Abstract: Process for separating gases from a fluidized gas/solid mixture, comprising at least one injection of gas and optionally at least one injection of solids into and at least one discharge of solids from said fluidized bed, a discharge for gas from the mixture characterized in that it comprises a step of separating the solids entrained by the gas by means of an internal placed in that portion of the fluidized mixture where the voidage is greater than 0.7, occupying less than 10% of the free cross section of the bed.
Type:
Application
Filed:
August 12, 2011
Publication date:
July 25, 2013
Applicant:
TOTAL RAFFINAGE MARKETING
Inventors:
Juan-David Llamas, Patrick Leroy, Celine Derouin, Nicolas Lenepveu
Abstract: A method for the copolymerization of ethylene and a C3+ olefin copolymer in a loop reactor system and polymers formed therefrom are described herein.
Type:
Grant
Filed:
August 24, 2010
Date of Patent:
July 23, 2013
Assignee:
Total Petrochemicals Research Feluy
Inventors:
Louis Fouarge, Eric Damme, Olivier Miserque, Daniel Siraux, Philippe Bodart, André Lewalle, Marc Van der Auwera, Frans Van den Brande, Giacomo Conti, Hugo Vandaele, Mark Verleysen, Carl Van Camp, Etienne Laurent, Philippe Marechal, Marc Moers, Leopold D'Hooghe, Marjan Sillis, Kai Hortman, Pascal Folie, Renaud Oreins
Abstract: Borohydride metallocene complex of lanthanide, preparation process, catalytic system incorporating borohydride metallocene complex, process for copolymerization of olefins employing catalytic system. The complex corresponds to one or other of formulae A and B: where, in A, two ligands Cp1, Cp2, each composed of a cyclopentadienyl group, are connected to the lanthanide Ln, such as Nd, and where, in B, a ligand molecule, composed of two cyclopentadienyl groups Cp1, Cp2 connected to one another via a bridge P of formula MR1R2, M is an element from group IVa, and R1 and R2, which are identical or different, represent an alkyl group comprising from 1 to 20 carbon atoms, is connected to the lanthanide Ln, L is alkali metal, N is molecule of a complexing solvent, x is integral or non-integral number?0, p is integer?than 1 and y is integer?0.
Type:
Grant
Filed:
November 3, 2011
Date of Patent:
July 23, 2013
Assignees:
Michelin Recherche et Technique S.A., Total Petrochemicals France, Centre National de la Recherche Scientifique Ecole Superieure de Chimie-Physique-Electronique
Inventors:
Julien Thuilliez, Christophe Boisson, Roger Spitz
Abstract: The present invention discloses post-metallocene complexes based on sterically encumbered bi- and tri-dentate naphthoxy-imine ligands. It also relates to the use of such post-metallocene complexes in the oligomerization of ethylene to selectively prepare vinyl-end capped linear alpha-olefins.
Type:
Grant
Filed:
April 24, 2009
Date of Patent:
July 23, 2013
Assignees:
Total Petrochemicals Research Feluy, Centre National de la Recherche Scientifique (CNRS)
Inventors:
Jean-François Carpentier, Evgueni Kirillov, Abbas Razavi
Abstract: The invention deals with hydrocarbon feedstock molecular weight increase via olefin oligomerization and/or olefin alkylation onto aromatic rings. Addition of a purification section allows improved unit working time and lower maintenance.
Abstract: The invention relates to a method of imaging a longitudinal conduit resting by its base on the seabed, comprising the following steps: acquiring a set of images of at least a part of the conduit by a mobile underwater acquisition device, each image being associated with a temporal reference corresponding to the moment of its acquisition, extracting from each image the zone included in one and the same window, said window being predefined with respect to the frame of the images, and effecting an unwrapped image of at least a part of the conduit by juxtaposing, in chronological order, the extracted zones of each image.
Abstract: The invention concerns a catalyst containing a support comprising at least one binder and at least one zeolite having at least one series of channels the opening of which is defined by a ring containing 12 oxygen atoms, said catalyst comprising phosphorus, at least one C1-C4 dialkyl succinate, acetic acid and a hydrodehydrogenating function comprising at least one element from group VIB and at least one element from group VIII, the Raman spectrum of the catalyst comprising bands at 990 and/or 974 cm?1, characteristic of at least one Keggin heteropolyanion, the characteristic bands of said succinate and the characteristic principal band of acetic acid at 896 cm?1. The invention also concerns the process for preparing the catalyst and its use in hydroconversion.
