Patents Assigned to Union Carbide Corporation
  • Patent number: 4751340
    Abstract: Alkylation of aromatics is effected by use of an alkylating agent, e.g., methanol, and novel alkylation catalysts containing non-zeolitic molecular sieves.
    Type: Grant
    Filed: June 16, 1986
    Date of Patent: June 14, 1988
    Assignee: Union Carbide Corporation
    Inventors: Regis J. Pellet, Gary N. Long, Jule A. Rabo
  • Patent number: 4751263
    Abstract: Described herein are curable molding compositions comprising a mixture of:(a) a poly(acrylate) characterized by the following empirical formula: ##STR1## wherein R is the hydroxy-free residue of an organic polyhydric alcohol which contained alcoholic hydroxyl groups bonded to different carbon atoms, R.sub.1 and R.sub.2 are independently hydrogen or methyl, and n is 1 to 3,(b) acrylic or methacrylic acid or a functionalized derivative thereof having a molecular weight of less than 300 which is different from (a), and(c) an ethylenically unsaturated monomer which is soluble in and copolymerizable with (a) and (b) and which is different from (a) and (b). The compositions can also contain one or more fibers with a melting point or a glass transition temperature above about 130.degree. C.
    Type: Grant
    Filed: March 25, 1987
    Date of Patent: June 14, 1988
    Assignee: Union Carbide Corporation
    Inventors: Linda A. Domeier, Michael J. Michno, Jr., Edward N. Peters
  • Patent number: 4749384
    Abstract: A method and apparatus for quick-filling a full charge of compressed natural gas into an adsorbent filled cylinder.
    Type: Grant
    Filed: April 24, 1987
    Date of Patent: June 7, 1988
    Assignee: Union Carbide Corporation
    Inventors: Jeffert J. Nowobilski, Frank Notaro, Arun Acharya
  • Patent number: 4749556
    Abstract: A process for producing boron nitride which comprises providing a nitrogen-containing nitride promoter, preferably melamine or dicyandiamide, in contact with an admixture of boron oxide and a sufficient amount of boric acid to enhance the formation of boron nitride under a non-oxidizing atmosphere, and maintaining same at sufficiently elevated temperature to form boron nitride.
    Type: Grant
    Filed: December 4, 1985
    Date of Patent: June 7, 1988
    Assignee: Union Carbide Corporation
    Inventors: Lien N. Parrish, Charles C. Chase
  • Patent number: 4748261
    Abstract: Transition metal-bis-phosphite catalyzed carbonylation processes, especially hydroformylation, as well as transition metal-bis-phosphite compositions, bis-phosphite ligands and transition metal-bis-phosphite catalysts.
    Type: Grant
    Filed: September 5, 1985
    Date of Patent: May 31, 1988
    Assignee: Union Carbide Corporation
    Inventors: Ernst Billig, Anthony G. Abatjoglou, David R. Bryant
  • Patent number: 4746683
    Abstract: This invention describes novel molded flexible polyurethane foam surfactants which can be used in foam having high concentrations of reinforcing graft copolymer solids. The invention also describes an improved process for making these foams using the novel surfactants.
    Type: Grant
    Filed: September 29, 1987
    Date of Patent: May 24, 1988
    Assignee: Union Carbide Corporation
    Inventor: John A. Kilgour
  • Patent number: 4744886
    Abstract: Catalytic cracking catalysts, the process of their preparation and the process of their use. Cracking catalysts are disclosed for improving the octane number of gasoline products. The catalysts comprise a zeolitic aluminosilicate having a mole ratio of oxides in the dehydrated state of(0.85-1.1) M.sub.2/n O:Al.sub.2 O.sub.3 :xSiO.sub.2wherein M is a cation having a valence of "n" and "x" has a value greater than 6.0 to about 11.0; has an x-ray powder diffraction pattern having at least the d-spacings of Table A; has extraneous silicon atoms in the crystal lattice in the form of framework SiO.sub.4 tetrahedra; has between greater than zero to less than 5.0 percent by weight, expressed as the oxide, of at least one rare earth cation selected from the group consisting of cerium, lanthanum, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium; and less than 1.2 weight percent Na.sub.
