Abstract: This invention relates a wax inhibitor for hydrocarbon oils comprising an esterified copolymer having repeating structural units derived from an esterified ethylenically unsaturated dicarboxylic acid and ?-olefins having at least 18 carbon atoms, whereof at least 3 mol-% of the ?-olefins have 30 or more carbon atoms, and wherein the ethylenically unsaturated dicarboxylic acid has been esterified with a mixture of alcohols comprising i) 70 to 97 mol-% of a saturated fatty alcohol having 18 to 24 carbon atoms and ii) 3 to 30 mol-% of an unsaturated alcohol having 16 to 24 carbon atoms.
Type:
Grant
Filed:
April 21, 2021
Date of Patent:
July 4, 2023
Assignee:
CLARIANT INTERNATIONAL LTD
Inventors:
Anton Kaiser, Michael Feustel, Christoph Kayser, Matthias Krull, Michael Schaefer, Rashod Smith
Abstract: A catalytic microscale reactor with spiral reactor geometry may have a high surface area to volume ratio, high catalytic surface area, high heat transfer surface area, long residence time, and high single pass conversion. The catalytic surface may be treated with microsphere spacer particles which serve to maintain the space between them at an engineered distance without the need for precise manufacturing techniques. The design of the reactor may allow for a catalyst surface to be removed, uncoiled, refurbished, and recoiled in an automated continuous process. An automated continuous process may be suitable both for initially preparing a new catalytic surface as well as refurbishing a fouled catalytic surface and may reduce the time and cost to prepare a new surface.
Abstract: The present invention relates to a process for the production of polymers from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by treatment of a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to a separation unit; (f) performing a separation operation in the separation unit to obtain a product stream E comprising a monomer; (g) supplying the product stream E to a polymerisation reactor; and (h) performing a polymerisation reaction in the polymerisation reactor to obtain an polymer.
Type:
Grant
Filed:
January 24, 2020
Date of Patent:
June 27, 2023
Assignee:
SABIC GLOBAL TECHNOLOGIES B.V.
Inventors:
Anthoni Van Zijl, Nicolas Goyheneix, Lara Galan-Sanchez, Christoph Roosen, Johan Pastwa, Safa Farajzadeh Bibalan
Abstract: The present invention relates to a catalyst for preparing a light olefin, a preparation method therefor, and a method for preparing a light olefin by using same, and can provide a catalyst for preparing a light olefin, a preparation method therefor, and a method for preparing a light olefin by using same, the catalyst comprising a porous zeolite, a clay, an inorganic oxide binder, and Ag2O and P2O5 which are supported in the pores and/or on the surface of the porous zeolite.
Type:
Grant
Filed:
May 2, 2019
Date of Patent:
June 20, 2023
Assignee:
KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY
Inventors:
Na Young Kang, Yong Ki Park, Yu Jin Lee
Abstract: The present invention deals with catalysts for the conversion of CO by the shifting reaction of high temperature water gas, free from chromium and iron, consisting of alumina promoted by potassium, by zinc and copper oxides and in a second embodiment also additionally nickel. The catalysts thus prepared maintain high CO conversion activity, not having the environmental limitations or operating limitations with low excess steam in the process, which exist for catalysts in accordance with the state of the art. Such catalysts are used in the hydrogen or synthesis gas production process by the steam reforming of hydrocarbons, allow the use of low steam/carbon ratios in the process, exhibiting high activity and stability to thermal deactivation and lower environmental restrictions for production, storage, use and disposal, than the industrially used catalysts based on iron, chromium, and copper oxides.
Abstract: A nanocatalyst including single atoms of platinum dispersed on a nanoscale metal oxide, and the nanocatalyst comprises 0.01 wt % to 1 wt % platinum. Preparing the nanocatalyst includes combining a solution comprising a nanoscale metal oxide and a compound containing a Group 10 metal to yield a mixture, aging the mixture for a length of time, filtering the mixture to yield a solid, washing the solid to eliminate water soluble anions, and calcining the solid to yield a nanocatalyst including single atoms or clusters of atoms of the Group 10 metal on the nanoscale metal oxide.
