Abstract: The present invention is a process for the production of styrene monomer from ethylbenzene comprising the steps of: a) catalytically dehydrogenating said ethylbenzene in the presence of steam thereby catalytically producing a dehydrogenation effluent gas containing essentially unreacted ethylbenzene, styrene monomer, hydrogen, steam and divinylbenzene; b) quenching said effluent gas with an aqueous reflux in at least a quenching column to cool said effluent gas, and thereby obtaining a gas at the overhead and in the bottom a liquid stream warmer than the aqueous reflux; c) condensing said overhead gas thereby producing a liquid organic phase, an aqueous phase and a gaseous phase; d) using a portion or the whole of said aqueous phase of step c) as reflux for said step b) of quenching; e) sending to a decanter the liquid stream obtained at step b) to recover an aqueous phase and an organic phase.
Abstract: Split capture of USB protocol streams is disclosed. A first set of packets associated with a first USB protocol and a second set of packets associated with a second USB protocol are received at a hardware protocol analyzer via a monitored bus. The first set of packets and the second set of packets are maintained as separate streams at the hardware protocol analyzer. The first set of packets and the second set of packets are transferred from the hardware protocol analyzer to an analysis computer via a first logical connection configured to transfer packets comprising the first set of packets and a second logical connection configured to transfer packets comprising the second set of packets.
Type:
Grant
Filed:
October 21, 2010
Date of Patent:
May 28, 2013
Assignee:
Total Phase, Inc.
Inventors:
Etai Bruhis, Gopal Santhanam, Aki Niimura
Abstract: A process for preparing graft polymers from a polymer is based on conjugated diene units and a graft which is a thiol derivative. The process has an absence of solvent and any radical initiator. The graft polymer can be advantageously be used as additive for a bitumen/polymer composition and in particular permits thermoreversible cross-linking.
Type:
Application
Filed:
July 8, 2011
Publication date:
May 23, 2013
Applicants:
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS), TOTAL RAFFINAGE MARKETING
Abstract: The present invention relates to a method for consecutively producing at least two different polyethylene resins in one slurry loop reactor, comprising producing a first polyethylene resin in the presence of a Ziegler-Natta and/or a Chromium catalyst, and consecutively producing a second polyethylene resin in the presence of a metallocene catalyst, characterized in that the ratio of the melt flow index of the first produced polyethylene resin to the melt flow index of the second produced polyethylene resin is at least 0.3.
Type:
Application
Filed:
July 29, 2011
Publication date:
May 23, 2013
Applicant:
TOTAL RESEARCH & TECHNOLOGY FELUY
Inventors:
Peter Stevens, Franky Fant, Daan Dewachter, Alain Brusselle
Abstract: The present invention relates to a process of preparing a polyolefin in a loop reactor by introducing anti-fouling agent in by-pass pipes. Also, the invention relates to the use of anti-fouling agent to prevent blockage by feeding the anti-fouling agent into the by-pass pipes of the loop reactor.
Type:
Application
Filed:
July 29, 2011
Publication date:
May 23, 2013
Applicant:
TOTAL RESEARCH & TECHNOLOGY FELUY
Inventors:
Daniel Siraux, Daan Dewachter, Louis Fouarge
Abstract: A system and method for providing backup communications over an Ethernet cable are disclosed. A backup communication system (BCS) is provided as part of a networked (TCP/IP) hospital communication system. The BCS is coupled to an Ethernet cable used for normal TCP/IP communications. When TCP/IP communications are interrupted, the BCS receives patient call signals from patient room terminals over a secondary communication mode of the Ethernet cable, and transmits those call signals to a nurses' station. The call signals are transmitted as voltage coded data such as voltage pulses or static levels. The voltage can include call information. 10V can represent a normal patient call, 15V can represent a patient emergency call, and 24V can represent a code call. Information can be relayed back to the room terminals using the same signaling technique. Thus, basic communications can be achieved when TCP/IP communications are unavailable. Other embodiments are disclosed and claimed.
