Abstract: Disclosed are compounds, methods, reagents, systems, and kits for the preparation and utilization of monomeric or polymeric metal-based compounds. These metal-based compounds are organometallic catalysts composed of substituted dipyrrin ligands bound to transition metals. C—H bond functionalization catalysis can be performed with the disclosed organometallic catalysts to yield C—N bonds to generate substituted bicyclic, spiro, and fused nitrogen-containing heterocycles, all common motifs in various pharmaceutical and bioactive molecules.
Type:
Grant
Filed:
September 19, 2019
Date of Patent:
March 5, 2024
Assignee:
President and Fellows of Harvard College
Abstract: Animal litter comprising composite particles including powdered sodium bentonite and powdered activated carbon, agglomerated together into the composite particles, wherein the animal litter has a particle size distribution of 16/50 mesh (i.e., 300 ?m to 1180 ?m in size). The litter may include non-composite, granular clay particles (e.g., granular sodium bentonite) having the same particle size distribution (16/50 mesh). Such particle size characteristics significantly reduce dusting, without the need for a de-dusting agent, reduce clump depth and/or reduce clump width at the bottom of the clump (both acting to reduce risk of clumps sticking to the bottom of the litter box) and result in more efficient use of the litter in clumping (reduced clump weight) by increasing absorbency.
Type:
Grant
Filed:
December 4, 2020
Date of Patent:
March 5, 2024
Assignee:
THE CLOROX COMPANY
Inventors:
Anisa M. Nuanes, Jacob L. Orlowicz, Robert W. Peugh, Donald K. Swatling, Ahmed Drief
Abstract: The invention provides a process for regenerating a catalyst used for the hydrogenation of an aromatic species, consisting of several steps. First the system is purged with nitrogen, then air is metered in stepwise, and the addition of nitrogen is subsequently ended until only air is present.
Type:
Grant
Filed:
December 10, 2021
Date of Patent:
March 5, 2024
Assignee:
Evonik Operations GmbH
Inventors:
Johan Anton, Michael Grass, Johannes Kraft, Thomas Schneider, Grzegorz Ziomek
Abstract: Disclosed herein are hydrocarbon based compositions derived from pyrolysis of a feedstock comprising post-consumer and/or post-industrial plastics and methods of making and use thereof.
Abstract: Disclosed herein are hydrocarbon based compositions derived from pyrolysis of a feedstock comprising post-consumer and/or post-industrial plastics and methods of making and use thereof.
Abstract: Provided are an ammonia decomposition catalyst and a method of decomposing ammonia. The ammonia decomposition catalyst includes an activated carbon carrier and a metal loaded on the carrier, wherein a Brunauer, Emmett and Teller (BET) specific surface area of the carrier is about 850 m2/g or more, and the metal includes cerium (Ce).
Type:
Grant
Filed:
April 5, 2022
Date of Patent:
January 30, 2024
Assignees:
SAMSUNG ENGINEERING CO., LTD., EST CO., LTD.
Inventors:
Jae Rim Yi, Sung Soo Lee, Sung Hun Hong, Jae Hun Hong, Sang Youp Hwang, Jae Kyeong Yoo, Sung Eun Jeoung, Jae Hoon Choi, Sang Bock Lee, Jung Jae Kim
Abstract: A system and method of distilling/desalinating water in a vacuum-applied multi-phase manner purifies water of its dissolved and/or undissolved contaminants. The system includes at least one primary vessel, at least one vacuum apparatus, and at least one secondary vessel. The primary vessel initially retains a quantity of source water. A vacuum pressure is then generated inside the primary vessel with the vacuum apparatus, which evaporates a first water portion off the source water and freezes a second water portion on the source water. The first water portion is then condensed inside the secondary vessel. After the remaining source water is drained out of the primary vessel, the first water portion in its liquid state is transferred into the primary vessel and poured onto the second water portion in its solid state, which melts the first water portion and the second water portion together to be a quantity of purified water.