Type:
Grant
Filed:
June 6, 2022
Date of Patent:
June 6, 2023
Assignee:
Arizona Board of Regents on behalf of Arizona State University
Abstract: An integrated process that is operated to create both a higher value pipelineable crude and a higher value carbon fiber product from a lower value common heavy hydrocarbon feedstock where the feedstock is processed in a thermal reactor followed by a solvent deasphalting unit with the liquids being gathered and processed to reduce olefins for pipeline transport and the solids are processed to generate a marketable carbon fiber product with any gases generated throughout the entire process reused in the process or sold.
Type:
Grant
Filed:
August 22, 2022
Date of Patent:
June 6, 2023
Inventors:
Tom Corscadden, Darius Remesat, David Denton
Abstract: The present invention provides an improved catalytic fast pyrolysis process for increased yield of useful and desirable products. In particular, the process comprises an improved catalytic fast pyrolysis process for producing aromatic compounds, such as, for example, benzene, toluene and xylenes, from biomass feedstock containing impurities, such as, for example alkali and alkaline earth metal, sulfur and nitrogen components.
Type:
Grant
Filed:
June 2, 2020
Date of Patent:
May 30, 2023
Assignee:
Anellotech, Inc.
Inventors:
Jian Shi, Charles Sorensen, Terry Mazanec, Ruozhi Song, Sandeep Goud, Scott Han, Yu-Ting Cheng, Victoria L. Frank, William F. Igoe, Jr., Marc Schneidkraut
Abstract: Alumina support compositions comprising at least 0.1 wt % of silica are disclosed. The alumina support are characterized by a pore volume of greater than 0.60 cc/g, a median pore size ranging from about 70 to about 120, a pore size distribution such that at least 90% of the total pore volume falls within the range of about 20 to about 250, and a pore size distribution width of no less than about 40. Alumina compositions of the present invention exhibit a primary peak mode at a pore diameter less than the median pore diameter. Also provided are catalysts made from the alumina supports, and processes of preparing and using the supports and catalysts.
Type:
Grant
Filed:
August 3, 2021
Date of Patent:
May 9, 2023
Assignee:
Advanced Refining Technologies LLC
Inventors:
Xianghua Yu, Bruno Nesci, Roberto Romero, Gill M. Malick, Jifei Jia, Cecelia A. Radlowski
Abstract: This invention provides supported catalysts comprising a carrier, phosphorus, at least one Group VI metal, at least one Group VIII metal, and a polymer. In the supported catalyst, the molar ratio of phosphorus to Group VI metal is about 1:1.5 to less than about 1:12, the molar ratio of the Group VI metal to the Group VIII metal is about 1:1 to about 5:1, and the polymer has a carbon backbone and comprises an amido group. Also provided are a process for preparing such supported catalysts, as well as methods for hydrotreating, hydrodenitrogenation, and/or hydrodesulfurization, using supported catalysts.
Type:
Grant
Filed:
November 5, 2021
Date of Patent:
April 25, 2023
Assignee:
ALBEMARLE CATALYSTS COMPANY B.V.
Inventors:
Bastiaan Maarten Vogelaar, Tjøstil Vlaar, Viktoria Andreevna Renkema-Krysina, Vincentius Theodorus Maria Raven
Abstract: Processes for forming multimetallic catalysts by grafting nickel precursors to metal oxide supports. Dry reforming reaction catalysts having nickel and promotors grafted to metal oxides supports. Methanation reaction catalysts having nickel and promotors grafted to metal oxides supports.