    Type: Grant
    Filed: February 5, 1986
    Date of Patent: May 17, 1988
    Assignee: Union Carbide Corporation
    Inventors: Robert L. Chiang, Mark T. Staniulis
  • Patent number: 4744905
    Abstract: Method for replacing a coolant containing PCB in electrical induction apparatus having a tank containing the PCB-containing coolant, an electrical winding and porous solid cellulosic electrical insulation immersed in, and impregnated with, the PCB-containing coolant with a substantially PCB-free permanent coolant to convert said electrical apparatus into one in which the rate of elution of PCB into the PCB-free coolant is below the maximum allowable rate of elution into the coolant of an electrical apparatus rated as non-PCB comprising steps of: (a) draining the PCB-containing coolant from said tank; (b) filling the tank with an interim dielectric cooling liquid; (c) electrically operating the apparatus; (d) thereafter draining the interim dielectric cooling liquid containing the eluted PCB from the tank; (e) repeating the cycle of steps (b), (c) and (d) a sufficient number of times until the PCB elution rate does not exceed the rate of 50 ppm PCB based on the weight of the permanent coolant after 90 days of
    Type: Grant
    Filed: June 3, 1985
    Date of Patent: May 17, 1988
    Assignee: Union Carbide Corporation
    Inventor: Gilbert Atwood
  • Patent number: 4744915
    Abstract: Silicone fluids with the nominal structures RO--D.sub.x --R where x is an integer having a value of from about 4 to about 60 and R is a 2-methylcyclohexyl group have been synthesized and used as hydraulic fluids.These fluids exhibit superior viscosity, % rubber swell, % compressibility and air dissolubility characteristics in hydraulic systems.
    Type: Grant
    Filed: August 24, 1987
    Date of Patent: May 17, 1988
    Assignee: Union Carbide Corporation
    Inventor: Richard A. Budnik
  • Patent number: 4744885
    Abstract: Novel class of crystalline microporous ferroaluminophosphate compositions containing as lattice constituents in addition to AlO.sub.2 and PO.sub.2 structural units, ferric and/or ferrous iron in tetrahedral coordination with oxygen atoms. These compositions are prepared hydrothermally using organic templating agents and are suitably employed as catalysts or adsorbents.
    Type: Grant
    Filed: August 19, 1985
    Date of Patent: May 17, 1988
    Assignee: Union Carbide Corporation
    Inventors: Celeste A. Messina, Brent M. Lok, Edith M. Flanigen
  • Patent number: 4744970
    Abstract: Crystalline molecular sieves having three-dimensional microporous framework structures of CoO.sub.2, AlO.sub.2, SiO.sub.2, PO.sub.2 and tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Co.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Co.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of cobalt, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents catalysts, etc. is also disclosed.
    Type: Grant
    Filed: April 13, 1984
    Date of Patent: May 17, 1988
    Assignee: Union Carbide Corporation
    Inventors: Brent M. Lok, Bonita K. Marcus, Edith M. Flanigen
  • Patent number: 4743344
    Abstract: Method for treating waste slurries containing solid impurities, e.g. in the form of metal chlorides, and silicon tetrachloride and trichlorosilane by evaporation and separation techniques to recover more of the silicon tetrachloride and trichlorosilane.
    Type: Grant
    Filed: March 26, 1986
    Date of Patent: May 10, 1988
    Assignee: Union Carbide Corporation
    Inventors: William C. Breneman, Chi-Cheng Yang, Gunnar Henningsen
  • Patent number: 4743550
    Abstract: A process for the recovery of enzymes from an aqueous system having at least two aqueous phases wherein the partition coefficient with respect to an enzyme may be improved through the addition of organo-compatible, compounds having anionic functionality, such as polyacrylic acid, polyvinyl sulfonate and sodium dodecylsulfate.
    Type: Grant
    Filed: November 12, 1985
    Date of Patent: May 10, 1988
    Assignee: Union Carbide Corporation
    Inventors: Kavssery P. Ananthapadmanabhan, Errol D. Goddard
  • Patent number: 4741694
    Abstract: A method for calcining carbonaceous materials in a rotary kiln is disclosed. An oxygen injection lance provides oxygen through the wall of a firing hood and into the carbonaceous bed, which is at an elevated temperature. The oxygen burns a portion of the carbonaceous material, providing the necessary heat for calcining the remainder of the carbonaceous materials in the kiln.
