Patents Examined by D. E. Gantz
  • Patent number: 4554065
    Abstract: A process for dewaxing a hydrocarbon feedstock with a relatively high pour point and containing normal and slightly branched paraffins by subjecting said feed to catalytic dewaxing over a noble metal promoted zeolite beta catalyst followed by dewaxing with a base metal promoted zeolite beta catalyst. The feed may be hydrotreated before dewaxing.
    Type: Grant
    Filed: May 3, 1984
    Date of Patent: November 19, 1985
    Assignee: Mobil Oil Corporation
    Inventors: Kenneth R. Albinson, Jonathan E. Child
  • Patent number: 4553978
    Abstract: The present invention relates to a process for converting ligneous matter of vegetable origin by torrefaction, and to the product obtained. Wood or any other ligneous matter is subjected in a neutral atmosphere to a treatment of torrefaction at a temperature of between 200.degree. and 280.degree. C., and preferably between 240.degree. and 260.degree. C. for a duration of 30 mins. to 5 hours. The product of the invention is not fermentable, it has a specific mass close to 0.25 kg/dm.sup.3, a calorific power of at least about 5000 kcal/kg, a content of fixed carbon of 35 to 40% and can be broken up by hand; it may be used as fuel in boilers and in gas generators.
    Type: Grant
    Filed: August 23, 1982
    Date of Patent: November 19, 1985
    Assignee: Association pour la Recherche et le Developpement des Methodes et Processus Industriels
    Inventor: Schwob Yvan
  • Patent number: 4552855
    Abstract: Zeolite-metal catalysts having a substantial amount of catalytically active metal, e.g. iron, deposited in the cavities of the zeolite in zero-valent, small cluster form, are prepared by vaporizing the metal under low vapor pressure conditions in the vicinity of an organic liquid solvent, e.g. toluene, such that the metal dissolves in the solvent as a labile solvated zero-valent metal complex. This complex is contacted with the zeolite so that the complex diffuses into the cavities of the zeolite. Upon subsequent warming the solvated metal complex decomposes, leaving zero-valent small metal clusters in the zeolite cavities.
    Type: Grant
    Filed: November 30, 1983
    Date of Patent: November 12, 1985
    Inventors: Geoffrey A. Ozin, Linda F. Nazar, Francois Hugues
  • Patent number: 4552645
    Abstract: A process for cracking heavy hydrocarbon feedstocks by separation into light and heavy fractions and concommitantly thermally cracking the light fraction and coking the heavy fraction.
    Type: Grant
    Filed: March 9, 1984
    Date of Patent: November 12, 1985
    Assignee: Stone & Webster Engineering Corporation
    Inventors: Robert J. Gartside, Axel R. Johnson, Joseph L. Ross
  • Patent number: 4552650
    Abstract: A process for hydrotreating hydrocarbons uses a catalyst which comprises a carrier and at least one catalytic metal selected from vanadium, molybdenum, tungsten, nickel, cobalt and/or iron; this catalyst is in the form of a plurality of juxtaposed agglomerates of acicular platelets, oriented radially to each other. It is prepared from agglomerates of activated alumina subjected to reaction with an acid and a compound providing an anion able to combine with aluminum ions in solution.
    Type: Grant
    Filed: June 5, 1984
    Date of Patent: November 12, 1985
    Assignee: Societe Francaise des Produits pour Catalyse Pro-Catalyse
    Inventors: Herve Toulhoat, Yves Jacquin, Thierry Dupin
  • Patent number: 4552643
    Abstract: The formation of carbon on metals exposed to hydrocarbons in a thermal cracking process is reduced by contacting such metals with an antifoulant selected from the group consisting of a combination of tin and copper, a combination of antimony and copper and a combination of tin, antimony and copper.
    Type: Grant
    Filed: January 22, 1985
    Date of Patent: November 12, 1985
    Assignee: Phillips Petroleum Company
    Inventors: Randall A. Porter, Larry E. Reed
  • Patent number: 4552649
    Abstract: An improved fluid coking process is provided in which an aqueous sludge comprising an organic waste is used as quench in a quench elutriator to cool the coke product and convert at least a portion of the organic waste to a vaporous compound (e.g., hydrocarbon) which is recycled to the heating zone to increase the fuel value of the heating zone gaseous effluent.
