Patents Examined by Caixia Lu
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Patent number: 11613593Abstract: Metallocene complexes represented by the structure below are useful for alpha olefin oligomerization in the presence of an activator to generate polyalphaolefins having a high percentage of vinylidene termination and relatively low Mn values. M is a group 4 transition metal. A is a bridging group having one bridging atom extending between a first indenyl ring and a second indenyl ring. Each X is independently an anionic ligand, or two Xs are joined and bound to M to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene ligand. R1, R1?, R3, R3?, R4, R4?, R7 and R7? are hydrogen. R5, R5?, R6, and R6? are independently a C1-C10, optionally substituted, hydrocarbyl group, or R5 and R6 and/or R5? and R6? are bonded together to form an optionally substituted hydrocarbyl ring structure.Type: GrantFiled: February 11, 2021Date of Patent: March 28, 2023Assignee: ExxonMobil Chemical Patents Inc.Inventors: Jo Ann M. Canich, Jian Yang, Alexander Z. Voskoboynikov, Andrey F. Asachenko, Oleg V. Samsonov, Georgy P. Goryunov
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Patent number: 11613592Abstract: The present disclosure relates to a Ziegler-Natta catalyst system with self-extinguishing properties suitable for olefin polymerization. The catalyst system of the present disclosure comprises a pro-catalyst, a co-catalyst, and an external donor having a mixture of a selectivity control agent and an activity control agent. The catalyst system of the present disclosure is adapted to prevent the temperature of the polymerization reaction to go beyond the softening temperature of the polymer, thereby exhibiting the self-extinguishing properties.Type: GrantFiled: February 7, 2019Date of Patent: March 28, 2023Assignee: RELIANCE INDUSTRIES LIMITEDInventors: Virendrakumar Gupta, Robert Grubbs, Sunil Dhamaniya
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Patent number: 11608396Abstract: Catalyst systems and methods for making and using the same are disclosed. A catalyst composition is provided that includes a catalyst compound supported to form a supported catalyst system, the catalyst compound including: where each of R1, R2, R3, R4, R5, R6, R7 and X are as discussed herein.Type: GrantFiled: March 15, 2021Date of Patent: March 21, 2023Assignee: Univation Technologies, LLCInventors: Donna J. Crowther, C. Jeff Harlan, Jackie Lovell, Haiqing Peng
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Patent number: 11603419Abstract: The present invention concerns a process for the preparation of a copolymer comprising the steps of copolymerizing under suitable reaction conditions at least one first type of olefin monomer and at least one second type of functionalized olefin monomer using a catalyst system to obtain a polyolefin main chain having one or multiple functionalized short chain branches, the catalyst system comprising: i) a single-site catalyst or catalyst precursor comprising a metal selected from Ti3+ or Cr3+; ii) a co-catalyst; iii) optionally a scavenger.Type: GrantFiled: December 4, 2017Date of Patent: March 14, 2023Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Robbert Duchateau, Miloud Bouyahyi, Lidia Jasinska-Walc
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Patent number: 11597782Abstract: The present disclosure provides methods for producing an olefin polymer by contacting a C3-C40 olefin, ethylene and a diene with a catalyst system including an activator and a metallocene catalyst compound comprising a substituted or unsubstituted indacenyl group and obtaining a C3-C40 olefin-ethylene-diene terpolymer typically comprising from 1 to 35 mol % of ethylene, from 98.9 to 65 mol % C3-C40 olefin, and, optionally, from 0.1 to 10 mol % diene. Preferably, a propylene-ethylene-ethylidene norbornene is obtained.Type: GrantFiled: December 14, 2020Date of Patent: March 7, 2023Assignee: ExxonMobil Chemical Patents Inc.Inventors: Jo Ann M. Canich, John R. Hagadorn, Rhutesh Shah, Florin Barsan, Sarah J. Mattler
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Patent number: 11584845Abstract: This disclosure relates to ethylene interpolymer compositions and films prepared therefrom. Specifically: ethylene interpolymer products having: a dimensionless nonlinear rheology network parameter, ?int., greater than or equal to 0.01, satisfying 0.01×(Z?50)0.78??int.?0.01×(Z?60)0.78 inequality wherein Z is a normalized molecular weight defined by Z = M w M e where Mw and Me are the weight average and entanglement molecular weights, and; a residual catalytic metal of from ?0.03 to ?5 ppm of hafnium. The disclosed ethylene interpolymer products have a melt index from about 0.3 to about 500 dg/minute, a density from about 0.855 to about 0.975 g/cc, a polydispersity, M w M n , from about 1.7 to about 25 and a Composition Distribution Breadth Index (CDBI50) from about 1% to about 98%.Type: GrantFiled: March 22, 2022Date of Patent: February 21, 2023Assignee: NOVA Chemicals (International) S.A.Inventors: Soheil Sadeghi, Fazle Sibtain, Zengrong Zhang, Niousha Kazemi, Monika Kleczek, Vinod Konaganti, Bronwyn Gillon, Shivendra Goyal, Sepideh Kasiri, Stephen Salomons, Kenneth Taylor, Mehdi Keshtkar
