of a hydrocarbon containing feedstock in parallel in an autothermal steam reformer and heat exchange reformer, the heat for the steam reforming reactions in the heat exchange reformer being provided by indirect heat exchange with the combined effluent of the heat exchange reformer and a portion of the autothermal steam reformer.
Abstract: A hydrocracking process by the steps of: (a) providing a mixture comprising hydrocarbonaceous feedstock and hydrogen; (b) obtaining a hydrocracked effluent; (c) separating the hydrocracked effluent into a first vapor portion and a first liquid portion; (d) heating the first liquid portion to form a vapourised first liquid portion; (e) feeding the vaporised first liquid portion to a fractionation section producing individual product fractions including a heavy bottom fraction; (f) withdrawing from the fractionation section the heavy bottom fraction; (g) splitting the heavy bottom fraction in a stream for stripping and a heavy bottom fraction recycle stream; (h) stripping the stream for stripping, with a stripping medium, in a counter current stripping column to form an overhead vapor and a stripped liquid; (i) feeding the overhead vapor to the fractionation section, to a recycle stream or to a position upstream the fractionation section.
Type:
Grant
Filed:
October 5, 2011
Date of Patent:
February 28, 2017
Assignee:
Haldor Topsoe A/S
Inventors:
Gordon Gongngai Low, Michael Glenn Hunter
Abstract: Method and system for removal of soot, ash and heavy metals, and optionally additionally NOx and SOx being present in exhaust gas from an engine operated on heavy fuel oil with sulphur content 0.1%-4.0 wt % and a heavy metal element content of 5 mg/kg to 1000 mg/kg.
Abstract: A process for the direct synthesis of Cu-SAPO-34 comprising at least the steps: preparation of a mixture of water, at least one silicon source, at least one Al source, at least one P source, at least one Cu source, at least one 0SDA1 (any polyamine), and at least one OSDA2 source (where OSDA2 is any organic molecule capable of directing the synthesis of SAPO 34); and where the final synthesis mixture has the molar composition: a Si:0.5 Al:c Cu:d OSDA1:e OSDA2:f H2O wherein a is in the range from 0.01 to 0.3; b is in the range from 0.2 to 0.49; c is in the range from 0.001 to 0.6; d is in the range from 0.001 to 0.6; e is in the range from 0.001 to 2; f is in the range 1 to 200; hydrothermal treatment of the mixture at 80?200° C. until formation of the crystalline material, and recovery of the crystalline material.
Abstract: The invention provides a method and system for the purification of exhaust gas from an internal combustion engine, comprising a filter and a SCR catalyst. The filter is periodically regenerated increasing the temperature of the exhaust gas up to 850° C. and the water vapor content up to 100% by volume. The SCR catalyst comprises a hydrothermally microporous stable zeolite and/or zeotype having the AEI type framework and being promoted with copper.
Type:
Grant
Filed:
April 27, 2012
Date of Patent:
February 7, 2017
Assignee:
Haldor Topsoe A/S
Inventors:
Manuel Moliner Marin, Cristina Franch Marti, Antonio Eduardo Palomares Gimeno, Avelino Corma Canós, Peter N. R. Vennestrøm, Marie Grill, Arkady Kustov, Joakim Reimer Thøgersen
Abstract: The present disclosure relates in a broad form to a pseudo-isothermal flow reactor (100) for an exothermal reaction comprising at least two reaction enclosures (108, 114) and a cooling medium enclosure (102) configured to hold a cooling medium under pressure at the boiling point of said cooling medium, said reaction enclosures (108, 114) having an outer surface configured to be in thermal contact with the cooling medium, and each of said reaction enclosures (108, 114) having an inlet and an outlet with the associated benefit of enabling a two-stage pseudo-isothermal operation while only requiring a single cooling medium enclosure (102) and only single cooling medium circuit.
Type:
Application
Filed:
March 31, 2015
Publication date:
January 26, 2017
Applicant:
Haldor Topsøes A/S
Inventors:
Christian Wix, Michael Boe, Anders Helbo Hansen
Abstract: NH3—SCR catalyst, containing iron promoted beta-zeolite, cerium oxide and titanium oxide and optionally further containing at least one of tungsten oxide, neodymium oxide, silicon oxide and diatomaceous earth, and method of preparation thereof.
Type:
Grant
Filed:
August 31, 2012
Date of Patent:
December 27, 2016
Assignee:
Haldor Topsoe A/S
Inventors:
Lived J. Lemus-Yegres, Niklas Bengt Jakobsson