Patents Assigned to Union Carbide Corporation
  • Patent number: 4761165
    Abstract: The present invention provides a method and apparatus for automatically controlling product repressurization in a pressure swing adsorption (PSA) process. According to the invention the same valve employed for withdrawing product from a bed during adsorption is employed to feed product gas to that bed during product repressurization. This enables the elimination of several valves, including a system-dependent valve, thereby improving system reliability. The same controllable valve may also be used to control the pressure in the PSA system.
    Type: Grant
    Filed: September 1, 1987
    Date of Patent: August 2, 1988
    Assignee: Union Carbide Corporation
    Inventors: Jorg Stocker, Michael Whysall
  • Patent number: 4759919
    Abstract: Molecular sieve compositions having three-dimensional microporous framework structures of CrO.sub.2, AlO.sub.2 and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(Cr.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Cr.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represent the mole fractions of chromium, aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.
    Type: Grant
    Filed: February 19, 1986
    Date of Patent: July 26, 1988
    Assignee: Union Carbide Corporation
    Inventors: Edith M. Flanigen, Brent M. T. Lok, Robert L. Patton, Stephen T. Wilson
  • Patent number: 4760200
    Abstract: The process for the liquid-phase hydration of a vicinal alkylene oxide(s) to the corresponding alkylene glycol(s) comprising carrying out such hydration in an aqueous medium containing a water miscible alkylene glycol ether co-solvent.
    Type: Grant
    Filed: December 31, 1985
    Date of Patent: July 26, 1988
    Assignee: Union Carbide Corporation
    Inventors: Brian T. Keen, John H. Robson, George E. Keller, II
  • Patent number: 4758419
    Abstract: Crystalline molecular sieves having a three-dimensional microporous framework structures of MgO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(Mg.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Mg.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of magnesium, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is disclosed.
    Type: Grant
    Filed: April 13, 1984
    Date of Patent: July 19, 1988
    Assignee: Union Carbide Corporation
    Inventors: Brent M. Lok, Lawrence D. Vail, Edith M. Flanigen
  • Patent number: 4758637
    Abstract: Polyester resin is modified with siloxane block polymers in such a manner so as to form silicone-modified polyester copolymer domains of controlled size and distribution dispersed in the polyester matrix. These domains undergo microphase segregation and migration during the melt spinning and cold-drawing to the surface of the polyester fiber being formed so as to provide a silicone-sheathed polyester fiber.
    Type: Grant
    Filed: November 21, 1986
    Date of Patent: July 19, 1988
    Assignee: Union Carbide Corporation
    Inventors: James H. Merrifield, George H. Greene
  • Patent number: 4758418
    Abstract: An improved process for converting hydrocarbons using a catalyst which is periodically regenerated to remove carbonaceous deposits, the catalyst being comprised of a mixture containing, as a major component, solid particles capable of promoting hydrocarbon conversion at hydrocarbon conversion conditions, and, as a minor component, discrete entities comprising at least one spinel, preferably alkaline earth metal-containing spinel; thereby reducing the amount of sulfur oxides exiting the catalyst regeneration zone.Improved hydrocarbon conversion catalysts are also disclosed.
    Type: Grant
    Filed: December 11, 1986
    Date of Patent: July 19, 1988
    Assignee: Union Carbide Corporation
    Inventors: Jin S. Yoo, John A. Jaecker
  • Patent number: 4758521
    Abstract: A method of assaying ketones in ambient air comprising contacting the air with beaded activated carbon followed by desorption with a solvent and analysis of the solvent solution for ketone content has been developed which provided superior results over prior art adsorbents, particularly when the sampling operation is conducted in the presence of humid air.
    Type: Grant
    Filed: February 15, 1985
    Date of Patent: July 19, 1988
    Assignee: Union Carbide Corporation
    Inventors: Robley E. Lushbaugh, Richard A. Conway, Joe E. Neff
  • Patent number: 4758367
    Abstract: Single-phase, thermally-stable, corrosion-inhibiting heat transfer fluids comprising triethylene glycol, a corrosion-inhibiting amount of a mixture of a soluble borate compound and a soluble Group VIa metal oxygenate compound selected from the group consisting of chromate, molybdate and tungstate compounds, and, optionally, water, a copper corrosion inhibitor and sodium nitrate.
    Type: Grant
    Filed: May 22, 1986
    Date of Patent: July 19, 1988
    Assignee: Union Carbide Corporation
    Inventor: Kathleen F. George
  • Patent number: 4758654
    Abstract: A method for removing unpolymerized gaseous monomers from a solid olefin polymer in a single purge vessel while deactivating Ziegler-Natta catalysts and organometallic catalyst residues present in said solid olefin polymer by utilizing a two diameter purge vessel wherein hydrolysis of the catalysts are effected in the portion of the reactor having the smaller diameter with the gaseous monomers being removed in the larger diameter portion.
    Type: Grant
    Filed: April 28, 1987
    Date of Patent: July 19, 1988
    Assignee: Union Carbide Corporation
    Inventors: William B. Brod, Billy J. Garner
  • Patent number: 4755495
    Abstract: A process for activating a titanium or vanadium compound and producing polyethylene comprising (i) dissolving a divalent magnesium halide and a Lewis acid having the formula R.sub.m A1X.sub.n or R.sub.m BX.sub.
