Abstract: The present invention disclose catalyst compositions for the selective catalytic reduction of nitrogen oxides, consisting of at least one oxide of vanadium in an amount of 2.0 to 4.0 wt.-%, calculated as V2O5 and based on the total weight of the catalyst composition, at least one oxide of tungsten in an amount of 2.5 to 7.2 wt.-%, calculated as WO3 and based on the total weight of the catalyst composition, at least one oxide of antimony in an amount of 0.6 to 3.4 wt.-%, calculated as Sb2O5 and based on the total weight of the catalyst composition, at least one oxide of zirconium in an amount of 0 to 1.0 wt.-%, calculated as ZrO2 and based on the total weight of the catalyst, and at least one oxide of titanium in an amount of 84.6 to 94.9 wt.-% calculated as TiO2 and based on the total weight of the catalyst, wherein the weight ratio of the oxides of vanadium, tungsten, antimony, titanium and optionally zirconium, calculated as V2O5, WO3, Sb2O5, TiO2 and optionally ZrC2, respectively, add up to 100 wt.-%.

Abstract: The invention relates to tetraalkylammonium-tetra- or hexahydroxometallates such as tetraethylammonium hexahydroxoplatinate, (N(alkyl)4)y[M(OH)x], a method for the production thereof, and the use thereof for producing catalysts.

Abstract: The present invention is directed toward a platinum electrolyte which contains certain additives, and to a method for the electrolytic deposition of a platinum layer with the aid of the electrolyte according to the invention.

Abstract: A bimodal lithium transition metal oxide based powder mixture comprises a first and a second lithium transition metal oxide based powder. The first powder comprises particles of a material A comprising the elements Li, a transition metal based composition M and oxygen. The first powder has a particle size distribution characterized by a (D90?D10)/D50?1.5. The second powder comprises a material B having single crystal particles, said particles having a general formula Li+bN??bO2, wherein ?0.03?b?0.10, and N?=NixM?yCozEd, wherein 0.30?x?0.92, 0.05?y?0.40, 0.05?z?0.40 and 0?d?0.10, wherein M? is one or both of Mn or Al, and E is a dopant different from M?. The first powder has an average particle size D50 between 10 and 40 ?m. The second powder has a D50 between 2 and 4.5 ?m. The weight ratio of the second powder in the mixture is between 15 and 60 wt %.

Abstract: The invention relates to the use of a metal complex, which has at least one ligand of the formula R1—N3—R2, wherein R1 and R2 are hydrocarbon moieties, for depositing the metal or a compound of the metal from the gas phase. The invention further relates to methods for depositing metals from the metal complexes, and to metal complexes, substituted triazene compounds and to methods for the production thereof.

Abstract: The invention is directed to the use of electrolytic bronze deposits as substitutes for the noble metal electroplating of electronic circuits, e.g. for use in electronic payment cards and identity cards. The invention also relates to a novel layer sequence of bronze layers.

Abstract: Metal complexes of formula (I) are described: [M(L1)x(L2)y(hydra)z]n??formula (I) wherein: M=metal atom having an atomic number selected from the ranges a) through c): a) 12, 21 to 34, with the exception of 30, b) 39 to 52, with the exception of 48, c) 71 to 83, with the exception of 80, L1=neutral or anionic ligand, with x=0 or 1, L2=neutral or anionic ligand, with y=0 or 1, (hydra)=acetone dimethylhydrazone monoanion, with z=1, 2, or 3, n=1 or 2, and the total charge of the complex is 0.

Abstract: A process is divulged for recovering metals from a metal-bearing material containing, in oxidized form, more than 1% of Co, a total of Co and Ni of more than 15%, and more than 1% Mg, comprising smelting said metal-bearing material in a bath furnace together with slag formers, thereby producing an alloy phase with more than 80% of the Co, and less than 1% of the Mg, and a slag phase, by applying reducing smelting conditions, and by selecting CaO, SiO2, and Al2O3 as slag formers, in amounts to obtain a final slag composition according to the ratio's 0.25<SiO2/Al2O3<2.5, 0.5<SiO2/CaO<2.5, and MgO>10%; and separating the alloy phase from the slag phase. This process ensures quantitative recovery of Co in an alloy phase along with other metals such as Ni, while collecting Mg into a slag.

Abstract: The invention provides a method for synthesizing musk macrocycles comprising contacting an easily accessible diene starting materials bearing a Z-olefin moiety and performing a ring closing metathesis reaction in the presence of a Group 8 olefin metathesis catalyst.

Abstract: The present disclosure concerns a process for the concentration of lithium in metallurgical fumes. The process comprises the steps of: —providing a metallurgical molten bath furnace; —preparing a metallurgical charge comprising lithium-bearing material, transition metals, and fluxing agents; —smelting the metallurgical charge and fluxing agents in reducing conditions in said furnace, thereby obtaining a molten bath with an alloy and a slag phase; and, —optionally separating the alloy and the slag phase; characterized in that a major part of the lithium is fumed as LiCl from the molten slag, by addition of alkali or earth alkali chloride to the process. Using a single smelting step, valuable transition metals such as cobalt and nickel also present in the charge are collected in an alloy phase, while the lithium reports to the fumes. The lithium in the fumes is available in concentrated form, suitable for subsequent hydrometallurgical processing.

