Patents Assigned to Umicore
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Patent number: 12288872Abstract: A positive electrode active material powder suitable for lithium-ion batteries, comprising lithium transition metal-based oxide particles, said particles comprising a core and a surface layer, said surface layer being on top of said core, said particles comprising the elements: Li, M? and oxygen, wherein M? has a formula: M?=NizMnyCoxAk, wherein A is a dopant, 0.60?z?0.90, 0.05?y?0.20, 0.05?x?0.20, x+y+z+k=1, and k?0.01, said positive electrode active material powder having a median particle size D50 ranging from 5 ?m to 15 ?m, a span ranging from 0.25 to 0.90, and a surface layer thickness ranging from 10 nm to 200 nm, said surface layer comprising: sulfur in a content superior or equal to 0.150 wt % and inferior or equal to 0.375 wt % with respect to the total weight of the positive electrode active material powder, and sulfate ion (SO42?) in a content superior or equal to 4500 ppm and inferior or equal to 11250 ppm.Type: GrantFiled: July 2, 2020Date of Patent: April 29, 2025Assignees: UMICORE, UMICORE KOREA LTD.Inventors: Maxime Blangero, KyungSub Jung, Bin-Na Yun, Olesia Karakulina
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Patent number: 12281403Abstract: A method of electroplating nanograined copper on a substrate includes: providing the substrate; providing an electroplating bath that includes a copper salt, an acid, a leveler, a chlorine compound, an accelerator, a suppressor; and water; and electroplating the substrate in the electroplating bath to form the nanograined copper at room temperature. The suppressor is a ployether polyol compound, the nanograined copper has an average grain size of about 100 nm, and the nanograined copper has a resistivity of about 1.78-1.90 ?Ohm·cm. A nanograined copper prepared according to the method is also disclosed.Type: GrantFiled: May 23, 2022Date of Patent: April 22, 2025Assignee: UMICORE SUZHOU SEMICONDUCTOR MATERIALS CO., LTD.Inventors: Yun Zhang, Peipei Dong, Jing Wang
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Patent number: 12274980Abstract: Systems and methods directed at removing HCN from an FCC process flue gas (and/or generated in the catalyst system reactions themselves) such that the final HCN output is satisfactory; while, in so doing, avoiding undesirable levels of other pollutants contained in that exhaust gas such as NOx. A system includes an assembly having a fluid catalytic cracking (FCC) unit generating a flue gas with HCN and NOx and a catalyst device placed in the flue gas line to remove HCN and NOx. The catalyst device having one or more SCR catalytic articles, as in one free of platinum group metal material (PGM) or a dual functioning SCR catalyst with PGM, or a combination of each. The assembly can be provided with an ammonia supplier and optionally an H2O supplier with associated injection for supply into the flue gas upstream of a catalytic article(s).Type: GrantFiled: September 1, 2023Date of Patent: April 15, 2025Assignee: UMICORE AG & CO. KGInventors: Hendrik-David Noack, David Taylor
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Patent number: 12270326Abstract: The present invention relates to a wall-flow filter for removing particles from the exhaust gas of an internal combustion engine, which comprises a coating F, which comprises a sintered material S, wherein material S comprises an oxide, oxide-hydroxide, carbonate, sulphate, silicate, phosphate, mixed oxide, composite oxide, molecular sieve or a mixture comprising two or more of these materials.Type: GrantFiled: March 22, 2022Date of Patent: April 8, 2025Assignee: UMICORE AG & CO. KGInventors: Massimo Colombo, Jan Schoenhaber, Meike Antonia Gotthardt, Carolin Braun
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Patent number: 12255326Abstract: A method for preparing a powderous positive electrode material comprising single crystal monolithic particles and having a general formula Li1+a((Niz(Ni1/2Mn1/2)yCox)1-k Ak)1-aO2, wherein A is a dopant, ?0.03?a?0.06, 0.05?x?0.35, 0.10?z?0.95, x+y+z=1 and k?0.05 is described. The method comprises providing a mixture comprising a Ni- and Co- bearing precursor and a Li bearing precursor, subjecting the mixture to a multiple step sintering process whereby in the final sintering step a sintered lithiated intermediate material is obtained comprising agglomerated primary particles having a primary particle size distribution with a D50 between 2.0 and 8.0 ?m, subjecting the lithiated intermediate material to a wet ball milling step to deagglomerate the agglomerated primary particles and obtain a slurry comprising deagglomerated primary particles, separating the deagglomerated primary particles from the slurry, and heat treating the deagglomerated primary particles at a temperature between 300° C. and at least 20° C.Type: GrantFiled: March 13, 2019Date of Patent: March 18, 2025Assignees: UMICORE, UMICORE KOREA LTD.Inventors: Jens Paulsen, Shinichi Kumakura, TaeHyeon Yang, Dae-Hyun Kim, HyeJeong Yang
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Patent number: 12247505Abstract: The present invention is directed to the purification of exhaust gases of an internal combustion engine operated predominantly with a stoichiometric fuel mixture. The exhaust system has in particular 4 purification functions in a particular order. A three-way catalyst (TWC1) near the engine is followed by a gasoline particle filter (GPF) and another three-way catalyst (TWC2) downstream thereof. The system additionally has a nitrogen oxide storage function.Type: GrantFiled: July 11, 2022Date of Patent: March 11, 2025Assignee: UMICORE AG & CO. KGInventors: Jan Schoenhaber, Joerg-Michael Richter, Carolin Braun, Tim Palm
