Abstract: The present invention relates to a process for the production of a high melt flow propylene homopolymer or random copolymer with low odor and low volatiles content, which is suitable for thin-walled injection molding applications, said process comprising the step of polymerizing propylene and one or more optional comonomers in presence of a Ziegler-Natta catalyst comprising a titanium compound having at least one titanium-halogen bond, and a diether compound as internal electron donor, both supported on a magnesium halide in active form, an organoaluminium compound and an optional external donor.
Abstract: The present invention discloses a method for preparing an heterogeniseded catalyst component comprising the steps of: a) providing a halogenated precursor component of formula (I) —X—[—CH2]—CH3 b) reacting the halogenated precursor with an ionic liquid precursor in a solvent to prepare an ionic liquid; IL+X? c) optionally, reacting the intermediate IL+X? with a salt C+A?, wherein C+ is a cation that can be selected from K+, Na+, NH4+, and A? is an anion that can be selected from PF6?, SbF6?, BF4?, (CF3—SO2)2N?CIO4—, CF3SO3?, NO3— or CF3CO2?.
Type:
Grant
Filed:
March 1, 2005
Date of Patent:
October 6, 2009
Assignee:
Total Petrochemicals Research Feluy
Inventors:
Olivier Lavastre, Fabien Bonnette, Abbas Razavi
Abstract: The present invention discloses multiple loop reactor wherein one of the settling legs transferring polymer product from one loop to a further loop can be taken out of service or re-opened without interfering with the operation of said multiple loop reactor.
Abstract: The present invention relates to the field of single site catalyst systems based on phosphino-iminophenol complexes that are suitable for oligomerising or polymerising ethylene and alpha-olefins.
Abstract: A process for cracking an olefin-containing hydrocarbon feedstock which is selective towards light olefins in the effluent, the process comprising passing a hydrocarbon feedstock containing one or more olefins through a moving bed reactor containing a crystalline silicate catalyst selected from an MFI-type crystalline silicate having a silicon/aluminium atomic ratio of at least 180 and an MEL-type crystalline silicate having a silicon/aluminium atomic ration of from 150 to 800 which has been subjected to a steaming step, at an inlet temperature of from 500 to 600° C., at an olefin partial pressure of from 0.
Abstract: A process of producing polyethylene, the process comprising copolymerizing ethylene and an alpha-olefinic comonomer comprising from 3 to 8 carbon atoms in the presence of a chromium-based catalyst in a main polymerization reactor and, in a gas-phase preliminary reactor upstream of the main polymerization reactor, chemically treating the chromium-based catalyst with at least one treatment agent prior to introduction of the catalyst into the main polymerization reactor and releasing from the preliminary reactor waste gases produced during the chemical treatment.
Abstract: The present invention relates to an apparatus for degassing polymer powder comprising a chamber having a first end and a second end opposite to each other, said chamber being equipped with at least one powder inlet and at least one gas outlet at the first end and with at least one powder outlet and at least one gas inlet at the second end, and a valve provided with a powder entry and a powder exit and arranged at the powder outlet of said chamber. The apparatus is characterised in that said chamber is equipped with a gas line joining a gas exit of the valve to the inside of the chamber at a position that is at a distance h2 from the first end (20), said distance h2 being 20-70% of the height H of the chamber and at a distance l1 from a wail of said chamber, said distance being l1 5-50% of the largest diameter L of the chamber.
Abstract: A process for producing a catalyst additive for an FCC catalytic cracking process, the process comprising the steps of providing an MFI or MEL aluminosilicate having a silicon/aluminium atomic ratio of from 10 to 250; de-aluminating the MFI or MEL aluminosilicate by extracting from 20 to 40 wt % of the alumina therefrom; combining the de-aluminated MFI or MEL aluminosilicate with a binder; and calcining the combination of the de-aluminated MFI or MEL aluminosilicate and the binder at elevated temperature to produce the catalyst additive.
Type:
Application
Filed:
December 14, 2006
Publication date:
August 27, 2009
Applicant:
Total Petrochemicals Research Feluy
Inventors:
Jean-Pierre Dath, Walter Vermeiren, Andre Noiret
Abstract: The invention relates to a device for taking out and analysing a sample from a polymerisation reactor comprising one or more sample conduits (2), for taking a sample out of said reactor and for conducting said sample to one or more sample flash tanks (3), whereby said conduits each are in communication with said reactor (19) and each are provided with at least two sampling valves (4, 5); comprising one or more sample flash tanks (3), for separating said solid particles and evaporated gas, whereby said sample flash tanks are connected to said conduits (2) and provided with means for analysing said evaporated gas (7), and comprising one or more sample receivers (6), for purifying said solid particles, whereby said receivers are connected to said sample flash tanks (3) and provided with means (8) for analysing said solid particles. The invention further relates to a method for improving a polymerisation reaction in a polymerisation reactor.
