Abstract: The present invention relates to a method for degassing polymer powder comprising flushing the polymer powder in a first chamber with a first flow of flushing gas, transferring the polymer powder into a second chamber and flushing the polymer powder with a second flow of flushing gas in said second chamber. The present invention also relates to a system suitable for carrying out this method.
Type:
Application
Filed:
March 6, 2007
Publication date:
February 18, 2010
Applicant:
Total Petrochemicals Research Feluy
Inventors:
Eric Damme, Marc Moers, Lieven Van Looveren
Abstract: The invention discloses high clarity multilayer films that are easy to tear in the transverse direction, wherein the core layer is made of a blend of from 5 to 50 wt % of crystal polystyrene and from 95 to 50 wt % of transparent styrene-butadiene block copolymer (5-40 wt % 1,3-butadiene, 60-95 wt % styrene) and the outer layers comprise from 85 to 100 wt % of a metallocene catalysed polyethylene (density:0.915-0.960 g/cm3, MI2:0.
Abstract: The present invention relates to an injection-stretch blow molding process (ISBM) for the manufacture of an impact-resistant container with good optical properties from a polyolefin composition comprising a polypropylene and a polyethylene produced with a metallocene-based catalyst.
Abstract: Degraded polypropylene (co)polymer modified with a linear dialkylperoxide in order to retain its impact strength and a process for its preparation.
Abstract: This invention relates to fluorinated alkoxy-imino metallic complexes and their use in catalyst systems for the polymerisation or oligomerisation of ethylene and alpha-olefins.
Type:
Application
Filed:
September 14, 2007
Publication date:
February 4, 2010
Applicant:
Total Petrochemicals Research Feluy
Inventors:
Jean-Francois Carpentier, Evgueni Kirillov, Christophe Thomas, Abbas Razavi, Nicolas Marquet
Abstract: A polylactide-urethane copolymer obtainable by a process, which comprises the step of contacting: an ?, ? dihydroxyl polylactide prepolymer of general formula I wherein: X is NH or O, R is an alkyl or an aryl group, n and n? are integer numbers which are substantially the same and which are comprised in the range from 20 to 140, a diisocyanate compound of general formula II O?C?N—R?—N?C?O wherein: R? is an alkyl or an aryl group and an amine or an alcohol of general formula III R??[X?]2 wherein: R? is an alkyl or an aryl group and X? is NH2 or OH with the proviso that at least one of R or R? is an aryl group
Type:
Application
Filed:
September 27, 2007
Publication date:
January 21, 2010
Applicant:
TOTAL PETROCHEMICALS RESEARCH FELUY
Inventors:
Philippe Dubois, Philippe Coszach, gloria Vendrell, Philippe Degee, Michael Alexandre, Ibrahim Barakat, Jean Marie Raquez
Abstract: The present invention discloses a method for preparing containers by one-stage injection-stretch-blow-moulding with a resin comprising: a random copolymer of propylene (RCP) having a melt index of from 1.5 to 35 dg/min, an ethylene content of less than 6 wt % with respect to the weight of the RCP; and optionally a nucleating and/or a clarifying agent; wherein the preform injection temperature is larger than 200° C. and wherein the stretching and blowing temperature Tsb is limited to a very narrow range ?T of at most 15° C., said range being a function of the injection temperature Tinj.
Abstract: The present invention relates to a method of transition between polymer grades in a polymerisation process comprising polymerising at least one monomer in at least a first reactor and a second reactor connected to each other in series, wherein the monomer feed in the first reactor is maintained essentially constant during the transition.
Type:
Application
Filed:
March 28, 2007
Publication date:
January 21, 2010
Applicant:
TOTAL PETROCHEMICALS RESEARCH FELUY
Inventors:
Marc Moers, Lieven Van Looveren, Mathias Wijffels
Abstract: The present invention discloses an active supported catalyst system comprising: a) one or more non-metallocene catalyst component; b) an alkylating agent; c) an activating functionalised and fluorinated support. It also discloses a method for preparing said active support and its use in the polymerisation of polar and non polar monomers.
