Patents Examined by Bryant Young
  • Patent number: 6183884
    Abstract: A metallic article includes a bond coating and a ceramic thermal barrier coating on the bond coating. The ceramic thermal barrier coating includes a plurality of columnar grains, which extend perpendicularly to the surface of the metallic article. Each columnar grain includes a plurality of layers. Some of the layers include sub-grains extending at an acute angle to the surface of the metallic article to form voids between adjacent sub-grains. The voids are arranged at an acute angle to the surface of the metallic article and reduce the thermal conductivity of the ceramic thermal barrier coating. Some of the layers include sub-grains extending perpendicularly to the surface of the metallic article to provide erosion resistance.
    Type: Grant
    Filed: December 16, 1998
    Date of Patent: February 6, 2001
    Assignees: Rolls-Royce PLC, Chromalloy United Kingdom Limited
    Inventor: David S Rickerby
  • Patent number: 6183871
    Abstract: A sealing glass paste which comprises at least one sealing glass frit powder and an aqueous binder which comprises an aqueous solution, dispersion or emulsion of a polymeric material and a water soluble oxidant which decomposes at a temperature of below 475° C., the polymeric material burning out or decomposing at a temperature of below 475° C., in the presence of the oxidant, to leave less than 2% of residues based on the total weight of the solids content of the binder. The sealing glass pastes may be used in the assembly of cathode ray tubes. The aqueous binder system which is used results in low carbonaceous residue levels after firing and does not contain volatile organic solvents. Furthermore, using this aqueous binder system sealing glass pastes can be prepared with sealing glasses which include PbO therein.
    Type: Grant
    Filed: June 29, 1998
    Date of Patent: February 6, 2001
    Assignee: Fry's Metals, Inc.
    Inventors: Warren Lee, Jason Robert Brewer
  • Patent number: 6180260
    Abstract: A method for providing a substantially-smooth protective coating on a metal-based substrate is disclosed. It comprises the steps of: (a) applying a thermal barrier coating over the substrate by plasma-spraying; (b) plasma-heating the applied coating according to a time- and temperature schedule sufficient to re-melt the surface region of the coating, allowing it to flow and smoothen; and then (c) cooling the surface region to a temperature below its melting point. The thermal barrier coating is often zirconia-based, e.g., yttria-stabilized zirconia. After being cooled, the surface is much smoother than when originally applied, thereby allowing the coating to be used in a higher-temperature environment.
    Type: Grant
    Filed: June 3, 1999
    Date of Patent: January 30, 2001
    Assignee: General Electric Company
    Inventors: Dennis Michael Gray, Wayne Charles Hasz, Timothy Francis Bethel, Curtis Alan Johnson, Marcus Preston Borom
  • Patent number: 6180218
    Abstract: Radiation stable glass for space applications, especially glass in the form of thin sheet for cladding of spacecraft, is produced by including at least 5% by weight of barium oxide in a borosilicate glass composition. Because barium has a low absorption in the ultra violet, its use enables radiation stable glasses of low ultra violet absorption to be produced, alleviating problems of overheating when the glasses are used for cladding space craft. The glass is useful in the production of solar cell cover slips and second surface mirrors for cladding purposes, and space applications generally.
    Type: Grant
    Filed: January 26, 1999
    Date of Patent: January 30, 2001
    Assignee: Pilkington PLC
    Inventors: Kenneth Melvin Fyles, Helen Louise Eaves, Peter Shorrock
  • Patent number: 6180259
    Abstract: In order to advantageously solve problems such as lowering of the productivity, contamination of alloy coating due to the adoption of different metal, increase of the cost due to the adoption of different coating process, a coating of MCrAlX alloy containing an oxide such as CoO, NiO or the like is directly formed at a thickness of 10˜500 &mgr;m through a low pressure plasma spraying process containing substantially no oxide and thereafter the same MCrAlX alloy xontaining no oxide is applied thereonto at a thickness of 100˜800 &mgr;m through a low pressure plasma spraying process in a non-oxidizing atmosphere to form a composite sprayed coating.
