Patents Examined by Carman J. Seccuro
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Patent number: 5310801Abstract: Disclosed herein is a process for the production of cycloolefin random copolymers comprising flash drying a solution of a cylcoolefin random copolymer in a hydrocarbon, said solution being obtained by copolymerization of ethylene and a specific cycloolefin in said hydrocarbon in the presence of a catalyst. Further proposed herein is a process for the production of cycloolefin random copolymers by copolymerization of ethylene with a specific cycloolefin of the in a hydrocarbon in the presence of a catalyst wherein said copolymerization is carried out in a polymerization reactor where a gas phase is not substantially present.Type: GrantFiled: April 27, 1993Date of Patent: May 10, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Takashi Hayashi, Shunyo Uesugi, Hiroo Wamura
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Patent number: 5308699Abstract: A thermoplastic elastomer powder for powder slush molding, comprising an elastomer composition of an ethylene-.alpha.-olefin copolymer rubber and a polyolefin resin, wherein said elastomer composition has a complex dynamic viscosity .eta.*(1) as measured at a frequency of 1 radian/sec. in a dynamic viscoelasticity measurement at 250.degree. C., of 1.5.times.10.sup.5 poise or less, a Newtonian viscosity index n calculated from the following formula by using the complex dynamic viscosity .eta.*(1) at a frequency of 1 radian/sec. and the complex dynamic viscosity .eta.*(100) at a frequency of 100 radian/sec. of 0.67 or less:n=[log.eta.*(1)-log.eta.*(100)]/2.Type: GrantFiled: October 2, 1991Date of Patent: May 3, 1994Assignee: Sumitomo Chemical Company LimitedInventors: Tadashi Hikasa, Hiroaki Mendori, Tatsuo Hamanaka, Toshio Igarashi, Yuu Shida
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Patent number: 5308908Abstract: A polypropylene resin composition comprising:(A) 45 to 70% by weight of an ethylene-propylene block copolymer synthesized under the process comprising the steps of;(a) polymerizing propylene with a Ziegler-Natta catalyst to obtain a highly crystalline polypropylene that contain not less than 97% by weight of a fraction insoluble in boiling n-heptane, and(b) copolymerizing ethylene with the polypropylene (a), and which(a) contains 0.5 to 10% by weight of ethylene,(b) contains 5 to 20% by weight of a fraction being soluble in p-xylene at room temperature and having an intrinsic viscosity value of not less than 2 (measured in decalin at 135.degree. C.),(c) has a melt-flow index value of 30 to 100 g/10 min., and,(d) has a value of flexural modulus of not less than 18,000 kg/cm.sup.2,(B) 10 to 20% by weight of an amorphous ethylene-propylene copolymer having(a) an ethylene content of 70 to 90% by weight,(b) a Mooney viscosity value (ML.sub.1+4 at 100.degree. C.) of 5 to 70,(C) 5 to 15% by weight of an ethylene-.Type: GrantFiled: August 28, 1992Date of Patent: May 3, 1994Assignee: Ube Industries, Ltd.Inventors: Osamu Fukui, Kouhei Ueno, Yoshifumi Nakano, Ikunori Sakai, Takao Nomura, Takeyoshi Nishio, Hisayuki Iwai
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Patent number: 5308700Abstract: A thermoplastic elastomer powder for powder molding, comprising an elastomer composition of an ethylene-.alpha.-olefin copolymer rubber and a polyolefin resin, wherein said elastomer composition has a complex dynamic viscosity .eta.*(1) as measured at frequency of 1 radian/sec. in dynamic viscoelasticity measurement at 250.degree. C., of 1.5.times.10.sup.5 poise or less, a Newtonian viscosity index n calculated from the following formula by using the complex dynamic viscosity .eta.*(1) at a frequency of 1 radian/sec. and the complex dynamic viscosity .eta.*(100) at a frequency of 100 radian/sec. of 0.67 or less, and a hardness (shore D) of 45 or less:n={log.eta.*(1)-log.eta.*(100)}/2.Type: GrantFiled: October 2, 1991Date of Patent: May 3, 1994Assignee: Sumitomo Chemical Company LimitedInventors: Tadashi Hikasa, Hiroaki Mendori, Tatsuo Hamanaka, Toshio Igarashi, Yuu Shida
