Abstract: Methods of preparing titanated silica catalysts, and titanated silica catalysts. The titanated silica catalysts may include a silica support, which may include spherical beads. Methods of olefin epoxidation, which may include contacting an olefin with a titanated silica catalyst in the presence of an oxidant.

Abstract: Embodiments of the present disclosure are directed to a process for modifying catalysts comprising introducing a precursor agent and hydrogen gas to a conversion reactor; contacting the precursor agent with a conversion catalyst in the conversion reactor, thereby producing an active agent; introducing the active agent to a production reactor; and contacting the active agent with a hydroprocessing catalyst in the production reactor, thereby producing a modified hydroprocessing catalyst.

Abstract: Provided herein are catalyst supports, catalyst systems, and methods for making catalyst supports, catalyst systems, and performing chemical reactions with the catalyst systems. The catalyst supports include a zeolite and a binder including non-sodium counterions, such as ammonium counterions and/or potassium counterions. The catalyst systems include the catalyst supports and a catalytic material. The catalyst systems may be used to perform chemical reactions, including reactions of one or more hydrocarbons.

Abstract: Methods and systems are provided for desalting wash water treatment and recycling processes and control of those processes. More specifically, treatment of wash water and wastewater streams using forward osmosis are provided. Additional methods and systems for desalting processes are provided, including recycling wash water. Methods for controlling operations of desalting systems and processes are provided.

Abstract: Aspects of the present disclosure generally relate to catalyst compositions including metal chalcogenides, processes for producing such catalyst compositions, processes for enhancing catalytic active sites in such catalyst compositions, and uses of such catalyst compositions in, e.g., processes for producing conversion products. In an aspect, a process for forming a catalyst composition is provided. The process includes introducing an electrolyte material and an amphiphile material to a metal chalcogenide to form the catalyst composition. In another aspect, a catalyst composition is provided. The catalyst composition includes a metal chalcogenide, an electrolyte material, and an amphiphile material. Devices for hydrogen evolution reaction are also provided.

Abstract: The present invention relates to a catalyst and a method for preparation of that catalyst for the selective hydrogenation of diolefins present in gasoline streams along with the shifting of lighter sulfur compounds in the feed stock to heavier sulfur compound by the reaction with olefinic compounds.

Abstract: The present invention relates to granulated particles with improved attrition and a method for producing granulated particles by fluidized bed granulation of inorganic particles wherein particles of reduced particle size are fed into a fluldized-bed granulation reactor thereby producing granulated particles with improved attrition.

Abstract: The present disclosure relates to the recovery of an alkoxide catalyst used in a process depolymerizing a polyester to form a diacid or diester and a diol. The present disclosure also relates to the recovery of an alkoxide catalyst used in a process depolymerizing polyethylene terephthalate to form dimethyl terephthalate and mono ethylene glycol.

Abstract: The present disclosure relates to the technical field of water purifying material, and in particular to a kaolin-based water purifying material, a preparation method and use thereof. The method for preparing a kaolin-based water purifying material provided by the present disclosure includes the following steps: mixing kaolin and a modifier with water, and conducting hydrothermal reaction to obtain a kaolin-based water purifying material; the modifier is an organic or inorganic modifier; the organic modifier is octadecyl trimethyl ammonium chloride (OTAC), and the inorganic modifier is one or more of polyaluminum chloride, Al2(SO4)3, Fe2(SO4)3, AlCl3 and FeCl3; the kaolin is 200-400 mesh in particle size. The water purifying material of the present disclosure enables efficient algae removal and water purification, and is safe and eco-friendly.

Abstract: A process for activating a hydrogenation catalyst comprising nickel to produce a selective hydrogenation catalyst, comprising contacting the hydrogenation catalyst with a mixed gas comprising and hydrogen sulfide and periodically increasing the temperature of the mixed gas in increments until the mixed gas reaches a temperature that facilities the efficient catalytic hydrogenation of both acetylene and butadiene by the modified catalyst, while the modified catalyst is simultaneously characterized by low selectivity for the hydrogenation of ethylene. The disclosure further claims a process that utilizes the modified catalyst to selectively hydrogenate acetylene and butadiene contaminants in a raw light olefin stream produced by thermal cracking, thereby extending the useful catalytic lifespan of a downstream oligomerization catalyst that converts the light olefins stream to a liquid transportation fuel, or a blend stock thereof.

Abstract: A highly active hydroprocessing catalyst that comprises a doped support having been impregnated with a metal-impregnation solution, comprising a complexing agent and a hydrogenation metal, and filled with an organic additive blend. The catalyst is made by providing a doped support particle followed by impregnating the doped support particle with a metal impregnation solution that contains both a hydrogenation metal component and a complexing agent component to provide a metal-impregnated doped support particle. The metal-impregnated doped support particle is dried, but not calcined, and impregnated with an organic additive blend component.

