Abstract: Alkylation of aromatics is effected by use of an alkylating agent, e.g., methanol, and novel alkylation catalysts containing non-zeolitic molecular sieves.
Type:
Grant
Filed:
June 16, 1986
Date of Patent:
June 14, 1988
Assignee:
Union Carbide Corporation
Inventors:
Regis J. Pellet, Gary N. Long, Jule A. Rabo
Abstract: Described herein are curable molding compositions comprising a mixture of:(a) a poly(acrylate) characterized by the following empirical formula: ##STR1## wherein R is the hydroxy-free residue of an organic polyhydric alcohol which contained alcoholic hydroxyl groups bonded to different carbon atoms, R.sub.1 and R.sub.2 are independently hydrogen or methyl, and n is 1 to 3,(b) acrylic or methacrylic acid or a functionalized derivative thereof having a molecular weight of less than 300 which is different from (a), and(c) an ethylenically unsaturated monomer which is soluble in and copolymerizable with (a) and (b) and which is different from (a) and (b). The compositions can also contain one or more fibers with a melting point or a glass transition temperature above about 130.degree. C.
Type:
Grant
Filed:
March 25, 1987
Date of Patent:
June 14, 1988
Assignee:
Union Carbide Corporation
Inventors:
Linda A. Domeier, Michael J. Michno, Jr., Edward N. Peters
Abstract: A process for producing boron nitride which comprises providing a nitrogen-containing nitride promoter, preferably melamine or dicyandiamide, in contact with an admixture of boron oxide and a sufficient amount of boric acid to enhance the formation of boron nitride under a non-oxidizing atmosphere, and maintaining same at sufficiently elevated temperature to form boron nitride.
Abstract: Transition metal-bis-phosphite catalyzed carbonylation processes, especially hydroformylation, as well as transition metal-bis-phosphite compositions, bis-phosphite ligands and transition metal-bis-phosphite catalysts.
Type:
Grant
Filed:
September 5, 1985
Date of Patent:
May 31, 1988
Assignee:
Union Carbide Corporation
Inventors:
Ernst Billig, Anthony G. Abatjoglou, David R. Bryant
Abstract: This invention describes novel molded flexible polyurethane foam surfactants which can be used in foam having high concentrations of reinforcing graft copolymer solids. The invention also describes an improved process for making these foams using the novel surfactants.
Abstract: Catalytic cracking catalysts, the process of their preparation and the process of their use. Cracking catalysts are disclosed for improving the octane number of gasoline products. The catalysts comprise a zeolitic aluminosilicate having a mole ratio of oxides in the dehydrated state of(0.85-1.1) M.sub.2/n O:Al.sub.2 O.sub.3 :xSiO.sub.2wherein M is a cation having a valence of "n" and "x" has a value greater than 6.0 to about 11.0; has an x-ray powder diffraction pattern having at least the d-spacings of Table A; has extraneous silicon atoms in the crystal lattice in the form of framework SiO.sub.4 tetrahedra; has between greater than zero to less than 5.0 percent by weight, expressed as the oxide, of at least one rare earth cation selected from the group consisting of cerium, lanthanum, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium; and less than 1.2 weight percent Na.sub.
Abstract: Method for replacing a coolant containing PCB in electrical induction apparatus having a tank containing the PCB-containing coolant, an electrical winding and porous solid cellulosic electrical insulation immersed in, and impregnated with, the PCB-containing coolant with a substantially PCB-free permanent coolant to convert said electrical apparatus into one in which the rate of elution of PCB into the PCB-free coolant is below the maximum allowable rate of elution into the coolant of an electrical apparatus rated as non-PCB comprising steps of: (a) draining the PCB-containing coolant from said tank; (b) filling the tank with an interim dielectric cooling liquid; (c) electrically operating the apparatus; (d) thereafter draining the interim dielectric cooling liquid containing the eluted PCB from the tank; (e) repeating the cycle of steps (b), (c) and (d) a sufficient number of times until the PCB elution rate does not exceed the rate of 50 ppm PCB based on the weight of the permanent coolant after 90 days of
Abstract: Silicone fluids with the nominal structures RO--D.sub.x --R where x is an integer having a value of from about 4 to about 60 and R is a 2-methylcyclohexyl group have been synthesized and used as hydraulic fluids.These fluids exhibit superior viscosity, % rubber swell, % compressibility and air dissolubility characteristics in hydraulic systems.
Abstract: Novel class of crystalline microporous ferroaluminophosphate compositions containing as lattice constituents in addition to AlO.sub.2 and PO.sub.2 structural units, ferric and/or ferrous iron in tetrahedral coordination with oxygen atoms. These compositions are prepared hydrothermally using organic templating agents and are suitably employed as catalysts or adsorbents.
Type:
Grant
Filed:
August 19, 1985
Date of Patent:
May 17, 1988
Assignee:
Union Carbide Corporation
Inventors:
Celeste A. Messina, Brent M. Lok, Edith M. Flanigen
Abstract: Crystalline molecular sieves having three-dimensional microporous framework structures of CoO.sub.2, AlO.sub.2, SiO.sub.2, PO.sub.2 and tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Co.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Co.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of cobalt, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents catalysts, etc. is also disclosed.