Type:
Application
Filed:
July 26, 2006
Publication date:
January 14, 2010
Applicants:
TOTAL PETROCHEMICALS RESEARCH FELUY, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)
Inventors:
Floran Prades, Roger Spitz, Christophe Boisson, Sabine Sirol, Abbas Razavi
Abstract: The present invention discloses a transfer system between the first and second reactors in a double loop reactor that is equipped to reduce clogging in the transfer lines by providing a regulation mechanism arranged to insure equivalent flushing in each transfer line.
Abstract: The invention discloses a metallocene catalysed slurry polymerisation process s of ethylene in the presence of a low concentration of scavenger. This allows improving the anti-sheeting of the reactor during the polymerisation process.
Type:
Application
Filed:
March 29, 2007
Publication date:
December 24, 2009
Applicant:
TOTAL PETROCHEMICALS RESEARCH FELUY
Inventors:
Olivier Miserque, Martine Slawinski, Daniel Siraux, Alain Brusselle
Abstract: The present invention relates to a method for determining activity of a catalyst in a polymerisation process, said polymerisation process comprising the steps of feeding a catalyst and a diluent into a storage vessel, to form a concentrated settled catalyst, feeding said concentrated settled catalyst into a mixing vessel equipped with mixing means and feeding hydrocarbon diluent into said mixing vessel, to form a diluted catalyst slurry, feeding said diluted catalyst slurry into a polymerisation reactor via a volumetric pump, and feeding at least one monomer into said polymerisation reactor to form a polymer.
Abstract: The present invention discloses a method for preparing vials, preferably medical vials by two-stage injection-stretch-blow-moulding with a random copolymer of propylene having a melt index MI2 of from 1 to 3 dg/min and an ethylene content of from 2 to 3.5 wt % based on the weight of the resin, and wherein the preform injection temperature is of at least 280° C.
Abstract: A method for predicting the drop impact resistance of a stretch-blow moulded polypropylene container which comprises the steps of measuring the initial size of the container, placing it in an oven, remeasuring its size after removing it from the oven, calculating the percentage difference in size of the container and determining its drop impact resistance, which is proportional to said difference.
Abstract: The present invention relates of a polymerization process for the production of propylene polymers with low ash content using a Ziegler-Natta catalyst with a diether as internal electron donor. The present invention also relates to the propylene polymers produced with said process as well as to films, fibers and nonwovens made with said propylene polymer.
Type:
Application
Filed:
April 24, 2007
Publication date:
December 17, 2009
Applicant:
TOTAL PETROCHEMICALS RESEARCH FELUY
Inventors:
Alain Standaert, Jerome Gromada, David Vandewiele
Abstract: The present invention discloses coloured rotomoulded articles prepared from a dry blend of pigment and copolymer of ethylene prepared with a catalyst system based on a bridged bistetrahydroindenyl component optionally additivated with polyether-block co-polyamide.
Abstract: A catalytic system usable for the copolymerization of at least one conjugated diene and at least one monoolefin, a process for preparing this catalytic system, a process for preparing a copolymer of a conjugated diene and at least one monoolefin using said catalytic system, and said copolymer are described.
Type:
Application
Filed:
May 7, 2009
Publication date:
October 29, 2009
Applicants:
MICHELIN RECHERCHE ET TECHNIQUE S.A., TOTAL PETROCHEMICALS RESEARCH FELUY
Inventors:
Christophe Boisson, Vincent Monteil, Roger Spitz
Abstract: The present invention discloses a class of metallocene catalyst systems suitable for the homogeneous polymerisation of ethylene or alpha olefins that does not require the addition of aluminoxane or perfluorophenylborates as activating agent.
Type:
Application
Filed:
May 23, 2007
Publication date:
October 29, 2009
Applicants:
TOTAL PETROCHEMICALS RESEARCH FELUY, INSTITUTE OF PROBLEMS OF CHEMICAL PHYSICS OF THE RUSSIAN ACABEMY OF SCIENCES
Inventors:
Sergei Mikhailovich Aldoshin, Natalia Mikhailovna Bravaya, Andrei Nikolaevich Panin, Olga Mikhallovna Chukanova, Abbas Razavi