Patents Assigned to Topsoe A/S
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Publication number: 20200369577Abstract: In a method for the production of a fertilizer from the sulfur and ammonia content in a feed gas, including steps of (a) combustion of the H2S-rich gas in air to convert H2S to SO2, (b) formation of ammonium hydrogen sulfite (AHS) by absorption of SO2 and NH3 in water, and (c) reaction of the AHS from step (b) with H2S and NH3 to form an aqueous solution of ammonium thiosulfate (ATS), reaction (a) is carried out in a catalytic reactor as a selective oxidation of the H2S content to SO2 over a selective catalyst having one or more metal oxides, in which the metal is selected from the group of V, W, Ce, Mo, Fe, Ca and Mg, and one or more supports taken from the group of Al2O3, SiO2, SiC and TiO2, optionally in the presence of other elements in a concentration below 1 wt %.Type: ApplicationFiled: February 11, 2019Publication date: November 26, 2020Applicant: HALDOR TOPSØE A/SInventors: Niklas Bengt JAKOBSSON, Kurt Agerbæk CHRISTENSEN, Janus Emil MÜNSTER-SWENDSEN, Kresten EGEBLAD
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Publication number: 20200368706Abstract: A method and reactor for performing exothermic reactions with parallel operated catalyst modules arranged in stacked order within a pressure shell and adapted to axial flow of process gas through one or more catalyst layers and at least one catalyst layer cooled by an intrabed heat exchanger.Type: ApplicationFiled: December 19, 2018Publication date: November 26, 2020Applicant: Haldor Topsøe A/SInventors: Christian Henrik Speth, Tommy Lykke Wind, Uffe Bach Thomsen, Anders Helbo Hansen
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Publication number: 20200368684Abstract: A process for the removal of nitrous oxide (N2O) contained in a process off-gas in an axial flow reactor. The process includes the steps of (a) adding an amount of reducing agent into the process off-gas; (b) in a first stage passing in axial flow direction the process off-gas admixed with the reducing agent through a first monolithic shaped catalyst active in decomposing nitrous oxide by reaction with the reducing agent to provide a gas with a reduced amount of nitrous oxide and residual amounts of reducing agent; and (c) in a second stage passing the gas with a reduced amount of nitrous oxide and residual amounts of the reducing agent in axial flow direction through a second monolithic shaped catalyst active in oxidation of the residual amounts of the reducing agent.Type: ApplicationFiled: May 12, 2020Publication date: November 26, 2020Applicant: Haldor Topsøe A/SInventors: Janus Emil Münster-Swendsen, Niklas Bengt Jakobsson
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Patent number: 10835884Abstract: A means for retaining particulate matter, for use in process equipment operated with a fluid, including: a particle retention chamber, a means of suspension, a means of fastening, a support, wherein the particle retention chamber is configured to be suspended from the support by the means of suspension; the means of fastening is configured to fasten the means of suspension to the support.Type: GrantFiled: October 19, 2018Date of Patent: November 17, 2020Assignee: HALDOR TOPSØE A/SInventors: Emir Zahirovic, Daniel Morton, Marc Rogato, Flemming Plougstrup Nielsen
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Patent number: 10835854Abstract: A process for the cleaning of a lean gas stream contaminated with volatile organic compounds (VOCs) and/or sulfur-containing compounds comprises the steps of adding ozone to the contaminated lean gas stream, subjecting the ozone-containing lean gas stream to ultraviolet irradiation, thereby transforming VOCs to particles, maintaining the irradiated gas stream in a stay zone for a sufficient time to allow aerosol particle growth, and passing the gas stream through a catalytic bag filter at a temperature down to room temperature to remove the formed particles and eliminate any remaining ozone. The bag filter has been made catalytic by impregnation with one or more metal oxides in which the metals are selected from V, W, Pd and Pt, supported on TiO2.Type: GrantFiled: September 11, 2017Date of Patent: November 17, 2020Assignee: Haldor Topsoe A/SInventors: Janus Emil Münster-Swendsen, Niklas Bengt Jakobsson
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Publication number: 20200354216Abstract: A synthesis gas plant for producing synthesis gas, said synthesis gas plant including an electrically heated reforming reactor system including a first catalyst active for catalyzing steam methane reforming reaction, said electrically heated reforming reactor system being arranged to receive a feed gas comprising hydrocarbons and outletting a first synthesis gas stream. The synthesis gas plant also includes a post converter downstream the electrically heated reforming reactor system, said post converter housing a second catalyst active for catalyzing steam methane reforming/methanation reactions and reverse water gas shift reaction, said post converter being arranged to receive at least part of said first synthesis gas stream and outletting a second synthesis gas stream. Furthermore, the synthesis gas plant includes means for adding a heated CO2 rich gas stream to the at least part of the first synthesis gas stream upstream the post converter and/or into the post converter.Type: ApplicationFiled: November 15, 2018Publication date: November 12, 2020Applicant: HALDOR TOPSØE A/SInventor: Peter Mølgaard MORTENSEN