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Patent number: 12246306Abstract: The present invention relates to a catalyst comprising a carrier substrate of length L and at least two washcoat layers A and B wherein washcoat layer A comprises alumina; ceria; an alkaline earth compound and/or an alkali compound; platinum, palladium or platinum and palladium; washcoat layer B comprises a zeolite and palladium, wherein the palladium is present as palladium cation in the zeolite structure or is wholly or partially present as palladium metal and/or as palladium oxide in the zeolite structure and/or on the surface of the zeolite structure; and wherein washcoat layer A is arranged below washcoat layer B.Type: GrantFiled: November 18, 2020Date of Patent: March 11, 2025Assignee: UMICORE AG & CO. KGInventors: Badr Bassou, Anke Woerz
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Patent number: 12227430Abstract: A cobalt oxide precursor powder for use in preparing a positive electrode active material and methods of production thereof are described. The precursor powder comprises particles has a Fd-3m structure and a formula Co1-yAyOx, wherein 1<x?4/3, 0?y?0.05, wherein A comprises at least one element from the group consisting of Ni, Mn, Al, Mg, Ti, and Zr. The particles have a D50?15 ?m and a compressive strength at least 100 MPa and at most 170 MPa.Type: GrantFiled: December 10, 2019Date of Patent: February 18, 2025Assignees: UMICORE, UMICORE KOREA LTD.Inventors: KyeongSe Song, AReum Park, HeeSuk Ku, JinWook Kim
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Patent number: 12221456Abstract: The invention relates to the use of a metal complex, which has at least one ligand of the formula R1—N3—R2, wherein R1 and R2 are hydrocarbon moieties, for depositing the metal or a compound of the metal from the gas phase. The invention further relates to methods for depositing metals from the metal complexes, and to metal complexes, substituted triazene compounds and to methods for the production thereof.Type: GrantFiled: December 12, 2018Date of Patent: February 11, 2025Assignee: Umicore AG & Co. KGInventors: Joerg Sundermeyer, Susanne Pulz, Fabian Schroeder
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Patent number: 12220658Abstract: The present invention relates to a method for producing a coated wall-flow filter. The wall-flow filter is coated with a powder aerosol.Type: GrantFiled: May 8, 2019Date of Patent: February 11, 2025Assignee: UMICORE AG & CO. KGInventors: Martin Foerster, Antje Oltersdorf, Naina Deibel, Sascha Zoelle, Jürgen Koch, Manuel Gensch, Wolfgang Hasselmann
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Publication number: 20250041834Abstract: The present invention is directed towards a catalytic coating comprising a composite oxide which accelerates soot combustion. The oxide is used in a catalytic coating in soot filters for the abatement of noxious pollutants in exhaust gases from combustion processes. A process for the production of catalytic coatings comprising these composite oxides is also given.Type: ApplicationFiled: September 30, 2022Publication date: February 6, 2025Applicant: UMICORE AG & CO. KGInventors: Alberto FERNANDEZ-ARROYO, Dirk VAN GENECHTEN, Jan SCHOENHABER, Massimo COLOMBO
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Publication number: 20250041839Abstract: The invention relates to a wall flow filter for removing particulate matter from the exhaust of internal combustion engines, comprising a wall flow filter substrate having a length L, and a coating F, the wall flow filter substrate being provided with channels E and A which run parallel between a first end and a second end of the wall flow filter substrate, separated by porous walls, and forming surfaces OE and OA. Channels OE are closed at the second end and channels A are closed at the first end. Coating F is disposed in the porous walls and/or on surfaces OE, but not on surfaces OA, and comprises a particulate metal compound and no precious metal, characterised in that the particulate metal compound catalyses the oxidation of soot.Type: ApplicationFiled: September 30, 2022Publication date: February 6, 2025Applicant: UMICORE AG & CO. KGInventors: Jan SCHOENHABER, Gabriela KUCEROVA, Naina DEIBEL, Meike Antonia GOTTHARDT
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Patent number: 12215407Abstract: A process is disclosed for the recovery of valuable metals from oxidic ores, in particular from polymetallic nodules. The process is suitable for the recovery of Cu, Co, Ni, Fe, and Mn, which are the main metals of interest in such polymetallic nodules. The present process is, among others, characterized by the handling of Fe, which is dissolved and kept in solution until the step of crystallization rather than removed at an earlier stage. A mixed Mn—Fe residue is obtained, which, after thermal treatment, provides a Mn—Fe oxide that is suitable for the steel or for the manganese industry. Excellent Cu, Co and Ni yields are obtained, while Fe is leached and valorized together with Mn.Type: GrantFiled: July 27, 2020Date of Patent: February 4, 2025Assignee: UMICOREInventors: Michel Daniels, Jean Scoyer, Michael Baltes, Margot Neven, Jan Leyssen
