Patents Examined by Earl A. Nielsen
  • Patent number: 4997910
    Abstract: The invention relates to a process for condensing at least one epoxide on at least one cyclic anhydride of a dicarboxylic acid in the presence of a catalyst consisting of at least one titanium peroxidic complex of the peroxo type of the A form ##STR1## Said process allows to obtain a perfectly alternate polyester.
    Type: Grant
    Filed: December 7, 1989
    Date of Patent: March 5, 1991
    Assignees: Institut Francais du Petrole, L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, Elf France
    Inventors: Jacques Garapon, Remi Touet, Catherine Huet, Bernard Damin
  • Patent number: 4997865
    Abstract: The invention relates to an aqueous coating agent, obtained from an epoxy resin, ethylenically unsaturated monomers, some of which contain carboxyl groups, a peroxide initiator in a proportion of at least 2% by weight, relative to the total weight of the monomers, a crosslinking agent, a neutralizing agent, organic solvents, and, if appropriate, further conventional additives, such as plasticizers, stabilizers, wetting agents, dispersion auxiliaries, catalysts and pigments.
    Type: Grant
    Filed: February 14, 1989
    Date of Patent: March 5, 1991
    Assignee: BASF Lacke & Farben AG
    Inventors: Karl-Heinz Scherping, Hans-Jorg Holscher, Uwe Reichelt, Udo Reiter
  • Patent number: 4996284
    Abstract: A process for the preparation of a sulfonamide-based epoxy resinous composition, which includes the step of reacting a sulfonamide compound with a resinous composition containing a plurality of epoxide groups in the presence of a Lewis acid, is disclosed. The epoxy sulfonamide resins of the invention, which are being claimed, have applications in nail lacquer compositions and other cosmetics, adhesives, and in wood and paper coatings, as a plasticizer and as a modifier in injection molding applications for various resins.
    Type: Grant
    Filed: April 24, 1989
    Date of Patent: February 26, 1991
    Inventor: Leo X. Mallavarapu
  • Patent number: 4996294
    Abstract: A process in which an amine tetrol prepared by oxyalkylation of a propanediol with propylene oxide is catalytically aminated to provide, for example, an aminotetramine is disclosed. The aminotetramines are useful for preparing polyurea products and as curing agents for epoxy resins.
    Type: Grant
    Filed: October 31, 1989
    Date of Patent: February 26, 1991
    Assignee: Texaco Chemical Company
    Inventors: Michael Cuscurida, Wei-Yang Su, George P. Speranza
  • Patent number: 4996278
    Abstract: Substantially fully imidized polyimidesiloxanes which are based on a selected pyridine compound are soluble in diglyme which gives them particular utility in the micro-electronics industry. The polymers are prepared from the dianhydride, a difunctional siloxane monomer and an organic diamine that has the formula ##STR1## wherein X is hydrogen, halogen, phenyl or combinations thereof,Z=--O--, --S--, ##STR2## >C(CX.sub.3).sub.2, --or --Y--Ar--Y--, Ar' is an aromatic radical of 6 to 10 carbon atoms, ##STR3## Y=--O--, --S--, ##STR4## >C(CX.sub.3).sub.2, or --. n=0 or 1.
    Type: Grant
    Filed: February 7, 1989
    Date of Patent: February 26, 1991
    Assignee: Occidental Chemical Corporation
    Inventor: Chung J. Lee
  • Patent number: 4996285
    Abstract: Novel thermosetting compositions, well adapted for the production, e.g., of molded and laminated shaped articles, are comprised of a copolymerizate of (a) at least one N,N'-bisimide, (b) at least one diprimary diamine, and (c) at least one epoxy resin.
    Type: Grant
    Filed: October 11, 1989
    Date of Patent: February 26, 1991
    Assignee: Rhone-Poulenc Chimie
    Inventor: Rene Arpin
  • Patent number: 4994074
    Abstract: Copolymer of a predominant amount of .epsilon.-caprolactone, the balance being glycolide and glycolic acid. Coating for an absorbable, multifilament surgical suture prepared by dissolving the copolymer in an organic solvent.
    Type: Grant
    Filed: February 1, 1990
    Date of Patent: February 19, 1991
    Assignee: Ethicon, Inc.
    Inventors: Rao S. Bezwada, Alastair W. Hunter, Shalaby W. Shalaby
  • Patent number: 4990587
    Abstract: Toughened epoxy resins are prepared by curing a mixture of epoxy resin, a liquid carboxyl-terminated elastomer, and, as curing agent, a non-aromatic heterocyclic amine or a salt thereof. Cure is in two stages, the first stage at a temperature of at least 135.degree. C. for less than two hours to provide a partly cured formulation comprising phase-separated rubbery particles in an epoxy resin matrix, and a second stage of completing the cure.
