Abstract: Partially grafted flexible thermoplastic compositions formed by melt blending under high shear, a thermoplastic material having available graft sites, said thermoplastic material being at least one continuous phase of the composition, an ethylene copolymer containing an unsaturated mono-carboxylic acid, and a polymeric grafting agent having reactive groups capable of reacting with the mono-carboxylic acid in the ethylene copolymer and with the available graft sites in the thermoplastic material. These compositions have use in a wide range of molding, coating and adhesive applications, including various automotive applications, wire and cable coating applications and high temperature adhesive applications.
Abstract: Polymeric blends of a styrene/acrylonitrile grafted elastomer, nylon, a compatibilizer resin particularly styrene/acrylonitrile/maleic anhydride copolymer, and a core/shell grafted elastomer having an acid functionalized shell have greatly improved notch sensitivity.
Abstract: This invention relates to molding resin compositions, and more particularly relates to polyimide resin compositions having markedly improved molding ability in addition to excellent high temperature stability, chemical resistance and mechanical strength.The polyimide resin composition of this invention comprises 99.9 to 50% by weight of the polyimide and 0.1 to 50% by weight of high temperature engineering polymer. The polyimide has recurring units of the following formula: ##STR1## wherein X is a sulfonyl radical or a carbonyl radical and R is a tetravalent radical selected from an aliphatic radical, alicyclic radical, monoaromatic radical, condensed aromatic radical and non-condensed aromatic radical.
Abstract: Described herein are miscible blends of polycarbonomides, defined as amide and/or imide containing polymers, and a polyarylate or arylate-carbonate copolymer which are useful in the manufacture of extruded sheets, high temperature connectors, aircraft and mass transportation vehicle interiors, injection molded articles, and extruded profiles and thermoformable articles.
Type:
Grant
Filed:
August 14, 1989
Date of Patent:
January 28, 1992
Assignee:
Amoco Corporation
Inventors:
James E. Harris, Markus Matzner, Lloyd M. Robeson
Abstract: Vinyl halide polymer compositions exhibiting reduced gas permeability are described which comprise a mixture of(a) at least one vinyl halide polymer; and(B) from about 1 to about 40 parts by weight per 100 parts of vinyl halide polymer (A) of at least one olefinic nitrile polymer.The vinyl halide polymers preferably are vinyl chloride homopolymers and copolymers, and the olefinic nitrile polymers are copolymers of an olefinically unsaturated nitrile such as acrylonitrile and one or more monomers from the group of conjugated dienes, monoolefins, olefinically unsaturated carboxylic acid esters, and vinyl aromatic compounds. The olefinic nitrile polymer can be chosen or manufactured to have a refractive index which is similar to the refractive index of the vinyl halide polymer thereby resulting in a more transparent composition.
Type:
Grant
Filed:
October 30, 1989
Date of Patent:
January 28, 1992
Assignee:
The B. F. Goodrich Company
Inventors:
Thomas C. Braden, Sally A. Kline, Scott Perry
Abstract: Polyol(allyl carbonate) compositions and polymerizates thereof that have an enhanced resistance to yellowing on exposure to external heating are described. In particular, a polyol(allyl carbonate) composition comprising (a) from about 55 to about 90 weight percent of a polyol(allyl carbonate), e.g., diethylene glycol bis(allyl carbonate), from about 10 to about 40 weight percent of aliphatic polyurethan having terminal ethylenic unsaturation, e.g., an aliphatic polyesterurethan diacrylate, and from about 0 to about 5 weight percent of a difunctional monomer selected from the group consisting of allyl methacrylate and allyl acrylate and (b) from about 0.01 to about 0.5 weight percent of a dialkyl pyrocarbonate, e.g., diethyl pyrocarbonate, based on the weight of the polymerizable reactants is described. Polymerizates of such polyol(allyl carbonate) compositions have an enhanced resistance to yellowing when heated at elevated temperatures, e.g., 130.degree. C.
Abstract: Higher yields of graft copolymer occur when a catalytic amount of base is present during the grafting reaction of a polyamide and a polyglutarimide. The resulting blends of ungrafted polyamide and polyglutarimide with higher graft-copolymer content, the graft copolymer being a polyamide-grafted poly(glutarimide)ionomer, exhibit improved toughness and clarity.
