Abstract: The invention relates to a process for condensing at least one epoxide on at least one cyclic anhydride of a dicarboxylic acid in the presence of a catalyst consisting of at least one titanium peroxidic complex of the peroxo type of the A form ##STR1## Said process allows to obtain a perfectly alternate polyester.
Type:
Grant
Filed:
December 7, 1989
Date of Patent:
March 5, 1991
Assignees:
Institut Francais du Petrole, L'Air Liquide Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude, Elf France
Inventors:
Jacques Garapon, Remi Touet, Catherine Huet, Bernard Damin
Abstract: The invention relates to an aqueous coating agent, obtained from an epoxy resin, ethylenically unsaturated monomers, some of which contain carboxyl groups, a peroxide initiator in a proportion of at least 2% by weight, relative to the total weight of the monomers, a crosslinking agent, a neutralizing agent, organic solvents, and, if appropriate, further conventional additives, such as plasticizers, stabilizers, wetting agents, dispersion auxiliaries, catalysts and pigments.
Abstract: A process for the preparation of a sulfonamide-based epoxy resinous composition, which includes the step of reacting a sulfonamide compound with a resinous composition containing a plurality of epoxide groups in the presence of a Lewis acid, is disclosed. The epoxy sulfonamide resins of the invention, which are being claimed, have applications in nail lacquer compositions and other cosmetics, adhesives, and in wood and paper coatings, as a plasticizer and as a modifier in injection molding applications for various resins.
Abstract: A process in which an amine tetrol prepared by oxyalkylation of a propanediol with propylene oxide is catalytically aminated to provide, for example, an aminotetramine is disclosed. The aminotetramines are useful for preparing polyurea products and as curing agents for epoxy resins.
Type:
Grant
Filed:
October 31, 1989
Date of Patent:
February 26, 1991
Assignee:
Texaco Chemical Company
Inventors:
Michael Cuscurida, Wei-Yang Su, George P. Speranza
Abstract: Substantially fully imidized polyimidesiloxanes which are based on a selected pyridine compound are soluble in diglyme which gives them particular utility in the micro-electronics industry. The polymers are prepared from the dianhydride, a difunctional siloxane monomer and an organic diamine that has the formula ##STR1## wherein X is hydrogen, halogen, phenyl or combinations thereof,Z=--O--, --S--, ##STR2## >C(CX.sub.3).sub.2, --or --Y--Ar--Y--, Ar' is an aromatic radical of 6 to 10 carbon atoms, ##STR3## Y=--O--, --S--, ##STR4## >C(CX.sub.3).sub.2, or --. n=0 or 1.
Abstract: Novel thermosetting compositions, well adapted for the production, e.g., of molded and laminated shaped articles, are comprised of a copolymerizate of (a) at least one N,N'-bisimide, (b) at least one diprimary diamine, and (c) at least one epoxy resin.
Abstract: Copolymer of a predominant amount of .epsilon.-caprolactone, the balance being glycolide and glycolic acid. Coating for an absorbable, multifilament surgical suture prepared by dissolving the copolymer in an organic solvent.
Type:
Grant
Filed:
February 1, 1990
Date of Patent:
February 19, 1991
Assignee:
Ethicon, Inc.
Inventors:
Rao S. Bezwada, Alastair W. Hunter, Shalaby W. Shalaby
Abstract: Toughened epoxy resins are prepared by curing a mixture of epoxy resin, a liquid carboxyl-terminated elastomer, and, as curing agent, a non-aromatic heterocyclic amine or a salt thereof. Cure is in two stages, the first stage at a temperature of at least 135.degree. C. for less than two hours to provide a partly cured formulation comprising phase-separated rubbery particles in an epoxy resin matrix, and a second stage of completing the cure.
Type:
Grant
Filed:
January 4, 1990
Date of Patent:
February 5, 1991
Assignee:
The Secretary of State for Defence in Her Britannic Majesty's Government of the United Kingdom and Northern Ireland
Abstract: A water absorbent latex polymer foam produced by the process of combining a foamed latex polymer product with a water absorbent polymer and drying that blend to form a foamable latex polymer containing a water absorbent polymer is disclosed in this invention. The latex foams produced by this process are of great use, for example, within diapers, sanitary napkins, packaging materials, and the like. In particular, the use of water absorbent polymers with particle size less than about 30 microns has been shown to produce particularly effective absorbent latex foams.
Abstract: A process in which a di-trimethylol alkane initiator is oxyalkylated to form an alkylene oxide adduct which is then catalytically aminated to provide, for example, a tetramine. These compounds are useful for preparing polyurethane products and as curing agents for epoxy resins.
Abstract: Cyclic ethers having 4 and 5 member rings are polymerized with a alcohol initiator and an acid catalyst. The acid catalyst is used at a molar ratio relative to hydroxyl groups of the alcohol initiator of between about 0.05:1 and about 0.5:1.
