Abstract: According to the present invention a process is provided for producing glycolide which comprises contacting glycolaldehyde dimer with an oxidizing agent to produce a glycolide product. Preferably, the process is carried out in an aprotic environment, such as in a reaction mixture comprising the glycolaldehyde dimer, the oxidizing agent, the glycolide product and an aprotic solvent.
Type:
Application
Filed:
November 29, 2019
Publication date:
November 11, 2021
Applicant:
HALDOR TOPSØE A/S
Inventors:
Amanda Birgitte SØLVHØJ, Rik DE CLERCQ, Esben TAARNING
Abstract: A catalytic reactor comprises a load distributor assembly to evenly transfer a load from equipment (internals) to a reactor support ring or support structure fixed within the reactor shell, thereby maximizing the possible load to be applied to the support ring or support structure without any hot-work modifications and without exceeding the allowable tensions/stress.
Type:
Application
Filed:
December 4, 2019
Publication date:
November 4, 2021
Applicant:
HALDOR TOPSØE A/S
Inventors:
Marc Nybo HAMMER, Klaus RISBJERG JARLKOV
Abstract: The invention relates to a method of preparing a sodium metal oxide material comprising NaxMyCozO2-?, where M is one or more of the following elements: Mn, Cu, Ti, Fe, Mg, Ni, V, Zn, Al, Li, Sn, Si, Ga, Ge, Sb, W, Zr, Nb, Mo, Ta, 0.7?x?1.3, 0.9?y?1.1, 0?z<0.15, 0???0.2 and wherein the average length of primary particles of said sodium metal oxide material is between 2 and 10 ?m, preferably between 5 and 10 ?m. The invention also relates to such a material.
Abstract: In a cooled axial flow converter, in which process gas passes from an outer annulus via a catalyst bed, wherein the process gas is converted to a product, to an inner centre tube, the catalyst bed comprises at least one module comprising at least one catalyst layer. Feed means are arranged to provide a flow of process gas from the outer annulus to an inlet part of one or more modules, and collector means are arranged to provide a flow of product stream of converted process gas, which has passed axially down the catalyst bed of one or more of the modules to the centre tube. At least one of the one or more modules comprises one or more cooling plates arranged to be cooled by a cooling fluid.
Abstract: The invention relates to a sodium metal oxide material for an electrode of a secondary battery, where the sodium metal oxide material comprises: NaxMyCozO2-?, where M contains one or more of the following elements: Mn, Cu, Ti, Fe, Mg, Ni, V, Zn, Al, Li, Sn, Sb, 0.7?x?1.3, 0.9?y?1.1, 0?z<0.15, 0??<0.2 and wherein the average length of primary particles of said sodium metal oxide material is between 3 and 10 ?m, preferably between 5 and 10 ?m. The invention also relates to a method for producing the sodium metal oxide material of the invention.
Abstract: In a process for the start-up of a hydrodesulfurization section, comprising the steps of providing a natural gas feed, passing the natural gas feed through the waste heat section of a reformer, thereby heating the natural gas feed, and passing the heated natural gas feed through a hydrodesulfurization section, thereby heating the hydrodesulfurization section while producing a desulfurized natural gas stream, a part of the desulfurized natural gas stream is provided as fuel for the reformer, while the remainder of the desulfurized natural gas is recycled to at least one point upstream the waste heat section.
Abstract: A process for separation of a liquid phase from a gas phase and a process for production of a hydrocarbon product employing such a separation as well as a fractionation section and a hydrocracker section for carrying out such processes. The separation process includes: directing a feed for separation to a feed inlet of a means of separation; directing a stripping medium to a stripping medium inlet of the means of separation; withdrawing a liquid product stream from a means of separation; withdrawing a gaseous fraction comprising the stripping medium from the means of separation; directing the stripping medium fraction or the gaseous fraction as a recycled stripping medium; pressurizing at least an amount of the recycled stripping medium and directing it as the stripping medium, wherein the stripping medium comprises at least 80% vol/vol % of gases from the group comprising N2, H2, He, Ar, Ne and CO2.
Abstract: A process for hydrodesulfurizing an olefinic naphtha feedstock while retaining a substantial amount of the olefins, which feedstock has a T95 boiling point below 250° C. and contains at least 50 ppmw of organically bound sulfur and from 5% to 60% olefins, the process including hydrodesulfurizing the feedstock in a sulfur removal stage in the presence of a gas including hydrogen and a hydrodesulfu-rization catalyst, at hydrodesulfurization reaction conditions, to convert at least 60% of the organically bound sulfur to hydrogen sulfide and to produce a desulfurized product stream, with the associated benefit of such a process providing a lower octane loss at all severities above 60% HDS, compared to a process with similar conversion of organic sulfur with a lower gas to oil ratio, as measured by the selectivity slope, while avoiding excessive increase of equipment size by limiting gas to oil ratio.
Abstract: In a method for the precipitation of particles of a metal carbonate material comprising nickel and manganese in an atomic ratio of 0?Ni:Mn?1:3, aqueous solutions comprising sulfates or nitrates of nickel and manganese are mixed with aqueous solutions of carbonates or mixtures of carbonates and hydroxides of sodium or potassium in a stirred reactor at pH>7.5 without the use of a chelating agent. Thereby agglomerated particles are formed without any subsequent process steps, in particular no subsequent process at temperatures higher than the precipitation temperature.