Type:
Application
Filed:
November 22, 2011
Publication date:
May 23, 2013
Applicants:
TOTAL WALTHER GMBH, FEUERSCHUTZ UND SICHERHEIT, SIMPLEXGRINNELL LP
Inventors:
Joseph D. Farley, Heinrich Zettler, Werner Schuhmann
Abstract: The present invention relates to the use of a catalyst preparation system for the preparation of a diluted catalyst slurry. In particular, the invention relates to a catalyst preparation system comprising a mixing vessel for mixing a particulate catalyst and a liquid hydrocarbon diluent. According to the invention, diluted catalyst slurry is prepared in a mixing vessel comprising a rotatable axial impeller system comprising at least two double-bladed hubs. The invention also relates to a process for preparing diluted catalyst slurry for use in the preparation of a particulate polyethylene product in a loop reactor with the catalyst preparation system as described herein.
Abstract: A system and method for providing backup communications using Power over Ethernet (PoE) are disclosed. A backup communication system (BCS) is provided as part of a networked (TCP/IP) hospital communication system. The BCS is coupled to a power line used to provide power to a PoE switch. When TCP/IP communications are interrupted, the BCS receives patient call signals from patient room terminals over a secondary communication mode of the power line, and transmits those call signals to a nurses' station. The call signals can be generated by coupling a pulse-coded AC signal onto the PoE wires, or by sending voltage coded data in one direction and current-coded data in the other direction. Different signals or signal levels can be used to distinguish normal patient calls, patient emergency calls, and code calls. Thus, basic communications can be achieved when TCP/IP are unavailable. Other embodiments are disclosed and claimed.
Type:
Application
Filed:
November 22, 2011
Publication date:
May 23, 2013
Applicants:
Total Walther Gmbh, Feuerschutz und Sicherheit, SimplexGrinnell LP
Inventors:
Joseph D. Farley, Werner Schuhmann, Heinrich Zettler
Abstract: The present invention relates to a method for feeding metallocene catalyst slurry to an olefin polymerization loop reactor (1) using a positive displacement device (5) positive displacement device comprising a first chamber and a second chamber, each chamber having an inlet and an outlet and each chamber comprising an ball arranged between the walls of said chamber, wherein said chambers are connected to each other by a pump chamber operably connected to a pump, wherein, the difference between the diameter of said ball and the diameter of said chamber is comprised between 5 to 200 times the average particle size (d50) of said catalyst.
Abstract: The present invention relates to a process for preparing catalyst slurry in a catalyst slurry preparation system and supplying catalyst slurry to an ethylene polymerization loop reactor wherein an accurate control of the pressure within said catalyst slurry preparation system is provided.
Type:
Application
Filed:
July 29, 2011
Publication date:
May 23, 2013
Applicant:
TOTAL RESEARCH & TECHNOLOGY FELUY
Inventors:
Alain Brusselle, Daan Dewachter, Louis Fouarge
Abstract: The invention relates to the assembly of a tube (1) made from composite material and a tubular metal part (2) in order to produce pipes. The assembly process comprises:—inserting a portion of the metal part (2) into the composite material tube (1); and—radially deforming the metal part (2) to a plastic deformation range sufficient to cause elastic deformation of said composite material tube (1), in order to obtain a radial contact between the outer wall of the metal part (2) and the inner wall of the composite material tube (1).
Type:
Application
Filed:
July 4, 2011
Publication date:
May 23, 2013
Applicants:
SOLETANCHE FREYSSINET, TOTAL SA, DORIS ENGINEERING, STE DES FIBRES DE CARBONE
Inventors:
Ivica Zivanovic, Julien Mercier, William Lindsay Hudson, Maurice Geli
Abstract: The present invention relates to an injection-stretch blow molding process (ISBM) for the manufacture of an impact-resistant container with good optical properties from a polyolefin composition comprising a polypropylene and a polyethylene produced with a metallocene-based catalyst.