    Type: Grant
    Filed: November 20, 1998
    Date of Patent: January 30, 2001
    Assignee: Tocalo Co., Ltd.
    Inventors: Yoshio Harada, Tatsuo Suizu, Takema Teratani
  • Patent number: 6177186
    Abstract: An air sprayable, fluid, non-metallic coating mixture to provide an article coating having the ability to reflect at least 75% of heat energy in the frequency range of up to 2.6 microns comprises the combination of two different alpha alumina powders. A first powder predominantly is in a particle size range of less than about 1 micron; a second powder is of a particle size greater than 7 times the particle size of the first powder. The mixture includes a glass powder having a melting point of at least about 1400° F. and of a particle size less than about 45 microns. The mixture includes a binder that will form up to about 80% of its weight in silica when heated to a temperature of at least the melting point of the glass powder. In the article coating, provided by air spraying the mixture onto an article and heating to a temperature sufficient to melt the glass powder and to form the silica from the binder, the glass and silica form a matrix about and binding together the alumina powder.
    Type: Grant
    Filed: April 30, 1999
    Date of Patent: January 23, 2001
    Assignee: General Electric Company
    Inventors: Andrew J. Skoog, Norbert O. Maurer, Jane A. Murphy
  • Patent number: 6174608
    Abstract: The present invention provides a ceramic tile and a glaze composition for use in forming the tile. The glaze composition comprises a glass component, an expansion modifier and a spodumene crystallization promoter. The spodumene crystallization promoter comprises a material that promotes the formation of beta spodumene during the firing of the glaze composition.
    Type: Grant
    Filed: November 12, 1998
    Date of Patent: January 16, 2001
    Assignee: Ferro (Italia) SRL
    Inventors: Paolo Bertocchi, Emanuela Neri, Bruno Burzacchini, Marzia Barattini
  • Patent number: 6174583
    Abstract: An aluminum nitride sintered body has characteristics such that an amount of total metal elements other than aluminum is smaller than 100 ppm, and a volume resistivity at room temperature is greater than 1.0×109 &OHgr;·cm and is smaller than 1.0×1013 &OHgr;·cm. A metal including member has such a construction that a metal member is embedded in the aluminum nitride sintered body mentioned above. An electrostatic chuck is made by the metal including member mentioned above. In the metal including member mentioned above in which the metal member is embedded in the aluminum nitride sintered body mentioned above, a volume resistivity thereof can be controlled without adding a low resistance material in aluminum nitride.
    Type: Grant
    Filed: September 8, 1999
    Date of Patent: January 16, 2001
    Assignee: NGK Insulators, Ltd.
    Inventors: Naohito Yamada, Yukimasa Mori, Yuki Bessho, Hiromichi Kobayashi
  • Patent number: 6168869
    Abstract: The present invention relates to an improvement in an anodic aluminum oxide coating on which microbials are easy to adhere and propagate, for constantly keeping it clean. The present invention provides an anti-microbial aluminum product comprising: a porous oxide coating covering the surface of the aluminum core for the product and an inorganic bacteria controlling ingredient being carried in the micropores of the oxide coating. The anodic oxide coating is preferably sealed.
    Type: Grant
    Filed: May 6, 1998
    Date of Patent: January 2, 2001
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Toshikazu Tomioka, Akihiko Yoshida
  • Patent number: 6168874
    Abstract: A thermal barrier coating system and a method for forming the coating system on a component designed for use in a hostile thermal environment, such as superalloy turbine, combustor and augmentor components of a gas turbine engine. The coating system includes a diffusion aluminide bond coat whose oxide growth rate is significantly reduced to improve the spallation resistance of a thermal barrier layer by forming the bond coat to include a dispersion of aluminum, chromium, nickel, cobalt and/or platinum group metal oxides. The oxides preferably constitute about 5 to about 20 volume percent of the bond coat. A preferred method of forming the bond coat is to initiate a diffusion aluminizing process in the absence of oxygen to deposit a base layer of diffusion aluminide, and then intermittently introduce an oxygen-containing gas into the diffusion aluminizing process to form within the bond coat the desired dispersion of oxides.
