Patents Examined by Allan M. Lieberman
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Patent number: 4892903Abstract: An elastic fiber or film prepared from a composition comprising at least one block copolymer containing at least two polymeric blocks containing predominantly monoalkenyl aromatic hydrocarbon monomer units having a weight-average molecular weight within the range from about 4,000 to about 50,000 and at least one polymeric block containing predominantly hydrogenated conjugated diolefin monomer units having a weight-average molecular weight within the range from about 10,000 to about 200,000, a relatively low molecular weight polymer selected from the Group consisting of anionic styrene homopolymers, .alpha.-methylstyrene homopolymers, hydrogenated styrene, copolymers of .alpha.-methylstyrene and styrene and mixtures thereof and may contain a wax. In particularly preferred embodiments, the elastic fiber or film will contain at least one A-B-A triblock copolymer and an A-B' diblock copolymer.Type: GrantFiled: August 20, 1987Date of Patent: January 9, 1990Assignee: Shell Oil CompanyInventor: Glenn R. Himes
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Patent number: 4891395Abstract: Very low viscosity polymer polyols having high styrene/acrylonitrile ratios and good stability may be achieved by the use of epoxy resin-modified polyols as dispersants. The epoxy resin-modified polyols useful as dispersants may be made by reacting a polyol initiator having an active hydrogen functionality of 3 to 8 and one or more alkylene oxides with an epoxy resin. It is preferred that all of the epoxy resin-modified base polyol dispersant be initially charged to the reactor, along with part of the base polyol. In this invention, the base polyol is a conventional polyol unmodified with epoxy resin. The use of epoxy resin-modified polyols as dispersants results in polymer polyols having higher styrene contents, and improved stability and viscosity properties.Type: GrantFiled: May 24, 1988Date of Patent: January 2, 1990Assignee: ARCO Chemical Technology, Inc.Inventors: Robert G. Gastinger, John E. Hayes
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Patent number: 4889880Abstract: Modified asphalt compositions are described which comprise(A) asphalt, and(B) a minor amount, sufficient to reduce or retard degradation of the asphalt in service, of at least one polymer derived from a butene having a weight average molecular weight (Mw) of about 5,000 to about 1,000,000. Generally, the modified asphalt composition will contain from about 0.01 to about 10% by weight, based on the weight of the asphalt, of the polymer as defined. The modified asphalt compositions of the present invention are useful in roofing applications and in preparing aggregate-containing asphalt concretes which can be employed as paving compositions.Type: GrantFiled: March 14, 1988Date of Patent: December 26, 1989Assignee: The Lubrizol CorporationInventor: H. Richard Miller
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Patent number: 4889890Abstract: The thermosetting powder coating composition which has good stability and good physical properties, such as appearance, flexibility, hardness, solvent resistance and corrosion resistance, is disclosed. The composition comprises a co-reactable particulate mixture of a carboxylic acid group-containing polymer, a polyepoxide, and a beta-hydroxylalkylamide.Type: GrantFiled: December 30, 1987Date of Patent: December 26, 1989Assignee: PPG Industries, Inc.Inventors: Paul R. Kerr, Paul H. Pettit, Jr., William S. Ewing
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Patent number: 4888395Abstract: Core/shell polymers containing a rubber-core and a thermoplastic shell acrylate-vinylacetate-acrylic terpolymer having excellent cold seal strength properties.Type: GrantFiled: July 2, 1987Date of Patent: December 19, 1989Assignee: Mobil Oil CorporationInventor: Taeik Min
