Abstract: The present invention relates to a process for preparing an activating support for metallocene complexes in the polymerization of olefins comprising the steps of: I) providing a support consisting in particles formed from at least one porous mineral oxide; II) optionally fixing the rate of silanols on the surface of the support; III) functionalizing the support with a solution containing a metallic salt; IV) heating the functionalized support of step c) under an inert gas or hydrogen; V) oxidizing the support of step IV by treatment under N2O and then under oxygen; VI) retrieving an active support having a controlled number of OH groups. That activating support is used to activate a metallocene catalyst component for the polymerization of olefins.
Type:
Grant
Filed:
April 29, 2010
Date of Patent:
September 3, 2013
Assignee:
Total Research & Technology Feluy
Inventors:
Gaëlle Pannier, Christophe Boisson, Roger Spitz
Abstract: A process for producing polylactic acid (PLA) comprising the steps: fermenting in a fermentation vessel a micro-organism of the genus Monascus in a medium at a pH less than or equal to 5 under conditions which produce lactic acid into the medium, converting the lactic acid produced into lactide, and polymerizing the lactide to form PLA.
Type:
Application
Filed:
October 28, 2011
Publication date:
August 29, 2013
Applicant:
TOTAL RESEARCH & TECHNOLOGY FELUY S.A.
Inventors:
Alexander Ruud Weusthuis, Emil Johan Harald Wolbert, Jan Springer, John Van Der Oost, Gerrit Eggink
Abstract: The present invention relates to a process for producing steam using heat recovered from a polymerization reaction. In particular, the present invention relates to a process for producing steam using heat recovered from a polymerization reaction for producing polyolefin, comprising the steps of: thermally contacting said polymerization reaction with a cooling fluid such that the cooling fluid removes heat from said reaction, thermally contacting at least part of said cooling fluid with at least one absorption cycle thereby transferring heat from the cooling fluid to said absorption cycle, using said absorption cycle to produce steam from a condensate, wherein the cooling fluid is used as a hot source for heating at least one evaporator and at least one generator comprised in said at least one absorption cycle. The present invention also relates to a process for cooling a polymerization reaction using a process as described herein. Said invention also relates to a polyolefin producing unit.
Abstract: Formulated jet turbine fuels and methods of forming the same are described herein including a method of manufacturing a jet turbine fuel that includes hydrocarbon fluids.
Abstract: A resin composition comprising at least 0.1% by weight of poly(hydroxy carboxylic acid) and at least 50% by weight of polypropylene prepared with a single-site catalyst, preferably with a metallocene catalyst.
Abstract: A supported catalyst system comprising a coprecipitated silica-and titania-containing support, comprising alumoxane as acatalyst activating agent, and a metallocene, wherein the supported catalyst system has a Ti content of at least 0.1 wt %.
Type:
Application
Filed:
August 16, 2011
Publication date:
August 29, 2013
Applicant:
TOTAL RESEARCH & TECHNOLOGY FELUY
Inventors:
Christopher Willocq, Aurélien Vantomme, Martine Slawinski
Abstract: The present invention relates to metalloaluminophosphate (MeAPO) molecular sieve with lamellar crystal morphology having an empirical chemical composition on an anhydrous basis, after synthesis and calcination, expressed by the formula HxMeyAlzPkO2 wherein, y+z+k=1 x<=y said molecular sieve having predominantly a plate crystal morphology in which the width (W) and the thickness (T) are W/T is >=10 The above metalloaluminophosphate (MeAPO) molecular sieve can be made by a method which comprises: a) forming a reaction mixture containing a texture influencing agent (TIA), an organic templating agent (TEMP), at least a reactive inorganic source of MeO2 insoluble in the TIA, reactive sources of AI203 and P205, b) crystallizing the above reaction mixture thus formed until crystals of the metalloaluminophosphate are formed, c) recovering a solid reaction product, d) washing it with water to remove the TIA and e) calcinating it to remove the organic template.
Type:
Grant
Filed:
March 10, 2008
Date of Patent:
August 27, 2013
Assignees:
Total Petrochemicals Research Feluy, Centre National de la Recherche Scientifique (CNRS)
Inventors:
Walter Vermeiren, Nikolai Nesterenko, Carolina Petitto, Francesco Di Renzo, Francois Fajula
Abstract: The present invention relates to the field of group 4 post-metallocene complexes based on sterically encumbered bis(naphthoxy)pyridine and bis(naphthoxy)thiophene ligands. It also relates to the use of such post-metallocene complexes in the polymerization of ethylene and alpha-olefins.
