Abstract: The present application relates to a process for treating the off gas from a carbon black process, said process comprising the steps of: providing an off gas from a carbon black process, reacting said off gas in a first reaction step forming water and S, and condensing the S at a temperature Tcon where S is in a liquid phase and the water is in gas form thereby achieving a gaseous stream comprising water and a liquid stream comprising S, and wherein the first reaction step is carried out over a monolith catalyst.
Type:
Application
Filed:
January 25, 2018
Publication date:
June 18, 2020
Applicant:
Haldor Topsøe A/S
Inventors:
Niklas Bengt Jakobsson, Peter Bo Olsen, Janus Emil Münster-Swendsen
Abstract: A process for combined removal of siloxanes and sulfur-containing compounds from biogas streams, such as streams from landfills or anaerobic digesters, comprises heating the biogas stream and optionally mixing it with air, feeding the gas to a first filter unit with high temperature resistance, injecting a dry sorbent into the first filter unit to capture siloxanes present in the gas, recycling part of the exit gas from the first filter unit to the inlet thereof for the sulfur-containing compounds to be captured by the dry sorbent or optionally to a second filter unit inlet for the sulfur-containing compounds to be captured by a sulfur-specific sorbent and recovering clean gas from the first or optionally from the second filter unit.
Type:
Grant
Filed:
June 13, 2017
Date of Patent:
June 16, 2020
Assignee:
Haldor Topsoe A/S
Inventors:
Niklas Bengt Jakobsson, Janus Emil Münster-Swendsen
Abstract: A catalyst-containing ceramic dust filter for off-gas or exhaust gas cleaning is prepared by a method comprising the steps of making a water-based impregnation slurry, which comprises a catalytically effective amount of at least one catalytically active metal and an oxide support, to form a catalytically active metal oxide support, impregnating the filter substrate with the impregnation slurry, spraying from the inside to control the amount of liquor while leaving the outer few millimeters of the filter wall dry, and drying the impregnated filter. The impregnated filter is preferably dried by using microwave energy.
Abstract: In a process for the production of ammonia synthesis gas from a hydrocarbon-containing feedstock, comprising steam reforming of the feedstock and treatment of the synthesis gas obtained, the shift of the synthesis gas comprises two shift steps, both including stable catalysts, whereby the formation of hazardous by-products is avoided or at least reduced to an acceptable low level. The two shift steps can both be HTS, or they can be one HTS and one LTS or one HTS and one MTS. The catalyst used in the HTS and the LTS steps is based on zinc oxide and zinc aluminum spinel, and the catalyst used in the MTS and the LTS steps can be based on copper.
Type:
Application
Filed:
June 28, 2018
Publication date:
June 11, 2020
Applicant:
HALDOR TOPSØE A/S
Inventors:
Annette E. KRØLL JENSEN, Christian Henrik SPETH, Thomas ROSTRUP-NIELSEN
Abstract: Oxygen is removed from a gas feed such as a landfill gas, a digester gas or an industrial CO2 off-gas by removing sulfur-containing compounds and siloxanes from the feed gas, heating the feed gas, injecting one or more reactants for oxygen conversion into the heated feed gas, carrying out a selective catalytic oxygen conversion in at least onesuitable reactor and cleaning the resulting oxygen-depleted gas. The reactants to be injected comprise one or more of H2, CO, ammonia, urea, methanol, ethanol and dimethylether (DME).
Abstract: A process including (a) directing a hydrocarbon mixture to contact a material catalytically active in hydrocracking under hydrocracking conditions, (b) providing a first hydrocracked product, (c) directing an amount of the first hydrocracked product and an amount of a converted hydrocracked product to a product separation step separating it into one or more products and a recycle oil having a higher boiling point than the products, (d) directing the recycle oil to contact a second material catalytically active in hydrocracking under hydrocracking conditions providing a second hydrocracked product, (e) directing at least an amount of the second hydrocracked product as feed to a second separation step, separating the second hydrocracked product in at least two fractions, a converted hydrocracked product and an unconverted oil an unconverted oil having a higher average boiling point than the recycle oil, (f) withdrawing at least an amount of the unconverted oil as purge.
Abstract: A method for the purification of a raw gas stream by selective catalytic oxidation, in which organic and inorganic sulfur compounds, halogenated and non-halogenated volatile organic compounds are selectively oxidized without substantially oxidizing the lower hydrocarbons and the sulfur containing compounds present in the gas to sulfur trioxide and excess of oxygen is removed by oxidation of lower alcohols, ethers or hydrogen added to the raw gas stream upstream the catalytic oxidation.
Abstract: A heat exchanger has a pass baffle which is formed as an enclosure with two openings, one opening for connection to a shell-side fluid opening and one opening for passing heat exchanger tubes.
Abstract: The invention relates to a chemical reactor comprising at least one catalyst support system and anti-blocking means arranged around and above a reactor opening, which prevents catalyst or other reactor parts to enter or exit a reactor opening.
Type:
Grant
Filed:
February 22, 2018
Date of Patent:
May 26, 2020
Assignee:
Haldor Topsoe A/S
Inventors:
Anders Helbo Hansen, Thomas Sandahl Christensen, Magnus Møller Jørgensen, Johannes Ruben Larsen
Abstract: A process for the combined preparation of methanol and ammonia based on primary steam reforming a hydrocarbon feed stock and adiabatic secondary reforming with oxygen enriched air from electrolysis of water.