    Type: Grant
    Filed: March 15, 1985
    Date of Patent: November 12, 1985
    Assignee: Exxon Research and Engineering Co.
    Inventors: Ann D. Patterson, Wayne M. Kachel
  • Patent number: 4552647
    Abstract: A process for economically converting carbo-metallic oils to lighter products. The carbo-metallic oils contain 650.degree. F.+ material which is characterized by containing material which will not boil below about 1025.degree. F., a carbon residue on pyrolysis of at least about 2, and a nickel plus vanadium content of at least about 4 parts per million. This process comprises adding an additive to the feedstock consisting of a compound containing titanium, zirconium, or aluminum so as to restore cracking activity of high metal contaminated and deactivated, zeolite containing catalysts, resulting from processing of these carbo-metallic oils.
    Type: Grant
    Filed: April 18, 1984
    Date of Patent: November 12, 1985
    Assignee: Ashland Oil, Inc.
    Inventors: William P. Hettinger, Jr., Stephen M. Kovach, Hubert W. Beck
  • Patent number: 4552644
    Abstract: The invention is a method for cracking heavy oils to olefins. In parallel streams, the heavy stream and a steam diluent are heated to the point of partial thermal cracking while in the other stream a lighter oil and steam are cracked to produce olefins. The hot, olefinic light stream is then mixed with the heated heavy stream and further cracked. The hot, olefinic stream acts as both a diluent and a heat source for cracking the heavy oil to an olefin containing product.
    Type: Grant
    Filed: February 24, 1984
    Date of Patent: November 12, 1985
    Assignee: Stone & Webster Engineering Corporation
    Inventors: Axel R. Johnson, Swami Narayanan, Herman N. Woebcke
  • Patent number: 4552854
    Abstract: Described is a process for removing arsenic from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon.Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic bound to it from contacting petroliferous liquid as described above and involves:a. treating said spent catecholated polystyrene, at a temperature in the range of about 20.degree. to 100.degree. C. with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10 and,b. separating the solids and liquids from each other. Preferably the regeneration treatment is in two steps wherein step (a) is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, steps (a) and (b) are repeated using a bicarbonate.
    Type: Grant
    Filed: February 8, 1985
    Date of Patent: November 12, 1985
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventor: Richard H. Fish
  • Patent number: 4552642
    Abstract: An H-Coal Process hydrogenation operation and catalyst life is substantially improved when using colloidal particles of catalyst comprising a colloidal matrix of silica, alumina, titania and combinations thereof coated with hydrogenating components selected from cobalt, molybdenum, nickel, tungsten and combinations thereof. The colloidal catalyst activity may be altered by alkaline promoters, other metals and acidic promoters.
    Type: Grant
    Filed: June 27, 1983
    Date of Patent: November 12, 1985
    Assignee: Ashland Oil, Inc.
    Inventor: William P. Hettinger, Jr.
  • Patent number: 4552648
    Abstract: A process for catalytically cracking a hydrocarbon feed in a reaction zone under catalytic cracking conditions in the absence of added hydrogen with a catalyst comprising a conventional cracking catalyst. The improvement comprises adding to the conventional cracking catalyst a thermally treated zeolite having a mole ratio of SiO.sub.2 :Al.sub.2 O.sub.3 of about 10:1 to 100:1 and a constraint index of about 1 to 12. Thermal treatment reduces the additive zeolite's alpha activity to about 1 to 10 prior to use.
    Type: Grant
    Filed: February 8, 1984
    Date of Patent: November 12, 1985
    Assignee: Mobil Oil Corporation
    Inventors: Edward J. Rosinski, Albert B. Schwartz, Francis G. Dwyer
  • Patent number: 4552646
    Abstract: Arsenic impurities and, optionally, iron impurities are removed from a hydrocarbon-containing feed stream, preferably shale oil, by contacting it with an aqueous solution of a metal chlorate and an acid having a pKa of less than 3.
    Type: Grant
    Filed: December 24, 1984
    Date of Patent: November 12, 1985
    Assignee: Phillips Petroleum Company
    Inventor: Paul R. Stapp
  • Patent number: 4551225
    Abstract: An improved process for preparing an optically anisotropic pitch which comprises heating a pitch feed material at a temperature within the range of about 350.degree. C. to 450.degree. C. while passing an inert gas therethrough at a rate of at least 2.5 SCFH/lb of pitch feed material and agitating said pitch feed material at a stirrer rate of from about 500 to 600 rpm to obtain an essentially 100% mesophase pitch product suitable for carbon production.