Type:
Grant
Filed:
February 17, 2009
Date of Patent:
August 27, 2013
Assignees:
Total Petrochemicals Research Feluy, Centre National de la Recherche Scientifique (CNRS)
Inventors:
Jean-François Carpentier, Evgueni Kirillov, Abbas Razavi
Abstract: The invention relates to a method for sampling a sulphur-containing solid product including supplying a gas flow comprising hydrogen sulphide, bringing the gas flow into contact with a solid reagent and reacting the solid reagent with the hydrogen sulphide contained in the gas flow, the reaction fixing the sulphur of the hydrogen sulphide by forming a sulphur-containing solid product which is different in color from the solid reagent, and recovering the sulphur-containing solid product. The invention also relates to a device suitable for the implementation of this method.
Type:
Grant
Filed:
April 20, 2009
Date of Patent:
August 27, 2013
Assignee:
Total S.A.
Inventors:
Daniel Dessort, Robert Le Van Loï, Nadine Loubere
Abstract: The present invention relates to an injection-stretch blow molding process (ISBM) for the manufacture of an impact-resistant container with good optical properties from a polyolefin composition comprising a polypropylene and a polyethylene produced with a metallocene-based catalyst.
Abstract: A user-friendly crane mat carrier is provided for conveniently transporting, storing and supporting crane mats, pads and other items. The economical light weight crane mat assembly can comprise a frame assembly with a main load-supporting bar, crossbars and perimeter bars. The special crane mat carrier can be easily connected to a crane, such as with a drawbar fixture, securing plate and locking plate. A hanger assembly with a suspension bar can be provided to hang the crane mat carrier. A latch mechanism can also be provided to securely lock the crane mat carrier.
Abstract: The present invention is a process for the dehydration of an alcohol having at least 2 carbon atoms to make the corresponding olefin, comprising: a) introducing in a reactor a stream (A) comprising at least an alcohol, optionally water, optionally an inert component, b) contacting said stream with an acidic catalyst in said reactor at conditions effective to dehydrate at least a portion of the alcohol to make an olefin, c) recovering from said reactor a stream (B) comprising: the inert component and at least an olefin, water and optionally unconverted alcohol, d) optionally fractionating the stream (B) to recover the unconverted alcohol and recycling said unconverted alcohol to the reactor of step a), e) optionally fractionating the stream (B) to recover the inert component, water and the olefin and optionally recycling said inert component and optionally a part of the water to the reactor of step a), wherein, f) an effective amount of a component capable to neutralize a part of the catalyst active site is i
Type:
Application
Filed:
June 20, 2011
Publication date:
August 22, 2013
Applicant:
TOTAL RESEARCH & TECHNOLOGY FELUY
Inventors:
Delphine Minoux, Cindy Adam, Nikolai Nesterenko, Jean-Pierre Dath, Walter Vermeiren, Sander Van Donk
Abstract: The present invention relates to a process for making essentially ethylene and propylene comprising: a) providing an alcohol mixture (A) comprising about 20 w % to 100% isobutanol, b) introducing in a reactor (A) a stream comprising the mixture (A) mixed with methanol or dimethyl ether or mixture thereof, optionally water, optionally an inert component, c) contacting said stream with a catalyst (A1) in said reactor (A), the MTO reactor, at conditions effective to convert at least a part of the alcohol mixture (A) and at least a part of the methanol and/or dimethyl ether to olefins, d) recovering from said reactor (A) an effluent comprising: ethylene, propylene, butene, water, optionally unconverted alcohols, various hydrocarbons, and the optional inert component of step b), e) fractionating said effluent of step d) to produce at least an ethylene stream, a propylene stream, a fraction consisting essentially of hydrocarbons having 4 carbon atoms or more, water and the optional inert component of step a), op
Type:
Application
Filed:
July 8, 2011
Publication date:
August 22, 2013
Applicant:
TOTAL RESEARCH & TECHNOLOGY FELUY
Inventors:
Cindy Adam, Delphine Minoux, Nikolai Nesterenko, Sander Van Donk, Jean-Pierre Dath
Abstract: The present invention is a process to make isoprene comprising: a) providing a reaction zone comprising an acidic aqueous solution, b) introducing, continuously or intermittently, in said reaction zone a mixture comprising (i) isobutanol and optionally (ii) t-butanol or an iso-butene precursor which is not isobutanol and not t-butanol or iso-butene or any combination of two or three of these (ii) components, an aqueous solution of formaldehyde, c) operating said reaction zone at conditions effective to dehydrate isobutanol and optionally (ii) t-butanol and optionally the iso-butene precursor to iso-butene and produce isoprene by reaction of formaldehyde and iso-butene while distilling away a mixture comprising produced isoprene, water, unreacted starting materials and other low boiling point components from this reaction zone to the outside of the reaction zone. In another embodiment isobutanol provides 10% or more of the iso-butene for the isoprene synthesis.
