Abstract: The present invention relates to an apparatus for preparing and supplying catalyst to an ethylene slurry loop polymerisation reactor and to an apparatus for controlling the injection of catalyst slurry in a polymerization reactor wherein polyethylene is prepared. The present invention a Iso relates to a method for optimising catalyst supply to a polymerisation reactor. The diluted catalyst is transferred to the reactor (1) using a membrane pump (5) controllable in function of the concentration of a reactant in said reactor (1).
Abstract: Rotomoulded articles and methods of forming the same are described herein. The rotomoulded articles generally have a permeability of less than 1 g/day. The rotomoulded articles generally include polyethylene obtained by injecting into a reactor a catalyst system including a metallocene catalyst component of specific formula and an activating agent; injecting into the reactor ethylene monomer at a concentration of at least 6.5 wt %; injecting an amount of hydrogen such that a ratio of hydrogen to ethylene (H2/C2) in the feed is less than 85 g/106 g; maintaining the reactor under polymerisation conditions at a temperature of less than 90° C.; and retrieving polyethylene exhibiting a melt index (MI2) of at least 3.
Abstract: The present invention relates to fibers, in particular to as-spun fibers, having an improved bonding performance. In particular, the present invention relates to as-spun fibers comprising a metallocene random copolymer of propylene and one or more comonomers. The present invention further relates to nonwovens comprising such fibers and to a process for producing such fibers and nonwovens. The fibers and nonwovens of the present invention are characterized by a wider bonding window as the prior art fibers and nonwovens.
Type:
Application
Filed:
February 19, 2009
Publication date:
March 10, 2011
Applicant:
TOTAL PETROCHEMICAL RESEARCH FELUY
Inventors:
John Bieser, Guillaume Pavy, Hugues Haubruge, Alain Standaert, William Rusty Wheat
Abstract: This invention relates to the use of a cyclic ketone peroxide of half-life time larger than one second at a temperature of 225° C., for producing a controlled rheology polypropylene heterophasic copolymer of melt index MI2 larger than 15 g/10 min, having simultaneously a very high impact resistance and a high flexural modulus.
Type:
Grant
Filed:
March 3, 2009
Date of Patent:
March 8, 2011
Assignee:
Total Petrochemicals Research Feluy
Inventors:
Philippe VanDeurzen, Lisa K. Albe, William Wheat, Michel Daumerie
Abstract: The present invention relates to a method for determining activity of a catalyst in a polymerization process, said polymerization process comprising the steps of feeding a catalyst and a diluent into a storage vessel, to form a concentrated settled catalyst, feeding said concentrated settled catalyst into a mixing vessel equipped with mixing means and feeding hydrocarbon diluent into said mixing vessel, to form a diluted catalyst slurry, feeding said diluted catalyst slurry into a polymerization reactor via a volumetric pump, and feeding at least one monomer into said polymerization reactor to form a polymer.
Abstract: The present invention relates to a polymerization process for producing olefin polymers in a loop reactor comprising the steps of: introducing into the loop reactor one or more olefin reactants, polymerization catalysts and diluents, and while circulating said reactants, catalysts and diluents, polymerizing said one or more olefin reactants to produce a polymer slurry comprising essentially liquid diluent and solid olefin polymer particles, said process further comprising one or more cycles of: (a) allowing said polymer slurry to settle in one or more setting legs connected to said reactor, and (b) discharging from a setting leg a predetermined volume of polymer slurry substantially equal to the volume of polymer slurry settled in said settling leg since its previous discharge.
Abstract: The present invention relates to a blend comprising metallocene polypropylene and an elastomer for automobile parts, characterized in that said blend has low volatile organic compounds emissions. The invention also relates to the use of said blend in parts for automobiles.
Type:
Application
Filed:
April 30, 2008
Publication date:
March 3, 2011
Applicant:
TOTAL PETROCHEMICALS RESEARCH FELUY
Inventors:
Christian Ter Woort, Emmanuelle Koscher, Filip Vandoorne
Abstract: The present relates to a process for optimizing the recovery of unreacted monomers from a polymerization process, wherein said process comprises the steps of recovering a fluid stream generated by the separation of the polyolefin product from the polymerization fluid comprising unreacted monomers and optionally comonomers; contacting said fluid stream in an absorption zone with a scrub liquid comprising at least one C4-10 hydrocarbons, thereby absorbing at least a portion of the unreacted monomers in said scrub liquid; and withdrawing from said absorption zone (i) a vapor overhead comprising light gas and (ii) an absorber bottoms scrub liquid comprising said C4-10 hydrocarbons and said unreacted monomer; thereby recovering said unreacted monomer in said absorber bottoms scrub liquid comprising said C4-10 hydrocarbons.
Abstract: The invention relates to a process for producing polyethylene aseptic squeezable pouches. The invention also covers said pouches and their use for medical packaging applications.