Abstract: The present invention discloses a method for separating tethered functional organo-chains, through their dilution with tethered non-functional organo-chains, in the presence of soluble molecular derivatives that are able to self-assemble and to interact with the functional organo-silane.
Type:
Application
Filed:
November 18, 2005
Publication date:
August 13, 2009
Applicants:
TOTAL PETROCHEMICALS RESEARCH FELUY, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
Inventors:
Philippe Banet, Daniel Brunel, Dan Lerner, Francois Fajula, Sabine Sirol, Abbas Razavi
Abstract: The invention discloses a method for making a hydrogenated metallocene catalyst component comprising the steps of: 1. Providing a compound comprising at least one aromatic group; 2. Hydrogenating the at least one aromatic group in the presence of hydrogen and a hydrogenation catalyst to form a hydrogenated compound; and 3. Forming a metallocene catalyst component from the hydrogenated compound from step 2.
Abstract: The present system discloses a transfer system devised in order to produce optimal flow from the first to the second loop reactor, by connecting the transfer lines to a by-pass line and by separating the connecting points of the transfer lines into the by-pass line by at least 70 cm.
Type:
Application
Filed:
February 21, 2007
Publication date:
July 23, 2009
Applicant:
TOTAL PETROCHEMICALS RESEARCH FELUY
Inventors:
Andre Lewalle, Denis Mignon, Sandra Davidts
Abstract: This invention relates to the use of a cyclic ketone peroxide of half-life time larger than one second at a temperature of 225 ° C., for producing a controlled rheology polypropylene heterophasic copolymer of melt index MI2 larger than 15 g/10 min, having simultaneously a very high impact resistance and a high flexural modulus.
Type:
Application
Filed:
March 3, 2009
Publication date:
July 2, 2009
Applicant:
TOTAL PETROCHEMICALS RESEARCH FELUY
Inventors:
Philippe VanDeurzen, Lisa K. Albe, William Wheat, Michel Daumerie
Abstract: A catalytic system usable for the copolymerization of at least one conjugated diene and at least one monoolefin, a process for preparing this catalytic system, a process for preparing a copolymer of a conjugated diene and at least one monoolefin using said catalytic system, and said copolymer are described.
Type:
Grant
Filed:
February 10, 2006
Date of Patent:
June 16, 2009
Assignees:
Michelin Recherche et Technique S.A., Total Petrochemicals Research Feluy
Inventors:
Christophe Boisson, Vincent Monteil, Roger Spitz
Abstract: Tubes and pipes and methods of forming the same are described herein. The tubes and pipes include a wall structure having an external surface and an internal surface defining an internal chamber, said wall structure including at least one layer including a metallocene produced polyethylene resin and having an external surface having a gloss of at least 40 as determined by the standard test of ASTM D2457-90.
Abstract: This invention discloses a method for preparing a preform for two-stage injection-stretch-blow-moulding (ISBM) from polypropylene resin produced with a Ziegler-Natta catalyst system and having a melt flow index MI2 of from 1 to 20 dg/min, wherein polypropylene is injected at a melt temperature of at least 265° C. Also disclosed are the preforms obtainable by the method, the use of the preforms for preparing bottles, and the bottles prepared from the preforms.
Abstract: Provided is a process for producing a polyolefin having a multimodal molecular weight distribution, which process comprises: (a) polymerising a first olefin monomer in the presence of an isomerisable metallocene catalyst, to form a first multimodal polyolefin component; and (b) polymerising a second olefin monomer in the presence of a second metallocene catalyst to form a second polyolefin component; wherein the molecular weight distribution of the first polyolefin component overlaps with the molecular weight distribution of the second polyolefin component.
Abstract: The present invention relates to an injector nozzle defining a passage for a flow of reactants to be injected into a loop reactor suitable for olefin slurry polymerization, consisting essentially of a fluid conduit extending into a discharge orifice portion to be connected to an opening in the reactor wherein the passage of the discharge orifice portion has a non-circular cross-section and the passage of the fluid conduit has a circular cross-section. The invention also relates to the use of the injector nozzle for injecting reactants into a loop reactor suitable for olefin polymerization reaction, wherein said injector nozzle is connected on an inner three quarter circle on or above an elbow section of the reactor.
Abstract: The present invention discloses the use of a supercritical fluid to improve the homogeneity of heterogeneous bi- or multi-modal resins resulting from a physical or a chemical blend of two or more fractions of the same type of polymer resin, said fractions having different molecular weights or of two or more polymer resins having different chemical compositions, or both. It also discloses the use of a supercritical fluid to improve the dispersion of additives or fillers into a polymer resin. It further discloses the process for preparing the homogeneous resin.
Abstract: This invention discloses the use in the production of a polyolefin of a slurry loop reactor wherein all internal parts in contact with the slurry are polished first by a mechanical process to a level of at most 70 RMS roughness value and are subsequently polished by a chemical or electrochemical process, to a final level of at most 40 RMS roughness value.