Abstract: This invention is related to the field of olefin polymerisation in double loop reactors and especially to the polymerisation of olefins with very active catalyst systems. It discloses a method for reducing blockage when transferring polymer product from the first loop to the second loop of a double loop reactor.

Abstract: The present invention discloses a method for predicting the melt index and density of the polymer in terms of the operating conditions in the reactor and vice-versa, to select the operating conditions necessary to obtain the desired product specifications.

Abstract: This invention is related to the preparation of polyethylene pipe resins suitable for transporting water containing chlorine.

Abstract: The present invention relates to the polymerisation of olefin monomers in a slurry loop reactor and to a model for determining and optimising the changes in operating conditions that need to be applied when changing from one polymer grade to another.

Abstract: The present invention describes a reactor comprising two interconnected loops wherein the growing polymer flows continuously in circuit from the first loop to the second loop through a First pipe and back to the first loop through a second pipe. It also discloses process for polymerising olefins in two interconnected loop reactors.

Abstract: The present invention concerns a catalyst for the production of high density polyethylene, by homopolymerising ethylene or copolymerising ethylene and an alpha-olefinic comonomer comprising 3 to 10 carbon atoms, prepared by the steps of: a) selecting a silica support with a specific surface area larger than 300 m2/g; b) treating the silica support with a titanium compound, in order to introduce titanium into the support, or with an aluminium compound, in order to introduce aluminum into the support; c) either treating the titanated silica support with an aluminum compound, in order to introduce aluminum into the titanated silica support, or treating the aluminated silica support with a titanium compound, in order to introduce titanium into the aluminated silica support; d) depositing a chromium compound on the titanated and aluminated silica support to form a catalyst; e) activating the catalyst of step d) under air in a fluidised bed at a temperature of from 600 to 800° C.

Abstract: This invention relates to an improved method for improving the tacticity of Ziegler-Natta catalyst systems and for controlling the behaviour of the active stereospecific sites.

Abstract: The present invention relates to new tridentate ligand compounds with imino furan units, to a method for manufacturing said compounds and to their use in the preparation of catalysts for the homopolymerisation or copolymerisation of ethylene and alpha-olefins.

Abstract: A fluid dispenser device comprising: a body (10); at least one individual reservoir (21); movable support means (50) that receive at least one reservoir (21), and that are displaceable between a non-dispensing position and a dispensing position; reservoir-opening means (80) for opening a reservoir when said opening means are actuated; loading means (800) for urging said movable support means towards said dispensing position; blocking means (100) for retaining said movable support means in the non-dispensing position; and inhalation trigger means (60); said blocking means (100) comprising a blocking element (110) that is movable between a blocking position and an unblocking position, said blocking element (110) co-operating with a projection (501) that is secured to movable support means (50).

Abstract: This invention is related to the preparation of polyethylene pipe resins suitable for transporting hot and cold water containing chloramine.

Abstract: The invention discloses a metallocene catalysed slurry polymerisation process of ethylene in the presence of a low concentration of scavenger. This allows improving the anti-sheeting of the reactor during the polymerisation process.

Abstract: The present invention discloses the use of aromatic diamine ligands to prepare catalyst systems suitable for the oligomerization or polymerization of ethylene and alpha-olefins.

Abstract: The present invention relates to a process for producing a multilayer film comprising at least one polyethylene (except high pressure polyethylene) and polypropylene layer, wherein the adhesion between the polyethylene and polypropylene is enhanced without the use of any tie layer by processing the film with a freezing time of less than ten seconds.

Abstract: The present invention discloses single site catalyst systems having anionic scorpion-like three dimensional structure, that are suitable for oligomerising or polymerising ethylene and alpha-olefins.

Abstract: Disclosed is a method for steam-cracking naphtha, according to which a charge of hydrocarbons containing a portion of paraffinic naphtha, which is modified by adding a combination of a first component containing a portion of gasoline and a second component containing a portion of at least one hydrocarbonated refinery gas, and a paraffin-rich change containing at least one paraffin selected among propane, butane, or a mixture thereof are fed through a steam cracker in the presence of vapor. Also disclosed is a hydrocarbon composition suitable for steam cracking, containing a portion of a paraffinic naphtha, which is modified by adding a combination of a first component containing a portion of gasoline and a second component containing a portion of at least one hydrocarbonated refinery gas and a paraffin-rich charge containing at least one paraffin selected among propane, butane, or a mixture thereof.

Abstract: The present invention is a phosphorous modified zeolite (A) made by a process comprising in that order: selecting a zeolite with low Si/Al ratio (advantageously lower than 30) among H+ or NH4+-form of MFI, MEL, FER, MOR, clinoptilolite, said zeolite having been made preferably without direct addition of organic template; steaming at a temperature ranging from 400 to 870° C. for 0.01-200 h; leaching with an aqueous acid solution containing the source of P at conditions effective to remove a substantial part of Al from the zeolite and to introduce at least 0.3 wt % of P; separation of the solid from the liquid; an optional washing step or an optional drying step or an optional drying step followed by a washing step; a calcination step.

Abstract: The present invention relates to a process for cooling a polymerization reaction for producing polyolefin comprising the steps of: (a) thermally contacting said polymerization reaction with a cooling fluid such that the cooling fluid removes thermal energy from said reaction, (b) thermally contacting said cooling fluid with a working fluid thereby recovering said thermal energy from said cooling fluid in said working fluid, and (c) thermally contacting the cooling fluid obtained in step (b) with the polymerization reaction thereby cooling said reaction, wherein the working fluid is phase converted thereby providing energy in the form of heat and/or electricity and/or mechanical power back to the polyolefin production process. Said invention also relates to a polymerization process for producing olefin polymers in a reactor, and also relates to a process for energy optimization of energy consumption in a polymerization process and to a polymerization unit.

Abstract: The present invention is a process for converting methane to methanol, comprising: feeding methane and gaseous air or oxygen or gaseous air enriched with oxygen to a reactor under an elevated pressure; said reactor having an internal surface, made of silica or coated with silica, surrounding a zone in which said gases react; and reacting said gases in said reaction zone at an elevated temperature at conditions effective to produce methanol and for valuable oxygenates. Advantageously the internal surface is made of quartz or coated with quartz Advantageously the internal surface, made of silica (advantageously quartz) or coated with silica (advantageously quartz), is treated with HF before the conversion of methane to methanol. Advantageously the reaction is carried out in the absence in said reaction zone of any added material which measurably affects the rate of the reaction or the yield of the product. Advantageously the reactor is operated under a pressure from 1 to 7.5 MPa.

Abstract: Reactor systems suitable for the polymerization of an olefin monomer including first and second loop reactors effective for the polymerization of an olefin monomer and polymers formed therefrom are described herein.

Abstract: Methods for supplying a catalyst to an ethylene slurry loop polymerization reactor and polymers formed therefrom are described herein. The method generally includes preparing a catalyst slurry in a preparation vessel wherein the slurry includes a hydrocarbon diluent liquid which contains a Ziegler-Natta catalyst; supplying the catalyst slurry from the preparation vessel to a buffer vessel; withdrawing the catalyst slurry from the buffer vessel and supplying the catalyst slurry to a slurry loop polymerization reactor in which ethylene is polymerized; mixing a co-catalyst with the Ziegler Natta catalyst in the slurry prior to the supplying of the catalyst slurry to the slurry loop polymerization reactor; and controlling the transfer of catalyst slurry from the preparation vessel to the buffer vessel and the withdrawal of catalyst slurry from the buffer vessel to maintain the level of catalyst slurry in the buffer vessel substantially constant relative to the level of catalyst slurry in the preparation vessel.