    Type: Grant
    Filed: January 4, 1990
    Date of Patent: February 5, 1991
    Assignee: The Secretary of State for Defence in Her Britannic Majesty's Government of the United Kingdom and Northern Ireland
    Inventors: Steven J. Shaw, David A. Tod
  • Patent number: 4990541
    Abstract: A water absorbent latex polymer foam produced by the process of combining a foamed latex polymer product with a water absorbent polymer and drying that blend to form a foamable latex polymer containing a water absorbent polymer is disclosed in this invention. The latex foams produced by this process are of great use, for example, within diapers, sanitary napkins, packaging materials, and the like. In particular, the use of water absorbent polymers with particle size less than about 30 microns has been shown to produce particularly effective absorbent latex foams.
    Type: Grant
    Filed: November 9, 1989
    Date of Patent: February 5, 1991
    Assignee: Hoechst Celanese Corp.
    Inventors: Steven F. Nielsen, Dai W. Kim
  • Patent number: 4990576
    Abstract: A process in which a di-trimethylol alkane initiator is oxyalkylated to form an alkylene oxide adduct which is then catalytically aminated to provide, for example, a tetramine. These compounds are useful for preparing polyurethane products and as curing agents for epoxy resins.
    Type: Grant
    Filed: October 31, 1989
    Date of Patent: February 5, 1991
    Assignee: Texaco Chemical Company
    Inventors: Michael Cuscurida, Jiang-Jen Lin
  • Patent number: 4988797
    Abstract: Cyclic ethers having 4 and 5 member rings are polymerized with a alcohol initiator and an acid catalyst. The acid catalyst is used at a molar ratio relative to hydroxyl groups of the alcohol initiator of between about 0.05:1 and about 0.5:1.
    Type: Grant
    Filed: March 14, 1989
    Date of Patent: January 29, 1991
    Assignee: Thiokol Corporation
    Inventors: Robert B. Wardle, Jerald C. Hinshaw
  • Patent number: 4987205
    Abstract: Disclosed is a modified epoxy resin composition comprising a resin having recurring units represented by the following general formula: ##STR1## wherein R.sub.1 stands for --CH.sub.2 --, >CHCH.sub.3,>C(CH.sub.3).sub.2, ##STR2## R.sub.2 stands for H or --CH.sub.3, R.sub.3 stands for H or a halogen atom, and having an epoxy group, a phenolic hydroxyl group and a primary alcoholic hydroxyl group as terminal functional groups in specific amounts.This composition has a high reactivity with an active methylol group, and when this composition is combined with a curing agent resin such as an amino resin or a phenolic resin, a coating having an excellent bending processability is obtained.
    Type: Grant
    Filed: February 16, 1989
    Date of Patent: January 22, 1991
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Goro Suzuki, Matsuura Seiji
  • Patent number: 4985530
    Abstract: A new thermosetting resin composition is disclosed which comprises a Bisphenol A-type epoxy resin having a number average molecular weight of smaller than 650 but not smaller than 450 and a ratio of the weight average molecular weight thereof to the number average molecular weight thereof of in the range of 1.3-3.0; and a curing agent capable of cross-linking the epoxy resin. The curing agent is preferably a compound represented by the following general formula: ##STR1## wherein X is --CR.sub.1 R.sub.2 --, --CO--, --COO--, --SO.sub.2 --, --SO--, --S--, --O--, --NR.sub.1 --, --SiR.sub.1 R.sub.2 -- or --POR.sub.1 -- where R.sub.1 and R.sub.2 each stands for hydrogen, a lower alkyl or a phenyl; Y and Y' each stands for hydrogen, a lower alkyl or an electron attractive group; R is a lower alkyl; and m and n each is an integer of 1-4, or a mixture thereof with a primary amine, a phenolic compound or an acid anhydride.
    Type: Grant
    Filed: July 27, 1989
    Date of Patent: January 15, 1991
    Assignee: Tonen Corporation
    Inventors: Shinkichi Murakami, Osamu Watanabe, Sadahisa Wada, Hiroshi Inoue
  • Patent number: 4985529
    Abstract: The invention provides an imide compound represented by the general formula (I), ##STR1## wherein X represents a hydroxyl or amino group, Ar.sub.1 and Ar.sub.2 independently represent an aromatic residue, R.sub.1 represents a hydrogen atom or a C.sub.1 -C.sub.10 alkyl group, R.sub.2 represents a hydrogen atom, a C.sub.1 -C.sub.20 alkyl or alkoxy group or a hydroxyl group, and n represents a number of from 0 to 6, and also provides an epoxy resin composition containing the imide compound (B) and epoxy resins (A) as essential components.