Type:
Application
Filed:
December 21, 2012
Publication date:
July 18, 2013
Applicants:
IFP ENERGIES NOUVELLES, TOTAL RAFFINAGE MARKETING
Inventors:
TOTAL RAFFINAGE MARKETING, IFP ENERGIES NOUVELLES
Abstract: The invention relates to a method for simulating karstification phenomena in a karstic region, comprising a) defining a gridded geological model of the karstic region, in order to model a plurality of environments including a first environment described by values of at least one geological grid parameter, and a second environment described by values of edge parameters between two grid nodes, b) simulating stochastic displacements of particles in the grid of the geological model, the probability of each displacement of a particle being calculated taking into account values describing the environment within which the displacement is carried out, and c) modifying the values describing the first and/or second environment according to the courses taken by the particles.
Abstract: The subject of the invention is a process for producing an oxygen-containing compound chosen from C1 to C4 alcohols or carboxylic acids, and mixtures thereof, comprising the following steps: a step of catalytic decomposition of a hydrocarbon-based feedstock to give carbon, said step also producing hydrogen; the partial oxidation of the resulting carbon to give CO, using CO2, the CO stream being separated from the hydrogen stream; and the conversion of the resulting CO to give an oxygen-containing compound by anaerobic fermentation in an aqueous medium, the fermentation also producing CO2, the partial oxidation step being carried out with the CO2 produced during the fermentation.
Abstract: Apparatus and methods for dynamically producing and managing events are disclosed. In various embodiments, an event sequence generator is used to generate a production schedule or script that includes content elements and event milestones. Methods of generating a production schedule and a promotion schedule are also disclosed. The production schedule and reports based on the event can be produced and accessed remotely.
Abstract: The instant invention discloses a method for the improvement of flakes recovery from hydrocarbon processing units and in particular slurry reactors as well as slurry flakes obtained thereof.
Type:
Application
Filed:
June 29, 2011
Publication date:
July 11, 2013
Applicant:
TOTAL RAFFINAGE MARKETING
Inventors:
Katell Le Lannic-Dromard, Sylvain Prout, Gloria Vendrell
Abstract: The invention relates to a method for storing a cryogenic fluid, implementing a tank including at least one vessel capable of containing the cryogenic fluid. The method including the following steps: a) placing the tank on, in, or partially in soil including permafrost; b) feeding the cryogenic fluid into the vessel; and c) exchanging heat between the cryogenic fluid and the soil, in order to freeze and/or keep a portion of the soil frozen, such that said portion of the soil can be used as the foundation for the tank.
Abstract: The present invention is a process for removing oxygenated contaminants and water from an hydrocarbon stream comprising: introducing the contaminated hydrocarbon stream in a gaseous phase in an absorption zone, contacting said hydrocarbon stream in said absorption zone with an absorbent capable to absorb water and oxygenated contaminants at conditions effective to produce, an overhead hydrocarbon stream having a reduced oxygenated contaminants and water content and an absorbent bottoms stream comprising the absorbent, hydrocarbons and having an enhanced oxygenated contaminants and water content, introducing the above absorbent bottoms stream in a stripping zone at conditions effective to produce, an absorbent bottoms stream essentially free of hydrocarbons, oxygenated contaminants and water and an overhead stream comprising essentially hydrocarbons, water and the oxygenated contaminants, recycling the absorbent bottoms stream of the stripping zone to the absorption zone, optionally fractionating the ov
Abstract: According to the invention, elastic parameters, including density, pressure wave propagation speed, and/or shear in pervious layers located in a dense underground area along an array of horizontal positions, are estimated by inverting 4D seismic data. Firstly, an estimate of variations in the elastic parameters in one or more starting positions of the array, which can be located on bored wells within the area in question, is obtained. Then, a propagation algorithm is used in order to gradually carry out the 4D data inversion on the basis of the starting positions. The inversion takes into account the previously estimated parameter variations. A spatial variation in the depth and/or the thickness of the pervious lavers in question can also be taken into account. Propagation is based on positions that are consecutively selected as providing optimal values for a cost function assessed in order to invert the 4D data.