Abstract: The present invention relates to a catalyst for a hydrocarbon resin hydrogenation reaction and a preparation method for the same, wherein the catalyst is a nickel powder catalyst including nickel (Ni), copper (Cu), and sulfur (S), and more particularly, a nickel-based catalyst for a hydrogenation reaction, which is added to a hydrogenation reaction in order to improve the color of the hydrocarbon resin. According to an embodiment of the present invention, provided is a catalyst for a hydrogenation reaction, includes 40-80 parts by weight of nickel, 0.01-5 parts by weight of copper, 1-10 parts by weight of sulfur, and 10-60 parts by weight of a silica support based on 100 parts by weight of the entire dried catalyst including a support. Therefore, the catalyst can improve the quality of hydrocarbon resin. Furthermore, the catalyst can provide colorless, odorless, and transparent water-white hydrocarbon resin with improved thermal stability by removing unsaturated bonds in the hydrocarbon resin.
Type:
Grant
Filed:
October 28, 2019
Date of Patent:
January 23, 2024
Assignee:
HANWHA SOLUTIONS
CORPORATION
Inventors:
Woo Jin Park, Yong Hee Lee, Bong Sik Jeon, Eui Geun Jung, Wan Jae Myeong
Abstract: A catalytic conversion process for producing gasoline and propylene includes the steps of 1) subjecting a feedstock oil to a first catalytic conversion reaction in a first catalytic conversion reaction device to obtain a first reaction product; 2) separating the first reaction product to obtain a propylene fraction, a gasoline fraction and a fraction comprising C4 olefin; 3) carrying out an oligomerization reaction on the fraction comprising C4 olefin in an oligomerization reactor to obtain an oligomerization product comprising C12 olefin, and optionally separating the oligomerization product to obtain a fraction comprising C12 olefin; 4) recycling the C12 olefin-containing oligomerization product or fraction to the first catalytic conversion reaction device, and/or sending the C12 olefin-containing oligomerization product or fraction to a second catalytic conversion reaction device for a second catalytic conversion reaction to obtain a second reaction product comprising propylene.
Type:
Grant
Filed:
March 17, 2020
Date of Patent:
January 16, 2024
Assignees:
CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
Abstract: Provided herein are methods and systems of making a high quality isoparaffinic base stock which include contacting an adsorbent material with a hydrocarbon feedstock and a solvent and separating at least some of the one or more high VI components from the hydrocarbon feedstock to produce a first fraction base stock having a first fraction base stock viscosity index. The adsorbent material is desorbed with a second solvent to produce a second fraction base stock having a second fraction base stock viscosity index. In these methods, the first fraction base stock viscosity index is less than the hydrocarbon feedstock viscosity index and the second fraction base stock viscosity index is greater than the hydrocarbon feedstock viscosity index.
Type:
Grant
Filed:
May 19, 2022
Date of Patent:
January 16, 2024
Assignee:
EXXONMOBIL TECHNOLOGY AND ENGINEERING COMPANY
Inventors:
Randall D. Partridge, Changyub Paek, Yogesh V. Joshi, Carmen C. Lasso, Scott J. Weigel
Abstract: Process for preparing a catalyst containing an active phase based on a group VIII metal and a porous support, comprising the following steps: bringing said support into contact with an organic compound comprising at least oxygen and/or nitrogen; bringing the porous support into contact with a solution containing a precursor of the active phase comprising a group VIII metal; drying the catalyst precursor at a temperature of less than 200° C. so as to obtain a dried catalyst precursor; calcining the dried catalyst precursor at a temperature of between 200° C. and 1100° C. under a stream of inert gas and/or of oxidizing gas, it being understood that the velocity of said gas stream, defined as the mass flow rate of said gas stream per volume of catalyst per hour, is greater than 1 litre per gram of catalyst and per hour.
Abstract: Disclosed is a hydrocarbon composition containing isomerised paraffins having specific cut-off points in a distillation curve, a density from 768.0 to 772.0 and an average carbon number of 14.3 to 15.1. The hydrocarbon composition can be used as a fuel or fuel component, especially a jet fuel. Disclosed is also a method to produce a hydrocarbon composition. The isomerised paraffins in the hydrocarbon composition can be from a renewable source.