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Patent number: 11578156Abstract: Ethylene-based polymers having a density of 0.952 to 0.968 g/cm3, a ratio of HLMI/MI from 185 to 550, an IB parameter from 1.46 to 1.80, a tan ? at 0.1 sec?1 from 1.05 to 1.75 degrees, and a slope of a plot of viscosity versus shear rate at 100 sec?1 from 0.18 to 0.28 are described, with low melt flow versions having a HLMI from 10 to 30 g/10 min and a Mw from 250,000 to 450,000 g/mol, and high melt flow versions having a HLMI from 30 to 55 g/10 min and a Mw from 200,000 to 300,000 g/mol. These polymers have the processability of chromium-based resins, but with improved stress crack resistance and topload strength for bottles and other blow molded products.Type: GrantFiled: October 20, 2020Date of Patent: February 14, 2023Assignee: Chevron Phillips Chemical Company LPInventors: Jeremy M. Praetorius, Yongwoo Inn, Alfred E. Brown, Jr., Brandy Rutledge-Ryal, Carlos A. Cruz, Jay M. Chaffin
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Patent number: 11578148Abstract: A metal complex of the formula (1) TCyLMZp (1), wherein M is a group 4 metal, Z is an anionic ligand, p is the number 1 or 2, TCy is a thiophene-fused cyclopentadienyl-type ligand of the formula (2) is described. Methods of making and using the metal complex are also described.Type: GrantFiled: December 13, 2018Date of Patent: February 14, 2023Inventors: Alexandra Berthoud, Maxence Valla, Georgy P. Goryunov, Oleg V. Samsonov, Dmitry Y. Mladentsev, Dmitry V. Uborsky, Alexander Z. Voskoboynikov
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Patent number: 11572376Abstract: The present invention relates to a novel ligand compound, a transition metal compound and a catalyst composition comprising the same. The novel ligand compound and the transition metal compound of the present invention may be useful as a catalyst of polymerization reaction for preparing an olefin-based polymer having a low density.Type: GrantFiled: February 26, 2021Date of Patent: February 7, 2023Inventors: Yoon Hee Cho, Jae Kwon Jang
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Patent number: 11571686Abstract: The present disclosure provides a method that embodies a simple and effective route to remove homogeneous catalysts from solutions wherein NMR/MRI signal amplification by reversible exchange (SABRE) or parahydrogen-induced polarization (PHIP) is performed. A method for recovering a homogeneous SABRE/PHIP catalyst for reuse is also described.Type: GrantFiled: February 17, 2020Date of Patent: February 7, 2023Assignees: Board of Trustees of Southern Illinois University, Vanderbilt University, The Regents of the University of CaliforniaInventors: Boyd M. Goodson, Eduard Y. Chekmenev, Igor V. Koptyug, Kirill V. Kovtunov, Roman V. Shchepin, Bryce E. Kidd, Jonathan Gesiorski, Max E. Gemeinhardt, Danila A. Barskiy
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Patent number: 11566037Abstract: The present invention describes a process for preparing isopropylidene bis(cyclopentadienyl)zirconium dichloride comprising the steps of: (a) reacting acetone and cyclopentadiene in the presence of sodium methoxide or sodium ethoxide so as to form 2,2-dicyclopentadienylpropane; and (b) reacting said 2,2-dicyclopentadienylpropane with zirconium(IV) chloride in the presence of n-butyl lithium so as to form isopropylidene bis(cyclopentadienyl) zirconium dichloride.Type: GrantFiled: March 16, 2018Date of Patent: January 31, 2023Assignee: LANXESS Organometallics GmbHInventors: Angelika Preetz, Silvia Maus