Type:
Application
Filed:
July 11, 2017
Publication date:
September 30, 2021
Applicant:
HALDOR TOPSØE A/S
Inventors:
Line Holten KOLLIN, Rainer Küngas, Steen Henrik Olsen, Anni Stahl, Søren DAHL
Abstract: Process for the co-production of methanol and ammonia from a hydrocarbon feed without venting to the atmosphere carbon dioxide captured from the methanol or ammonia synthesis gas and without using expensive air separation units and water gas shift.
Abstract: Process for the co-production of methanol and ammonia together with urea production from a hydrocarbon feed without venting to the atmosphere carbon dioxide captured from the methanol or ammonia synthesis gas and without using expensive air separation units and water gas shift. Carbon dioxide removal from flue gas from reforming section to convert partially or fully all ammonia into urea. Synergi of having methanol, ammonia and urea production to produce coating material for the urea production.
Abstract: The present invention relates to a process for the production of glycolaldehyde by thermolytic fragmentation of a carbohydrate feedstock comprising mono- and/or di-saccharide(s) and a system suitable for performing the process. The process and the system are suitable for industrial application, and the process may be performed in a continuous process.
Type:
Application
Filed:
December 8, 2017
Publication date:
September 23, 2021
Applicant:
HALDOR TOPSØE A/S
Inventors:
Christian Mårup Osmundsen, Morten Boberg Larsen
Abstract: A process for producing an ammonia synthesis gas, said process comprising the steps of: —Reforming a hydrocarbon feed in a reforming step thereby obtaining a synthesis gas comprising CH4, CO, CO2, H2 and H2O, —Shifting the synthesis gas in one in or more shift steps in series, —Optionally wash the synthesis gas leaving the shift section with water, —Sending the process condensate originating from cooling and washing the synthesis gas leaving the shift section to a process condensate stripper wherein the dissolved shift byproducts and dissolved gases are stripped out of the process condensate using steam resulting in a steam stream containing more than 99% of the dissolved methanol in process condensate. —Adding all or part of said steam stream from the process condensate stripper to the synthesis gas downstream the reforming step, prior to the last shift step, wherein —The steam/carbon ratio in the reforming step and the shift step is less than 2.6.
Type:
Grant
Filed:
March 7, 2018
Date of Patent:
September 21, 2021
Assignee:
Haldor Topsoe A/S
Inventors:
Christian Henrik Speth, Per Juul Dahl, Annette E. Krøll Jensen, Niels Christian Schjødt, Marcus Symreng
Abstract: A process for co-production of methanol and ammonia in parallel based on autothermal reforming with oxygen enriched air from electrolysis of water and separation of air and preparation of ammonia with hydrogen from the electrolysis of water and nitrogen from the separation of air.
Abstract: A method for converting a feedstock comprising solid hydrocarbons to a sweet synthesis gas, involving the steps a. gasifying said feedstock in the presence of steam, an oxygen rich gas and an amount of sour process gas to form a raw synthesis gas optionally comprising tar, b. optionally conditioning said raw synthesis gas to a sour shift feed gas, c. contacting said sour shift feed gas with a sulfided material catalytically active in the water gas shift process for providing a sour hydrogen enriched synthesis gas, d. separating H2S and CO2 from said sour hydrogen enriched synthesis gas, for providing said sour recycle gas and a sweet hydrogen enriched synthesis gas.
Abstract: In a novel method for start-up heating of a converting re-actor in an ammonia synthesis plant, the conventional use of a gas fired heater is replaced by inductive heating. The inductive heating is obtained using an alternating high frequency current, which is passed through an inductive coil located inside the reactor, especially mounted inside a pressure shell. The method makes it possible to run reactions at high temperatures and high pressures in a very efficient way.
Abstract: A reactor layout for a process of methanol production from low quality synthesis gas, in which relatively smaller adiabatic reactors can be operated more efficiently, some of the inherent disadvantages of adiabatic reactors for methanol production are avoided. This is done by controlling the outlet temperature in the pre-converter by rapid adjustment of the recycle gas, i.e. by manipulating the gas hourly space velocity in the pre-converter.
Abstract: A method for increasing the carbon utilisation of a synthesis gas plant is provided, as well as a synthesis gas plant arranged to perform said method. Various gas streams can be combined and recycled to allow for efficient use of a natural gas feedstock.
Type:
Application
Filed:
September 26, 2019
Publication date:
September 2, 2021
Applicant:
HALDOR TOPSØE A/S
Inventors:
Peter Mølgaard MORTENSEN, Arunabh SAHAI
Abstract: A method for producing methanol comprises the steps of passing a feed stream of methanol synthesis pas through a main methanol reactor containing a methanol synthesis catalyst, to form a mixed gas containing methanol, cooling the mixed gas containing methanol, separating methanol from the mixed pas and heating the mixed gas. The stream of heated mixed gas is passed through an additional methanol reactor containing a methanol synthesis catalyst, and the effluent from the additional methanol reactor is mixed with the feed stream of methanol synthesis gas and passed through the main methanol reactor.
Abstract: A process for large scale and energy efficient production of oxygenates from sugar is disclosed in which a sugar feedstock is introduced into a thermolytic fragmentation reactor comprising a fluidized stream of heat carrying particles which are separated from the reaction product and directed to a reheater comprising a resistance heating system.
Type:
Application
Filed:
July 16, 2019
Publication date:
August 26, 2021
Applicant:
HALDOR TOPSØE A/S
Inventors:
Lars Storm PEDERSEN, Morten Boberg LARSEN, Peter Mølgaard MORTENSEN