Abstract: Oxygen is removed from a gas feed such as a landfill gas, a digester gas or an industrial CO2 off-gas by heating the feed gas, optionally removing siloxanes and silanols from the heated feed gas, optionally removing part of the sulfur-containing compounds in the heated feed gas, injecting one or more reactants for oxygen conversion into the heated feed gas, carrying out a selective catalytic conversion of any or all of the volatile organic compounds (VOCs) present in the gas, including sulfur-containing compounds, chlorine-containing compounds and any of the reactants injected, in at least one suitable reactor, and cleaning the resulting oxygen-depleted gas. The reactants to be injected comprise one or more of H2, CO, ammonia, urea, methanol, ethanol and dimethyl ether (DME).
Abstract: In a method for cooling of process gas between catalytic layers or beds in a sulfuric acid plant, in which sulfuric acid is produced from feed gases containing sulfurous components like SO2, H2S, CS2 and COS or liquid feeds like molten sulfur or spent sulfuric acid, one or more boilers, especially water tube boilers, are used instead of conventional steam superheaters to cool the process gas between the catalytic beds in the SO2 converter of the plant. Thereby a less complicated and more cost efficient heat exchanger layout is obtained.
Abstract: A reformer device including a reaction chamber for carrying out a reaction having a hydrocarbon stream as a reactant gas and with hydrogen rich synthesis gas as a reaction product. The membrane is provided within the reaction chamber. The reformer device further includes a heating reactor for heating the reaction chamber, where the membrane is a semi-permeable membrane arranged to allow CO2 pass through it; the reaction chamber includes a catalyst material arranged to catalyze a steam methane reforming reaction and to catalyze a water gas shift reaction; and the reformer device is arranged to carry out the steam methane reforming reaction at a pressure between about 15 and about 50 barg within the reaction chamber. A method for carrying out a reaction having a hydrocarbon stream as a reactant gas and with hydrogen rich synthesis gas as reaction product, in a reformer device.
Type:
Grant
Filed:
March 31, 2016
Date of Patent:
May 12, 2020
Assignee:
HALDOR TOPSØE A/S
Inventors:
Peter Mølgaard Mortensen, Martin Østberg
Abstract: A lithium positive electrode active material intermediate comprising less than 80 wt % spinel phase and a net chemical composition of LixNiyMn2-yO4-? wherein 0.9?x?1.1; 0.4?y?0.5; and 0.1??; where the lithium positive electrode active material intermediate has been heat treated in a reducing atmosphere at a temperature of from 300° C. to 1200° C. A process for the preparation of a lithium positive electrode active material with high tap density for a high voltage secondary battery where the cathode is fully or partially operated above 4.4 V vs. Li/Li+, comprising the steps of a) heating a precursor in a reducing atmosphere at a temperature of from 300° C. to 1200° C. to obtain a lithium positive electrode active material intermediate; b) heating the product of step a. in a non-reducing atmosphere at a temperature of from 300° C. to 1200° C.
Type:
Grant
Filed:
August 24, 2016
Date of Patent:
May 12, 2020
Assignee:
HALDOR TOPSØE A/S
Inventors:
Jon Fold Von Bülow, Søren Dahl, Jonathan Højberg, Jakob Weiland Høj
Abstract: Method for the preparation of synthesis gas by combining electrolysis of water, autothermal reforming and heat exchange reforming of a hydrocarbon feed stock.
Type:
Application
Filed:
July 20, 2018
Publication date:
May 7, 2020
Applicant:
Haldor Topsøe A/S
Inventors:
Kim Aasberg-Petersen, Pat A. Han, Peter Mølgaard Mortensen
Abstract: Sulfur trioxide is produced from a feed stream comprising sulfur-containing compounds and dissolved metals, such as alkali metals, in a plant comprising an incineration furnace, a waste heat boiler, a dilution air heater, a dust removal absorber and an SO2 converter. The plant may further comprise a sulfuric acid condenser for the production of sulfuric acid.
Abstract: Method for the preparation of synthesis gas based on a combination of the ATR process or partial oxidation of hydrocarbon fee stock using oxygen from the electrolysis of water and an air separation unit to produce the synthesis gas.
Abstract: The invention is a method and a sulfuric acid plant design for reduction of start-up SO2, SO3 and H2SO4 emissions in sulfuric acid production, in which SO2 is converted to SO3 in n successive catalyst beds, where n is an integer >1. The final catalytic beds are used as absorbents for SO2 to SO3 during the start-up procedure, and one or more of the m beds downstream the first bed are purged, either separately or simultaneously, with hot gas, where m is an integer >1 and m<n, during the previous shut-down. Also, one separate purge with hot gas is used on the final bed.
Type:
Grant
Filed:
October 24, 2016
Date of Patent:
April 28, 2020
Assignee:
HALDOR TOPSØE A/S
Inventors:
Mårten Nils Rickard Granroth, Per Aggerholm Sørensen, Kurt Agerbæk Christensen