Abstract: Nylon compositions useful for molding and film applications with film properties and impact strength are made of a polyamide resin and a block copolymer of poly(amide-ether) of the formula ##STR1## where R is an alkyl or substituted alkyl group with from one to 12 carbons, n is an integer from 2 to 20, m is an integer from 2 to 6, and x and y are numbers from about 50 to about 30,000. In one embodiment, a nonpolymeric amide is added to the composition. Articles made from the claimed compositions have improved impact strength; films made from the compositions have improved drapeability over the unmodified resin, both at room temperature and after heat-aging. Reinforced compositions are obtained by including mineral and other reinforcing fillers, including glass fibers, in the extrusion process. The reinforced compositions exhibit improved impact characteristics.
Type:
Grant
Filed:
August 27, 1990
Date of Patent:
December 1, 1992
Assignee:
Allied Signal Inc.
Inventors:
Varkki P. Chacko, George M. Johns, Mocherla K. Rao, Michael F. Tubridy, Donald F. Stewart
Abstract: A process for modifying the dyeability of polyamide polymers is disclosed, the process involving the addition of co-fed polyamide flake of the same type of polyamide as the base polyamide with the co-fed flake having a significant effect on the final dyeability. The additive flake comprises high- or low-amine-end polyamide flake which is mixed and melted with the base polyamide to adjust the total number of amine ends in the polymer, thereby controlling the polymer dyeability.
Abstract: Polyphenylene ether- polyamide compositions having improved resistance to water absorption and swell are provided by incorporating therein a phenolic compound.
Abstract: A heat resistant polyvinyl chloride copolymer or a heat and impact resistant polyvinyl chloride copolymer is prepared by conducting graft copolymerization of N-substituted maleimide on a vinyl chloride resin or a rubber containing vinyl chloride resin.The graft copolymerization reaction is carried out in the presence of a radical polymerizable monomer which is (1) liquid at the polymerization temperature, (2) capable of dissolving the N-substituted maleimide at the temperature, (3) 70.degree. C. or more in glass transition temperature of the polymer thereof, and (4) used in an amount sufficient to dissolve the N-substituted maleimide.
Abstract: Polyamide-polyimide block copolymers having an average molecular weight M.sub.n of 1,000-50,000 and containing recurring units of the formula I--(PA)-(PI)--. (I)in which (PA) is a polyamide block having an average molecular weight M.sub.n of 300-20,000 and containing at least one (recurring) unit of the formula II ##STR1## in which R.sup.1 is ##STR2## and R.sup.2 is ##STR3## in which Q is a direct bond, --CH.sub.2 --, --CH.sub.2 CH.sub.2 --, ##STR4## --O--, --S--, --SO.sub.2 -- or --C(O)--, and n is 2-12, and Y.sub.a, Y.sub.b, Y.sub.c and Y.sub.d independently of one another are hydrogen, halogen or C.sub.1 -C.sub.4 alkyl, and (PI) is a polyimide block having an average molecular weight M.sub.n of 300-20,000 and containing at least one (recurring) unit of the formula III ##STR5## in which R.sup.3 is ##STR6## and Q and R.sup.2 are as defined above, with the proviso that 25-100 mol % of all the bridge members R.sup.2 are ##STR7## and the (cyclo)aliphatic proportion of bridge members R.sup.
Abstract: Novel polypropylene-polyamide molding compositions which comprise, based on 100 parts by weight of the molding compositions,A) 10 to 89.9 parts by weight of one or more polypropylene homopolymer and/or copolymer,B) 10 to 89.9 parts by weight of one or more polyamide,C) 0.1 to 5.0 parts by weight of one or more olefinically unsaturated carboxylic acid and/or one or more olefinically unsaturated carboxylic acid derivate,D) 0 to 3.0 parts by weight of an impact modifier, andE) 0 to 60.0 parts by weight of a reinforcing agent and/or additive,are prepared by melting together components (A), (C) and, if desired (D) at from 200.degree. to 300.degree. C. in a first reaction step and then, in a second reaction step, introducing component (B) and, if appropriate, components (D) and/or (E) into the modified melt obtained, and melting together the components.The molding compositions obtained are used for the production of moldings.