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Patent number: 4886857Abstract: Styrene based resin compositions comprise a styrene resin and a graft copolymer obtained by graft-polymerizing, in the presence of a butadiene based rubbery polymer, a monomer mixture composed of a monomer containing 1-50 ethylene oxide groups and one ethylenically-unsaturated bond and styrene or a monomer mixture compound of styrene as a principal component and at least one monomer copolymerizable with styrene. The a styrene based resin compositions are obtained by blending the graft copolymer with a styrene resin and having excellent impact strength and visual properties.Type: GrantFiled: March 21, 1988Date of Patent: December 12, 1989Assignee: Kureha Kagaku Kogyo K. K.Inventors: Masanori Ota, Fumio Akutsu, Kazuo Takahashi
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Patent number: 4886850Abstract: A rubber composition having improved weather resistance, thermal resistance, resistance to crack growth and wear resistance comprises not less than 20 parts by weight of a rubber compound mainly of ethylene, propylene and diene and satisfying all of particular requirements. Further, the rubber composition is applied to a tread and/or a sidewall of a pneumatic tire for improving a tire appearance.Type: GrantFiled: August 31, 1988Date of Patent: December 12, 1989Assignee: Bridgestone CorporationInventors: Masaki Ogawa, Yasuro Shiomura, Toshiki Takizawa
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Patent number: 4884814Abstract: The subject invention relates to golf ball technology, and more particularly, golf ball cover technology. The invention is concerned with a particular mixture of ionic resins as a golf ball cover composition.Ionomers have been widely used as golf ball cover materials for the past 15 years. While these ionomers are very durable, they have a deficiency as a golf ball cover material in that they tend to be hard. This invention is concerned with a mixture of a hard ionomer with a soft ionomer in order to produce a golf ball cover composition wherein the cover is softer than the prior art ionomer covers.A golf ball covered in accordance with this invention is durable and a skilled golfer can impart back spin to the ball in play.Type: GrantFiled: January 15, 1988Date of Patent: December 5, 1989Assignee: Spalding & Evenflo Companies, Inc.Inventor: Michael J. Sullivan
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Patent number: 4883834Abstract: A primer composition usable for steel sheet and plastic sheet in vehicle bodies consists essentially of a component A composed of a resin obtained by graft-polymerizing a styrene-butadiene-styrene block copolymer or its hydrogenated polymer with .alpha.,.beta.-unsaturated carboxylic acid or its anhydride, a component B of a crosslinking agent and a component C of an epoxy compound, and has particular weight ratios as solid content of component A to component B and components A+B to component C.Type: GrantFiled: July 13, 1987Date of Patent: November 28, 1989Assignee: Nippon Oil and Fats Company, LimitedInventors: Shosaku Yamamoto, Kazuo Kakinuma, Fumio Sodeyama, Junji Mayumi, Riichiro Maruta
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Patent number: 4882383Abstract: Thermoplastic compositions comprising rubber modified polyalkenyl aromatic resin and a modifying agent having a core-shell structure comprised of an interpenetrating, cross-linked (meth)acrylate core and a cross-linked styrenic resin shell have significantly improved impact strength, thermal resistance and surface appearance following molding into shaped articles.Type: GrantFiled: July 21, 1987Date of Patent: November 21, 1989Assignee: General Electric Co.Inventor: Sai-Pei Ting
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Patent number: 4882373Abstract: An asphaltic composition having improved tensile properties is disclosed. Also disclosed is a method for producing said composition which comprises:A. contacting an asphalt with a mineral acid;B. contacting the acid modified asphalt thus formed with an oxygen-containing gas;C. adding a thermoplastic elastomer to the acid/oxygen modified asphalt thus formed; andD. adding an unsaturated functional monomer to the polymer modified asphalt.In a preferred embodiment, the asphalt is contacted with an oxygen-containing gas prior to and during contact with the mineral acid.Type: GrantFiled: August 15, 1988Date of Patent: November 21, 1989Assignee: Exxon Research and Engineering CompanyInventor: Lyle E. Moran