Abstract: This system for thermoplastic adhesives includes (A) a first composition without anhydride groups, containing: a) at least one polymer chosen from the thermoplastic polymers and the synthetic rubbers; b) at least one compound containing at least one group which can react with anhydride groups; c) at least one tackifying resin; and d) if desired, at least one plasticizer; (B) a second composition containing constituents Ba, Bc and Bd which are respectively analogous to the constituents Aa, Ac and Ad, and b) at least one polymer containing anhydride groups; and (C) at least one activator of the reaction between the reactive groups of Ab and the anhydride functions of Bb. Advantageously the activator (C) is wholly incorporated in the composition A and/or in the composition B, so as to form a two-component system.
Abstract: Graft copolymers of polymerizable monomers and olefin/carbon monoxide copolymers are uniquely suitable as compatibilizing agents in the preparation of polyester or polycarbonate containing resin blends.
Abstract: A thermotropic liquid crystal polyester consisting essentially of ethylene glycol residue, terephthalic acid residue and parahydroxybenzoic acid residue wherein the mol ratio of ethylene glycol residue to terephthalic acid residue is substantially about 1:1 and the mol ratio of terephthalic acid residue to parahydroxybenzoic acid residue is in the range of about 5:95 to about 25:75, the polyester having an intrinsic viscosity of at least about 0.5 dl/g measured in a 50:50 by weight solvent mixture of phenol and 1,1,2,2-tetrachlorethane at 20.degree. C., and a transmittance of at least about 80% to 530 nm light at a light path length of said solvent mixture. A method for forming the thermotropic liquid crystal polyester is also disclosed.
Abstract: This invention relates to soft, rubber-like, thermoplastically processible polymer alloys based on 10 to 50% by weight of (cyclo)aliphatic, thermoplastic polyamides and 90 to 50% by weight of special cross-linked, particulate alkyl acrylate copolymer rubbers suitable for the preparation of rubber-like, elastic moulding compounds.The invention also relates to a process for their preparation.
Type:
Grant
Filed:
August 10, 1990
Date of Patent:
December 24, 1991
Assignee:
Bayer Aktiengesellschaft
Inventors:
Christian Lindner, Lothar Meier, Otto Billinger, Karl-Erwin Piejko
Abstract: The present invention encompasses non-phase-separated thermoplastic block copolymers containing rigid rod PBZ blocks and thermoplastic PBZ blocks; dopes and compositions containing those block copolymers; a process for making shaped articles from thermoplastic block copolymers containing rigid rod PBZ blocks and thermoplastic PBZ blocks; and shaped articles made by that process.
Type:
Grant
Filed:
March 23, 1989
Date of Patent:
December 24, 1991
Assignee:
The Dow Chemical Company
Inventors:
William J. Harris, Zenon Lysenko, Wen-Fang Hwang
Abstract: A thermoplastic resin composition is obtained by blending 100 parts by weight of a resin blend consisting of 10 to 90% by weight of at least one polypropylene type resin (A) selected from the group consisting of modified polypropylenes and compounds composed of modified polypropylenes and polypropylenes, and 90 to 10% by weight of a polyamide resin (B); 2 to 30 parts by weight of an epoxy group containing copolymer (C) and 2 to 100 parts by weight of an ethylene-.alpha..beta.-unsaturated carboxylic acid alkyl estermaleic anhydride terpolymer (D).The composition can easily be processed into a molded product, a film, a sheet or the like by a conventional processing method such as injection molding and extrusion molding. The resulting product has a very good balance in physical properties such as heat resistance, coating properties, impact strength and flexural modulus. The composition of this invention is useful in the fields of automobiles, electric industry and electronic industry.
Abstract: A polymer composition contains a polyarylketone, a polyarylsulphone and a polyimide. The polyketone may be a polyaryletheretherketone, and the polyarylsulphone may be a polyarylethersulphone. The polyimide may be a polyetherimide in which the repeating group contains the unit ##STR1## The composition contains at least 5% by weight of the polyarylketone and the polyarylsulphone and at least 10% of the polyimide. The proportion of the polyarylketone is preferably 30 to 70% by weight. The proportion of polyarylsulphone is preferably 15 to 40% by weight. The proportion of polyimide is preferably 10 to 30% by weight. A composition of 60% by weight of polyaryletheretherketone; 20% by weight of polyarylethersulphone and 20% by weight of polyetherimide forms a mixture with good compatibility, has a high glass transition temperature and retains a melting point close to that of the polyaryletheretherketone.