Type:
Grant
Filed:
June 8, 1990
Date of Patent:
November 10, 1992
Assignee:
BASF Aktiengesellschaft
Inventors:
Dietrich Lausberg, Wolfgang F. Mueller, Erhard Seiler
Abstract: An AB type-block copolymer of the formula: ##STR1## wherein R.sup.1 is a hydrocarbon group having 1 to 10 carbon atoms; R.sup.2 is a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms; R.sup.3 is a benzyl group, an alkyl group having 1 to 18 carbon atoms or ##STR2## wherein R.sup.4 is an alkyl group having 1 to 18 carbon atoms; M represents a fluorine-containing AB-type block copolymer having a fluorine-containing polymer chain and a polymer chain having affinity for a resin.
Type:
Grant
Filed:
November 21, 1990
Date of Patent:
November 10, 1992
Assignee:
Mitsubishi Petrochemical Company Limited
Abstract: Improved compositions comprise polymer blends of a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon with a high rubber graft copolymer, and, optionally, an acidic polymer containing moieties of an .alpha.-olefin and an .alpha.,.beta.-ethylenically unsaturated carboxylic acid. The blends demonstrate improved toughness and impact strength at both ambient and low temperatures.
Abstract: This invention provides a halogen-containing thermoplastic resin composition comprising a halogen-containing thermoplastic resin (A), a melt-moldable vinyl alcohol polymer (B) and a polyesteramide (C), the proportions of (B) and (C) being 0.1 to 100 parts by weight and 0.1 to 10 parts by weight, respectively, based on 100 parts by weight of (A). The component (C) improves the compatibility between the components (A) and (B).
Abstract: This invention is a semi-interpenetrating polymer network which includes a high performance thermosetting polyimide having a nadic end group acting as a crosslinking site and a high performance linear thermoplastic polyimide having the following repeating unit. ##STR1## wherein Z=C or SO.sub.2. Provided is an improved high temperature matrix resin which is capable of performing in the 200.degree. to 300.degree. C. range. This resin has significantly improved toughness and microcracking resistance, excellent processability, mechanical performance and moisture and solvent resistances.
Type:
Grant
Filed:
October 31, 1989
Date of Patent:
October 27, 1992
Assignee:
The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
Abstract: A thermoplastic elastomer composition comprising (a) 20 to 70 parts by weight of a polyamide and (b) 80 to 30 parts by weight of a butyl rubber modified with a functional-group-containing compound having at least one group selected from a carboxyl group, an acid anhydride group and an epoxy group as the functional group, the total amount of the (a) and (b) components being 100 parts by weight. The thermoplastic elastomer composition is resistant to permeation of FREON gases containing hydrogen atom in their molecules and has excellent flexibility, low-temperature resistance and oil resistance.
Abstract: This invention relates to molding resin compositions, and more particularly relates to polyimide resin compositions having markedly improved molding ability in addition to excellent high temperature stability, chemical resistance and mechanical strength.The polyimide resin compositions of this invention comprises 99.9 to 50.0% by weight of the polyimide and 0.1 to 50.0% by weight of polyphenylene sulfide and/or aromatic polysulfone and/or aromatic polyetherimide high-temperature engineering polymer.
Abstract: A novel thermoplastic resin composition is here disclosed which contains(I) 99 to 1 part by weight of a polyarylate resin and(II) 1 to 99 parts by weight of at least one selected from a polyamide resin and a polyarylene sulfide resin with(III) 0.1 to 100 parts by weight, based on 100 parts by weight of the resins (I)+(II), of a multi-phase structure thermoplastic resin which is composed of 5 to 95% by weight of an epoxy group-containing olefin copolymer and 95 to 5% by weight of a vinyl polymer or copolymer obtained from at least one kind of vinyl monomer, either on both the components being in the state of a dispersion phase having a particle diameter of 0.001 to 10 .mu.m.Furthermore, a novel method for preparing the above-mentioned thermoplastic resin composition is also disclosed here.
Abstract: Novel polyimide blends are formed of polyimide polymers each having moieties derived from dianhydride and diamine comonomers. The miscible blends of the present invention may be formed by selecting polyimide polymers having structurally different dianhydride-derived moieties, as well as structurally different diamine-derived moieties. More specifically, the blends of this invention include at least one polyimide polymer which is a reaction product of 2,2-bis(3,4-dicarboxyphenyl) hexafluoropropane dianhydride, and 2,2-bis(3-aminophenyl) hexafluoropropane; and at least another polyimide polymer which is a reaction product of 2,2-bis(4-aminophenyl) hexafluoropropane and a dianhydride which is at least one selected from the group consisting of pyromellitic dianhydride, bis(3,4-dicarboxyphenyl) ether dianhydride, and 3,3',4,4'-benzophenone tetracarboxylic dianhydride.