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Patent number: 5306775Abstract: A composition of matter comprising: (a) 30 to 70 weight percent inclusive of a low molecular weight ethylene resin made using a chromium catalyst system said resin having a density of at least 0.955 grams per cubic centimeter, a melt index from 25 to 400 grams per 10 minutes, and a heterogeneity index between 2 and 35 inclusive; and (b) 30 to 70 weight percent inclusive of a high molecular weight ethylene copolymer resin made using a titanium catalyst system said resin having a density not greater than 0.955 grams per cubic centimeter, a high load melt index between 0.1 and 50 grams per 10 minutes inclusive, and a heterogeneity index between 2 and 10 inclusive; wherein said composition of matter has a melt index greater than 0.05 grams per 10 minutes.Type: GrantFiled: April 16, 1993Date of Patent: April 26, 1994Assignee: Phillips Petroleum CompanyInventors: Joel L. Martin, M. Bruce Welch, William R. Coutant, Max P. McDaniel
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Patent number: 5304606Abstract: A thermoplastic resin composition according to the present invention comprises a polymer comprising recurring units derived from a polycyclic (meth)acrylate represented by the following formula [I] and a soft polymer in the proportion by weight of the polymer to the soft polymer of 99:1 to 40:60 ##STR1## where m is 0 or a positive integer, n is 0 or 1, R is hydrogen or methyl, R.sup.1 -R.sup.18 are each independently an atom or a group selected from the group consisting of hydrogen, halogen and hydrocarbon groups, R.sup.15 -R.sup.18, linked together, may form a monocyclic or polycyclic group which may have a double bond, or an alkylidene group, p is 0 or 1, and R.sup.a and R.sup.b each independently represent a hydrogen atom or a hydrocarbon group when p is 1.Type: GrantFiled: March 15, 1993Date of Patent: April 19, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Yohzoh Yamamoto
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Patent number: 5302454Abstract: Polypropylene compositions having valued plasto-elastic properties, in the form of spheroidal flowable particles with an average diameter included between 500 and 7000 um having the following composition:A) 10-60 parts by weight of homopolymer polypropylene with isotactic index greater than 90, or of crystalline propylene copolymer with ethylene and/or an alpha olefin such as butene-1, pentene-1 or 4-methyl-1-pentene, containing over 85% by weight of propylene and having an isotactic index greater than 85;B) 10-40 parts by weight of a polymer fraction containing ethylene, insoluble in xylene at room temperature;C) 30-60 parts by weight of an amorphous copolymer ethylene-propylene fraction optionally containing small proportions of a diene, soluble in xylene at room temperature and containing 40-70% by weight of ethylene.Type: GrantFiled: August 17, 1992Date of Patent: April 12, 1994Assignee: HIMONT IncorporatedInventors: Giuliano Cecchin, Floriano Guglielmi
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Patent number: 5300577Abstract: A pneumatic tire with a tread comprising a blend of 3,4-polyisoprene rubber, cis 1,4-polybutadiene rubber, and a terpolymer of styrene/isoprene/butadiene. The triblend of the three basic elastomers when compounded and cured into a polymer network gives a high tan delta at 0.degree. C. associated with good wet traction and a low tan delta at 60.degree. C. which has been associated with low rolling resistance.Type: GrantFiled: February 6, 1992Date of Patent: April 5, 1994Assignee: The Goodyear Tire & Rubber CompanyInventors: Raymond R. DiRossi, Gregory M. Holtzapple, Joseph K. Hubbell, Mark H. Seloover, John J. A. Verthe
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Patent number: 5300365Abstract: Disclosed are films or sheets comprising an olefin polymer composition which is comprised of(a) from about 10 to 50 parts of a propylene homopolymer having an isotactic index greater than 80, or a copolymer of propylene with ethylene and/or an another alpha-olefin, containing over 80% propylene and having an isotactic index greater than 80;(b) from about 5 to 20 parts of a semi-crystalline copolymer fraction, which copolymer is insoluble in xylene at room or ambient temperature; and(c) from about 40 to 80 parts of a copolymer fraction of ethylene with propylene and/or another alpha-olefin, and optionally with minor amounts of a diene, said copolymer fraction containing less than 40% ethylene and/or other alpha-olefin, being soluble in xylene at room temperature, and having an intrinsic viscosity from 1.Type: GrantFiled: February 16, 1993Date of Patent: April 5, 1994Assignee: Himont IncorporatedInventor: Kumar Ogale