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Patent number: 11560394Abstract: A metal complex of the formula (1) InCyLMZp (1), wherein M is a group 4 metal, Z is an anionic ligand, p is number of 1 to 2, InCy is an indole fused cyclopentadienyl-type ligand of the formula (2) wherein R1 independently is a C1-C4-alkyl, m is a number of 0 to 4, R2 is a C1-C10-alkyl, C5-C10-cycloalkyl, or a C6-C10-aryl unsubstituted or substituted with C1-C10-alkyl or C1-C4-dialkyl amino, R3, R4 and R5 each is independently selected from hydrogen, C1-C4-alkyl, C6-C10-aryl unsubstituted or substituted with C1-C4-alkyl, halide, or both of C1-C4-alkyl and halide and, L is an amidinate ligand of the formula (3a) wherein the amidine-containing ligand (3a) is bonded to the metal M via the imine nitrogen atom N2, wherein R7 is independently selected from C1-C4-alkyl and halide and q is a number of 0 to 4, Sub4 is a cyclic or linear aliphatic or aromatic substituent.Type: GrantFiled: April 15, 2019Date of Patent: January 24, 2023Inventors: Georgy Pavlovich Goryunov, Oleg Vladimirovich Samsonov, Dmitry Vadimovich Uborsky, Alexander Zel'Manovich Voskoboynikov, Alexandra Berthoud, Maxence Valla
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Patent number: 11560440Abstract: Catalyst system, the catalyst system comprising (i) at least one metallocene complex of formula (I) wherein Mt1 is Hf, X is a sigma-donor ligand, R1, R2, R3 are the same or different from each other and can be hydrogen or a saturated linear or branched C1-C10 alkyl, whereby the alkyl group can optionally contain up to 2 heteroatoms belonging to groups 14-16 of the periodic table, or R1 and R2 or R2 and R3 can form a ring having 4 to 6 C-atoms and 1 to 3 double bonds, R4 and R5 are the same or different from each other and can be saturated linear or branched C1-C10 alkyl, C5-C10 aryl, C6-C20 alkylaryl or C6-C20 arylalkyl groups, which can optionally contain up to 2 heteroatoms belonging to groups 14-16 of the periodic table, n can be 1 to 5, Ar is a C6-C20-aryl or -heteroaryl group, which can be unsubstituted or substituted by 1 to 5 linear or branched C1-C10 alkyl group(s), and (ii) an aluminoxane cocatalyst and (iii) optionally an aluminium alkyl compound AI(R7)3, with R7 being a linear or branched C2-C8-alkType: GrantFiled: March 28, 2018Date of Patent: January 24, 2023Assignee: Borealis AGInventors: Luigi Maria Cristoforo Resconi, Noureddine Ajellal, Anna Fait, Irfan Saeed, Maria Ranieri, David Quin, Vyatcheslav V. Izmer, Dmitry S. Kononovich, Oleg Samsonov, Alexander Z. Voskoboynikov
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Patent number: 11560441Abstract: The present disclosure relates to a method for preparing a polyolefin using a supported hybrid metallocene catalyst. According to the present disclosure, a polyolefin having a narrow molecular weight distribution can be prepared very effectively by introducing a cocatalyst in an optimum content in the presence of a supported hybrid metallocene catalyst containing two or more metallocene compounds having a specific chemical structure. The polyolefin prepared according to the present disclosure exhibits excellent uniformity in chlorine distribution in polyolefin during chlorination, thereby significantly improving elongation of the chlorinated polyolefin, compatibility with PVC and impact reinforcing performance. Thus, it exhibits excellent chemical resistance, weather resistance, flame retardancy, processability and impact strength reinforcing effect, and can be suitably applied as an impact reinforcing agent for PVC pipes and window profiles.Type: GrantFiled: January 9, 2019Date of Patent: January 24, 2023Inventors: Bog Ki Hong, Jin Young Park, Si Jung Lee, Yi Young Choi, Soung Hun Yoo, Sunghyun Park, Chang Woan Han, Sun Mi Kim
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Patent number: 11542352Abstract: The present invention relates to an olefin-based polymer, which has (1) a density (d) ranging from 0.85 to 0.90 g/cc, (2) a melt index (MI, 190° C., 2.16 kg load conditions) ranging from 0.1 g/10 min to 15 g/10 min, (3) the density (d) and the melt temperature (Tm) satisfying Tm (° C.)=a×d?b of Equation 1 (2,350<a<2,500, and 1,900<b<2,100), and (4) a ratio (hardness/Tm) of the hardness (shore A) to the melt temperature (Tm) in a range of 1.0 to 1.3. The olefin-based polymer according to the present invention exhibits excellent anti-blocking properties due to having improved hardness as a low-density olefin-based polymer.Type: GrantFiled: December 24, 2018Date of Patent: January 3, 2023Inventors: Sang Eun Park, Eun Jung Lee, Hyun Jin Ju, In Sung Park, Kyung Bok Bae, Choong Hoon Lee
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Patent number: 11542346Abstract: New bisindenyl ligand complexes and catalysts comprising those complexes. The invention is directed to improving the manufacturing of specific C1-symmetric bisindenyl complexes by modifying one of the indenyl ligands in order to improve the selectivity of the complex synthesis towards the desired anti-isomer, increase the yield and simplify the purification of the complex. The invention also relates to the use of the new bisindenyl metallocene catalysts for the production of polypropylene homopolymers or propylene copolymers.Type: GrantFiled: March 18, 2019Date of Patent: January 3, 2023Assignee: Borealis AGInventors: Vyatcheslav V. Izmer, Dmitry S. Kononovich, Alexander Z. Voskoboynikov, Ville Virkkunen, Luigi Maria Cristoforo Resconi