Abstract: The disclosure includes a lubricant composition further including: (a) at least one synthetic base oil and optionally at least one additive and (b) carbon nanotubes, the composition having a weight percentage of carbon nanotubes (b) relative to the total amount of base oils (a) of the composition of between 0.15 and 3.50%, the ratio between the weight percentage of carbon nanotubes, and the apparent density of the powder of carbon nanotubes, expressed in g/1 and measured according to the standard ISO 60-ASTM D1895 being greater than 102.
Type:
Application
Filed:
August 25, 2011
Publication date:
July 11, 2013
Applicants:
NANOCYL SA, TOTAL RAFFINAGE MARKETING
Inventors:
Vanessa Chauveau, Patrick Turello, Julien Amadou, Olivier Rochez
Abstract: Use of a metallocene compound of general formula Ind2R?MQ2 as a component of a catalyst system in producing polyethylene, wherein each Ind is the same or different and is indenyl or substituted indenyl; R? is a bridge which comprises a C1 to C4 alkylene radical, a dialkyl germanium or silicon or siloxane, alkyl phosphine or amine, which bridge is substituted or unsubstituted, M is a Group IV metal or vanadium and each Q is hydrocarbyl having 1 to 20 carbon atoms or halogen; and the ratio of meso to racemic forms of the metallocene in the catalyst system is at least 1:3. The metallocene may be supported. The ethylene may be polymerized in a reaction medium that is substantially free of any external comonomer, with comonomer being formed in situ. The produced polyethylene may have long chain branching. The produced polyethylene may be atactic.
Abstract: The present invention is a process for removing oxygenated contaminants and water from an hydrocarbon stream comprising: introducing the contaminated hydrocarbon stream in a gaseous phase in an absorption zone, contacting said hydrocarbon stream in said absorption zone with an absorbent capable to absorb water and oxygenated contaminants at conditions effective to produce, an overhead hydrocarbon stream having a reduced oxygenated contaminants and water content and an absorbent bottoms stream comprising the absorbent, hydrocarbons and having an enhanced oxygenated contaminants and water content, introducing the above absorbent bottoms stream in a stripping zone at conditions effective to produce, an absorbent bottoms stream essentially free of hydrocarbons, oxygenated contaminants and water and an overhead stream comprising essentially hydrocarbons, water and the oxygenated contaminants, recycling the absorbent bottoms stream of the stripping zone to the absorption zone, optionally fractionating the ov
Abstract: The invention concerns a process for upgrading lower quality carbonaceous feedstock using a slurry catalyst composition. The use of particular organometallic compounds as precursors for the dispersed active catalyst allows for reduced coke formation.
Type:
Application
Filed:
July 5, 2011
Publication date:
July 4, 2013
Applicant:
TOTAL RAFFINAGE MARKETING
Inventors:
Didier Borremans, Jean-Pierre Dath, Kai Hortmann
Abstract: The present invention is a process for removing oxygenated contaminants and water from an hydrocarbon stream comprising: introducing the contaminated hydrocarbon stream in a gaseous phase in an absorption zone, contacting said hydrocarbon stream in said absorption zone at a pressure of at least 5 bars, advantageously in the range 5 to 40 bars with an alcohol capable to absorb water and oxygenated contaminants at conditions effective to produce an overhead hydrocarbon stream having a reduced oxygenated contaminants and water content and an absorbent bottoms stream comprising the alcohol, hydrocarbons and having an enhanced oxygenated contaminants and water content, sending the overhead of the absorption zone to a wash column (referred to as the high pressure water wash column) at a pressure of at least 5 bars, advantageously in the range 5 to 40 bars, essentially washed with water at conditions effective to produce an overhead hydrocarbon stream having a reduced oxygenated contaminants and an aqueous bott
Abstract: The present disclosure relates to compositions for preparing textile auxiliaries, which are used in particular to enhance the dyeing affinity of textile fibers.