Abstract: A premium coke is made by the delayed coking of a blend of pyrolysis tar and hydrotreated decant oil.

Abstract: Linear and/or branched claim C.sub.2 to C.sub.12 olefins are converted to hydrocarbon mixtures suitable for use as liquid motor fuels by contact with a catalyst capable of ensuring the production of desirable products with only a relatively minor amount of heavy products boiling beyond the diesel oil range. The catalyst having desirable stability during continuous production operations, comprises a steam stabilized zeolite Y catalyst of hydrophobic character, desirably in aluminum-extracted form. The olefins such as propylene, may be diluted with inerts, such as paraffins or with water, the latter serving to moderate the acidity of the catalyst, or to further moderate the activity of the aluminum-extracted catalyst, so as to increase the effective life of the catalyst.

Abstract: A process to produce Methyl Amyl Ketone heterogeneously via the cross-aldol condensation reaction between a C.sub.3 (isopropanol or acetone feed) and a C.sub.4 (butanol or butyraldehyde feed). The catalyst, hydrogen reduced copper oxide on gamma alumina, produces both high reactivity and long catalyst lifetimes. The catalyst is successfully regenerated. Efficiencies to MAK range from 50 to 80 wt. % and efficiencies to useful products range from 75 to 95 wt. % depending on the composition of the feed and temperature. Temperatures range from 200.degree. to 262.degree. C.In general, this catalyst readily catalyzes the cross-aldol condensation reaction between aldehydes (or primary alcohols) and ketones (or secondary alcohols) to produce higher molecular weight ketones; likewise, this catalyst catalyzes the aldol condensation reaction between the same or different ketones to again produce higher molecular weight ketones.

Abstract: Molecular sieve compositions having three-dimensional microporous framework structures of CrO.sub.2, AlO.sub.2, PO.sub.2 and SiO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(Cr.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Cr.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of chromium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.

Abstract: Method of replacing a PCB-containing coolant in electrical induction apparatus having a vessel containing said PCB-containing coolant, an electrical winding and porous solid cellulosic electrical insulation immersed in, and impregnated with, said PCB-containing coolant with a substantially PCB-free high boiling dielectric permanent coolant into which any residual PCBs elute at no greater than a selected target rate comprising steps of (a) draining the PCB-containing coolant from the vessel, (b) filling the vessel with an interim dielectric coolant, (c) electrically operating the apparatus, (d) removing interim coolant containing eluted PCB, (e) repeating steps (b), (c) and (d) a sufficient number of times until the PCB elution rate does not exceed 5 times a selected target rate, (f) filling the vessel with PCB-free high boiling dielectric silicone oil as coolant, (g) electrically operating the apparatus, (h) thereafter removing the silicone oil coolant containing eluted PCB, (i) repeating steps (f), (g) and (

Abstract: An atomizer and atomizing process of a post-mixed liquid fuel fired burner comprising angular direction of atomizing fluid into liquid fuel as it passes along a fuel passage length of increasing surface area causing the formation of a fuel film on the fuel passage surface area with the increasing thinning of the fuel film as it passes across the increasing surface area, resulting in a shearing action at the fuel passage end and the formation of an atomized spray.

Abstract: A method is provided for increasing the solubility of an enzyme in an aqueous solution comprising providing a water-soluble anionic surfactant to the solution and further providing the solution with a pH above that which result in the formation of an enzyme/surfactant precipitate. The application is further directed to an aqueous solution containing an anionic surfactant and having an enzyme concentration contained therein which is higher than that possible in the absence of the surfactant.

Abstract: An aluminum melt is processed by the injection of a sparging gas through a spinning nozzle into the melt in a preheat, conditioning and processing step sequence, with a predetermined proportion of hydrogen being employed with the sparging gas during the processing step to assure that the hydrogen content of the melt is such that the density of the solidified product is within a desired range on a repeatable basis. The conditioning step is employed to facilitate the attaining of the desired result on such repeatable basis in an advantageous manner such as to minimize the processing time and the amount of the hydrogen/sparging gas mixture necessary for the desired density control.