Type:
Grant
Filed:
November 18, 2020
Date of Patent:
January 2, 2024
Assignee:
NESTE OYJ
Inventors:
Kati Sandberg, Väinö Sippola, Janne Suppula, Jesse Vilja
Abstract: A method for thermal processing and catalytic cracking of a biomass to effect distillate oil recovery can include, particle size reduction. slurrying the biomass with a carrier fluid to create a reaction mixture, slurrying a catalyst with a carrier fluid to create a catalyst slurry, heating the reaction mixture and/or the catalyst slurry, and depolymerizing the reaction mixture with the catalyst. The reaction mixture can undergo distillation and fractionation to produce distillate fractions that include naphtha, kerosene, and diesel. In some embodiments, thermal processing and catalytic cracking includes vaporization of the biomass followed by distillation and fractionation. In some embodiments, a resulting distillate can be used as a carrier fluid. In some embodiments, the method can include desulfurization, dehydration, and/or decontamination.
Type:
Grant
Filed:
February 22, 2021
Date of Patent:
January 2, 2024
Assignee:
Cielo Waste Solutions Corp.
Inventors:
Roderick Michael Facey, Clayton Donald Allan
Abstract: Provided are beads for blood processing having porous beads and a polymer carried on the surface of the porous beads, wherein: the porous beads are configured from at least one resin selected from the group consisting of acrylic resins, styrene resins, and cellulose resins; and the polymer includes a specific monomer defined in the description as a monomer unit.
Abstract: Systems and methods for processing full range naphtha feeds to produce a light olefins stream and an aromatics stream are described. In particular, the invention concerns integration of catalytic cracking with steam cracking to maximize production of aromatics.
Abstract: Provided are beads for blood processing having porous beads and a polymer carried on the surface of the porous beads, wherein: the porous beads are configured from at least one resin selected from the group consisting of acrylic resins, styrene resins, and cellulose resins; and the polymer includes a specific monomer defined in the description as a monomer unit.
Abstract: An ammonia synthesis catalyst, includes a composite oxide carrier in which at least one additive metal element selected from the group consisting of titanium (Ti), zirconium (Zr), hafnium (Hf), aluminum (Al), gallium (Ga), indium (In), silicon (Si), germanium (Ge), and tin (Sn) is solid-solutionized in a composite oxide containing cerium (Ce) and a lanthanide other than Ce and having a composition represented by the following formula: CexA1-x-yByOd (in the formula, A represents a lanthanide other than Ce, B represents the additive metal element, x represents a molar fraction of Ce, y represents a molar fraction of the additive metal element, 1?x?y represents a molar fraction of a lanthanide other than Ce, x and y satisfy 0.1?x?0.9, 0.01?y?0.3, and 0.11?x+y?0.91, d represents a molar ratio of oxygen atoms, and 1.5?d?2 is satisfied); and ruthenium (Ru) supported on the composite oxide carrier.
Abstract: The present invention relates to the use of n-butyllithium for catalyzing the hydroboration of an imine and a borane. A catalyst, the borane and the imine are sequentially stirred and mixed uniformly, and are reacted for 1-2 h; the mixture is exposed to air to terminate the reaction; and the reaction liquid is subjected to reduced pressure to remove the solvent, so as to obtain a borate with different substituents. The n-butyllithium disclosed in the present invention can be used for catalyzing the hydroboration of the imine and the borane in high activity under room temperature conditions, the amount of the catalyst is only 4-5 mol % of the molar weight of the imine, and the yield of the reaction can reach 90% or more.
Abstract: The present invention relates to a method for producing mixtures of hydrocarbons and aromatic compounds, for use as fuel components (preferably in the range C5-C16), by means of catalytic conversion of the oxygenated organic compounds contained in aqueous fractions derived from biomass treatments, wherein said method can comprise at least the following steps: (i) bringing the aqueous mixture containing the oxygenated organic compounds derived from biomass in contact with a catalyst comprising at least Sn and Nb, Sn and Ti, and combinations of Sn, Ti and Nb; (ii) reacting the mixture with the catalyst in a catalytic reactor at temperatures between 100 and 350° C. and under pressures from 1 to 80 bar in the absence of hydrogen; and (iii) recovering the products obtained by means of the liquid/liquid separation of the aqueous and organic phases.
Type:
Grant
Filed:
May 23, 2019
Date of Patent:
December 12, 2023
Assignees:
CONSEJO SUPERIOR DE INVESTIGACIONES CIENTIFICAS, UNIVERSITAT POLITECNICA DE VALENCIA
Inventors:
Marcelo Eduardo Domine, Alberto Fernández-Arroyo Naranjo, José Manuel López Nieto