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Patent number: 5298561Abstract: Propylene polymer compositions having good transparency and improved impact resistance at low temperature comprising:a) 70 to 98% by weight crystalline copolymer of ethylene with propylene and/or with an alpha olefin of the formula H.sub.2 C=CHR where R is a C.sub.2-8 linear or branched alkyl radical and b) 2 to 30% by weight of an elastomeric propylene-ethylene copolymer. The portion of said copolymer b) soluble in xylene at room temperature has an intrinsic viscosity (I.V. 2) which satisfies the following relation:0.2.ltoreq.(I.V. 2/I.V. 1).times.(C.sub.2.sup.-).ltoreq.0.6where I.V. 1 is the intrinsic viscosity of the crystalline propylene copolymer, (C.sub.2.sup.-) is the ethylene weight content of b). The ratio between the ethylene weight content in b) and the weight of the xylene soluble portion is equal to or less than 1.5.Type: GrantFiled: September 11, 1992Date of Patent: March 29, 1994Assignee: Himont IncorporatedInventors: Giuliano Cecchin, Floriano Guglielmi
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Patent number: 5298551Abstract: The present invention provides a vinyl chloride resin composition having an elevated heat distortion temperature, comprising]I[ [A] a vinyl chloride resin, and[II] [B] cycloolefin ring opening polymer or copolymer formed by ring opening polymerization of a cycloolefin represented by the formula [I], or a hydrogenated product thereof, and/or[C] a cycloolefin random copolymer of ethylene and a cycloolefin represented by the formula [I], said copolymer having an intrinsic viscosity [.eta.], as measured in decalin at 135.degree. C., of 0.05 to 10 dl/g and a glass transition temperature Tg of at least 70.degree. C., ##STR1## wherein n is 0 or 1, and m is 0 or a positive integer.Type: GrantFiled: April 28, 1992Date of Patent: March 29, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventor: Youzo Yamamoto
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Patent number: 5296553Abstract: Low molecular weight olefin resins are blended with small amounts of high molecular weight olefin resins and the blends are chlorinated or chlorosulfonated. Melt and film strengths of the resultant low molecular weight chlorinated and chlorosulfonated resins are thereby increased sufficiently to enable recovery by means of methods which require film or strand formation. The chemical properties and solution characteristics of the blends are substantially maintained compared to those of the low molecular weight chlorinated resins themselves.Type: GrantFiled: November 20, 1992Date of Patent: March 22, 1994Assignee: E. I. du Pont de Nemours and CompanyInventor: Edward G. Brugel
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Patent number: 5296554Abstract: An adhesive resin composition comprises (A) 2 to 98% by weight of an ethylene copolymer resin containing 0.01 to 20% by weight of the unit of an unsaturated carboxylic acid anhydride in the main chain; and (B) 98 to 2% by weight of a resin mixture comprising (i) 50 to 90% by weight of a copolymer resin of ethylene/vinyl acetate, (ii) 40 to 9.5% by weight of a binary copolymer resin of ethylene and an .alpha.-olefin having 3 to 12 carbon atoms, and (iii) 10 to 0.5% by weight of an ethylene/propylene/unconjugated diene terpolymer. The resin mixture is obtained by mixing (i), (ii) and (iii) in a molten state and has a toluene extraction residue of 10 to 60% by weight. The adhesive resin composition is utilized as an adhesive material between layers of a multi-layer laminate and scrap or waste material from the adhesive resin composition or from the multilayer laminate can be recycled as an adhesive resin composition having excellent interlayer strength and compatibility.Type: GrantFiled: April 7, 1993Date of Patent: March 22, 1994Assignee: Showa Denko K.K.Inventors: Kazuyuki Watanabe, Yuji Kira