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Patent number: 10829376Abstract: A process plant for production of sulfuric acid from a process gas comprising SO2, including a process gas inlet, a first SO2 converter having an inlet and an outlet, a first condenser having a gas inlet, a gas outlet and a liquid outlet, a gas mixing device having a first inlet, a second inlet and an outlet, a process gas heater having an inlet and an outlet, a second SO2 converter having an inlet and an outlet, a second condenser having a gas inlet, a gas outlet and a liquid outlet, one or more means for cooling and storage of sulfuric acid and a purified process gas outlet.Type: GrantFiled: June 29, 2016Date of Patent: November 10, 2020Assignee: HALDOR TOPSØE A/SInventors: Mads Lykke, Rasmus Sverdrup, Morten Thellefsen
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Patent number: 10821411Abstract: A catalytic reactor comprises a filter unit which extracts and collects particles from the fluid flow stream above the reactor internals, the filter unit comprises elements which are safely, easily and quickly handled without the need for tools.Type: GrantFiled: July 3, 2018Date of Patent: November 3, 2020Assignee: Haldor Topsøe A/SInventors: Klaus Risbjerg Jarlkov, Emir Zahirovic
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Publication number: 20200330944Abstract: A tube heat exchange reactor for carrying out an endothermic catalytic reaction. The tube heat exchange reactor includes: an outer tube with a first and a second end, where the first end is an inlet end and where the second end is a closed end, an inner tube coaxially arranged within the outer tube and spaced apart from the outer tube, where at least a part of the inner tube holds a bed of catalyst material susceptible for induction heating and where the inner tube has an inlet end and an outlet end, an induction coil placed within the annular space confined between the outer and the inner tube, and a power source arranged to supply alternating current to the induction coil in order to generate an alternating magnetic field within at least a part of the inner tube.Type: ApplicationFiled: March 28, 2017Publication date: October 22, 2020Applicant: HALDOR TOPSØE A/SInventors: Peter Mølgaard MORTENSEN, Poul Erik HØJLUND NIELSEN, Kim AASBERG-PETERSEN, Martin ØSTBERG
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Publication number: 20200333274Abstract: A method and an apparatus for detailed continuous monitoring of the thermal environment for a tube or a plurality of tubes and calculation and prediction of remaining lifetime of said tubes.Type: ApplicationFiled: May 3, 2017Publication date: October 22, 2020Applicant: HALDOR TOPSØE A/SInventor: Søren Gyde Thomsen
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Publication number: 20200332204Abstract: Processes and equipment for purification of a sour hydrocarbon mixture or a gas mixture including hydrocarbons and sour gas, at least including the steps of directing the gas mixture to contact an absorbent liquid having affinity for sour gas, providing a purified off-gas mixture, directing the purified off-gas mixture to contact a liquid hydrocarbon mixture, providing an enriched liquid hydrocarbon mixture, with the associated benefit of such a process having a high recovery of hydrocarbons from the gas mixture to the enriched liquid hydrocarbon mixture, while being efficient in removing hydrogen sulfide from the gas mixture. The gas mixture to be purified may either be a natural gas, a fuel gas or an intermediate gas stream, e.g. from naphtha, kerosene, diesel or condensate hydrotreatment or hydrocracking, and it may also include further constituents, typically hydrogen.Type: ApplicationFiled: October 9, 2018Publication date: October 22, 2020Applicant: HALDOR TOPSØE A/SInventors: Muhammad ILYAS, Liza LINDMARK, Ole Frej ALKILDE
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Publication number: 20200318015Abstract: Process and plant for recovering LPG in a refinery process combining the use of sponge absorber, deethanizer and debutanizer. The process and plant enable high LPG recovery and removal of hydrogen sulphide in the LPG product to low levels.Type: ApplicationFiled: June 23, 2020Publication date: October 8, 2020Applicant: HALDOR TOPSØE A/SInventor: Nghia Pham PHU
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Publication number: 20200317519Abstract: A process plant including a Claus reaction furnace, a means of Claus gas cooling, a Claus conversion section, a means for Claus tail gas oxidation and a sulfuric acid section, wherein a sulfuric acid outlet of the sulfuric acid section is in fluid communication with an inlet of said Claus reaction furnace, as well as a related process. The process has the associated benefit of such a process avoiding undesired production of sulfuric acid, as well as reducing the Claus process gas volume.Type: ApplicationFiled: November 28, 2018Publication date: October 8, 2020Applicant: HALDOR TOPSØE A/SInventor: Mads LYKKE
