Patents Examined by Andrew H. Metz
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Patent number: 4786400Abstract: A dual riser cracking operation in combination with sequential stages of catalyst regeneration in which the second regeneration stage is a riser regenerator is described in combination with deep solvent deasphalting a vacuum resid. The deasphalted resid is subjected to hydrogenation treatment prior to cracking thereof in a riser cracking zone in admixture with a heavy vacuum gas oil which may or may not be hydrogenated prior to cracking thereof. Lower boiling fractions of the crude oil are subjected to catalytic cracking in a separate riser cracking zone. Partially regenerated catalyst of dense fluid bed regeneration may be employed in the heavy oil feed riser cracking operation charged with deasphalted oil. The partially regenerated catalyst may be used alone or in combination with more completely regenerated catalyst of the riser regeneration operation.Type: GrantFiled: September 10, 1984Date of Patent: November 22, 1988Inventor: Carl D. Farnsworth
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Patent number: 4780448Abstract: A catalyst containing copper and silica is prepared by a process in which an aqueous alkali metal silicate solution containing from 1 to 26% by weight of SiO.sub.2 is brought to a pH of from 0.5 to 2.0 with nitric acid, an aqueous copper nitrate solution containing from 5 to 15% by weight of Cu is added, after the addition of the nitric acid, so that a clear solution containing from 0.18 to 3.0 moles of Cu per mole of SiO.sub.2 is formed, the resulting solution is mixed with an aqueous alkali metal carbonate solution at from 40.degree. to 80.degree. C., the pH of the mixture being kept at from 7.5 to 8.5, and the precipitated material is separated off, dried, calcined by heating at from 250.degree. to 400.degree. C. and pressed in a conventional manner to give catalyst moldings. The catalyst thus obtained is used for the hydrogenation of dialkyl dicarboxylates to diols.Type: GrantFiled: January 30, 1987Date of Patent: October 25, 1988Assignee: BASF AktiengesellschaftInventors: Franz J. Broecker, Rolf Fischer, Klaus-Dieter Malsch, Wolfgang Reiss, Rolf Schnabel, Hans-Martin Weitz
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Patent number: 4753033Abstract: A process for substantially reducing the amount of insoluble fluoride-forming species in a coal feed material comprising slurrying a coal feed with a fluoride acid in the presence of an amount of fluoride-complexing species at least equal to the amount necessary to form tightly-bound complex ions with substantially all free-fluoride-ions in the slurry to produce a leached coal product and a spent leach liquor, and separating the leached coal product from the spent leach liquor. The process produces a clean purified fuel with ash content of less than about 5%, and preferably less than about 1%. Loss of fluorine values by formation of insoluble fluorides is minimized. Alkali metals and alkaline earths are substantially dissolved.Type: GrantFiled: February 5, 1987Date of Patent: June 28, 1988Assignee: Williams Technologies, Inc.Inventor: James K. Kindig
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Patent number: 4727218Abstract: Method and apparatus for separating and/or purifying a substance from a molten mixture by crystallization, in which the molten mixture is conducted into an annular space defined by two substantially curvilinearly-shaped surfaces, one of the surfaces being cooled, and at least one of the surfaces rotating. The molten mixture is thereby cooled as the same flows through the annular space with material crystallizing to form a deposit upon the cooled surface. The crystallized deposit is then caused to be contacted by a source of heat, whereby the same is melted. At least part of the melted deposit is then removed from the annular space, to obtain the substance in purified form, while any remaining part of the melted deposit is conducted through the annular space in a direction away from the source of heat. Non-crystallized molten material which contains impurities is also removed from within the annular space.Type: GrantFiled: July 3, 1985Date of Patent: February 23, 1988Assignee: Neste OYInventor: Tomi Heiskanen
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Patent number: 4724069Abstract: An additive comprising a metal naphthenate selected from the group consisting of cobalt naphthenate and iron naphthenate is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing the additive is then contacted in a hydrofining process with a catalyst composition comprising a support selected from the group consisting of alumina, silica and silica-alumina and a promoter comprising at least one metal selected from Group VIB, Group VIIB and Group VIII of the Periodic Table. The introduction of the inventive additive may be commenced when the catalyst is new, partially deactivated or spent with a beneficial result occuring in each case.Type: GrantFiled: August 15, 1986Date of Patent: February 9, 1988Assignee: Phillips Petroleum CompanyInventors: Arthur W. Aldag, Jr., Stephen L. Parrott, Simon G. Kukes
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Patent number: 4724068Abstract: A hydrocarbon-containing feed stream, e.g., a heavy oil or residuum, is contacted under suitable reaction conditions with free hydrogen, hydrogen sulfide and at least one olefin polymer, preferably polypropylene or polystyrene, so as to produce a hydrocarbon product stream having increased API.sub.60 gravity and lower content of heavies. Generally, the amounts of impurities (sulfur, nitrogen, nickel and vanadium) contained in the feed stream are reduced in this hydrotreating process.Type: GrantFiled: July 17, 1986Date of Patent: February 9, 1988Assignee: Phillips Petroleum CompanyInventor: Paul R. Stapp