Type:
Grant
Filed:
April 13, 1984
Date of Patent:
May 17, 1988
Assignee:
Union Carbide Corporation
Inventors:
Brent M. Lok, Bonita K. Marcus, Edith M. Flanigen
Abstract: Method for treating waste slurries containing solid impurities, e.g. in the form of metal chlorides, and silicon tetrachloride and trichlorosilane by evaporation and separation techniques to recover more of the silicon tetrachloride and trichlorosilane.
Type:
Grant
Filed:
March 26, 1986
Date of Patent:
May 10, 1988
Assignee:
Union Carbide Corporation
Inventors:
William C. Breneman, Chi-Cheng Yang, Gunnar Henningsen
Abstract: A process for the recovery of enzymes from an aqueous system having at least two aqueous phases wherein the partition coefficient with respect to an enzyme may be improved through the addition of organo-compatible, compounds having anionic functionality, such as polyacrylic acid, polyvinyl sulfonate and sodium dodecylsulfate.
Type:
Grant
Filed:
November 12, 1985
Date of Patent:
May 10, 1988
Assignee:
Union Carbide Corporation
Inventors:
Kavssery P. Ananthapadmanabhan, Errol D. Goddard
Abstract: A method for calcining carbonaceous materials in a rotary kiln is disclosed. An oxygen injection lance provides oxygen through the wall of a firing hood and into the carbonaceous bed, which is at an elevated temperature. The oxygen burns a portion of the carbonaceous material, providing the necessary heat for calcining the remainder of the carbonaceous materials in the kiln.
Type:
Grant
Filed:
March 29, 1985
Date of Patent:
May 3, 1988
Assignees:
Reynolds Metals Co., Union Carbide Corporation
Abstract: Crystalline molecular sieves having three-dimensional microporous framework structures of M'O.sub.2, M"O.sub.2, AlO.sub.2, PO.sub.2, and SiO.sub.2 tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(M'.sub.u M".sub.v Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (M'.sub.u M".sub.v Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; M' and M" represent two elements capable of forming framework tetrahedral units; and "u", "v", "x", "y" and "z" represent the mole fractions of M', M", aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is disclosed.
Type:
Grant
Filed:
April 13, 1984
Date of Patent:
May 3, 1988
Assignee:
Union Carbide Corporation
Inventors:
Brent M. T. Lok, Bonita K. Marcus, Edith M. Flanigen
Abstract: Reforming and dehydrocyclization catalysts and processes are disclosed wherein reforming catalysts comprise a Group VIII metal and at least one medium pore non-zeolitic molecular sieve characterized in the calcined form by an adsorption of isobutane of at least 2 percent by weight at a partial pressure of 500 torr and a termperature of 20.degree. C. and characterized by an adsorption of triethylamine less than about 5 percent by weight at a partial pressure of 2.6 torr and a temperature of 22.degree. C. In one embodiment the catalyst includes a Group VII metal on a halogenated carrier.
Abstract: Xylene isomerization is carried out using specific non-zeolitic molecular sieve catalyst, e.g., the silicoaluminophosphate molecular sieves of U.S. Pat. No. 4,440,871, to provide improved production of p-xylene from C.sub.8 aromatic compounds and the conversion of ethylbenzene to a xylene.
Type:
Grant
Filed:
June 16, 1986
Date of Patent:
April 26, 1988
Assignee:
Union Carbide Corporation
Inventors:
Regis J. Pellet, Gary N. Long, Jule A. Rabo, Peter K. Coughlin
Abstract: Pyrolysis tars are upgraded by hydrotreatment thereof in the presence of an acidic catalyst. The treated pyrolysis tars are used to produce premium cokes useful in the production of graphite electrodes.
Abstract: In the process for preparing methyl tert.-alkyl ether comprising the steps of (a) contacting and reacting in the liquid phase a reaction mixture formed by combining a stream consisting essentially of C.sub.4 -C.sub.5 hydrocarbons and containing at least some proportion of isoalkylene and a stoichiometric excess of methanol, with respect to the isoalkylene, to form a reaction product comprising methyl tert.-alkyl ether, unreacted methanol and unreacted C.sub.4 -C.sub.5 hydrocarbons; (b) isolating the methyl tert.-alkyl ether from the reaction product; and (c) recovering the unreacted methanol from the residual portion of the reaction product; the improvement which comprises selectively adsorbing the methanol constituent of said residual reaction product in a bed of crystalline molecular sieve adsorbent and recovering same by desorption using as a purge-desorption stream, the C.sub.4 -C.sub.5 hydrocarbon stream used to prepare the initial reaction mixture.
Type:
Grant
Filed:
December 7, 1984
Date of Patent:
April 26, 1988
Assignee:
Union Carbide Corporation
Inventors:
Moez M. Nagji, Desh R. Garg, William C. Miller
Abstract: Process for removing metal carbonyl contaminants from a gaseous stream which comprises contacting the gaseous stream with a zinc sulfide absorbent to thereby remove metal carbonyl contaminants from the gaseous stream, and separating the gaseous stream from the zinc sulfide absorbent.