    Type: Grant
    Filed: February 2, 1998
    Date of Patent: January 2, 2001
    Assignee: General Electric Company
    Inventors: Bhupendra K. Gupta, Thomas E. Mantkowski, Nripendra N. Das, Raymond W. Heidorn
  • Patent number: 6165628
    Abstract: An article is described, which includes a metal-based substrate, such as a superalloy; a dense, primary bond layer; and a spongy secondary bond layer. A thermal barrier coating is applied over the secondary bond layer. The spongy layer has a microstructure which includes an open network of interconnected pores. A process is also described. It includes the step of applying a spongy, metallic bond layer over the substrate, followed by the application of a thermal barrier coating. A dense, primary bond layer may optionally be applied before the application of the spongy layer.
    Type: Grant
    Filed: August 30, 1999
    Date of Patent: December 26, 2000
    Assignee: General Electric Company
    Inventors: Marcus Preston Borom, Dennis Michael Gray, Yuk-Chiu Lau, Surinder Singh Pabla
  • Patent number: 6159618
    Abstract: This invention relates to a multi-layer material that comprises a substrate made of aluminum, magnesium or their alloys, having possibly been subjected to a surface treatment, this substrate being provided with a coating comprising a tungsten based deposit and an under-layer--inserted between said substrate and said deposit--of a material having mechanical and thermo-mechanical properties intermediate to those of said substrate and said deposit. This under-layer is made up of at least one layer of a material chosen from among chromium, molybdenum, niobium, titanium, zirconium, their nitrides and carbides, solid solutions of carbon and of nitrogen in said metals, and steels and greatly improves the adherence of said coating to said substrate.The invention also relates to the anti-erosion, anti-abrasion, anti-wear coating comprising said tungsten based deposit and said under-layer.
    Type: Grant
    Filed: May 29, 1998
    Date of Patent: December 12, 2000
    Assignee: Commissariat a l'Energie Atomique
    Inventors: Joel Danroc, Pierre Juliet, Andre Rouzaud
  • Patent number: 6156413
    Abstract: A glass circuit substrate wherein nuclei of Pd (palladium) are placed on a glass substrate and a plating layer of Pd--P (palladium--phosphorus) is placed on the nuclei. A fabrication method of the glass circuit substrate comprises steps of forming nuclei of Pd on a glass substrate; and therefore forming a plating layer of Pd--P on the nuclei.
    Type: Grant
    Filed: October 24, 1997
    Date of Patent: December 5, 2000
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yoshiaki Tomari, Makoto Kameyama, Yasuyuki Nakai
  • Patent number: 6150029
    Abstract: A method of forming a film having enhanced reflow characteristics at low thermal budget is disclosed, in which a surface layer of material is formed above a base layer of material, the surface layer having a lower melting point than the base layer. In this way, a composite film having two layers is created. After reflow, the surface layer can be removed using conventional methods.
    Type: Grant
    Filed: September 5, 1997
    Date of Patent: November 21, 2000
    Assignee: Micron Technology, Inc.
    Inventors: Gurtej Sandhu, Randhir P. S. Thakur
  • Patent number: 6136451
    Abstract: A method of improving oxidation resistance of a platinum modified aluminide diffusion coating on a substrate involves electroplating the substrate with a platinum layer from an aqueous hydroxide based electroplating solution and aluminizing the substrate to grow the platinum modified aluminide diffusion coating on said layer. The electroplating solution preferably includes an alkali element and/or alkaline earth element that is incorporated in the platinum layer and in the aluminide diffusion coating formed thereon to significantly improve oxidation resistance of the coating.