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Patent number: 4724134Abstract: The invention comprises high purity substantially spherical metal oxide particles having one or more predominant particle sizes formed from one or more metal alkoxides. In one embodiment there is disclosed multimodal particle size distributions of such substantially spherical metal hydroxide particles while a second embodiment describes the formation of such particles using more than one metal alkoxide to form either a mixed metal hydroxide particle or a layered particle comprising a core of a first metal hydroxide and at least one layer of an additional metal hydroxide.Type: GrantFiled: October 21, 1985Date of Patent: February 9, 1988Assignee: Aluminum Company of AmericaInventor: Ajay Sood
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Patent number: 4724226Abstract: A boria promoted hydrotreating catalyst is made having a microporous region with high surface area for desulfurization and preferably a macroporous region to transport large metal containing molecules into the interior of the catalyst particle. The alumina support has 0.1 to 5% boria to form a hydrotreating catalyst which minimizes the formation of tetrahedrally coordinated boron. It is calcined to a temperature of 1400.degree. F. or less to maintain a high desulfurization activity. Conventional hydrotreating catalytic elements from Groups VB, VIB, VIIIB and VA of the Periodic Table are added. Less than 75% of the boron is in tetrahedral coordination as measured by Magic Angle Spinning .sup.11 B NMR.Type: GrantFiled: September 23, 1986Date of Patent: February 9, 1988Assignee: W. R. Grace & Co.Inventors: Wu-Cheng Cheng, Carmo J. Pereira
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Patent number: 4723962Abstract: An improved process is described for recovering lithium from evaporatively concentrated brines. Epsom salt recovered from the brine at about 0.degree. C. is added to the concentrated lithium-containing brine, so as to precipitate lithium sulfate monohydrate, the brine having previously been subjected to the sequential steps of two stage chilling, evaporative concentration, further chilling and vacuum evaporation.Type: GrantFiled: June 5, 1986Date of Patent: February 9, 1988Assignee: Lithium Corporation of AmericaInventor: Vijay C. Mehta
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Patent number: 4722783Abstract: Burned oil shale recycled as heat transfer solids in retorting process conditioned under reducing conditions with hydrocarbon to improve product yield.Type: GrantFiled: June 22, 1983Date of Patent: February 2, 1988Assignee: Chevron Research CompanyInventors: Robert P. Sieg, P. Henrik Wallman, James R. Ouimette
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Patent number: 4722782Abstract: A method for the recovery of bitumen from tar sand comprises slurrying tar sand with about 0.5 to about 4.0 pound of a organic solvent per pound of tar sand, then adding greater than about 0.50 pound water per pound of tar sand, and separating a bitumen rich solvent phase. The method has the advantage of permitting separation of sand from the bitumen rich solvent extract without formation of a stable emulsion.Type: GrantFiled: October 31, 1983Date of Patent: February 2, 1988Assignee: Standard Oil CompanyInventors: Robert J. Graham, John J. Helstrom, Lawrence B. Peck, Richard A. Stone
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Patent number: 4722832Abstract: A process for the recovery of sulfur from sulfur-bearing ores employing an aqueous leaching solution containing calcium monosulfide, calcium hydrosulfide or mixtures of such calcium sulfide species. The sulfur ore is contacted in an extraction zone with the aqueous leaching solution under conditions to solubilize sulfur from the ore in the form of calcium polysulfide. Preferably, the extraction step is carried out at an elevated temperature. The loaded leaching solution is recovered from the extraction zone and applied to a sulfur-production zone. Here the loaded solution is contacted with hydrogen sulfide under conditions to react the hydrogen sulfide with the calcium polysulfide to produce calcium hydrosulfide and elemental sulfur. The calcium hydrosulfide solution is recycled for use as leaching solution in the sulfur extraction zone.Type: GrantFiled: August 27, 1986Date of Patent: February 2, 1988Assignee: Freeport-McMoRan Resource PartnersInventors: Charles W. Weston, John W. Wen
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Patent number: 4720306Abstract: Method for cleaning vessels and in particular, steam generators, having deposits which are dissolved chemically and removed mechanically. The copper compounds present in the deposits are dissolved chemically and subsequently, loose deposits and liquids are removed mechanically. Encrustations still remaining are softened chemically and finally, the loosened deposits as well as the remaining chemicals are flushed out.Type: GrantFiled: April 15, 1986Date of Patent: January 19, 1988Assignee: Kraftwerk Union AktiengesellschaftInventors: Hermann Emmert, Herbert Hehs, Detlev Coerlin, Klaus Kuhnke