Abstract: A 2-step high temperature process for recovering Ni, Co, and Mn from various sources comprises preparing a metallurgical charge comprising materials containing Ni, Co, and Mn, and Si, Al, Ca and Mg as slag formers; smelting the charge with slag formers in first reducing conditions, thereby obtaining a Ni—Co alloy comprising a major part of at least one of Co and Ni, with Si<0.1%, and a first slag comprising the major part of the Mn; separation of the first slag from the alloy; and, smelting the first slag in second reducing conditions, more reducing than said first reducing conditions, thereby obtaining a Si—Mn alloy comprising the major part of the Mn, with Si>10%, and a second slag. A Ni—Co alloy is produced, and a Si—Mn alloy is produced. The second slag is essentially free of heavy metals and therefore suitable for reuse.

Abstract: The invention is directed to ruthenium-based metathesis catalysts of the Grubbs-Hoveyda type. The new 2-aryloxy-substituted ruthenium catalysts described herein reveal rapid initiation behavior. Further, the corresponding styrene-based precursor compounds are disclosed. The catalysts are prepared in a cross-metathesis reaction starting from styrene-based precursors which can be prepared in a cost-effective manner. The new Grubbs-Hoveyda type catalysts are suitable to catalyze ring-closing metathesis (RCM), cross metathesis (CM) and ring-opening metathesis polymerization (ROMP). Low catalyst loadings are necessary to convert a wide range of substrates including more complex and critical substrates via metathesis reactions at low to moderate temperatures in high yields within short reaction times.

Abstract: The present invention relates to ?-nickel hydroxide doped with aluminum ions, in which the aluminum ions are homogeneously distributed in the crystal lattice of the ?-nickel hydroxide, as well as a method for their production. The present invention further relates to the use of the ?-nickel hydroxide according to the invention as a precursor material for the production of electrode material for lithium-ion batteries and nickel-metal hydride batteries and as a precursor material in the production of Raney nickel catalysts.

Abstract: A bimodal lithium transition metal oxide based powder mixture comprises a first and a second lithium transition metal oxide based powder. The first powder comprises particles of a material A comprising the elements Li, a transition metal based composition M and oxygen. The first powder has a particle size distribution characterized by a (D90?D10)/D50<1.0. The second powder comprises a material B having single crystal particles, said particles having a general formula Li+bN??bO2, wherein ?0.03?b?0.10, and N?=NixM?yCozEd, wherein 0.30?x?0.92, 0.05?y?0.40, 0.05?z?0.40 and 0?d?0.10, wherein M? is one or both of Mn or Al, and E is a dopant different from M?. The first powder has an average particle size D50 between 10 and 40 ?m. The second powder has a D50 between 2 and 4 ?m. The weight ratio of the second powder in the mixture is between 15 and 60 wt %.

Abstract: A precursor compound for manufacturing a lithium transition metal based oxide powder usable as an active positive electrode material in lithium-ion batteries, the precursor being either one of a metal-bearing M?-hydroxide, -oxyhydroxide or -carbonate, with M?=Ni1-x-y-zMnxCOyAz with x>0, y>0, 0.70?1-x-y-z?0.95 and 0?z<0.1, the precursor comprising having a core comprising a metal-bearing compound M?c and a shell comprising a metal-bearing compound M?s, wherein M?c=Ni1-xc-yc-zcMnxcCOycAzc with 0<xc?0.2, 0<yc?0.2, 0?zc<0.1 and 0.75?1-x-y-z?0.95, and M?s=Ni1-xs-ys-zsMnxsCOysAzs with 0<xs?0.25, 0.75<ys?0.95, 0?zs<0.1 and 0?1-xs-ys-zs?0.10.

Abstract: The present invention relates to an electrolyte and to a method for the electrolytic deposition of silver coatings and silver alloy coatings. The electrolyte according to the invention is cyanide-free, storage-stable and ensures the deposition of high-gloss, brilliant and white silver and silver alloy layers for technical and decorative applications.

Abstract: To provide a positive electrode active material of a lithium ion battery which has a large discharge capacity, excellent cycle characteristics, and suppressed gas generation. Resolution Means: A lithium metal composite oxide powder for use in a positive electrode active material for a lithium ion battery, the powder thereof having a composition of LiaNibCocAldO2 (wherein, a=0.8 to 1.2, b=0.7 to 0.95, c=0.02 to 0.2, d=0.005 to 0.1, and b+c+d=1) treated with an aqueous solution of an organic metal salt and soluble aluminum salt, and not causing volume expansion due to gas generation.

Abstract: Subject of the invention is a process for producing a biofuel from fatty acid methyl esters (FAMEs) obtained by transesterification of vegetable oils, comprising the steps of (a) ethenolysis of the fatty acid methyl esters in the presence of ethylene and an ethenolysis catalyst, and (b) isomerizing metathesis in the presence of an isomerization catalyst and a metathesis catalyst. The invention also relates to biofuels obtainable by the inventive process and to uses of ethylene for adjusting and optimizing biofuels.

Abstract: A crystalline precursor compound for manufacturing a lithium transition metal based oxide powder usable as an active positive electrode material in lithium-ion batteries, the precursor having a general formula Li1?a((Niz(Ni0.5Mn0.5)yCox)1?kAk)1+aO2, wherein A comprises at least one element of the group consisting of: Mg, Al, Ca, Si, B, W, Zr, Ti, Nb, Ba, and Sr, with 0.05?x?0.40, 0.25?z?0.85, x+y+z=1, 0?k?0.10, and 0?a?0.053, wherein said crystalline precursor powder has a crystalline size L, expressed in nm, with 15?L?36.

Abstract: The present invention pertains to a catalyst for use in the selective catalytic reduction (SCR) of nitrogen oxides comprising a monolithic substrate and a coating A, which comprises an oxidic metal carrier comprising an oxide of titanium and a catalytic metal oxide which comprises an oxide of vanadium wherein the mass ratio vanadium/titanium is 0.07 to 0.26.