Abstract: Process for the selective production of ethylene, propylene and isoprene from light hydrocarbons comprising: a) fractionating a butane fraction in a de-isobutanizer to obtain an enriched iso-butane fraction and an enriched normal-butane fraction, b) cracking said normal-butane fraction and optionally an ethane fraction, optionally a propane fraction, in a non-catalytic cracking zone to produce an olefin rich stream, c) treating said olefin rich stream in a separating section to recover: an ethylene stream, a propylene stream, d) transforming the recovered iso-butane of step a) into iso-butene or t-butyl hydroperoxide or partly into iso-butene and partly into t-butyl hydroperoxide, e) optionally reacting iso-butene of step d), if any, with formaldehyde to make isoprene, f) optionally reacting t-butyl hydroperoxide of step d), if any, with an olefin to give an epoxide and t-butanol and further separating t-butanol, or optionally having t-butyl hydroperoxide of step d), if any, decomposed to t-butanol and reacte
Abstract: The present invention discloses metallic complexes based on hydroxyl-carbonyl fulvene ligands, their method of preparation and their use in the oligomerisation or polymerisation of ethylene and alpha-olefins.
Type:
Application
Filed:
July 16, 2008
Publication date:
February 10, 2011
Applicants:
TOTAL PETROCHEMICALS RESEARCH FELUY, Centre National De La Recherche Scientifique (CNRS
Abstract: The present invention relates to a process for the production of propylene homo- and copolymers having a broad molecular weight distribution and a low ash content, with “ash” denoting aluminium as well as residues of catalyst, cocatalyst or any additive, such as titanium (Ti) or silicium (Si) derivatives, used in the production of propylene polymers. The propylene polymers of the present invention are useful to make films, such as capacitor films, as well as fibers and nonwovens, such as for example staple fibers, spunbond nonwovens, meltblown nonwovens.
Abstract: The present invention discloses catalyst components based on ferrocenyl ligands, their method of preparation and their use in the polymerization of olefins.
Abstract: The present invention relates to a process for making low ash propylene homo- or copolymers with improved properties, with “ash” denoting aluminium as well as residues of catalyst, cocatalyst or any additive, such as titanium (Ti) and silicium (Si) derivatives, used in the production of propylene polymers. The propylene polymers of the present invention are useful to make films, such as capacitor films, as well as fibers and nonwovens, such as for example staple fibers, spunbond nonwovens or meltblown nonwovens.
Abstract: This invention relates to the field of multilayer articles prepared by rotational moulding with a robotised rotomoulding machine wherein the mould is under direct heating.
Type:
Application
Filed:
November 4, 2008
Publication date:
January 27, 2011
Applicants:
TOTAL PETROCHEMICALS RESEARCH FELUY, PERSICO S.p.A.
Abstract: The present invention concerns an improved method for introducing free carbon black additive into a polymer powder or fluff, and in particular into polyethylene powder.
Abstract: The present invention discloses a process for preparing polyethylene resins in a double loop reactor wherein the catalyst system comprises a bis-tetrahydroindenyl and a bis-indenyl catalyst component deposited on the same support. It also discloses the polyethylene resins obtained by the process and their use to prepare films having a good compromise of haze, processing and mechanical properties.
Type:
Application
Filed:
November 4, 2008
Publication date:
January 20, 2011
Applicant:
TOTAL PETROCHEMICALS RESEARCH FELUY
Inventors:
Jacques Michel, Martine Slawinski, Guy Debras
Abstract: The present invention discloses a method for preparing an activating support and its use to activate metallocene or post-metallocene catalyst component for use in the oligomerisation and polymerisation of ethylene and alpha-olefins.
Type:
Application
Filed:
July 16, 2008
Publication date:
January 13, 2011
Applicants:
TOTAL PETROCHEMICALS RESEARCH FELUY, Centre National De La Recherche Scientifique (CNRS)
Inventors:
Abdelkrim El Kadib, Karine Molvinger, Daniel Brunel, Floran Prades, Sabine Sirol
Abstract: Processes for preparing reinforced polymeric material and the materials formed therefrom are discussed herein. The processes generally include providing a polymeric matrix, providing single-wall carbon nanotubes (SWNT) or multiple-wall carbon nanotubes (MWNT), purifying by the nanotubes in a single step of dissolving a support and catalyst particles with an agent appropriate to the nature of the support to form a purified support, functionalising the purified support by reaction with an alkylamine to form a functionalized support, dispersing the nanotubes in the polymeric matrix by mixing in the molten state to form a mixture and optionally orienting the mixture by stretching.
Type:
Grant
Filed:
December 10, 2008
Date of Patent:
January 4, 2011
Assignee:
Total Petrochemicals Research Feluy
Inventors:
Marc Dupire, Janos Nagy, Jacques Michel, Christophe Pirlot