Abstract: Thermoplastic molding materials contain, as essential components,A) 20-98% by weight of a partly aromatic amide copolymer essentially consisting ofa.sub.1) 40-90% by weight of units derived from terephthalic acid and hexamethylenediamine,a.sub.2) 0-50% by weight of units derived from .epsilon.-caprolactam anda.sub.3) 0-60% by weight of units derived from adipic acid and hexamethylenediamine,components a.sub.2) and/or a.sub.3) accounting altogether for not less than 10% by weight of the total number of units,B) 2-80% by weight of a partly crystalline thermoplastic polyamide which differs from A)and furthermoreC) 0-50% by weight of an elastomeric impact modifier andD) 0-60% by weight of fibrous or particulate fillers or a mixture of these.
Type:
Grant
Filed:
July 7, 1989
Date of Patent:
December 10, 1991
Assignee:
BASF Aktiengesellschaft
Inventors:
Eckhard M. Koch, Gerhard Heinz, Walter Goetz, Gunter Pipper
Abstract: New polymer composition which has excellent thermal stability, good impact resistance and processability, containing the following compounds:a) 20-75 wt. % of a graft copolymer which contains 10-90 wt. % rubber and grafted on the rubber a copolymer of acrylonitrile and styrene or .alpha.-methylstyreneb) 6-50 wt. % of a copolymer of styrene or .alpha.-methylstyrene containing 20-32 wt. % maleic anhydride, with a molecular weight of 50,000-500,000c) 5-70 wt. % polyamide andd) 0-30 wt. % of a copolymer of styrene or .alpha.-methylstyrene and acrylonitrile.
Type:
Grant
Filed:
August 10, 1989
Date of Patent:
December 10, 1991
Assignee:
Stamicarbon B.V.
Inventors:
Herman A. J. Schepers, Wilhelmus A. M. Debets
Abstract: Disclosed are blends of (a) a polyetherimide and (b) a (meth) acrylate-styrene-acrylonitile polymer (ASA). The blends exhibit an improved heat distortion temperature flexural properties and tensile properties over the ASA component alone and have lower impact strengths than that associated with the ASA polymer alone.
Type:
Grant
Filed:
December 31, 1986
Date of Patent:
December 3, 1991
Assignee:
General Electric Company
Inventors:
Harold F. Giles, Jr., William R. Schlich
Abstract: Compositions comprising from 50 to 95% by weight of at least one polyamide resin, and from 5 to 50% by weight % of a polymer composition comprising from 84 to 99.1 mole % of units derived from ethylene and from 0.9 to 16 mole % of units derived from an unsaturated anhydride of a dicarboxylic acid and optionally from at least one of an alkyl acrylate or methacrylate whose alkyl group has from 1 to 8 carbon atoms. The polymer composition is present in the form of a mixture of (A) a polymer of ethylene and (B) a copolymer of ethylene and an unsaturated anhydride of a dicarboxylic acid. The weight ratio (A) to (B) lies between 1 to 6 and 6 to 1.Application is to the production of articles having an improved impact resistance.
Abstract: Molded article having improved thermal resistance and strength formed from a homogeneous mixture comprising from about 5 to 75 percent by weight polybenzimidazole and from about 95 to 25 percent by weight of a polyaryleneketone. These articles are obtained by injection molding techniques.
Type:
Grant
Filed:
April 13, 1989
Date of Patent:
December 3, 1991
Assignee:
Hoechst Celanese Corporation
Inventors:
Edwardo Alvarez, Lorenzo P. DiSano, Bennett C. Ward
Abstract: Polymer blends comprising a major proportion of linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon, a minor proportion of a carboxylated, partially hydrogenated two-block copolymer of an alkenyl arene and a conjugated alkadiene and, optionally, a minor proportion of an .alpha.-olefin/.alpha.,.beta.-ethylenically unsaturated carboxylic acid polymer, demonstrate improved properties of low temperature toughness.