    Type: Grant
    Filed: April 26, 1989
    Date of Patent: January 15, 1991
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Yasuhisa Saito, Shuichi Kanagawa, Katsuya Watanabe, Kumimasa Kamio
  • Patent number: 4983692
    Abstract: Novel epoxy resins are prepared by dehydrohalogenating the reaction product of an epihalohydrin and a hydroxyalkyl containing polysulfide.
    Type: Grant
    Filed: December 12, 1989
    Date of Patent: January 8, 1991
    Assignee: The Dow Chemical Company
    Inventors: Robert E. Hefner, Jr., Paul L. Wykowski
  • Patent number: 4983689
    Abstract: Preparation of a macromolecular monomer of a lactone having an alpha-beta monoolefinically unsaturated "head" is effected at low temperature with a strong oxonium salt, such as a trialkyloxonium (TAO) hexafluorophosphate catalyst, with essentially no formation of cyclic oligomers and an insignificant amount of diacrylate. Cationic ring-opening polymerization of lactone monomer in conjunction with an unsaturated alcohol (propagator) having an acryloyl or methacryloyl double bond, produces a polylactone macromer having an ethylenic double bond at one end and a hydroxyl group at the other. The polymerization proceeds by polyaddition of the lactone to the OH group which is the propagating species. The macromer so formed allows the preparation of a macromer of block copolymer of the polylactone with a polyether such as epichlorohydrin, using the same TAO catalyst. In such a macromer of block copolymer, the polylactone ester block is next to the double bond, followed by the polyether block.
    Type: Grant
    Filed: December 12, 1988
    Date of Patent: January 8, 1991
    Inventor: Simon H. Yu
  • Patent number: 4981941
    Abstract: Fluoroepoxy resins for use in computer composite circuit boards. A "glass state" curing agent containing a fluorinated monoanhydride, a fluorinated dianhydride and a catalyst is compounded at a temperature of about 210.degree. C. The curing agent is blended with di- and tri-functional epoxy resins at 100.degree. C. or higher to give homogeneous fast-curing syrups. Fluoroepoxy resins inherently have low dielectric constants. This method produces a fluoroepoxy resin with higher crosslink densities and higher glass transition temperatures.
    Type: Grant
    Filed: March 27, 1989
    Date of Patent: January 1, 1991
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventor: James R. Griffith
  • Patent number: 4981948
    Abstract: According to the present invention, a zinc-containing solid catalyst prepared by contacting zinc oxide with an organic dicarboxylic acid in the presence of or in the absence of an organic solvent under a mechanical pulverization treatment is provided. The catalyst is in a good pulverized state and exhibits a high catalytic activity for polymerization of carbon dioxide with an epoxide to obtain a polyalkylene carbonate.
    Type: Grant
    Filed: August 3, 1989
    Date of Patent: January 1, 1991
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hideshi Kawachi, Shuji Minami, John N. Armor, Andrzej Rokicki, Beatrice K. Stein
  • Patent number: 4980399
    Abstract: The invention relates to water-dilutable binders for cationic electrocoating finishes, the said binders containing latent primary amino groups. In order to prepare the binders, an epoxy resin is reacted with a polyamine, which in addition to a sterically hindered primary amino group also contains at least one primary amino group blocked by reaction with a ketone or aldehyde, and, if appropriate, further primary or secondary amines.
    Type: Grant
    Filed: February 5, 1990
    Date of Patent: December 25, 1990
    Assignee: BASF Lacke & Farben AG
    Inventors: Michael Geist, Gunther Ott, Georg Schon
  • Patent number: 4978712
    Abstract: A device fabrication method is disclosed in which a precursor polymeric or oligomeric material, capable of undergoing a curing reaction involving crosslinking and/or imidization, is at least partially cured and incorporated into the device being fabricated. Significantly, the at least partial curing is achieved by heating the material at generally increasing (although not necessarily continuously increasing) temperatures. In addition, the heat is supplied at a rate so that the temperature of the material is always maintained at or below the corresponding glass transition temperature of the material, which increases during the heating process.
    Type: Grant
    Filed: March 16, 1989
    Date of Patent: December 18, 1990
    Assignee: AT&T Bell Laboratories
    Inventors: Harvey E. Bair, Shiro Matsuoka