Abstract: Disclosed is a modified epoxy resin composition comprising a resin having recurring units represented by the following general formula: ##STR1## wherein R.sub.1 stands for --CH.sub.2 --, >CHCH.sub.3,>C(CH.sub.3).sub.2, ##STR2## R.sub.2 stands for H or --CH.sub.3, R.sub.3 stands for H or a halogen atom, and having an epoxy group, a phenolic hydroxyl group and a primary alcoholic hydroxyl group as terminal functional groups in specific amounts.This composition has a high reactivity with an active methylol group, and when this composition is combined with a curing agent resin such as an amino resin or a phenolic resin, a coating having an excellent bending processability is obtained.
Abstract: A new thermosetting resin composition is disclosed which comprises a Bisphenol A-type epoxy resin having a number average molecular weight of smaller than 650 but not smaller than 450 and a ratio of the weight average molecular weight thereof to the number average molecular weight thereof of in the range of 1.3-3.0; and a curing agent capable of cross-linking the epoxy resin. The curing agent is preferably a compound represented by the following general formula: ##STR1## wherein X is --CR.sub.1 R.sub.2 --, --CO--, --COO--, --SO.sub.2 --, --SO--, --S--, --O--, --NR.sub.1 --, --SiR.sub.1 R.sub.2 -- or --POR.sub.1 -- where R.sub.1 and R.sub.2 each stands for hydrogen, a lower alkyl or a phenyl; Y and Y' each stands for hydrogen, a lower alkyl or an electron attractive group; R is a lower alkyl; and m and n each is an integer of 1-4, or a mixture thereof with a primary amine, a phenolic compound or an acid anhydride.
Abstract: The invention provides an imide compound represented by the general formula (I), ##STR1## wherein X represents a hydroxyl or amino group, Ar.sub.1 and Ar.sub.2 independently represent an aromatic residue, R.sub.1 represents a hydrogen atom or a C.sub.1 -C.sub.10 alkyl group, R.sub.2 represents a hydrogen atom, a C.sub.1 -C.sub.20 alkyl or alkoxy group or a hydroxyl group, and n represents a number of from 0 to 6, and also provides an epoxy resin composition containing the imide compound (B) and epoxy resins (A) as essential components.
Abstract: Preparation of a macromolecular monomer of a lactone having an alpha-beta monoolefinically unsaturated "head" is effected at low temperature with a strong oxonium salt, such as a trialkyloxonium (TAO) hexafluorophosphate catalyst, with essentially no formation of cyclic oligomers and an insignificant amount of diacrylate. Cationic ring-opening polymerization of lactone monomer in conjunction with an unsaturated alcohol (propagator) having an acryloyl or methacryloyl double bond, produces a polylactone macromer having an ethylenic double bond at one end and a hydroxyl group at the other. The polymerization proceeds by polyaddition of the lactone to the OH group which is the propagating species. The macromer so formed allows the preparation of a macromer of block copolymer of the polylactone with a polyether such as epichlorohydrin, using the same TAO catalyst. In such a macromer of block copolymer, the polylactone ester block is next to the double bond, followed by the polyether block.
Abstract: Fluoroepoxy resins for use in computer composite circuit boards. A "glass state" curing agent containing a fluorinated monoanhydride, a fluorinated dianhydride and a catalyst is compounded at a temperature of about 210.degree. C. The curing agent is blended with di- and tri-functional epoxy resins at 100.degree. C. or higher to give homogeneous fast-curing syrups. Fluoroepoxy resins inherently have low dielectric constants. This method produces a fluoroepoxy resin with higher crosslink densities and higher glass transition temperatures.
Type:
Grant
Filed:
March 27, 1989
Date of Patent:
January 1, 1991
Assignee:
The United States of America as represented by the Secretary of the Navy
Abstract: According to the present invention, a zinc-containing solid catalyst prepared by contacting zinc oxide with an organic dicarboxylic acid in the presence of or in the absence of an organic solvent under a mechanical pulverization treatment is provided. The catalyst is in a good pulverized state and exhibits a high catalytic activity for polymerization of carbon dioxide with an epoxide to obtain a polyalkylene carbonate.
Type:
Grant
Filed:
August 3, 1989
Date of Patent:
January 1, 1991
Assignee:
Mitsui Petrochemical Industries, Ltd.
Inventors:
Hideshi Kawachi, Shuji Minami, John N. Armor, Andrzej Rokicki, Beatrice K. Stein
Abstract: The invention relates to water-dilutable binders for cationic electrocoating finishes, the said binders containing latent primary amino groups. In order to prepare the binders, an epoxy resin is reacted with a polyamine, which in addition to a sterically hindered primary amino group also contains at least one primary amino group blocked by reaction with a ketone or aldehyde, and, if appropriate, further primary or secondary amines.
Type:
Grant
Filed:
February 5, 1990
Date of Patent:
December 25, 1990
Assignee:
BASF Lacke & Farben AG
Inventors:
Michael Geist, Gunther Ott, Georg Schon
Abstract: A device fabrication method is disclosed in which a precursor polymeric or oligomeric material, capable of undergoing a curing reaction involving crosslinking and/or imidization, is at least partially cured and incorporated into the device being fabricated. Significantly, the at least partial curing is achieved by heating the material at generally increasing (although not necessarily continuously increasing) temperatures. In addition, the heat is supplied at a rate so that the temperature of the material is always maintained at or below the corresponding glass transition temperature of the material, which increases during the heating process.