Abstract: The invention relates to a process for the preparation of a particulate bimodal polyethylene product having a median particle diameter of less than 300 ?m in a serially connected double loop reactor, wherein said polymerization catalyst applied in the polymerization process comprises a particulate metallocene-alumoxane catalyst immobilized on a porous silica support, wherein said polymerization catalyst has a median particle diameter of less than 50 ?m; and whereby the ratio of the median particle diameter of the obtained bimodal polyethylene product to the median particle diameter of the applied polymerization catalyst is less than 30.
Abstract: The present invention discloses a method for preparing long-chain-branched isotactic polypropylene by first oligomerizing propylene with a suitable oligomerization catalyst system and then copolymerizing propylene and the oligomer obtained in situ with a mono-aryl-substituted methylene bridged catalyst system.
Type:
Grant
Filed:
December 14, 2009
Date of Patent:
May 21, 2013
Assignees:
Total Petrochemicals Research Feluy, Centre National de la Recherche Scientifique (CNRS)
Inventors:
Jean-Franøois Carpentier, Evgueni Kirillov, Nicolas Marquet, Abbas Razavi
Abstract: A resin composition comprising at least 0.1% by weight of poly(hydroxy carboxylic acid) and at least 50% by weight of polypropylene prepared with a single-site catalyst, preferably with a metallocene catalyst.
Abstract: A 4D seismic technique, where a base seismic trace is measured at a first time in a region of the subsoil, and then a monitor seismic trace corresponding to the base seismic trace is measured at a second time. To interpret the 4D measurements, assumptions are made about the variation of elastic parameters in permeable layers at predefined positions in one direction between the first and the second time. Elastic parameters include the density (?) and the speed of propagation of the pressure waves (VP) in the permeable layers. Numerical evaluation is performed for a capability of each assumption about the variation of elastic parameters to give an account of a change between the measured base seismic trace and the measured monitor seismic trace, and the variation of the elastic parameters is estimated in accordance with an assumption of optimum capability.
Abstract: The present invention relates to a process of preparing a polyethylene in a loop reactor in the presence of antifouling agent comprising the steps of: a) feeding into said loop reactor diluent, monomers, optionally hydrogen, and optionally one or more co-monomers to produce a liquid phase; b) introducing antifouling agent into said loop reactor, c) introducing a catalyst into the liquid phase to produce a slurry; and d) polymerizing the monomers and optional co-monomers to form the polyethylene, characterized in that the time difference between introduction of the antifouling agent and introduction of the catalyst is at most 3 hours.
Abstract: The present invention relates to a process of preparing a polyolefin in a loop reactor by introducing anti-fouling agent through a sleeve provided around at least part of the shaft of the pump. Also, the invention relates to the use of anti-fouling agent to prevent or reduce fouling by feeding the anti-fouling agent against the impeller of the pump upon introduction to the loop reactor.
Type:
Application
Filed:
July 29, 2011
Publication date:
May 16, 2013
Applicant:
TOTAL RESEARCH & TECHNOLOGY FELUY
Inventors:
Daniel Siraux, Aurélien Vantomme, Eric Damme, Daan Dewachter
Abstract: The present invention relates to a method of continuously feeding catalyst slurry into an olefin polymerization reactor comprising the steps of: a) continuously feeding catalyst slurry into the reactor through a catalyst feeding line and then through a valve connected to the wall of the reactor, wherein said valve comprises a piston device comprising an actuator and a hollow casing, wherein said piston is connected to the actuator and wherein said piston is arranged in the hollow casing; and b) closing said valve by moving the piston through at least part of said valve towards the reactor and at least until the wall of the reactor, upon at least partial blockage of said valve.
Type:
Application
Filed:
July 29, 2011
Publication date:
May 16, 2013
Applicant:
TOTAL RESEARCH & TECHNOLOGY FELUY
Inventors:
Daan Dewachter, Benoît Decouvelaere, Louis Fouarge