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Publication number: 20200317514Abstract: A process for producing synthesis gas, the process including the steps of: a) in a reforming reactor, reacting a hydrocarbon feed stream together with an oxidant gas stream, thereby producing a first synthesis gas stream; b) providing a heated CO2 rich gas stream to an adiabatic post converter including a second catalyst active for catalyzing steam methane reforming, methanation and reverse water gas shift reactions; and c) in the adiabatic reforming post converter, letting at least a part of the first synthesis gas stream and the heated CO2 rich gas stream undergo steam methane reforming, methanation and reverse water gas shift reactions to thereby provide a product gas stream, the product gas stream being a synthesis gas stream. Also, a system for producing synthesis gas.Type: ApplicationFiled: November 15, 2018Publication date: October 8, 2020Applicant: HALDOR TOPSØE A/SInventors: Peter Mølgaard MORTENSEN, Kim AASBERG-PETERSEN
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Publication number: 20200299143Abstract: In a novel method for start-up heating of a converting re-actor in an ammonia synthesis plant, the conventional use of a gas fired heater is replaced by inductive heating. The inductive heating is obtained using an alternating high frequency current, which is passed through an inductive coil located inside the reactor, especially mounted inside a pressure shell. The method makes it possible to run reactions at high temperatures and high pressures in a very efficient way.Type: ApplicationFiled: April 24, 2017Publication date: September 24, 2020Applicant: Haldor Topsøe A/SInventor: Poul Erik HØJLUND NIELSEN
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Patent number: 10780425Abstract: The invention provides a method for the production of a supported nickel catalyst, in which an aqueous mixture comprising an alkali metal salt plus other metal salts is sintered to form a support material. A supported nickel catalyst comprising potassium ?-alumina is also provided.Type: GrantFiled: September 14, 2017Date of Patent: September 22, 2020Assignee: Haldor Topsoe A/SInventors: Joachim Harteg Jacobsen, Charlotte Vinding Ovesen, Christian Daugaard
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Publication number: 20200290868Abstract: A system for production of a synthesis gas, including: a synthesis gas generation reactor arranged for producing a first synthesis gas from a hydrocarbon feed stream; a post converter including a catalyst active for catalyzing steam methane reforming, methanation and reverse water gas shift reactions; the post converter including a conduit for supplying a CO2 rich gas stream into a mixing zone of the post converter, where the CO2 rich gas stream in the conduit upstream the mixing zone is in heat exchange relationship with gas flowing over the catalyst downstream the mixing zone; a pipe combining the at least part of the first synthesis gas and the CO2 rich gas stream to a mixed gas, in a mixing zone being upstream the catalyst; wherein the post converter further includes an outlet for outletting a product synthesis gas from the post converter. Also, a corresponding process.Type: ApplicationFiled: November 15, 2018Publication date: September 17, 2020Applicant: HALDOR TOPSØE A/SInventors: Peter Mølgaard MORTENSEN, Kim AASBERG-PETERSEN
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Publication number: 20200290003Abstract: A reactor system for aromatization of higher hydrocarbons within a given temperature range T upon bringing a reactant stream including higher hydrocarbons into contact with a catalytic mixture. The reactor system includes a reactor unit arranged to accommodate a catalytic mixture. The catalytic mixture includes a catalyst material and a ferromagnetic material. The catalyst material is arranged to catalyze the aromatization of higher hydrocarbons. The ferromagnetic material is ferromagnetic at least at temperatures up to an upper limit of the given temperature range T, where the temperature range T is the range from between about 400° C. and about 700° C. or a subrange thereof. The reactor system also includes an induction coil arranged to be powered by a power source supplying alternating current, whereby the ferromagnetic material is heated to a temperature within the temperature range T by means of an alternating magnetic field.Type: ApplicationFiled: March 31, 2017Publication date: September 17, 2020Applicant: HALDOR TOPSØE A/SInventors: Poul Erik HØJLUND NIELSEN, Peter Mølgaard MORTENSEN, Kim AASBERG-PETERSEN
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Patent number: 10767942Abstract: A u-tube heat exchanger has inlet tubes arranged in a pressure neutral inlet tube plate, a heating medium flows via the inlet tubes into u-tubes arranged in a tube sheet where the medium splits in two and flows from both ends of the u-tubes into a heating medium outlet chamber and exits the heat exchanger via an outlet nozzle.Type: GrantFiled: December 1, 2011Date of Patent: September 8, 2020Assignee: Haldor Topsoe A/SInventor: Svend Høst-Madsen
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Patent number: 10759726Abstract: A process for the preparation of ethylene glycol and other C1-C3 hydroxy compounds comprising the steps of hydrogenating a composition comprising C1-C3 oxygenate compounds. In particular the process is suitable for hydrogenating a composition comprising different C1-C3 oxygenate compounds, such as the product from a thermolytic fragmentation of a sugar composition.Type: GrantFiled: January 5, 2017Date of Patent: September 1, 2020Assignee: HALDOR TOPSØE A/SInventors: Martin Spangsberg Holm, Christian Mårup Osmundsen, Esben Taarning, Amanda Birgitte Sølvhøj, Morten Boberg Larsen