Abstract: Blends of nylon 6,6, nylon 6 or nylon 6,6/6 copolymer which contain a randomly copolymerized cationic dye modifier are formed by melt blending such copolymer with a polyamide having 8 to 22 carbon atoms per amide link to form a block copolymer composition which is resistant to staining with acid dyes under ambient temperature and pH conditions.
Abstract: A photopolymerizable composition comprising an addition polymerizable compound, an N-aryl-.alpha.-amino acid and a photosensitizer capable of absorbing a light having a wavelength of 300 nm or more such as thioxanthones, isoalloxazines, coumarines, and the like is excellent in sensitivity to irradiated light and is suitable for preparing relief images, photoresists, etc.
Abstract: Nylon compositions useful for molding and film applications with film properties and impact strength are made of a polyamide resin and a block copolymer of poly(amide-ether) of the formula ##STR1## where R is an alkyl or substituted alkyl group with from one to 12 carbons, n is an integer from 2 to 20, m is an integer from 1 to 6, and x and y are numbers from about 50 to about 30,000. In one embodiment, a non-polymeric amide is added to the composition. Articles made from the claimed compositions have improved impact strength; films made from the compositions have improved drapeability over the unmodified resin, both at room temperature and after heat-aging. Reinforced compositions are obtained by including mineral and other reinforcing fillers, including glass fibers, in the extrusion process. The reinforced compositions exhibit improved impact characteristics.
Type:
Grant
Filed:
August 27, 1990
Date of Patent:
October 6, 1992
Assignee:
Allied-Signal Inc.
Inventors:
Varkki P. Chacko, George M. Johns, Mocherla K. Rao, Michael F. Tubridy, Donald F. Stewart
Abstract: Curable thermosetting prepolymerized imide resin compositions are prepared by chemically reacting, at a temperature below 150.degree. C., a liquid mixture of carboxy-terminated polybutadiene/acrylonitrile (CTBN) and a co-reactant comprising at least one N,N'-bisimide of an unsaturated carboxylic acid of formula (I) where B represents a divalent radical containing a carbon-carbon double bond and A represents a divalent radical having at least two carbon atoms to yield a curable thermosetting prepolymerized imide resin composition containing copolymerized CTBN and co-reactant. A resin composition prepared by this method may be cured at a temperature between 100.degree. C. and 350.degree. C. to yield a fully cross-linked polyimide matrix containing a dispersion of phase-separated solid particles of copolymerized CTBN and co-reactant, the matrix having a lapshear strength at 20.degree. C. at least 50% greater than that of a fully cross-linked polyimide cured from the co-reactant alone.
Type:
Grant
Filed:
April 17, 1990
Date of Patent:
October 6, 1992
Assignee:
The Secretary of State for Defence in Her Majesty's Government of the United Kingdom of Great Britain and Northern Ireland
Abstract: Maleic anhydride is grafted onto unsaturated elastomeric terpolymers consisting of monomeric units coming from at least two different monomers having the formula R--CH.dbd.CH.sub.2 (R=hydrogen or an alkyl group containing from 1 to 6 carbon atoms) and from a conjugated or non-conjugated dienic monomer by mass reaction, which is carried out by heating at 120.degree.-350.degree. C. a mixture of said maleic anhydride with the terpolymer in the presence of a catalyst consisting of a compound having the formula:M.sub.n X.sub.zwherein:M=a metal of group VIII of the periodic system, and in particular Rh and Ru;X=a counterion,N=valence of the counterion; andZ=valence of the metal.
Abstract: A high strength synthetic resin based structural material in which a polymer having coil-like molecules is uniformly mixed with a second polymer having rigid rod-like molecules. This material is made, basically, by dissolving a thermoplastic matrix polymer having coil-like molecules in a suitable solvent, adding thereto thermosetting polymer reactants which then form a prepolymer. The rigid rod prepolymer may then be partially cyclized through heat or by the use of a chemical agent in order to reduce chain conformations. Excess cyclizing agent can then be removed and the mixture can be heated to complete polymerization to produce a high strength structure with rigid rod-like molecules intimately blended with the matrix coil-like molecules.
Type:
Grant
Filed:
August 10, 1990
Date of Patent:
September 29, 1992
Assignee:
General Dynamics Corporation, Convair Division