Abstract: Blends of diaminoisopropylbenzene (DAIPB) and diaminoethylbenzene (DAEB) are provided for curing epoxy resins. The cured epoxy resins have increased tensile strength and slightly lower glass transistion temperatures as compared with resins cured with either diamine alone.
Type:
Grant
Filed:
February 23, 1989
Date of Patent:
September 17, 1991
Assignees:
First Chemical Corporation, The University of Southern Mississippi
Inventors:
Robson F. Storey, Arthur C. Bayer, Sudhakar Dantiki
Abstract: An epoxy resin based powder coating composition which comprises: (A) 100 parts by weight of a mixed epoxy resin having a softening point of 60.degree.-80.degree. C. which consists of 50 to 70 wt. % of a bisphenol A expoxy resin having a number-average molecular weight of 800 to 1,800 and 30 to 50 wt. % of a cresol novolak epoxy resin; (B) 5 to 80 parts by weight of a novolak resin; (C) 0.5 to 5 parts by weight of triphenylphosphine; (D) 60 to 200 parts by weight of an inorganic powder having an average particle size of 0.5 to 75 um; and (E) 0.01 to 2 parts by weight of a microfine silica powder having an average particle size of 1 to 100 nm.The epoxy resin based powder coating composition can be coated on electrical and electronic components at 90.degree.-100.degree. C. with retaining the high moisture resistance, storage stability and free-flowing properties.
Abstract: The present invention generally relates to a thermosettable cyanate ester resin composition which contains a fortifier that is the reaction product of an epoxy and an aromatic reactant selected from an aromatic amine and an aromatic amide. Thermoset cyanate ester resin compositions of the present invention have improved flexural strength and/or flexural modulus. The compositions of the present invention may be used to prepare circuit boards or molded parts.
Abstract: A powder coating composition suitable for slot insulation is disclosed which includes an epoxy resin containing at least 60% by weight of a mixture of a first glycidyl ether of bisphenol A having a number average molecular weight of 2500-8000 with a second glycidyl ether of bisphenol A having a number average molecular weight of 350-1700, the mixture having a number average molecular weight of 1600-4600, a carboxyl group-terminated polyester resin in an amount of 5-100 parts by weight per 100 parts by weight of the epoxy resin, a curing agent, and an inorganic filler in an amount of 10-80% by weight.
Abstract: Discrete, non-agglomerating particles of polyalkylene carbonate are produced by solvent/non-solvent precipitation using certain solvent/non-solvent systems. The free-flowing particles obtained are from 30 to 3000 microns in diameter and are suitable for use in a variety of applications, particularly the preparation of foamed articles.
Type:
Grant
Filed:
September 6, 1990
Date of Patent:
August 20, 1991
Assignee:
Arco Chemical Technology, Inc.
Inventors:
Donald E. Hostetler, Michael J. Cannarsa, Haven S. Kesling, Jr., Hsiang-Ning Sun
Abstract: Copolymers of 1,3-dioxolane and 1,3-dioxepane in the form of non-crystalline high molecular weight elastomers having low glass transition temperatures (Tg) are disclosed. Such copolymers are formed by polymerizing from about 40 to about 60 mol percent of 1,3-dioxolane and correspondingly from about 60 to about 40 mol percent of 1,3-dioxepane under substantially anhydrous conditions in the presence of a cationic polymerization catalyst, e.g., a strong Bronsted acid such as trifluoromethanesulfonic acid. Blends of such non-crystalline copolymers with crystalline oxymethylene polymers are also disclosed.
Type:
Grant
Filed:
September 13, 1989
Date of Patent:
August 20, 1991
Assignee:
Hoechst Celanese Corp.
Inventors:
George L. Collins, William M. Pleban, Milton J. Hayes
Abstract: The invention relates to a process for the preparation of a bioabsorbable polyester comprising reacting said polyester under reduced pressure in the reaction system while maintaining said polyester in the molten state during the second half of the polymerization reaction or after completion of the reaction and obtaining said polyester which contain almost no residue of unreacted monomers and volatile ingredients of low molecular weight.