    Type: Grant
    Filed: December 15, 1986
    Date of Patent: July 5, 1988
    Assignee: Union Carbide Corporation
    Inventors: Kevin J. Cann, David L. Miles, Frederick J. Karol
  • Patent number: 4755361
    Abstract: An apparatus for the production of ammonia synthesis gas comprises a hydrocarbon convertor for converting a hydrocarbon feed to an effluent containing hydrogen and carbon monoxide by reaction with air which hydrocarbon convertor includes means to provide air in excess of the stoichiometric amount of nitrogen required for ammonia synthesis. The effluent from the hydrocarbon convertor is in communication with a water gas shift convertor for converting the carbon monoxide in the effluent to carbon dioxide. The water gas shift convertor is in communication with a pressure-swing adsorption system capable of selectively adsorbing carbon dioxide, carbon monoxide, methane and other impurities from hydrogen and a portion of the nitrogen fed in the gas mixture to the pressure swing adsorption system. The pressure swing adsorption system is provided with a conduit for discharging a partially purified ammonia synthesis gas mixture of hydrogen and nitrogen and a conduit for discharging purge gas.
    Type: Grant
    Filed: January 14, 1986
    Date of Patent: July 5, 1988
    Assignee: Union Carbide Corporation
    Inventor: Andrija Fuderer
  • Patent number: 4754951
    Abstract: A tuyere assembly and positioning method comprising mechanically separate or separable inner and outer tubes, the inner tube(s) being removeable and replaceable and the outer tube being extendable into a vessel and held in place by a flared end abutting the wall of a cavity through the vessel wall.
    Type: Grant
    Filed: August 14, 1987
    Date of Patent: July 5, 1988
    Assignee: Union Carbide Corporation
    Inventors: Ian F. Masterson, Roger Bridgeman, Steven Bailey
  • Patent number: 4755557
    Abstract: A molding composition is provided which, through the use of a lactone monomer, improves the surface characteristics of the molded composite. In particular, the use of .epsilon.-caprolactone (oxepane-2-one) provides a smoother surface and enhanced dimensional stability.
    Type: Grant
    Filed: June 19, 1986
    Date of Patent: July 5, 1988
    Assignee: Union Carbide Corporation
    Inventors: Kenneth E. Atkins, Raymond C. Gandy
  • Patent number: 4755202
    Abstract: A process and apparatus to produce ultra high purity oxygen comprising serially oriented absorbing and stripping columns having defined flow stream relationships.
    Type: Grant
    Filed: July 28, 1987
    Date of Patent: July 5, 1988
    Assignee: Union Carbide Corporation
    Inventor: Harry Cheung
  • Patent number: 4755575
    Abstract: Described herein is an improved process for rapidly fabricating fiber reinforced thermoset resin articles comprising: (a) providing in a heatable matched metal die mold a bonded web of one or more fibers with a melting point or a glass transition temperature above about 130.degree. C., (b) providing in an accumulator zone a liquid body of a thermosettable organic material having a viscosity determined at 120.degree. C.
    Type: Grant
    Filed: July 25, 1986
    Date of Patent: July 5, 1988
    Assignee: Union Carbide Corporation
    Inventors: Linda A. Domeier, Richard G. Angell, Jr.
  • Patent number: 4755276
    Abstract: A nitro-substituted pitch demonstrates softening point temperatures in the range of 75.degree.-250.degree. C. and a coking value of at least about 40%. Such pitch is produced by reacting a tar with a nitrating agent at a temperature below 150.degree. C. and above about 0.degree. C.
    Type: Grant
    Filed: November 17, 1986
    Date of Patent: July 5, 1988
    Assignee: Union Carbide Corporation
    Inventor: Irwin C. Lewis
  • Patent number: 4754075
    Abstract: Narrow, balanced alkoxylation product mixture distributions having at least one alkoxylation product constituting more than 20 weight percent of the mixture can be provided by modified, calcium-containing catalysts. Catalysts for alkoxylation processes can be produced from lime and can, with modification, be used to make the narrow, balanced alkoxylation product mixture distribution.
    Type: Grant
    Filed: October 6, 1986
    Date of Patent: June 28, 1988
    Assignee: Union Carbide Corporation
    Inventors: Robert J. Knopf, Louis F. Theiling, Jr.
  • Patent number: 4753993
    Abstract: Water-curable compositions, based on thermoplastic polymers having pendant thereto hydrolyzable silane moieties and metal carboxylate silanol condensation catalysts, which can be cured in a relatively short period of time to crosslinked products characterized by an excellent balance of commercially acceptable properties. The compositions of this invention are particularly useful as extrudates about wires and cables.
    Type: Grant
    Filed: August 14, 1986
    Date of Patent: June 28, 1988
    Assignee: Union Carbide Corporation
    Inventor: Michael J. Keogh
  • Patent number: 4752651
    Abstract: The process for the production of light olefins from a feedstock comprising at least an aliphatic hetero compound comprising contacting said feedstock in the presence of an aromatic diluent with a non-zeolitic molecular sieve at effective process conditions to produce light olefins.
    Type: Grant
    Filed: June 16, 1986
    Date of Patent: June 21, 1988
    Assignee: Union Carbide Corporation
    Inventor: Steven W. Kaiser
  • Patent number: 4751112
    Abstract: This invention is directed to high solids coating compositions comprising a hydroxyl functional acrylic polymer, an alkylolated melamine and, as a reactive diluent, a polycaprolactone polyol, wherein the ratio of the equivalent weight of the alkylolated melamine to the total hydroxyl equivalent weight of the hydroxyl functional acrylic polymer and the polycaprolactone polyol is from about 0.8 to about 2.5. The high solids coating compositions have utility as automotive finishes, appliance finishes, general metal finishing and the like.
    Type: Grant
    Filed: September 23, 1987
    Date of Patent: June 14, 1988
    Assignee: Union Carbide Corporation
    Inventors: Donald F. Smith, Jr., Glenn S. Peacock, Omayra M. Salgado