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Patent number: 11542351Abstract: The present invention relates to polyolefin. More specifically, the present invention relates to polyolefin having excellent dart drop impact strength, and exhibiting improved transparency, and such polyolefin has a density of 0.915 g/cm3 to 0.930 g/cm3 measured according to ASTM D1505; and satisfies the following requirements (provided that S1+S2+S3=1), when measuring the relative content of peak area according to melting temperature (Tm) using SSA (Successive Self-nucleation and Annealing) analysis: the content(S1) of peak area at Tm less than 100° C. is 0.33 to 0.35; the content(S2) of peak area at Tm of 100° C. or more and 120° C. or less is 0.52 to 0.56; and the content(S3) of peak area at Tm greater than 120° C. is 0.10 to 0.14.Type: GrantFiled: December 20, 2019Date of Patent: January 3, 2023Inventors: Jeongkyu Lee, Sung Min Lee, Hyojoon Lee, Chang Hwan Jang, Sung Ho Park, Seul Ki Im, Jinyoung Lee, Sung Joon Oh, Seyoung Kim, Jisoo Song
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Patent number: 11535760Abstract: Provided herein is a composition for treating aluminum containing surfaces, wherein the composition includes a reaction product of at least one amine-functionalized organosilane and/or oligomer and/or polymer thereof and at least one fatty acid, wherein the molar ratio of the amino group/s of the at least one amine-functionalized organosilane and/or oligomer and/or polymer thereof and of the at least one fatty acid is 1.2:1 to 1:2, and wherein the at least one amine-functionalized organosilane and/or oligomer and/or polymer thereof is linked to the at least one fatty acid by at least one carboxylic acid/amine salt bond and/or at least one amide bond.Type: GrantFiled: January 21, 2021Date of Patent: December 27, 2022Assignee: Chemetall U.S., Inc.Inventors: Hoon Kim, Ronald Ascenzo
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Patent number: 11530280Abstract: Catalyst system for producing ethylene copolymers in a high temperature solution process, the catalyst system comprising (i) a metallocene complex of formula (I), M is Hf or a mixture with Zr, provided that more than 50% by moles of the complex of Formula I has M=Hf, X is a sigma ligand, R are the same or different from each other and can be saturated linear or branched C1-C10 alkyl, C5-C10 aryl, C6-C20 alkylaryl or C6-C20 arylalkyl groups, which can optionally contain up to 2 heteroatoms or silicon atoms, R1 is a C6-C20-aryl, which can be unsubstituted or substituted by one or up to 5 linear or branched C1-C10 alkyl group(s), R2 is a saturated linear or cyclic C3-C20 alkyl group or a branched CR3R4R5 group, wherein R3 is hydrogen or an C1-C20 alkyl group and R4 and R5 are the same or are different and can be an C1-C20 alkyl group and (ii) a boron containing cocatalyst.Type: GrantFiled: December 12, 2017Date of Patent: December 20, 2022Assignee: Borealis AGInventors: Noureddine Ajellal, Anna Fait, Luigi Resconi, Vyatcheslav Izmer, Dmitry Kononovich, Alexander Voskoboynikov, Rafael Sablong, Timo Sciarone
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Patent number: 11525020Abstract: The present disclosure generally relates to processes to produce alpha-olefin oligomers and poly alpha-olefins. In an embodiment, a process to produce a poly alpha-olefin (PAO) includes introducing a first alpha-olefin and a first catalyst system comprising a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under first reactor conditions to form a first reactor effluent. The alpha-olefin is introduced to the reactor at a flow rate of about 100 g/hr or more. The first reactor effluent includes PAO dimer comprising at least 96 mol % of vinylidene and 4 mol % or less of trisubstituted vinylene and disubstituted vinylene, based on total moles of vinylidene, trisubstituted vinylene, and disubstituted vinylene. The method includes introducing the first reactor effluent, a second alpha-olefin and a second catalyst composition comprising an acid catalyst into a second reactor under second reactor conditions to form a second reactor effluent comprising PAO trimer.Type: GrantFiled: June 28, 2021Date of Patent: December 13, 2022Assignee: ExxonMobil Chemical Patents Inc.Inventors: Patrick C. Chen, Mark H. Li, Jennifer L. Rapp, Monica D. Lotz, Babak LotfizadehDehkordi, Craig J. Emett, Najeeb M. Kuzhiyil, Jian Yang