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Patent number: 4719195Abstract: The invention concerns a process for sulfurizing a catalyst, particularly a refining catalyst comprising a carrier and active metal oxides.In a first step, a sulfur compound mainly consisting of organic polysulfide is introduced into the catalyst mass. A second step consists of first sulfurizing, in the absence of hydrogen, the active metal oxides at a temperature lower than 275.degree. C. and then activating the catalyst at a temperature higher than 275.degree. C.The present invention concerns a process for presulfurizing a hydrocarbon treatment catalyst and/or preconditioning a catalyst in view of subsequent presulfurization.Type: GrantFiled: October 30, 1985Date of Patent: January 12, 1988Assignee: Europeenne de Retraitement de Catalyseurs (Eurecat)Inventors: Herve Toulhoat, Georges Berrebi
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Patent number: 4719002Abstract: A slurry hydroconversion process is provided in which a catalyst precursor concentrate comprising an aqueous solution of phosphomolybdic acid and a heavy oil is contacted with hot hydrogen to vaporize the water from the concentrate. The resulting catalyst precursor concentrate is introduced into a hydrocarbonaceous chargestock and the resulting mixture is heated in the presence of added hydrogen to convert the phosphomolybdic acid to a solid molybdenum-containing catalyst. The resulting slurry is subjected to hydroconversion conditions.Type: GrantFiled: April 21, 1986Date of Patent: January 12, 1988Assignee: Exxon Research and Engineering CompanyInventors: Francis X. Mayer, William E. Lewis
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Patent number: 4718945Abstract: A continuously operating sugar centrifugal is equipped with the following components, a massecuite supply device, a frustum-shaped screen drum which is rotatably drivable, a housing surrounding the screen drum, a distributor and accelerating device arranged for cooperation with the screen drum, cover water nozzles arranged in a fixed position in the drum, and an air guide ring. The air guide ring is located at the widening upper open end of the drum. The air guide ring widens conically and forms an extension or elongation of the screen drum. A passage or exit gap for the sugar to be discharged from the drum, is provided between the upper drum edge and a rim of the air guide ring facing the drum. The air guide ring rim facing away from the drum reaches into a ring-shaped air scoop and collecting space (17) which is open toward the interior of the drum.Type: GrantFiled: January 13, 1987Date of Patent: January 12, 1988Assignee: Braunschweigische Maschinenbauanstalt AGInventors: Helmut Schaper, Heinrich Kurland
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Patent number: 4717782Abstract: A continuous catalytic process for converting ethene-rich olefinic feedstock containing reducing gas to heavier liquid hydrocarbon product, comprising the steps ofcontacting the ethene-rich feedstock at elevated temperature in a catalytic reaction zone with a zeolite catalyst comprising a nickel-ethene oligomerization component and a shape-selective medium pore acid zeolite oligomerization component to convert at least a portion of the lower olefinic components to heavier olefinic hydrocarbons; andfeeding water with the feedstock in sufficient amount to prevent substantial reduction of the nickel component.Type: GrantFiled: August 5, 1986Date of Patent: January 5, 1988Assignee: Mobil Oil CorporationInventors: William E. Garwood, John D. Kushnerick, Samuel A. Tabak
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Patent number: 4717553Abstract: In a process for removing amines having normal boiling points under 100.degree. C., present in an oxygen-containing gas, which comprises passing the amine-containing gas through activated carbon and releasing the gas into the atmosphere, said gas containing from about 5 ppm by volume to about 5,000 ppm by volume of amines, the improvement which comprises adding about 500 ppm to about 30,000 ppm by volume of gaseous carbon dioxide to said gas prior to passing the gas through the activated carbon.Type: GrantFiled: October 14, 1986Date of Patent: January 5, 1988Assignee: J. Michael BrasseyInventor: Amos Turk
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Patent number: 4717426Abstract: Method by cleaning of printing ink and printing mould from the screen of a serigraphical frame (3), where the screen is cleaned with high pressure water to which has been added alkaline washing powder, to loosen the printing ink and the printing mould, thereafter flushing the screen with high pressure water to remove possible remaining printing ink and printing mould and finally to dry the cleaned screen for reuse.Type: GrantFiled: October 21, 1985Date of Patent: January 5, 1988Inventor: Erik Brynildsen
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Patent number: 4717468Abstract: An improved distillation process and apparatus are provided whereby liquid product recovery other than bottom product is maximized and feed stream heating is minimized. Inert gas streams combined with the feed stream and introduced into the distillation tower are controlled whereby feed stream heater residence time and partial pressures of feed stream components are minimized. The temperature of the combined inert gas-feed stream exiting the feed stream heater is controlled at a minimum temperature by establishing signals representative of overflash, bottom product specification and other conditions and comparing such signals whereby the signal which represents the lowest heater outlet temperature is utilized for controlling the heater operation.Type: GrantFiled: January 28, 1987Date of Patent: January 5, 1988Assignee: Phillips Petroleum CompanyInventor: Gary L. Funk