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Patent number: 12211992Abstract: A positive electrode composition for a rechargeable battery, the composition comprising a first and a second powderous lithium metal oxide, the first lithium metal oxide comprising either one or more of Ni, Mn and Co, the second lithium metal oxide powder having either: the formula LixWM?yOz, M? being a metal having a valence state of +2 or +3, with 0<y?1, 3?x?4, 5?z?6, whereby x=(2*z)?[y*(valence state of M?)]?(valence state of W).Type: GrantFiled: May 23, 2017Date of Patent: January 28, 2025Assignees: UMICORE, UMICORE KOREA LTD.Inventors: Shinichi Kumakura, Liang Zhu, Jens Martin Paulsen, Gyeong-Ok Kim
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Patent number: 12195869Abstract: The invention is directed to the use of electrolytic bronze deposits as substitutes for the noble metal electroplating of electronic circuits, e.g. for use in electronic payment cards and identity cards. The invention also relates to a novel layer sequence of bronze layers.Type: GrantFiled: June 30, 2022Date of Patent: January 14, 2025Assignee: Umicore Galvanotechnik GmbHInventors: Robert Ziebart, Guenter Wirth, Silvia Neuhaus, Stefan Mueller
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Publication number: 20250010281Abstract: The invention relates to a method for producing a substrate (1) for an exhaust gas aftertreatment device having the following steps: 1. Applying (S1) a coating material (12) on an elastic base (11) that is mounted over a flexible cushion (21); 2. Dipping or pressing (S2) a surface of the substrate (1), in which inlet openings of through-channels (2) through the substrate (1) are arranged, into the coating material (12); 3. Lifting the coated catalyst element (1); and 4. Aftertreating, and in particular drying or calcining (S3), the coating material (12) on the coated substrate (1).Type: ApplicationFiled: October 2, 2023Publication date: January 9, 2025Applicant: UMICORE AG & CO. KGInventors: Karlheinz RUCKDAESCHEL, Karoline KOZUBSKI, Melanie WASSMER
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Patent number: 12188392Abstract: The invention is directed to the purification of exhaust gases of an internal combustion engine operated predominantly with a stoichiometric fuel mixture. The exhaust system has in particular 4 purification functions in a particular order. A three-way catalyst (TWC1) near the engine is followed by a gasoline particle filter (GPF) and another three-way catalyst (TWC2) downstream thereof. The system additionally includes an ammonia storage function.Type: GrantFiled: July 20, 2022Date of Patent: January 7, 2025Assignee: UMICORE AG & CO. KGInventors: Jan Schoenhaber, Joerg-Michael Richter, Carolin Braun, Tim Palm
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Publication number: 20250001405Abstract: An object of the present invention is to provide a means for improving catalytic performance of a catalyst for exhaust gas purification. The invention relates to a catalyst for exhaust gas purification, containing a first catalyst layer and a second catalyst layer sequentially laminated onto a three-dimensional structure, in which the first catalyst layer contains rhodium, the second catalyst layer contains palladium, strontium, and alumina, the strontium content in the second catalyst layer (in terms of strontium oxide) per 1 liter of the three-dimensional structure is more than 0 g/L and less than 15 g/L, and the catalyst for exhaust gas purification has a pore volume of pores having a pore size of 2 nm or more and 40 nm or less of more than 0.26 mL/g in a pore volume distribution measured by nitrogen adsorption method.Type: ApplicationFiled: October 26, 2022Publication date: January 2, 2025Applicant: UMICORE SHOKUBAI JAPAN CO., LTDInventors: Yuji OGINO, Yusuke HANEDA, Keisuke KINUGASA, Yosuke GOTO, Kosuke MIKITA
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Patent number: 12180234Abstract: The invention relates to the synthesis and provision of a new class of volatile metal organic compounds based on bis(alkylimine)glyoxal and bis(dialkylhydrazone)glyoxal ligands in combination with cyclopentadienide and alkyl ligands for use in ALD and CVD processes.Type: GrantFiled: July 26, 2019Date of Patent: December 31, 2024Assignee: UMICORE AG & CO. KGInventors: Nicholas Rau, Joerg Sundermeyer, Andreas Rivas Nass, Ralf Karch, Annika Frey, Angelino Doppiu, Eileen Woerner
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Patent number: 12168812Abstract: The present disclosure concerns a process for the recovery of valuable metals from polymetallic nodules. A two-stage process using SO2 in an acidic aqueous media is disclosed. In a first step, performed in mildly acidic conditions, Mn, Ni, and Co are dissolved; in a second, more acidic step, Cu is dissolved. Under these conditions, the leachate of the first step contains most of the Mn, Ni, and Co, while being nearly Cu-free. The Ni and Co are precipitated as sulfides; the Mn can be recovered as sulfate by crystallization. Cu, which is leached in the second step, is selectively precipitated, also as sulfide.Type: GrantFiled: December 10, 2019Date of Patent: December 17, 2024Assignee: UMICOREInventors: Michel Daniels, Jean Scoyer, Michael Baltes, Margot Neven, Jan Leyssen