Abstract: A thermoplastic resin composition which comprises 1 to 98 parts by weight of polyolefin (A), 1 to 49 parts by weight of modified polyolefin (B) obtained by reacting a polyolefin with an unsaturated carboxylic acid or a derivative thereof, 1 to 98 parts by weight of polyamide (C) [provided that (A)+(B)+(C)=100 parts by weight], 5 to 50 parts by weight of modified ethylene-.alpha.-olefin copolymer (D) obtained by reacting a low-crystalline ethylene-.alpha.-olefin copolymer with an unsaturated carboxylic acid or its derivative, and a metal compound (E) in an amount of 0.5 to 5 times the molar quantity of the acid added to said component (B) and said component (D).The thermoplastic resin composition is preferably used for producing products excellent in both impact resistance and surface luster.
Abstract: A composition of terminal-modified imide oligomers is disclosed. The composition comprises a flexible terminal-modified imide oligomer (A) and a rigid terminal-modified imide oligomer (B). The flexible terminal-modified imide oligomer (A) is selected from specific oligomers (I) and (II). The rigid terminal-modified imide oligomer (B) is selected from specific oligomers (III) and (IV). The oligomer (I) is formed from biphenyltetracarboxylic acid or its derivative, an aromatic diamine compound (a) and an unsaturated monoamine compound or an unsaturated carboxylic acid or its derivative. The oligomer (II) is formed from biphenyltetracarboxylic acid or its derivative and an unsaturated monoamine compound. The oligomer (III) is formed from biphenyltetracarboxylic acid or its derivative, an aromatic diamine compound (b) and an unsaturated monoamine compound or an unsaturated carboxylic acid or its derivative.
Abstract: Compatibilized compositions comprising at least one polyamide and at least propylene polymer which is at least partially modified by a polar monomer, in which compositions the propylene polymer has a melt flow index (MFI) measured according to ASTM standard D 1238-86 (230/2.16 conditions) higher than 50 g/10 min.
Abstract: 4-component thermoplastic molding compositions which are easily processed on injection molding or extrusion machinery consisting essentially of amorphous copolyamides which can be produced from inexpensive raw materials, inexpensive elastomeric block polyetherpolyamides and block polyetheresterpolyamides as well as commercially available modified copolyolefins and are distinguished by high cold impact resistance, good ductility, variably adjustable rigidity which is independent of the degree of humidity and excellent pigment compatibility as well as by good stress crack resistance, thermal and dimensional stability.
Type:
Grant
Filed:
March 27, 1990
Date of Patent:
August 18, 1992
Assignee:
EMS-Inventa AG
Inventors:
Hans Dalla Torre, Hans-Jorg Liedloff, Franz Kerschbaumer
Abstract: A radical polymerizable composition comprising(A) a compound having a pi-electron conjugated structure and(B) a radical polymerizable compound, which is useful for molding into an arbitrary shape, which can be rendered electrically conductive and which is, therefore, useful as a material for electrodes or circuits in the electrical and electronic industry.
Abstract: A miscible blend comprising from about 5 to about 95 weight percent of a polybenzimidazole and from about 95 to about 5 weight percent of a polyamide-imide having fluorine-containing linking groups, total weight percent of the two polymers being 100. A process for preparing the blends comprises dissolving in a mutual solvent from about 5 to about 95 weight percent of the aromatic polybenzimidazole to about 95 to about 5 weight percent of the polyamide-imide having fluorine-containing linking groups, based on the total weight of those polymers and subsequently evaporating the solvent, thereby producing a dried blend of a polybenzimidazole and a polyamide-imide having fluorine-containing linking groups. The blends, particularly in the form of films, fibers or fibrets, may be post-treated with heat or sulfuric acid in order to minimize their shrinkage when subsequently subjected to heat and in order to increase their resistance to solvents and acid.
Type:
Grant
Filed:
September 22, 1989
Date of Patent:
August 11, 1992
Assignee:
Hoechst Celanese Corp.
Inventors:
Paul N. Chen, Sr., Morton Glick, Rohitkumar H. Vora, Michael Jaffe
Abstract: Binders for moisture-hardening coating or sealing compositions contain modified copolymers having a weight average molecular weight of from 1,500 to 75,000 determined by gel permeation chromatography of olefinically unsaturated compounds containing chemically incorporated moieties which are addition-reactive to amino wherein the modified copolymers contain both(i) intramolecular carboxylic anhydride moieties and(ii) olefinically unsaturated (meth)acrylate moieties in chemically bound form as the moieties which are addition-reactive to amino, with the anhydride equivalent weight being in the range from 392 to 9,800 and the (meth)acrylate equivalent weight in the range from 284 to 7,100.