    Type: Grant
    Filed: March 29, 1985
    Date of Patent: May 3, 1988
    Assignees: Reynolds Metals Co., Union Carbide Corporation
    Inventors: Donald R. Mason, Robert L. Chambers
  • Patent number: 4741892
    Abstract: Crystalline molecular sieves having three-dimensional microporous framework structures of M'O.sub.2, M"O.sub.2, AlO.sub.2, PO.sub.2, and SiO.sub.2 tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(M'.sub.u M".sub.v Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (M'.sub.u M".sub.v Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; M' and M" represent two elements capable of forming framework tetrahedral units; and "u", "v", "x", "y" and "z" represent the mole fractions of M', M", aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is disclosed.
    Type: Grant
    Filed: April 13, 1984
    Date of Patent: May 3, 1988
    Assignee: Union Carbide Corporation
    Inventors: Brent M. T. Lok, Bonita K. Marcus, Edith M. Flanigen
  • Patent number: 4741820
    Abstract: Reforming and dehydrocyclization catalysts and processes are disclosed wherein reforming catalysts comprise a Group VIII metal and at least one medium pore non-zeolitic molecular sieve characterized in the calcined form by an adsorption of isobutane of at least 2 percent by weight at a partial pressure of 500 torr and a termperature of 20.degree. C. and characterized by an adsorption of triethylamine less than about 5 percent by weight at a partial pressure of 2.6 torr and a temperature of 22.degree. C. In one embodiment the catalyst includes a Group VII metal on a halogenated carrier.
    Type: Grant
    Filed: March 27, 1986
    Date of Patent: May 3, 1988
    Assignee: Union Carbide Corporation
    Inventors: Peter K. Coughlin, Regis J. Pellet
  • Patent number: 4740650
    Abstract: Xylene isomerization is carried out using specific non-zeolitic molecular sieve catalyst, e.g., the silicoaluminophosphate molecular sieves of U.S. Pat. No. 4,440,871, to provide improved production of p-xylene from C.sub.8 aromatic compounds and the conversion of ethylbenzene to a xylene.
    Type: Grant
    Filed: June 16, 1986
    Date of Patent: April 26, 1988
    Assignee: Union Carbide Corporation
    Inventors: Regis J. Pellet, Gary N. Long, Jule A. Rabo, Peter K. Coughlin
  • Patent number: 4740291
    Abstract: Pyrolysis tars are upgraded by hydrotreatment thereof in the presence of an acidic catalyst. The treated pyrolysis tars are used to produce premium cokes useful in the production of graphite electrodes.
    Type: Grant
    Filed: December 20, 1984
    Date of Patent: April 26, 1988
    Assignee: Union Carbide Corporation
    Inventors: Rostislav Didchenko, Eric M. Dickinson
  • Patent number: 4740631
    Abstract: In the process for preparing methyl tert.-alkyl ether comprising the steps of (a) contacting and reacting in the liquid phase a reaction mixture formed by combining a stream consisting essentially of C.sub.4 -C.sub.5 hydrocarbons and containing at least some proportion of isoalkylene and a stoichiometric excess of methanol, with respect to the isoalkylene, to form a reaction product comprising methyl tert.-alkyl ether, unreacted methanol and unreacted C.sub.4 -C.sub.5 hydrocarbons; (b) isolating the methyl tert.-alkyl ether from the reaction product; and (c) recovering the unreacted methanol from the residual portion of the reaction product; the improvement which comprises selectively adsorbing the methanol constituent of said residual reaction product in a bed of crystalline molecular sieve adsorbent and recovering same by desorption using as a purge-desorption stream, the C.sub.4 -C.sub.5 hydrocarbon stream used to prepare the initial reaction mixture.
    Type: Grant
    Filed: December 7, 1984
    Date of Patent: April 26, 1988
    Assignee: Union Carbide Corporation
    Inventors: Moez M. Nagji, Desh R. Garg, William C. Miller
  • Patent number: 4740361
    Abstract: Process for removing metal carbonyl contaminants from a gaseous stream which comprises contacting the gaseous stream with a zinc sulfide absorbent to thereby remove metal carbonyl contaminants from the gaseous stream, and separating the gaseous stream from the zinc sulfide absorbent.
    Type: Grant
    Filed: March 27, 1986
    Date of Patent: April 26, 1988
    Assignee: Union Carbide Corporation
    Inventors: Robert L. Heyd, Thomas P. Pignet