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Patent number: 4882225Abstract: A modified powder or particulate material having a silicone polymer film coated on substantially the entire surface thereof, this powder or particulate material being produced by bringing at least one silicone compound, in the form of a vapor, having the general formula (I):(R.sup.1 HSiO).sub.a (R.sup.2 R.sup.3 SiO).sub.b (R.sup.4 R.sup.5 R.sup.6 SiO.sub.1/2).sub.c (I)Wherein R.sup.1, R.sup.2, and R.sup.3 represent, independently, hydrogen or a hydrocarbon residue having 1 to 10 carbon atoms, which may be substituted with at least one halogen atom, provided that R.sup.1, R.sup.2, and R.sup.3 are not hydrogen at the same time, R.sup.4, R.sup.5, and R.sup.Type: GrantFiled: April 26, 1988Date of Patent: November 21, 1989Assignee: Shiseido Company Ltd.Inventors: Hiroshi Fukui, Ryujiro Namba, Tsutomu Saito, Yutaka Ohtsu, Asa Kimura, Motokiyo Nakano, Okitsugu Nakata, Kenichi Tommita, Kazuo Tokubo, Kazuhisa Ohno, Toshio Yoneyama, Takashi Ogawa, Hideo Morohoshi, Junichi Koyama, Taketoshi Kanda, Kunihiro Kawaguchi, Yuzo Shimizu
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Patent number: 4880850Abstract: Compounds having defined functional groups are described which color stabilize aromatic carbonate polymers or blends therewith upon exposure to sterilizing radiation.Type: GrantFiled: February 7, 1989Date of Patent: November 14, 1989Assignee: General Electric CompanyInventors: Linda H. Nelson, Roger W. Avakian, Arnold Factor
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Patent number: 4880870Abstract: A polymer granulate whose particles consist of a core component and a coating component can be prepared by mixing a granular polymer with a pulverulent coating agent. The core component is made of a water-soluble polymer, in particular a polyvinyl alcohol. The coating component is a water-soluble or water-insoluble substance which is applied to the water-moistened particles of the core component. The particles of the polymer granulate have diameters within the range from 0.6 to 6 mm. The granulate has particularly good freeflowing properties; it is especially suitable for preparing adhesives.Type: GrantFiled: July 30, 1985Date of Patent: November 14, 1989Assignee: Hoechst AktiengesellschaftInventors: Wolfgang Zimmermann, Albrecht Harreus
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Patent number: 4880887Abstract: In curing dental resins, polymerizable compounds having at least one ethylenically unsaturated double bond, such as mono- or poly-functional acrylates or methacrylates are polymerized in the presence of N-cyclohexy-5-ethylpyrimidinetrione, a specific organometallic compound typically including acetylacetone copper or lithium acetate, and an organohalogen compound. The amounts of the ethylpyrimidinetrione, organometallic and organohalogen compounds used are respectively 0.1 to 10 parts by weight, 0.001 to 0.2 parts by weight and 0.1 to 5 parts by weight with respect to the polymerization compounds.Type: GrantFiled: March 3, 1988Date of Patent: November 14, 1989Assignee: G-C Toshi Kogyo CorporationInventor: Akira Hasegawa
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Patent number: 4879326Abstract: This invention provides cationic emulsions of bituminous binders of the bitumen/polymer type, formed by a dispersion of an organic phase of the binder in an aqueous phase containing a cationic nitrogenous emulsifier and a mineral or organic acid, the acid being in appropriate quantity so that the pH of the aqueous phase is comprised between 3 and 9. The aqueous phase also contains an agent consisting of at least one water-soluble sequestering salt of phosphonic acid, particularly a salt of alkaline metal or of amine of hydroxyalkyl-1,1-diphosphonic acid, and optionally a water-soluble thickening agent. To obtain the emulsions, which are usable for road applications, the emulsifying agent, the sequestering agent and optionally the thickening agent may be used in the form of a premixture containing the agents and called cationic emulsifying system.Type: GrantFiled: July 8, 1988Date of Patent: November 7, 1989Assignee: ELF FranceInventors: Francis Demangeon, Emile Lopez