Abstract: Molecular sieve compositions having three-dimensional microporous framework structures of BeO.sub.2, AlO.sub.2, PO.sub.2 and SiO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Be.sub.w Al.sub.x P.sub.Y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Be.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of beryllium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.

Abstract: Transition metal-diorganophosphite complex catalyzed carbonylation processes, especially hydroformylation, as well as transition metal-diorganophosphite ligand complex compositions, diorganophosphite ligands and transition metal-diorganophosphite catalysts.

Abstract: Process for hydrocracking a crude oil feed, hydrocracking catalyst employed therein and the process for its preparation. The instant invention employs new aluminosilicate zeolite catalysts derived from a new zeolites denominated "LZ-210" which provide hydrocracking catalysts which demonstrate improved activity in first and/or second stage operation.

Abstract: A castable mix formulation for casting ceramic articles which comprises ceramic particles and an organic resin binder composed of furfuryl alcohol and a catalyst consisting essentially of zinc chloride and para toluene sulfonic acid.

Abstract: Molecular sieve compositions having three-dimensional microporous framework structures of GaO.sub.2, AlO.sub.2, PO.sub.2 and SiO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Ga.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Ga.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of gallium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.

Abstract: Aldehydes can be converted to dienes by contacting the aldehydes with a non-zeolitic molecular sieve. Preferably the non-zeolitic molecular sieve has, in its calcined form, an adsorption of isobutane of at least about 2 percent by weight of the non-zeolitic molecular sieve at a partial pressure of 500 torr and a temperature of 20.degree. C. The non-zeolitic molecular sieves can achieve good conversion rates and selectivities for the reaction. The reaction is especially useful for the conversion of 2-methylbutyraldehyde to isoprene.

Abstract: A foamable composition comprising a polymer selected from the group consisting of a hydrolyzable ethylene/silane copolymer and a hydrolyzable ethylene/ethyl acrylate/silane terpolymer and the following components in about the following amounts per 100 parts by weight of polymer:______________________________________ Component Parts by Weight ______________________________________ azodicarbonamide 1 to 25 p,p'oxybis-benzene 0.5 to 3.5 sulfonyl hydrazide silanol condensation catalyst 0.02 to 0.

Abstract: Cracking catalysts and their use in cracking processes are disclosed. The cracking catalyst are prepared using mixtures of catalytic cracking catalysts containing zeolitic aluminosilicates effective in catalytic cracking and selected silicoaluminophosphate molecular sieves of U.S. Pat. No. 4,440,871.

Abstract: An improved liquid phase adsorption process is provided using a fixed bed system wherein the conventional post-regeneration bed-filling step and the post-adsorption bed-draining step are replaced by a displacement step. The bed volume of regeneration medium in a first bed of the system undergoing the final stage of regeneration cool-down is passed directly into a second bed of the system in the final stage of the adsorption step whereby the bed volume of void-space feedstock in said second bed is removed therefrom by displacement, thus effectively accomplishing in a single operation the filling step in the first bed and the draining step in the second bed.

Abstract: A method for the rapid acoustic emission testing of pressure vessels wherein the flow rate of the pressurizing fluid is increased while maintaining the velocity of the pressurizing fluid, as it enters the pressure vessel, below the velocity which would cause the generation of flow noise.

Abstract: The deactivation of Ziegler-Natta catalyst and organometallic cocatalyst residues present in the olefin polymer resins produced by the fluidized bed polymerization process is accomplished in a purge vessel by contacting the olefin polymer resin with an inert purge gas containing water the latter being present in said inert purge gas in an amount to establish and maintain a moisture front region in the resin bed of said purge vessel as to create a region above said moisture front substantially free of water and wherein deactivation of said catalyst and cocatalyst are effected in said moisture front region.

Abstract: A nonaqueous hydroformylation process for producing aldehydes using low volatile, organic solubilized monosulfonated tertiary phosphine metal salt ligands.