Abstract: A process for preparing polyepichlorohydrin which comprises polymerizing epichlorohydrin in the presence of a catalytic amount of 1,4-butaneditriflate. The resulting polymer can have a molecular weight of about 5,000 to about 15,000. The polymer is telechelic. It can be terminated with a broad variety of functional groups.
Type:
Grant
Filed:
April 27, 1990
Date of Patent:
August 20, 1991
Assignee:
The United States of America as represented by the Secretary of the Air Force
Abstract: An aqueous electrophoretic coating material, which can be deposited at the cathode and contains(A) 90 to 50% by weight, based on the total portion of synthetic resin vehicle, of one or several polycondensation, polymerization and/or poly-addition resins, the resin or, in the event that several resins are present, their mixture(a) having a number average molecular weight (Mn) of 700 to 10,000(b) having 1.2.times.10.sup.23 to 21.7.times.10.sup.23 lateral or terminal double bonds per 1,000 g, corresponding to a hydrogenation iodine number of 5 to 90,(c) optionally containing primary and/or secondary hydroxyl groups, corresponding to a hydroxyl number of 0 to 450 mg KOH/g of resin, and(d) tertiary amino groups corresponding to an amine number of 30 to 450 mg KOH/g of resin.
Type:
Grant
Filed:
September 30, 1988
Date of Patent:
August 13, 1991
Assignee:
Hoechst Aktiengesellschaft
Inventors:
Dietrich Saatweber, Georg Hendriux, Gerhard Brindopke, Helmut Plum
Abstract: An aniline-resorcin-formaldehyde copolycondensation product having a particular mol ratio of aniline to resorcin is used in an adhesive composition for well adhering fibrous material to rubber.
Abstract: Cathodic electrocoating binders which are water-dilutable on protonation with an acid are obtainable by reactingA) an epoxy compound or a mixture of epoxy compounds having an epoxide equivalent weight of less than 2,000 withB) a compound which is monofunctional with respect to epoxides and contains aliphatic or phenolic OH groups andC) a secondary amine of 2 to 36 carbon atoms, with the proviso that the reaction product of A), B) and C) still contains free epoxy groups, andD) an amount of an amidoamine containing primary amino groups which is equivalent to or greater than the amount of these free epoxy groups, the said amidoamine being obtainable from a primary diamine and a mono- and/or dicarboxylic acid.
Type:
Grant
Filed:
July 21, 1989
Date of Patent:
August 13, 1991
Assignee:
BASF Lacke & Farben Aktiengesellschaft
Inventors:
Thomas Schwerzel, Hans Schupp, Dirk Lawrenz, Hans Oslowski, Ulrich Heimann
Abstract: Methods are disclosed for the production of (I) a cationic water-soluble resin by the reaction of a polyethylene glycol polyhalohydrin ether resulting from the reaction between polyethylene glycol and an epihalohydrin with an aziridine compound and (II) and (III) cationic water-soluble resins by the reaction of (I) the resin with an epihalohydrin and/or a polyfunctional epoxy compound in the presence or absence of a polyalkyleneimine. The resins (I), (II), and (III) are stable over a wide range of pH value and are useful as a water-treating agent.
Abstract: A soluble or crosslinked graft copolymer of lignin-(2-propenamide)-(2-methyl-3-oxo-4-oxyhex-1-ene-6-ol) having a central lignin network and at least one grafted side chain, R, having randomly repeating units of the formula: ##STR1## such that the central lignin network has a molecular weight of about 1,000 to 150,000 and the total number of randomly repeating units in the grafted side chain or chains is in the range of 1 to 300,000, such that the total copolymer molecular weight is in the range of 1,000 to 30,000,000 for use as thickeners for water and aqueous solutions and may be advantageously used in the recovery of oil from subterranean wells, in the preparation and use of drilling fluid compositions, or in plastics and elastomers.