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Patent number: 4879343Abstract: A heat and impact resistant composition comprising:(A) 5-89 parts by weight of a graft polymer prepared by graft polymerizing 30-75 parts by weight of a mixture of 30-80% of an aromatic vinyl monomer, 10-50% of an N-substituted maleimide monomer, 10-45% of a vinyl cyanide monomer and 0-30% of another copolymerizable vinyl monomer onto 25-70 parts by weight of a diene rubber (a);(B) 10-90 parts by weight of a copolymer obtained by polymerizing a mixture of 30-80% of an aromatic vinyl monomer, 10-50% of an N-substituted maleimide monomer, 10-40% of a vinyl cyanide monomer and 0-30% of another copolymerizable vinyl monomer, or (B') an imido group--containing adduct of a copolymer obtained by reacting a primary amine and/or ammonia with a copolymer obtained by polymerizing a mixture of 30-80% of an aromatic vinyl monomer, 5-50% of an alpha, beta-unsaturated dicarboxylic acid anhydride monomer and 0-40% of another copolymerizable vinyl monomer;(C) 1-45 parts be weight of a graft polymer made by graft polymerizingType: GrantFiled: August 5, 1988Date of Patent: November 7, 1989Assignee: Mitsubishi Monsanto Chemical CompanyInventors: Yuji Aoki, Hiroaki Miyazaki
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Patent number: 4877833Abstract: A heat resistant copolymer composition is provided by blending two kinds of copolymers one of which is obtainable by polymerizing a maleimide monomer (A), an aromatic vinyl monomer (B), an unsaturated nitrile monomer (C) and optionally at least one other comonomer copolymerizable therewith (D) in a specific monomer ratio in the presence or absence of an elastomeric polymer and which has an intrinsic viscosity of 0.3 to 1.2 dl/g, and another of which is obtainable by copolymerizing the aromatic vinyl monomer (B), the unsaturated nitrile (C) and optionally at least one other comonomer copolymerizable therewith (D) in a specific monomer ratio in the presence or absence of the elastomeric polymer and which has an intrinsic viscosity of 0.3 to 1.5 dl/g.Type: GrantFiled: November 6, 1987Date of Patent: October 31, 1989Assignee: Sumitomo Naugatuck Co., Ltd.Inventors: Masatsune Kondo, Kiyoshi Ogura, Koiti Kuramoto
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Patent number: 4877606Abstract: A pharmaceutically or veterinarily acceptable amphipathic, non-cross linked linear, branched or graft block copolymer, which has a minimum weight average molecular-weight of 1000, in which the hydrophobic component is biodegradable or hydrolytically unstable under normal physiological conditions, and the hydrophilic component may or may not be biodegradable or hydrolytically unstable under such conditions, and which copolymer is self-dispersible in water; together with mixtures of such a copolymer and a drug, which may be water-soluble or water-insoluble, which mixtures are self-dispersible in waterf; and processes for the manufacture of such copolymers and such mixtures.Type: GrantFiled: January 19, 1988Date of Patent: October 31, 1989Assignee: Imperial Chemical Industries PLCInventors: Jeffrey R. Churchill, Francis G. Hutchinson
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Patent number: 4874675Abstract: Composition for preparing a polymer concrete, a method of protecting or reconditioning surfaces by treatment with the composition, the protected or reconditioned surfaces thus-treated, and multi-package systems for bringing the components of the composition to an application site, wherein the composition comprises a substantially non-aqueous slurry of (1) an aggregate material and (2) a monomer binder system effective to bind the aggregate, upon curing, into a polymer concrete, the binder system comprising (a) a liquid comonomer component, (b) a solid, thermoplastic macromonomer component dissolved in the comonomer and comprising a linear polymer terminated at one or both ends with a polymerizable end group, and (c) a polymerization catalyst.Type: GrantFiled: September 25, 1987Date of Patent: October 17, 1989Assignee: Sartomer Company, Inc.Inventor: Gary W Ceska