    Type: Grant
    Filed: May 23, 1984
    Date of Patent: November 5, 1985
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Ghazi B. Dickakian
  • Patent number: 4551235
    Abstract: There is disclosed a system for measuring and controlling the concentration of hydrogen in hydrogen recycle processes used in oil refineries and petrochemical plants. The system is intended to reduce the amount of hydrogen and hydrocarbon vapor circulating in such systems, thus reducing the quantity of utilities needed to operate such systems. Specifically, there is a savings of compressor power and fuel required for heating. The system is dependent on the recognition that a decrease in cooling medium temperature results in an increase in hydrogen flow, which can be decreased to the minimum permissible without endangering catalyst activity and stability and product yield if hydrogen concentration is monitored, and that partial pressure is the key parameter.
    Type: Grant
    Filed: June 28, 1984
    Date of Patent: November 5, 1985
    Assignee: UOP Inc.
    Inventor: Don B. Carson
  • Patent number: 4551238
    Abstract: Disclosed is a method and apparatus for separating and stabilizing a hydrotreater effluent into a stabilized liquid product and a dry gas product. The hydrotreater effluent is expanded in a first expansion drum from a high pressure to an intermediate pressure, evolving both gaseous and liquid phase components. The gaseous phase components are withdrawn as the gas product and the liquid phase components are further processed. The liquid phase components are further expanded in a second expansion drum, evolving further gas products which are compressed, cooled and returned to the first expansion drum. The second expansion drum liquid phase can comprise the liquid product output or can be further treated by an additional expansion stage.
    Type: Grant
    Filed: November 6, 1984
    Date of Patent: November 5, 1985
    Assignee: Mobil Oil Corporation
    Inventor: Charles E. Marks
  • Patent number: 4551234
    Abstract: Regenerated sorbent employed for refining of heavy crude feedstocks is used to remove contaminants from specialized hydrocarbons, especially used motor oil. The simultaneous operation of a decontaminating unit supplied with regenerated sorbent particulate from the regenerator of a heavy hydrocarbon refining system is utilized.
    Type: Grant
    Filed: August 3, 1984
    Date of Patent: November 5, 1985
    Assignee: Ashland Oil, Inc.
    Inventor: William P. Hettinger, Jr.
  • Patent number: 4551574
    Abstract: A new catalyst composition comprising a platinum group component, a tin component, an indium component, an alkali or alkaline earth component and a porous support material wherein the atomic ratio of indium to platinum group component is more than 1.0 is disclosed. The catalyst is particularly useful for dehydrogenating hydrocarbons. In one embodiment of the invention, detergent range normal paraffins (C.sub.10 -C.sub.15 or higher) are dehydrogenated to the corresponding normal olefins in the presence of the subject catalyst and hydrogen.
    Type: Grant
    Filed: August 13, 1984
    Date of Patent: November 5, 1985
    Assignee: UOP Inc.
    Inventors: Tamotsu Imai, Chi-wen Hung
  • Patent number: 4551130
    Abstract: A post-operative patient drainage and irrigation apparatus, employing a simplified two-position valve to control the passage of fluids into and out of the body of the patient. A two-channel catheter directs body fluids into and out of the control valve. A first flexible tube directs irrigating solutions from a source into the control valve. A second flexible tube, attached at one end to the control valve, serves as a waste conduit from the said valve to a waste receptacle. Check valves carried in rubber squeeze bulbs in the first and second flexible tubes further control the direction of fluid flow and serve to clear obstructions in the apparatus. A simple control changes the two-position control valve position from one mode to another.
    Type: Grant
    Filed: May 8, 1984
    Date of Patent: November 5, 1985
    Inventors: William B. Herbert, Rohit A. Patel
  • Patent number: 4551573
    Abstract: The alkylation of aromatic compounds with olefinic compounds is catalyzed by catalyst consisting essentially of aluminum halide and elemental iodine.
    Type: Grant
    Filed: October 1, 1984
    Date of Patent: November 5, 1985
    Assignee: Phillips Petroleum Company
    Inventor: Raymond L. Cobb