Abstract: An apparatus for heating a fluid is provided, the apparatus comprising a chamber and one or more tubes for conveying the fluid through the chamber, wherein at least one of the tubes has a bend and the bend comprises a removable bend cap including at least one microwave emitter. In another aspect, there is provided an apparatus for removably attaching a bend in tubing for conveying a fluid through the enclosure, the bend having a removable bend cap, and the apparatus comprising a sleeve extending through an opening in the enclosure, wherein the sleeve is adapted to receive the removable bend cap. In yet another aspect, there is provided an apparatus having an enclosure and tubing within the enclosure, the tubing being to convey fluid through the enclosure. At least one of the tubes has a bend, and the bend comprises a removable bend cap which comprises a cleaning device.

Abstract: The invention relates to a catalyst comprising a support based on alumina or silica or silica-alumina, at least one group VIII element, at least one group VIB element and at least one organic compound of formula (I) in which R1 is a hydrocarbon-based radical comprising from 1 to 12 carbon atoms, R2 and R3 are chosen from a hydrogen atom and a hydrocarbon-based radical comprising from 1 to 12 carbon atoms, X is chosen from an oxygen atom or a sulfur atom except when R2 and R3 represent a hydrogen atom, in which case X is an oxygen atom, Y is chosen from a hydrogen atom, a hydrocarbon-based radical comprising from 1 to 12 carbon atoms or a unit —C(O)R4, R4 being chosen from a hydrogen atom and a hydrocarbon-based radical comprising from 1 to 12 carbon atoms.

Abstract: Provided herein are catalyst supports, catalyst systems, and methods for making catalyst supports, catalyst systems, and performing chemical reactions with the catalyst systems. The catalyst supports include a zeolite and a binder including non-sodium counterions, such as ammonium counterions and/or potassium counterions. The catalyst systems include the catalyst supports and a catalytic material. The catalyst systems may be used to perform chemical reactions, including reactions of one or more hydrocarbons.

Abstract: A method of producing a catalytic carbon fiber may include: oxidizing a virgin carbon fiber to produce an oxidized carbon fiber; reacting the oxidized carbon fiber with a polyamine compound to produce an amine modified carbon fiber; and reacting the amine modified carbon fiber with an organometallic macrocycle to produce the catalytic carbon fiber.

Abstract: Direct steam injection (DSI) heating techniques can use a heater to heat a process stream in bitumen froth treatment. The DSI heater can include a diffuser with multiple side-by-side rows of outlets perpendicular to a longitudinal axis of the diffuser, and a piston plug that moves axially within the diffuser to selectively cover rows of outlets to vary steam injection. The piston plug has first and second annular seals and is moved between different axial positions in a stepwise fashion such that when one or more rows of outlets are completely covered, the first annular seal is located in between adjacent rows and the second annular seal abuts against the diffuser to inhibit passage of steam so as to prevent cavitation. The DSI heater can include various other features, such as particular seal unit constructions and diffuser outlet configurations.

Abstract: There is described a microwave pyrolysis process for the depolymerization of plastic for the production of monomers, waxes and heavy oils including the steps of: a) steam purge of the plastic from about 0.5% to about 50% w/w of a catalyst, in a media; b) pyrolysis of the plastic and the catalyst in the media with a microwave (MW) for a time sufficient to allow generation of heat providing a thermal treatment between 300° C. and 650° C. through absorption of microwaves by the catalyst and the media. The catalyst includes a compound having a high dielectric loss at the frequency of the MW to absorb microwaves, transfer heat to the plastic and initiate a pyrolysis reaction.

Abstract: Provided are a carbon-based noble metal-transition metal composite catalyst enabling high selective conversion of a carboxylic acid functional group into an alcohol functional group by pre-treating a carbon carrier including a predetermined ratio or more of mesopores, and a production method therefor.

Abstract: Commercially beneficial carbon-containing fractions can be recovered from hydrothermal liquefaction reactions in various types of processors. Feedstock slurry from waste solids is placed into a pressurized processor where it is maintained at temperature and pressure for a predetermined period. On discharge from the processor the processed discharge is separated into liquid and solid fractions. Gaseous fractions including carbon dioxide can also be removed or off-taken from the processor. New molecular structures are created in this reaction, resulting in fractions including biogas, biofuels, biosolids and biocrude. Silica, phosphates, potash and low concentration nitrogen based fertilizer, along with carbonaceous material can also be recovered.

Abstract: The present invention pertains to improved processes and catalysts for aromatization. The processes generally contacting a feed stream comprising a naphtha fraction having a C6 to C8 content with a catalyst pellet composition to form aromatic hydrocarbons. The catalyst pellet composition generally comprises a plurality of cylindrical pellets each pellet comprising a Group VIII metal on a zeolite. The pellets may have (a) a plurality of holes passing through the length of the cylindrical pellets, (b) a dome-shaped top and bottom, and (c) a plurality of semi-circular grooves along the length of the exterior of the cylinder.