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Patent number: 5296552Abstract: An adhesive resin composition is obtained by mixing at least one member (C) selected from the group consisting of unsaturated carboxylic acids and the derivatives thereof, a free-radical initiator (D), and a mixture consisting of a crystalline polyolefin resin (A) and an amorphous or low crystalline olefin copolymer of ethylene and an .alpha.-olefin (B), to obtain a precursor mixture, melt-kneading the precursor mixture in the first half of an extruder having at least one side feeder, to obtain a modified precursor mixture, and feeding a crystalline polyolefin resin (E) from the side feeder of the extruder and mixing the resin (E) with the modified precursor mixture.The adhesive resin composition has good extrudability and exhibits high adhesive property to polar materials such as polar polymeric materials and the like.Type: GrantFiled: February 25, 1992Date of Patent: March 22, 1994Assignee: Sumitomo Chemical Company, LimitedInventors: Tadayuki Ohmae, Yoshiki Toyoshima, Hisao Tanaka, Mitsuyuki Okada, Harunori Fujita
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Patent number: 5296548Abstract: Discosed are compositions of crystalline propylene polymers comprising (by weight):A) 30-65% of a copolymer of propylene with a C.sub.4 -C.sub.8 .alpha.-olefin, containing from 98 to 80% propylene;B) 35-70% of a copolymer of propylene with ethylene and optionally from 2 to 10% of a C.sub.4 -C.sub.8 .alpha.-olefin, said copolymer containing 2 to 10% ethylene when the C.sub.4 -C.sub.8 .alpha.-olefin is not present, and 0.5 to 5% ethylene when the C.sub.4 -C.sub.8 .alpha.-olefin is present.Type: GrantFiled: September 23, 1991Date of Patent: March 22, 1994Assignee: Himont IncorporatedInventors: Massimo Covezzi, Antonio Ciarrocchi
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Patent number: 5292811Abstract: Proposed herein is a process for preparing thermoplastic elastomers, which comprises dynamically heat treating polymer particles together with a crosslinking agent, each of the polymer particles being composed of a portion comprising a crystalline olefin polymer and portions comprising an amorphous olefin polymer, the polymer particles having an average particle diameter of at least 10 .mu.m and an apparent bulk density of at least 0.2 g/ml.Type: GrantFiled: March 18, 1993Date of Patent: March 8, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kazuhiko Murata, Shizuo Shimizu, Mamoru Kioka, Akinori Toyota
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Patent number: 5290866Abstract: The present invention relates to a film comprising a low density linear ethylene copolymer of ethylene and a higher olefin and up to about 10 percent by weight of the total composition of an acrylic polymer.Type: GrantFiled: April 16, 1992Date of Patent: March 1, 1994Assignee: Mobil Oil CorporationInventors: David V. Dobreski, Jack J. Donaldson
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Patent number: 5290635Abstract: Cold-stretched products comprising a propylene-based resin composition obtained by mixing(A) a polymer consisting mainly of propylene units, in a proportion of not more than 92% by weight and not less than 50% by weight,(B) a polymer consisting mainly of butene-1 units or an ethylene-.alpha.-olefin copolymer having a softening point of 95.degree. C. or lower, in a proportion of not more than 47% by weight and not less than 5% by weight,(C) a tackifier in a proportion of not more than 25% by weight and not less than 3% by weight, the sum of the proportions being 100% by weight; and a process for producing said cold-stretched products.Type: GrantFiled: February 21, 1991Date of Patent: March 1, 1994Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Disuke Matsumura, Mitsuyoshi Itada
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Patent number: 5290862Abstract: A tough polymer alloy is provided and comprises:(i) from 30 to 83 weight percent of a brittle polymer;(ii) from 3 to 50 weight percent of a rubbery polymer; and(iii) from 15 to 67 weight percent of a ductile polymer provided that the ductile polymer and the rubbery polymer are at least compatible.Type: GrantFiled: October 13, 1992Date of Patent: March 1, 1994Assignee: Novacor Chemicals (International) S.A.Inventor: William G. Blasius
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Patent number: 5288812Abstract: Polyphenylene ethers may show the property that their molecular weight increases considerably upon extrusion. This increase of the molecular weight leads to less good flow properties. It has been found that the addition of a conjugated, non-aromatic diene compound or of a dienophilic compound suppresses the increase of the molecular weight under extrusion.Type: GrantFiled: October 31, 1990Date of Patent: February 22, 1994Assignee: General Electric CompanyInventors: Jan Bussink, Roelof van der Meer