Abstract: This disclosure relates to the production of chemicals and plastics using pyrolysis oil from the pyrolysis of plastic waste as a co-feedstock along with a petroleum-based, fossil fuel-based, or bio-based feedstock. In an aspect, the polymers and chemicals produced according to this disclosure can be certified under International Sustainability and Carbon Certification (ISCC) provisions as circular polymers and chemicals at any point along complex chemical reaction pathways. The use of a mass balance approach which attributes the pounds of pyrolyzed plastic products derived from pyrolysis oil to any output stream of a given unit has been developed, which permits ISCC certification agency approval.
Type:
Grant
Filed:
September 23, 2022
Date of Patent:
April 4, 2023
Assignee:
CHEVRON PHILLIPS CHEMICAL COMPANY LP
Inventors:
Ronald G. Abbott, Scott G. Morrison, Steven R. Horlacher, Jamie N. Sutherland, Bruce D. Murray, Jacob M. Hilbrich, Charles T. Polito
Abstract: The treatment unit includes an evaporation device including a gas circulation pipe, and a material with a large specific surface filling an evaporation section of the circulation pipe; a device for circulating the gas through the circulation pipe; a liquid impregnating the material with a large specific surface, the liquid containing at least one product or a mixture of volatile biocide and/or phytoprotective products, with a boiling temperature between 130 and 280° C., the material with a large specific surface having a liquid retention capacity greater than 50 L/m3 of material with a large specific surface at 20° C.; a recharging device, arranged to re-impregnate the material with a large specific surface with liquid or to replace the spent material with a large specific surface with a new material with a large specific surface impregnated with liquid.
Type:
Grant
Filed:
June 27, 2018
Date of Patent:
March 28, 2023
Assignee:
XEDA INTERNATIONAL S.A.
Inventors:
Alberto Sardo, Stefano Sardo, Laura Paitel
Abstract: A process for preparation of catalyst to produce ultra-low sulfur diesel (ULSD) from high refractory sulfur feedstock. The catalyst composition comprises a modified alumina carrier, impregnated by metal of group VIB is in the range of 15-25% and metal of group VIIIB is in the range of 1-5% as oxides. The catalyst prepared in the present invention produces highly dispersed MoS2 active sites on the modified carrier. The catalyst produces ultra low sulfur diesel (ULSD) along with improved cetane, density reduction and endpoint reduction.
Type:
Grant
Filed:
August 27, 2021
Date of Patent:
March 28, 2023
Assignee:
INDIAN OIL CORPORATION LIMITED
Inventors:
Ramasubramanian Kanthasamy, Kochappilly Ouseph Xavier, Mani Karthikeyan, Alex Cheru Pulikottil, Madhusudan Sau, Gurpreet Singh Kapur, Sankara Sri Venkata Ramakumar
Abstract: Copper sulfide of the formula CuxSy, wherein x and y are integer or non-integer values, wherein (i) the copper sulfide has a sulfur 2p XPS spectrum with peaks at 162.3 eV (±1 ev), 163.8 eV (±1 ev) and 68.5 eV (±1 ev), characterised in that the peak at 168.5 eV has a lower value of counts per second (CPS) than both the peak at 162.3 eV and the peak at 163.8 eV; and (ii) the copper sulfide has a copper 2p XPS spectrum with peaks at 932.0 eV (±2 ev) and 933.6 eV (±3 eV) and characterised in that the XPS spectrum does not comprise identifiable satellite peaks at 939.8 eV and 943.1 eV (±3 eV).
Type:
Grant
Filed:
August 1, 2018
Date of Patent:
March 28, 2023
Assignee:
PETROLIAM NASIONAL BERHAD (PETRONAS)
Inventors:
Kenneth Seddon, Geetha Srinivasan, Mohammad Syamzari Rafeen, Kuah Yong Cheun, Amiruddin Hassan, Adi Aizat Razali, Sharizal Bin Mohd Azam Shah Wong
Abstract: Supported catalysts include a solid support, a metal-ligand complex tethered to a surface of the solid support through at least two surface reactive moieties of the metal-ligand complex, and a conformationally stable molecular pore defined between the metal-ligand complex and the surface of the solid support. The metal-ligand complex includes a catalytic metal center, such as a transition metal, coordinated with multiple monodentate ligands, a multidentate ligand, or a combination thereof. The ligands include a tethering portion that is terminated by a surface reactive moiety tethered to the surface of the solid support by a surface interaction. By tailoring the tethering portion, a volume of the molecular pore may be provided that is selective and suitable for a chosen reactant or a chosen reaction type.