Abstract: A modified epoxy resin provided with improved flexibility and curing properties is prepared by subjecting a bisphenol type epoxy resin (a) to steps (i) and (ii):(i) the step wherein the epoxy group is reacted with a primary amine (b), and(ii) the step wherein secondary hydroxyl group is at least partly esterified by a reaction with a lactone.
Abstract: Bioabsorbable copolymers comprising .rho.-dioxanone and AA-BB type polyalkylene carbonates are provided. The copolymers are useful in the fabrication of sterile surgical articles and bioabsorbable coatings for sutures and are produced from organic carbonates by way of prepolymeric synthetic intermediates.
Type:
Grant
Filed:
February 9, 1990
Date of Patent:
August 6, 1991
Assignee:
Ethicon, Inc.
Inventors:
Rao S. Bezwada, Shalaby W. Shalaby, Alastair W. Hunter
Abstract: A hardening agent for epoxy prepared by reacting A) a hydroxy containing ketimino compound with B) a diisocyanate compound with one isocyanate group blocked, reacting the resulting adduct with C) a polyether amine and hydrolysis of the reaction product, reactants A), B) and C) being in approximately stoichiometric amounts resulting in flexible hardened products of good resistance to chemicals and aging.
Type:
Grant
Filed:
June 7, 1990
Date of Patent:
July 23, 1991
Assignee:
Rutgerswerke AG
Inventors:
Achim Hansen, Alfred Mathes, Jurgen Zehrfeld
Abstract: Disclosed is a curing agent composition for epoxy resin, prepared by mixing together the following components (i), (ii) and (iii) and heating the mixture for modification:(i) at least one organic carboxylic acid zinc salt,(ii) at least one acid anhydride, and(iii) either (a) at least one phenol compound or (b) at least one glycidyl ester or glycidyl ether compound.
Abstract: Two part epoxy resin system comprising a main component comprising a bisphenol type epoxy resin having not more than 0.08% by weight of a content of a saponifiable chlorine-containing group and a curing component comprising a modified aromatic polyamine and a liquid imidazole, which has a long pot-life at room temperature and is curable even at an intermediate temperature such as about 50.degree. to 60.degree. C., and is useful as a paint composition, an adhesive, a lining material, a molding material and a floor covering material.
Abstract: The present invention relates to a dispersant for nonaqueous systems which can disperse insoluble fine powders in nonaqueous liquids in a short period of time and give long-term dispersion stability to the resulting dispersions without allowing the formation of a so-called hard cake. The dispersant consists essentially of at least one polyether compound derived from at least one member of the class consisting of polyamine compounds having 5 to 300 active hydrogen atoms per molecule, polyalkylenimine compounds having 5 to 300 active hydrogen atoms per molecule, and derivatives thereof having 5 to 300 active hydrogen atoms per molecule by addition of at least one of ethylene oxide and propylene oxide and at least one alpha-olefin oxide containing 4 to 30 carbon atoms. The polyether compound has a molecular weight of 1,000 to 1,000,000.
Abstract: A dimensionally heat-recoverable article carrying a heat curable adhesive coating on a surface thereof, the adhesive coating comprising (a) a mixture of substantially solid particles of a first reactive component with separate substantially solid particles of at least a second reactive component and (b) a water soluble polymeric binder having substantially no hydroxyl groups, the first and second reactive components being present in the adhesive coating as substantially unreacted separate particles capable of reacting together to effect curing when the article is heated to its heat recovery temperature.
Type:
Grant
Filed:
April 12, 1990
Date of Patent:
July 23, 1991
Assignee:
Raychem Limited
Inventors:
Michael J. Read, Michael R. Read, Stephen J. Osborne, Geoffrey P. Hakes