Abstract: A water treatment method includes: withdrawing water from the environment; filtering the withdrawn water in a membrane filtration unit; extracting a production flow from an underground formation containing hydrocarbons; separating and collecting production water from the production flow; filtering the production flow in the membrane filtration unit; collecting a treated water flow from the membrane filtration unit. An installation adapted for applying this method is also provided.
Type:
Application
Filed:
October 11, 2011
Publication date:
August 22, 2013
Applicant:
TOTAL S.A.
Inventors:
Samuel Heng, Pierre Pedenaud, Philippe Coffin
Abstract: The present invention relates to a process for the polymerization of an olefin monomer. In particular, the present invention relates to a process for the polymerization of an olefin monomer and one or more optional comonomers in presence of a polymerization catalyst and hydrogen, said process being characterized by an improved control of the hydrogen concentration in the polymerization reactor. In addition, the present invention provides for an improved hydrogen feeding system to a polymerization reactor. Furthermore, the present invention provides for a polymerization reactor comprising such an improved hydrogen feeding system.
Abstract: The present invention relates to a method suitable for establishing an analysis of a reactor effluent which is gaseous in process conditions and presents a gas phase and a liquid phase after cooling, comprising: providing a reactor producing a gaseous effluent at a temperature of at least about 100° C. and a pressure ranging from 0.
Type:
Application
Filed:
June 15, 2011
Publication date:
August 15, 2013
Applicant:
TOTAL RESEARCH & TECHNOLOGY FELUY
Inventors:
Guy Baeveghems, Eric Detemmeran, Dominique Viennet, Mary Gaëtan, Eric Romers
Abstract: The invention covers a supported catalyst system prepared according to a process comprising the following step: i). impregnating a silica-containing catalyst support having a specific surface area of from 150 m2/g to 800 m2/g, preferably 280 m2/g to 600 m2/g, with one or more titanium compounds of the general formula selected from RnTi(OR?)m and (RO)nTi(OR?)m, wherein R and R? are the same or different and are selected from hydrocarbyl groups containing from 1 to 12 carbon and halogens, and wherein n is 0 to 4, m is 0 to 4 and m+n equals 4, to form a titanated silica-containing catalyst support having a Ti content of at least 0.1 wt % based on the weight of the Ti-impregnated catalyst support wherein the supported catalyst system further comprises an alumoxane and a metallocene.
Type:
Application
Filed:
July 1, 2011
Publication date:
August 15, 2013
Applicant:
TOTAL RESEARCH & TECHNOLOGY FELUY
Inventors:
Christopher Willocq, Aurélien Vantomme, Martine Slawinski
Abstract: A particular subject of the invention is the creation of three-dimensional representations from real models having similar and predetermined characteristics, using a system comprising a support suitable for receiving such a real object, configured to present the object in a pose similar to that of use of said at least one real object, an image acquisition device configured to obtain at least two distinct images of the real object from at least two separate viewpoints and a data processing device configured to receive these images, to clip a representation of the real object in each of these images in order to obtain at least two textures of the real object, obtaining a generic three-dimensional model of the real object and creating a three-dimensional model of the real object from the textures and the generic three-dimensional model obtained.
Abstract: The disclosure relates to a bituminous composition comprising at least one bitumen and at least one organogelling molecule taken alone or as a mixture, said organogelling molecule being represented by the following general formula (I): where: A represents an acyclic, cyclic or polycyclic, saturated or unsaturated, linear or branched hydrocarbon-based group having 3 to 92 carbon atoms, resulting from the polymerization of the side chains of at least one unsaturated fatty acid, X represents an NH group or an oxygen atom O, R1 represents a group chosen from: a linear or branched hydrocarbon-based group having 2 to 40 carbon atoms, optionally comprising one or more heteroatoms and optionally comprising one or more unsaturations, or a substituted or unsubstituted aromatic group, R2 represents a group chosen from: a hydrogen atom, a linear or branched hydrocarbon-based group having 1 to 40 carbon atoms, comprising one or more heteroatoms and optionally comprising one or more unsaturations, or a substituted or unsub
Type:
Grant
Filed:
November 25, 2008
Date of Patent:
August 13, 2013
Assignees:
Total Raffinage Marketing, Universite Pierre et Marie Curie
Inventors:
Pierre Chaverot, Sylvia Dreessen, Laurent Bouteiller, Emmanuelle Bugnet