Type:
Grant
Filed:
February 22, 1991
Date of Patent:
August 4, 1992
Assignee:
Bayer Aktiengesellschaft
Inventors:
Christian Wamprecht, Harald Blum, Josef Pedain, Peter Hohlein
Abstract: A method for the preparation of miscible blends comprising biphenyl-containing poly(aryl sulfones) and polyimides is disclosed. The process comprises adding the monomeric polycarboxylic acid and aromatic diamine components of the polyimide to a suitable polyaryl sulfone in a vented extruder and melt-processing the resulting mixture, thereby polymerizing the monomers to form the polyimide component of the blend.
Abstract: The present invention relates to improved polyphenylene ether-polyamide composition wherein the polyamide component comprises a mixture of amorphous and crystalline polyamide. A compatibilizing material is added as well as a modifying resin is added. The composition have good impact strength and water resistance.
Abstract: Improved compositions comprise polymer blends of a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon with an acrylic shell-core modifier, and, optionally, an acidic polymer containing moieties of an .alpha.-olefin and an .alpha.,.beta.-ethylenically unsaturated carboxylic acid. The blends demonstrate improved toughness at both ambient and low temperatures.
Abstract: The processing temperature of linear thermoplastic polyurethane elastomers prepared from a polycarbonate polyol, a polyether polyol, an extender and a disocyanate compound which has been modified by reaction with a low molecular weight diol to form a modified diisocyanate compound prior to reaction with the other components of the elastomer, can be reduced by adding a millable thermoplastic linear polyurethane elastomer thereto. These materials possess an optimum combination of hydrolytic stability, toughness, flexibiity and low temperature processing characteristics.
Type:
Grant
Filed:
March 20, 1989
Date of Patent:
July 14, 1992
Assignee:
Reeves Brothers, Inc.
Inventors:
John R. Damewood, Jill R. Menzel, Fred N. Teumac, Bert A. Ross
Abstract: The ionomer salt of low molecular weight copolymer reaction product of a copolymer acid of an .alpha.-olefin and an unsaturated carboxylic acid, and at least one amino acid compound, and a cation containing material. The unsaturated carboxylic acid is preferably an .alpha., .beta.-ethylenically unsaturated carboxylic acid. The present invention includes a method of preparing the ionomer. The ionomer has excellent compatibility with other polymers, particularly polyamides. The ionomer is useful in a method to flush water from pigments.
Abstract: Hydroxy terminated polyamides are prepared having the formula: ##STR1## wherein R represents a defined hydrocarbon group,R' and R" represents defined oxypropylene groups, and R'" represents a defined oxyethylene group,the hydroxy terminated polyamide having been prepared by first preparing an intermediate dicarboxylic acid terminated polyoxypropylene polyamide by reacting an excess of a dicarboxylic acid component with a diamine mixture composed of a higher molecular weight polyoxypropylene diamine and a lower molecular weight polyoxypropylene diamine, and by reacting the intermediate polyamide with a molar excess of an oxyethylene amino alcohol.
Abstract: A polymerisable composition which comprises an unsaturated urethane, a C.sub.1 or C.sub.2 alkyl methacrylate and at least one other ethylenically unsaturated addition polymerisable substance copolymerisable therewith, such polymerisable compositions, where they contain an inorganic filler, overcome some of the problems associated with the polymerisable compositions described in European 0.064,809. Where the polymerisable substance comprises an unsaturated polyester, the shelf-life of the polymerisable composition can be extended by adding thereto a reagent which reacts with a portion of the free carboxyl group in the unsaturated polyester. The compositions may be used, for example, in the production of fibre-reinforced composites.
Abstract: It has now been found that a unique combination of additives makes semi-crystalline polyamides readily processible by extrusion blowmolding to make hollow, stiff parts of various shapes. The compositions consist essentially of a semicrystalline polyamide, a selected ionomeric toughening agent, and an anhydride-rich ethylene copolymer.
Abstract: This invention is a method of curing unsaturated polymers which do not have a significant amount of functional groups which undergo a cross-linking reaction with amino resins and which preferably comprise at least one conjugated diolefin monomer, said method comprising mixing said polymer with an amino resin in the presence of a proton-donating acid catalyst.
Abstract: Polycationic wet-strength materials such as KYMENE are chemically modified to provide unsaturated hydrocarbon substituents. The modified KYMENE is cross-linked onto and into latex particles to provide improved wet-strength agents for use in paper treatments. Thus, KYMENE is reacted, for example, with acrylic acid and cross-linked with styrene/butadiene to provide a polycationic latex wet-strength agent.
Abstract: It has now been found that a unique combination of additives makes semi-crystalline polyamides readily processible by extrusion blowmolding to make hollow, stiff parts of various shapes. The compositions consist essentially of semicrystalline polyamide, a selected toughening agent and an anhydride-rich ethylene copolymer.