    Type: Grant
    Filed: February 3, 1998
    Date of Patent: October 24, 2000
    Assignee: Howmet Research Corporation
    Inventors: Bruce M. Warnes, Thomas A. Legard, Nick S. DuShane, Jack E. Cockerill, Robert W. Beck
  • Patent number: 6132890
    Abstract: In order to advantageously solve problems such as lowering of the productivity, contamination of alloy coating due to the adoption of different metal, increase of the cost due to the adoption of different coating process, a coating of MCrAlX alloy is directly formed on a substrate surface of a member exposed to a high temperature at a thickness of 10.about.300 .mu.m through atmospheric plasma spraying process in air or flame spraying process (including low-velocity flame spraying process, high-velocity flame spraying process) and thereafter the same MCrAlX alloy is applied thereonto at a thickness of 100.about.800 .mu.m through low pressure plasma spraying process in a non-oxidizing atmosphere.
    Type: Grant
    Filed: November 20, 1998
    Date of Patent: October 17, 2000
    Assignee: Tocalo Co., Ltd.
    Inventors: Yoshio Harada, Tatsuo Suizu, Takema Teratani
  • Patent number: 6129976
    Abstract: The exothermic instrument for firing an explosive comprises a circuit board 1 having a heat resist layer 6 on a substrate 11 and an exothermic resistance 4, which connects to a pair of through hole conductive electrodes 13 passing through the substrate 11, contacting with the explosive 19 on the heat resist layer 6, a pair of electrode pins 8, each one thereof is inserted into each one of the through hole conductive electrodes, and an insulator for holding the circuit board 1 through which the electrode pins 8 pass.
    Type: Grant
    Filed: March 10, 1998
    Date of Patent: October 10, 2000
    Assignees: Nikko Company, Nichiyu Giken Kogyo Co., Ltd.
    Inventors: Kiyoshi Mizushima, Mamoru Mouri, Motoharu Miyakoshi, Satoshi Nakamura, Hiroshi Sato, Shinzo Tsuji, Masashi Watanabe, Eiji Arai
  • Patent number: 6129988
    Abstract: The present invention generally describes methods for modifying MCrAlY coatings by using gaseous carburization, gaseous nitriding or gaseous carbonitriding. The modified MCrAlY coatings are useful in thermal barrier coating systems, which may be used in gas turbine engines.
    Type: Grant
    Filed: August 14, 1998
    Date of Patent: October 10, 2000
    Assignee: Siemens Westinghouse Power Corporation
    Inventors: Steven J. Vance, John G. Goedjen, Stephen M. Sabol, Kelly M. Sloan
  • Patent number: 6129991
    Abstract: High temperature oxidation resistance of an aluminide diffusion overcoated MCrAlY coating system is substantially improved by CVD over-aluminizing the MCrAlY type overlay coating under CVD conditions that result in reduced concentrations of such tramp impurities as S and P in the aluminized MCrAlY overlay coating region of the coating system. The CVD aluminizing conditions yield an outwardly grown aluminide over-coat on the underlying MCrAlY type coating.
    Type: Grant
    Filed: August 14, 1997
    Date of Patent: October 10, 2000
    Assignee: Howmet Research Corporation
    Inventors: Bruce M. Warnes, William J. Shriver, Ronald J. Honick, Jr., Nick S. DuShane
  • Patent number: 6127048
    Abstract: An article of manufacture includes a substrate and an anchoring layer disposed on a surface of the substrate. The substrate is capable of developing a first oxide on the surface which is tightly bonded thereto and includes a first metallic element. Alternatively, the surface is formed of the first oxide. The anchoring layer is formed with a ternary oxide of the first metallic element, a second metallic element and oxygen. A second oxide layer, which contains an oxide of the second metallic element, is disposed on the anchoring layer. The anchoring layer is formed on the substrate in a series of process steps, which include: establishing an atmosphere containing oxygen around the article; evaporating a compound of the first metallic element and a compound of the second metallic element into the atmosphere and forming a ternary gas phase containing the first metallic element, the second metallic element and the oxygen; and precipitating the ternary gas phase on the article.
    Type: Grant
    Filed: January 25, 1999
    Date of Patent: October 3, 2000
    Assignee: Siemens Aktiengesellschaft
    Inventor: Wolfram Beele