Abstract: Provided are a method for producing a purified Salacia genus plant extract having improved flavor by increasing the ?-glucosidase inhibitory activity of the extract without significantly reducing the recovery rate of the extract concomitantly with purification; and a purified Salacia genus plant extract. The method for producing a purified Salacia genus plant extract includes an extraction step of bringing a Salacia genus plant-containing raw material extract including at least one of a Salacia genus plant, a Salacia genus plant extract, and a Salacia genus plant ground product, into contact with 0.1 to 20 mass % of activated carbon in the presence of an extraction solvent.
Abstract: A process to catalytically transform natural gas liquid (NGL) into higher molecular weight hydrocarbons includes providing an NGL stream, catalytically dehydrogenating at least a portion of the NGL stream components to their corresponding alkene derivatives, catalytically oligomerizing at least a portion of the alkenes to higher molecular weight hydrocarbons and recovering the higher molecular weight hydrocarbons. The NGL stream can be extracted from a gas stream such as a gas stream coming from shale formations. The higher molecular weight hydrocarbons can be hydrocarbons that are liquid at ambient temperature and ambient pressure.
Type:
Grant
Filed:
September 6, 2018
Date of Patent:
March 14, 2023
Assignee:
PURDUE RESEARCH FOUNDATION
Inventors:
Rakesh Agrawal, Jeffrey J. Siirola, Taufik Ridha, Yiru Li, Fabio H. Ribeiro, Jeffrey T. Miller
Abstract: A method of fabricating a carbon nanotube (“CNT”) array includes providing a substrate with a CNT catalyst disposed on a surface of the substrate, heating the CNT catalyst to an annealing temperature, exposing the CNT catalyst to a CNT precursor for an exposure period to pre-load the CNT catalyst, and exposing the pre-loaded CNT catalyst to a carbon source for a growth period to form the CNT array. The formed CNT array comprises a plurality of CNT bundles that are aligned with one another in an alignment direction. At least one of the plurality of bundles comprises an average structural factor of 1.5 or less along an entirety of the length thereof.
Type:
Grant
Filed:
March 31, 2021
Date of Patent:
March 14, 2023
Assignees:
Toyota Motor Engineering & Manufacturing North America, Inc., Vanderbilt University
Inventors:
Yuyang Song, Shailesh N. Joshi, Piran R. Kidambi, Peifu Cheng
Abstract: A catalyst has a modified silica support and comprises a modifier metal, zirconium and/or hafnium, and a catalytic metal on the modified support. The catalyst has at least a proportion, typically, at least 25%, of modifier metal present in moieties having a total of up to 2 modifier metal atoms. The moieties may be derived from a monomeric and/or dimeric cation source. A method of production:— provides a silica support with isolated silanol groups with optional treatment to provide isolated silanol groups (—SiOH) at a level of <2.5 groups per nm2; contacting the optionally treated silica support with a monomeric zirconium or hafnium modifier metal compound to effect adsorption onto the support; optionally calcining the modified support for a time and temperature sufficient to convert the monomeric zirconium or hafnium compound adsorbed on the surface to an oxide or hydroxide of zirconium or hafnium in preparation for catalyst impregnation.
Type:
Grant
Filed:
September 13, 2018
Date of Patent:
March 14, 2023
Assignee:
MITSUBISHI CHEMICAL UK LIMITED
Inventors:
Adam Cullen, David William Johnson, Ian Andrew York